CN105778587A - Low-temperature photo-curing paint - Google Patents

Low-temperature photo-curing paint Download PDF

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Publication number
CN105778587A
CN105778587A CN201610285524.9A CN201610285524A CN105778587A CN 105778587 A CN105778587 A CN 105778587A CN 201610285524 A CN201610285524 A CN 201610285524A CN 105778587 A CN105778587 A CN 105778587A
Authority
CN
China
Prior art keywords
parts
curing paint
curing
temperature photo
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610285524.9A
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Chinese (zh)
Inventor
黄波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Nashuo Technology Co Ltd
Original Assignee
Chengdu Nashuo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Nashuo Technology Co Ltd filed Critical Chengdu Nashuo Technology Co Ltd
Priority to CN201610285524.9A priority Critical patent/CN105778587A/en
Publication of CN105778587A publication Critical patent/CN105778587A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to the technical field of coating, in particular to low-temperature photo-curing paint. The low-temperature photo-curing paint comprises, by weight, 50-80 parts of perfluoroalkyl ethyl methacrylate, 25-35 parts of methacrylamide, 10-15 parts of ethyl acetate, 20-30 parts of tetraethyl orthosilicate, 25-50 parts of ethyl alcohol, 5-10 parts of trifluoroethyl acrylate, 1-3 parts of antiskinning agent, 5-8 parts of activated carbon powder and 5-7 parts of nanometer iron powder. The low-temperature photo-curing paint is fast in curing, curable at room temperature, high in production efficiency and convenient to produce, cured products are good in performance, prepared test samples after curing have excellent adhesion force, scratch resistance and corrosion resistance, and paint films formed by coating are matt, thick and wide in film formation and high in hardness.

Description

A kind of low temperature photo-curing paint
Technical field
The present invention relates to technical field of coatings, specifically about a kind of low temperature photo-curing paint.
Background technology
Acroleic acid polyurethane coating main film forming substance hydroxy-containing resin, because it has desirable physical mechanical ability and excellent protecting light, protect the feature such as color, weatherability and be widely used in the application of the product casing of high-chemical-resistance, such as this thermosetting photocuring finishing varnish may be used in the painting design of packaging, general industry, such as, being widely used in bicycle, motorcycle, automobile, electric refrigerator, washing machine, electric fan, instrument, instrument, precision optical machinery and the application on IT product surface.
Face coat owing to applying need to have outstanding outward appearance in terms of smoothness and glossiness, and need to have outstanding corrosion resistance, so that the coating of heavy dressing has outstanding tack, outstanding repastes tack.But, thermosetting acrylic coating compositions well known in the prior art, it is difficult to the face coat that formation has colored appearance simultaneously, corrosion-resistant, high temperature resistant, wear-resisting and tack is strong.
Summary of the invention
In order to solve above-mentioned technical problem of the prior art, it is an object of the invention to provide a kind of low temperature photo-curing paint with excellent adhesion and solvent resistance.
In order to realize foregoing invention purpose, a kind of low temperature photo-curing paint of the present invention, counts by weight and includes following components: perfluor alkyl ethide methacrylate 50-80 part, Methacrylamide 25-35 part, ethyl acetate 10-15 part, tetraethyl orthosilicate 20-30 part, ethanol 25-50 part, acrylic acid trifluoro ethyl ester 5-10 part, anti-skinning agent 1-3 part, activated carbon powder 5-8 part, nanometer iron powder 5-7 part.
Further, described low temperature photo-curing paint, counts by weight and includes following components: perfluor alkyl ethide methacrylate 60 parts, Methacrylamide 30 parts, ethyl acetate 12 parts, tetraethyl orthosilicate 28 parts, ethanol 35 parts, acrylic acid trifluoro ethyl ester 7 parts, anti-skinning agent 1.5 parts, activated carbon powder 6 parts, nanometer iron powder 5.5 parts.
Further, in described anti-skinning agent Oleum Terebinthinae, dipentene and butyl aldoxime one or more.
Further, described nanometer iron powder granularity is 800-1200 mesh.
Compared with prior art, the method have the advantages that curing rate of the present invention is fast, can be in normal temperature cure, production efficiency is high, easily manufactured, cured product performance is good, the sample prepared after solidification has adhesive force, resistance to marring and the corrosion resistance of excellence, and the paint film one-tenth Asia of application formation is photochromic, become thickness and wide, hardness height.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are described in detail.
Embodiment 1
A kind of low temperature photo-curing paint, counts by weight and includes following components: perfluor alkyl ethide methacrylate 50 parts, Methacrylamide 25 parts, ethyl acetate 10 parts, tetraethyl orthosilicate 20 parts, ethanol 25 parts, acrylic acid trifluoro ethyl ester 5 parts, anti-skinning agent 1 part, activated carbon powder 5 parts, nanometer iron powder 5 parts.
Embodiment 2
A kind of low temperature photo-curing paint, counts by weight and includes following components: perfluor alkyl ethide methacrylate 60 parts, Methacrylamide 30 parts, ethyl acetate 12 parts, tetraethyl orthosilicate 28 parts, ethanol 35 parts, acrylic acid trifluoro ethyl ester 7 parts, anti-skinning agent 1.5 parts, activated carbon powder 6 parts, nanometer iron powder 5.5 parts.
Embodiment 3
A kind of low temperature photo-curing paint, counts by weight and includes following components: perfluor alkyl ethide methacrylate 80 parts, Methacrylamide 35 parts, ethyl acetate 15 parts, tetraethyl orthosilicate 30 parts, ethanol 50 parts, acrylic acid trifluoro ethyl ester 10 parts, anti-skinning agent 3 parts, activated carbon powder 8 parts, nanometer iron powder 7 parts.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, above-described embodiment is only the present invention preferably embodiment, embodiments of the present invention are also not restricted to the described embodiments, should be appreciated that, those skilled in the art can be designed that a lot of other amendments and embodiment, and these amendments and embodiment will fall within spirit disclosed in the present application and spirit.

Claims (4)

1. a low temperature photo-curing paint, it is characterised in that: count by weight and include following components: perfluor alkyl ethide methacrylate 50-80 part, Methacrylamide 25-35 part, ethyl acetate 10-15 part, tetraethyl orthosilicate 20-30 part, ethanol 25-50 part, acrylic acid trifluoro ethyl ester 5-10 part, anti-skinning agent 1-3 part, activated carbon powder 5-8 part, nanometer iron powder 5-7 part.
Low temperature photo-curing paint the most according to claim 1, it is characterised in that: count by weight and include following components: perfluor alkyl ethide methacrylate 60 parts, Methacrylamide 30 parts, ethyl acetate 12 parts, tetraethyl orthosilicate 28 parts, ethanol 35 parts, acrylic acid trifluoro ethyl ester 7 parts, anti-skinning agent 1.5 parts, activated carbon powder 6 parts, nanometer iron powder 5.5 parts.
Low temperature photo-curing paint the most according to claim 1, it is characterised in that: in described anti-skinning agent Oleum Terebinthinae, dipentene and butyl aldoxime one or more.
Low temperature photo-curing paint the most according to claim 1, it is characterised in that: described nanometer iron powder granularity is 800-1200 mesh.
CN201610285524.9A 2016-05-04 2016-05-04 Low-temperature photo-curing paint Pending CN105778587A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610285524.9A CN105778587A (en) 2016-05-04 2016-05-04 Low-temperature photo-curing paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610285524.9A CN105778587A (en) 2016-05-04 2016-05-04 Low-temperature photo-curing paint

Publications (1)

Publication Number Publication Date
CN105778587A true CN105778587A (en) 2016-07-20

Family

ID=56400449

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610285524.9A Pending CN105778587A (en) 2016-05-04 2016-05-04 Low-temperature photo-curing paint

Country Status (1)

Country Link
CN (1) CN105778587A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753230A (en) * 2016-11-30 2017-05-31 四川中塑高分子材料有限公司 A kind of low temperature resistant athletic floor adhesive

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792619A (en) * 2010-03-25 2010-08-04 谭远清 Fluorine-containing resin photocuring optical fiber coating composite and preparation method thereof
CN103305044A (en) * 2013-06-17 2013-09-18 丹阳市佳美化工有限公司 Photocuring finishing paint
CN104945977A (en) * 2015-06-18 2015-09-30 成都纳硕科技有限公司 External wall applied water-based low temperature ultraviolet-curing coating
CN105131835A (en) * 2015-08-04 2015-12-09 天津大学 UV-cured POSS fluorine-containing acrylate segmented copolymer coating, preparation and application thereof
EP1926782B1 (en) * 2005-09-22 2016-04-13 Henkel AG & Co. KGaA Coating materials for metal surfaces with anti-adhesive properties

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1926782B1 (en) * 2005-09-22 2016-04-13 Henkel AG & Co. KGaA Coating materials for metal surfaces with anti-adhesive properties
CN101792619A (en) * 2010-03-25 2010-08-04 谭远清 Fluorine-containing resin photocuring optical fiber coating composite and preparation method thereof
CN103305044A (en) * 2013-06-17 2013-09-18 丹阳市佳美化工有限公司 Photocuring finishing paint
CN104945977A (en) * 2015-06-18 2015-09-30 成都纳硕科技有限公司 External wall applied water-based low temperature ultraviolet-curing coating
CN105131835A (en) * 2015-08-04 2015-12-09 天津大学 UV-cured POSS fluorine-containing acrylate segmented copolymer coating, preparation and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753230A (en) * 2016-11-30 2017-05-31 四川中塑高分子材料有限公司 A kind of low temperature resistant athletic floor adhesive

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PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
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Application publication date: 20160720