CN105778738A - Coating composition for golf club head and preparation method thereof - Google Patents
Coating composition for golf club head and preparation method thereof Download PDFInfo
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- CN105778738A CN105778738A CN201610157867.7A CN201610157867A CN105778738A CN 105778738 A CN105778738 A CN 105778738A CN 201610157867 A CN201610157867 A CN 201610157867A CN 105778738 A CN105778738 A CN 105778738A
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- club head
- coating composition
- mixture
- glof club
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a coating composition for a golf club head and a preparation method thereof. The coating composition comprises, by weight, 40-60 parts of alkyd resin, 3-4.5 parts of antioxidant, 6-16 parts of antirust agent, 7.5-16.5 parts of antifouling agent, 3-4 parts of coupling agent, 4.5-5.5 parts of dimethyl phthalate, 5-8 parts of titanium dioxide nanoparticles and 10-25 parts of 200# solvent oil. The coating composition has high antirust performance, antifouling performance, adhesiveness and flexibility and has gloss maintaining performance and fullness.
Description
Technical field:
The present invention relates to a kind of coating composition, particularly a kind of glof club head coating group
Compound and preparation method thereof.
Background technology:
Along with expanding economy, golf sports is more and more welcomed by the people, right on market
The demand of golf club is consequently increased, and people are to the outward appearance of golf club, the wanting of texture
Ask and also stepping up.Golf is generally carried out in outdoor, in impact, high
Golf ball head can be by multiple damage, such as the friction with ball, with the friction on ground.Rain simultaneously
Water, earth, all contains corrosive substance in grass stain etc., all can send out at surface of golf club head
Raw electrochemical corrosion.So it is generally required to golf club is carried out surface process and is protected,
Make it can be antifouling, antirust, extend service life.
The method wherein protecting golf club by electroplating surface layer of metal material, its behaviour
Making step complicated, need more accurate machine, the cost of making is higher.And use automatically
The method of deposition coating, simple and easy to operate, have been received by people and more and more pay attention to.
At present Application comparison coating of golf iron head material widely be with acrylic emulsion or
Epoxy resin is coating prepared by basic filmogen, but both materials are easily generated heat
Gluing and cold short performance, viscosity and heat resistance are the best, simultaneously the shortcoming to outdoor weatherability difference.
And with the coating material that alkyd resin is basic film forming agent, problem above can be solved.
Chinese patent 201310708342.4 discloses a kind of anti-rust coating composition and preparation thereof
Method, have employed low cost feedstock, simplifies production stage, and with the addition of ultra-violet absorber with
And hindered amine as light stabilizer is to play effect that is anti-aging and that extend antirust time.But in application
When glof club head, the adhesion property of antirust coat, and polish retention can still need
Improve.
Summary of the invention:
It is an object of the invention to provide a kind of glof club head coating composition, it has good
Good rust-preventing characteristic and soil resistance, have high adhesion force and a pliability, and have polish retention and
Richness is high.
It is a further object to provide the preparation method of this composite.
For achieving the above object, the present invention is by the following technical solutions:
Alkyd resin 40-60 part, antioxidant 3-4.5 part,
Antirust agent 6-16 part, anti-fouling agent 7.5-16.5 part,
Coupling agent 3-4 part, repefral 4.5-5.5 part,
Titania nanoparticles 5-8 part, 200# solvent naphtha 10-25 part.
Preferred as technique scheme, described alkyd resin be by vegetable oil, binary acid and
Polyalcohol is formed by esterification polycondensation.
Preferred as technique scheme, described vegetable oil be tung oil, linseed oil, castor oil,
One or more mixtures in soya-bean oil.
Preferred as technique scheme, described binary acid is for facing phthalate anhydride, isophthalic two
One or more mixtures in formic acid, terephthalic acid (TPA).
Preferred as technique scheme, described polyalcohol is glycerine, pentaerythrite, three hydroxyls
One or more mixtures in methylpropane.
Preferred as technique scheme, described antioxidant is antioxidant 168, antioxygen
Agent 1010, one or more mixtures in antioxidant 1076.
Preferred as technique scheme, described antirust agent is neopelex, lemon
Lemon acid sodium, sodium sulfite, the mixture that zinc sulfate mixes with the ratio of weight ratio 1:5:2:5.
Preferred as technique scheme, described anti-fouling agent is sodium metasilicate, Methyl Hydrogen Polysiloxane Fluid,
One or more mixtures in polytetrafluoroethylene (PTFE).
Preferred as technique scheme, described coupling agent be isobutyl triethoxy silane,
One or more mixtures in silane coupler DL602, silane coupler DL171.
A kind of preparation method of the glof club head antirust coat mixture of the present invention include with
Lower step:
(1) by alkyd resin, antirust agent, anti-fouling agent, 200# solvent naphtha uniformly mixes, and makes
Stirring with agitator, agitator speed is 30-50 rev/min, stirs 1 at 40-60 DEG C
Hour, obtain mixture A
(2) the mixture A obtained by step one adds antioxidant, coupling agent, adjacent
Rutgers, continues stirring, and rotating speed is 100-130 rev/min, stirs at 40-60 DEG C
Mix 30 minutes and obtain mixture B
(3) titania nanoparticles is joined in the mixture obtained by step 2,
At 80-100 DEG C after ultrasonic 40-60min evacuated eliminating bubble, by mixture with
The air spraying of 0.3-0.4MPa, in mould, solidifies 20min, obtains Gao Er at 150 DEG C
Husband's club head coating composite material.
The method have the advantages that
The addition of antirust agent can protect glof club head from electrochemical corrosion, thus plays
Antirust function.The addition of anti-fouling agent can make pollutant difficulty be infected with on glof club head, from
And reduce corrosion.Repefral is plasticizer of good performance, can increase film
Plasticity.The titania nanoparticles added can pass through coupling agent, is stably dispersed in this
In antirust coat material, polish retention and the richness of coating can be increased, thus improve height
The appearance tactile impression of your club head.
The application thickness of this coating material is 15-25um, has good rust-preventing characteristic, and stronger
Adhesive force, resistance to tortuosity, hardness of film is high, and wetability is strong, be not likely to produce " oil drop " it
Moistening badness phenomenon, recoatability is good.
Detailed description of the invention:
In order to be better understood from the present invention, below by embodiment, the present invention is further described,
Embodiment is served only for explaining the present invention, and the present invention will not constitute any restriction.
Embodiment 1
Alkyd resin 42 parts, antioxidant 3 parts,
Antirust agent 12 parts, anti-fouling agent 12.5 parts,
Coupling agent 3 parts, repefral 5.5 parts,
Titania nanoparticles 8 parts, 200# solvent naphtha 15 parts.
Its preparation method comprises the following steps
(1) by alkyd resin, antirust agent, anti-fouling agent, 200# solvent naphtha uniformly mixes, and makes
Stirring with agitator, agitator speed is 40 revs/min, stirs 1 hour at 55 DEG C,
Obtain mixture A
(2) the mixture A obtained by step one adds antioxidant, coupling agent, adjacent
Rutgers, continues stirring, and rotating speed is 120 revs/min, stirs 30 at 55 DEG C
Minute obtain mixture B
(3) titania nanoparticles is joined in the mixture obtained by step 2,
At 80 DEG C after ultrasonic 60min evacuated eliminating bubble, by mixture with 0.3-0.4MPa's
Air spraying, in mould, solidifies 20min at 150 DEG C, obtain glof club head and be coated with
Layer composite.
Embodiment 2
Alkyd resin 45 parts, antioxidant 3.5 parts,
Antirust agent 9 parts, anti-fouling agent 13 parts,
Coupling agent 3.5 parts, repefral 5 parts,
Titania nanoparticles 6 parts, 200# solvent naphtha 15 parts.
Its preparation method comprises the following steps
(1) by alkyd resin, antirust agent, anti-fouling agent, 200# solvent naphtha uniformly mixes, and makes
Stirring with agitator, agitator speed is 45 revs/min, stirs 1 hour at 60 DEG C,
Obtain mixture A
(2) the mixture A obtained by step one adds antioxidant, coupling agent, adjacent
Rutgers, continues stirring, and rotating speed is 120 revs/min, stirs 30 points at 60 DEG C
Clock obtains mixture B
(3) titania nanoparticles is joined in the mixture obtained by step 2,
At 100 DEG C after ultrasonic 60min evacuated eliminating bubble, by mixture with 0.3-0.4MPa's
Air spraying, in mould, solidifies 20min at 150 DEG C, obtain glof club head and be coated with
Layer composite.
Embodiment 3
Alkyd resin 53 parts, antioxidant 4 parts,
Antirust agent 9.5 parts, anti-fouling agent 7.5 parts,
Coupling agent 4 parts, repefral 5 parts,
Titania nanoparticles 7 parts, 200# solvent naphtha 10 parts.
Its preparation method comprises the following steps
(1) by alkyd resin, antirust agent, anti-fouling agent, 200# solvent naphtha uniformly mixes, and makes
Stirring with agitator, agitator speed is 45 revs/min, stirs 1 hour at 55 DEG C,
Obtain mixture A
(2) the mixture A obtained by step one adds antioxidant, coupling agent, adjacent
Rutgers, continues stirring, and rotating speed is 100 revs/min, stirs 30 points at 55 DEG C
Clock obtains mixture B
(3) titania nanoparticles is joined in the mixture obtained by step 2,
At 100 DEG C after ultrasonic 60min evacuated eliminating bubble, by mixture with 0.3-0.4MPa's
Air spraying, in mould, solidifies 20min at 150 DEG C, obtain glof club head and be coated with
Layer composite.
Embodiment 4
Alkyd resin 60 parts, antioxidant 3.5 parts,
Neopelex 2 parts, sodium citrate 4 parts,
Sodium sulfite 2.5 parts, 5.5 parts of zinc sulfate,
Coupling agent 3 parts, repefral 4.5 parts,
Titania nanoparticles 5 parts, 200# solvent naphtha 10 parts.
Its preparation method comprises the following steps
(1) by alkyd resin, antirust agent, anti-fouling agent, 200# solvent naphtha uniformly mixes, and makes
Stirring with agitator, agitator speed is 55 revs/min, stirs 1 hour at 60 DEG C,
Obtain mixture A
(2) the mixture A obtained by step one adds antioxidant, coupling agent, adjacent
Rutgers, continues stirring, and rotating speed is 110 revs/min, stirs 30 at 60 DEG C
Minute obtain mixture B
(3) titania nanoparticles is joined in the mixture obtained by step 2,
At 90 DEG C after ultrasonic 60min evacuated eliminating bubble, by mixture with 0.3-0.4MPa's
Air spraying, in mould, solidifies 20min at 150 DEG C, obtain glof club head and be coated with
Layer composite.
Above-described embodiment has all carried out rust-preventing characteristic and soil resistance test, and wherein comparative example is common
Glof club head coating composite material
Table 1
From the point of view of table 1, the glof club head coating material that the present invention provides has good
Antirust and antifouling capacity.
Claims (10)
1. a glof club head coating composition, it is characterised in that by weight
Said composition is composed of the following components:
Alkyd resin 40-60 part, antioxidant 3-4.5 part,
Antirust agent 6-16 part, anti-fouling agent 7.5-16.5 part,
Coupling agent 3-4 part, repefral 4.5-5.5 part,
Titania nanoparticles 5-8 part, 200# solvent naphtha 10-25 part.
Glof club head coating composition the most according to claim 1, its feature
It is: described alkyd resin is for being passed through esterification polycondensation by vegetable oil, binary acid and polyalcohol
Form.
Glof club head coating composition the most according to claim 2, its feature
It is: described vegetable oil is that one or more in tung oil, linseed oil, castor oil, soya-bean oil are mixed
Compound.
Glof club head coating composition the most according to claim 2, its feature
It is: described binary acid is to face in phthalate anhydride, M-phthalic acid, terephthalic acid (TPA)
Plant or multiple mixture.
Glof club head coating composition the most according to claim 2, its feature
It is: described polyalcohol is one or more in glycerine, pentaerythrite, trimethylolpropane
Mixture.
Glof club head coating composition the most according to claim 1, its feature
It is: described antioxidant is antioxidant 168, antioxidant 1010, antioxidant 1076
In one or more mixtures.
Glof club head coating composition the most according to claim 1, its feature
It is: described antirust agent is neopelex, sodium citrate, sodium sulfite, sulfuric acid
The mixture that zinc mixes with the ratio of weight ratio 1:5:2:5.
8. require the glof club head coating composition described in 1, it is characterised in that: institute
Stating anti-fouling agent is sodium metasilicate, Methyl Hydrogen Polysiloxane Fluid, one or more mixing in polytetrafluoroethylene (PTFE)
Thing.
Glof club head coating composition the most according to claim 1, its feature
It is: described coupling agent is isobutyl triethoxy silane, silane coupler DL602, silane
One or more mixtures in coupling agent DL171.
10. the preparation method of a glof club head coating composition, it is characterised in that by
Following steps form:
(1) by alkyd resin, antirust agent, anti-fouling agent, 200# solvent naphtha uniformly mixes, and makes
Stirring with agitator, agitator speed is 30-50 rev/min, stirs 1 at 40-60 DEG C
Hour, obtain mixture A
(2) the mixture A obtained by step one adds antioxidant, coupling agent, adjacent
Rutgers, continues stirring, and rotating speed is 100-130 rev/min, stirs at 40-60 DEG C
Mix 30 minutes and obtain mixture B
Titania nanoparticles is joined in the mixture B obtained by step 2,
Ultrasonic 40-60min at 80-100 DEG C, after evacuated eliminating bubble, by mixture with
The air spraying of 0.3-0.4MPa, in mould, solidifies 20min, obtains Gao Er at 150 DEG C
Husband's club head coating composite material.
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CN201610157867.7A CN105778738A (en) | 2016-03-18 | 2016-03-18 | Coating composition for golf club head and preparation method thereof |
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CN201610157867.7A CN105778738A (en) | 2016-03-18 | 2016-03-18 | Coating composition for golf club head and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108017985A (en) * | 2017-11-17 | 2018-05-11 | 广东科学技术职业学院 | A kind of glof club head coating and preparation method |
CN111909595A (en) * | 2020-08-14 | 2020-11-10 | 常州市武进晨光金属涂料有限公司 | Water-based anticorrosive paint for metal protection and preparation method thereof |
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CN1398934A (en) * | 2001-07-24 | 2003-02-26 | 大丰涂料株式会社 | Paint composition for metal product |
CN1712472A (en) * | 2004-06-25 | 2005-12-28 | 楠盛股份有限公司 | Coating of golf iron head |
CN104403500A (en) * | 2014-11-24 | 2015-03-11 | 东莞市日信真空科技有限公司 | Fingerprint preventing paint used on head of golf club and processing technology of fingerprint preventing paint |
CN105062204A (en) * | 2015-07-20 | 2015-11-18 | 苏州宇希新材料科技有限公司 | Nano-titanium dioxide printing ink and preparation method thereof |
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2016
- 2016-03-18 CN CN201610157867.7A patent/CN105778738A/en active Pending
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CN1398934A (en) * | 2001-07-24 | 2003-02-26 | 大丰涂料株式会社 | Paint composition for metal product |
CN1712472A (en) * | 2004-06-25 | 2005-12-28 | 楠盛股份有限公司 | Coating of golf iron head |
CN104403500A (en) * | 2014-11-24 | 2015-03-11 | 东莞市日信真空科技有限公司 | Fingerprint preventing paint used on head of golf club and processing technology of fingerprint preventing paint |
CN105062204A (en) * | 2015-07-20 | 2015-11-18 | 苏州宇希新材料科技有限公司 | Nano-titanium dioxide printing ink and preparation method thereof |
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刘德峥: "《精细化工生产工艺》", 30 September 2008 * |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108017985A (en) * | 2017-11-17 | 2018-05-11 | 广东科学技术职业学院 | A kind of glof club head coating and preparation method |
CN111909595A (en) * | 2020-08-14 | 2020-11-10 | 常州市武进晨光金属涂料有限公司 | Water-based anticorrosive paint for metal protection and preparation method thereof |
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