CN105778506A - Organic silicon resin composition and prepreg, laminated board, copper-clad plate and aluminum-based plate adopting same - Google Patents

Organic silicon resin composition and prepreg, laminated board, copper-clad plate and aluminum-based plate adopting same Download PDF

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Publication number
CN105778506A
CN105778506A CN201410829549.1A CN201410829549A CN105778506A CN 105778506 A CN105778506 A CN 105778506A CN 201410829549 A CN201410829549 A CN 201410829549A CN 105778506 A CN105778506 A CN 105778506A
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China
Prior art keywords
resin composition
prepreg
parts
copper
organosilicon resin
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CN201410829549.1A
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CN105778506B (en
Inventor
叶素文
唐国坊
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Shengyi Technology Co Ltd
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Shengyi Technology Co Ltd
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Priority to CN201410829549.1A priority Critical patent/CN105778506B/en
Priority to TW104105267A priority patent/TWI531617B/en
Priority to KR1020177020792A priority patent/KR101887841B1/en
Priority to EP15871611.8A priority patent/EP3239244B1/en
Priority to JP2017533822A priority patent/JP6514335B2/en
Priority to US15/539,467 priority patent/US10308808B2/en
Priority to PCT/CN2015/080474 priority patent/WO2016101535A1/en
Publication of CN105778506A publication Critical patent/CN105778506A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/017—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of aluminium or an aluminium alloy, another layer being formed of an alloy based on a non ferrous metal other than aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/04—Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C08G77/08—Preparatory processes characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/80—Siloxanes having aromatic substituents, e.g. phenyl side groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/036—Multilayers with layers of different types
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/07—Parts immersed or impregnated in a matrix
    • B32B2305/076—Prepregs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/08—PCBs, i.e. printed circuit boards
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01—Dielectrics
    • H05K2201/0137—Materials
    • H05K2201/0162—Silicon containing polymer, e.g. silicone
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    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/03—Conductive materials
    • H05K2201/0332—Structure of the conductor
    • H05K2201/0335—Layered conductors or foils
    • H05K2201/0358—Resin coated copper [RCC]
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    • H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/06—Thermal details
    • H05K2201/068—Thermal details wherein the coefficient of thermal expansion is important

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  • Insulated Metal Substrates For Printed Circuits (AREA)

Abstract

The invention relates to an organic silicon resin composition and prepreg, a laminated board, a copper-clad plate and an aluminum-based plate adopting the same.The organic silicon resin composition comprises, by weight, 100 parts of condensed type silicon resin, 0.0001 -2 parts of a catalyst and 0.001-10 parts of an auxiliary agent.The organic silicon resin composition has the advantages of being high in heat resistance, free of halogen and phosphorus, retardant to flame, good in peeling strength with copper foil, low in expansion coefficient and the like and can be used for preparing the prepreg, the laminated board and the aluminum-based plate for a high-performance printed circuit.

Description

A kind of organosilicon resin composition and use its prepreg, laminate, copper-clad plate and aluminium base
Technical field
The present invention relates to a kind of organosilicon resin composition, be specifically related to the organosilicon resin composition of a kind of high heat-resisting, non-halogen non-phosphate and low thermal coefficient of expansion and use its prepreg, laminate, copper-clad plate and aluminium base.
Background technology
Along with developing rapidly of electronic information technology, PCB increasingly develops to the direction of high density, highly reliable, multiple stratification, low cost and automatic continuous production, and thermostability and reliability to PCB substrate are had higher requirement.And FR-4 based on epoxy resin is due to the shortcoming of heat-resisting quantity difference all the time, unable to do what one wishes in the application requiring high temperature resistant and high reliability circuit.
Silicones is a kind of thermosetting resin, and one of its most prominent performance is excellent thermo oxidative stability.This is with Si-O-Si for skeleton mainly due to silicones, and therefore decomposition temperature is high, can at 200-250 DEG C life-time service and do not decompose or variable color, and coordinate heat-resistant filler resistant to higher temperature.
Silicones has the electrical insulation capability of excellence simultaneously, and due to silicones not polar functionalities, therefore its dielectric constant and dielectric loss angle tangent value vary less in broad temperature range and frequency range, and silicones has superior electric insulating quality simultaneously.Due to silicones can carbonization component less, therefore its resistance to electric arc and corona-resistance property are also very prominent.Silicones has prominent weatherability, be any organic resin too far behind to catch up.Even if under ultraviolet acute irradiation, silicones is resistance to yellowing also.
At present, in order to give laminate anti-flammability, use and with the formula of bromide fire retardant., due to the raising of the recent cry to environmental problem, crave for the resin combination not using halogen based compound, carry out replacing the phosphorus compound of halogenated flame retardant to study further.Phosphorus compound is likely to the toxic compounds such as generation phosphine when burning, even if it is therefore desirable for developing and do not use halogen based compound and phosphorus compound also have anti-flammability and have the laminate of low thermal coefficient of expansion.And silicones itself also has extraordinary fire resistance when being added without halogen and phosphonium flame retardant.
In view of silicones height is heat-resisting, halogen-free phosphorus-free inflaming retarding, have both superior electrical insulation capability, prominent weather resistance, the simultaneously silicones of completion of cure also have low-down thermal coefficient of expansion (< 2.0%), coordinate its performance of functional filler can be more superior.Therefore, with silicon resin system make laminate just meet a kind of high heat-resisting non-halogen non-phosphate of the market demand (high glass transition temperature>200 DEG C, the coefficient of expansion of low Z-direction<2.0%) high-performance printed circuit copper-clad laminate.
Summary of the invention
In consideration of it, an object of the present invention is in that to provide a kind of organosilicon resin composition, it has the advantages such as high-fire resistance, halogen-free flameproof and low-expansion coefficient.
In order to achieve the above object, present invention employs following technical scheme:
A kind of organosilicon resin composition, described organosilicon resin composition includes by weight:
Condensed type silicones 100 parts；
Catalyst 0.0001～2 part；
Auxiliary agent 0.001～10 part.
The content of described catalyst is such as 0.0005 part, 0.001 part, 0.005 part, 0.01 part, 0.05 part, 0.1 part, 0.5 part, 0.9 part, 1.3 parts, 1.7 parts, 1.9 parts.
The content of described auxiliary agent is such as 0.001 part, 0.005 part, 0.01 part, 0.05 part, 0.1 part, 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts or 9.5 parts.
In the present invention, the mixture of any one or at least two that described condensed type silicones is mainly in methyl silicon resin, methyl phenyl silicone resin or phenyl polysiloxane.
In the present invention, described condensed type silicones is any one in dehydrating condensation, dealcoholysis condensation or dehydrogenative condensation, and its reaction structure is as follows:
In the present invention, described condensed type silicones is the mixture of any one or at least two in R/Si=1.0～1.7 (such as 1.1,1.2,1.3,1.4,1.5,1.6 or 1.7) (mol ratio) and Ph/ (Me+Ph)=0～1.0 (such as 0.1,0.2,0.3,0.4,0.5,0.6,0.7,0.8, the 0.9 or 1.0) methyl silicon resin of (mol ratio), methyl phenyl silicone resin or phenyl polysiloxane, wherein Ph represents phenyl group, Me represents methyl group, and R represents organo-functional group-CH3、-Ph、-OCH3、-OCH2CH3,-H or-OH.In condensed type silicones, R/Si (mol ratio) is too small, Ph/Si (mol ratio) is too low, after silicones solidifies, flexibility is poor, paint film is hardening, and R/Si (mol ratio) is excessive, Ph/Si (mol ratio) too high laminate hardness is low, solidify slow, thermosetting is low, therefore described condensed type silicones is preferably R/Si=1.2～1.7 (mol ratio) and the methyl phenyl silicone resin of Ph/ (Me+Ph)=0.2-0.6 (mol ratio).
In the present invention, described catalyst is the combination of any one or at least two in zinc naphthenate, aphthenic acids stannum, cobalt naphthenate, iron naphthenate, cerium naphthenate, zinc polycarboxylate, carboxylic acid stannum, carboxylic acid cobalt, ferric carboxylate, cerium carboxylate, perfluorinated sulfonic acid, phosphonitrilic chloride, amine, quaternary ammonium base, zinc octoate, zinc Isoocatanoate, titanate esters or guanidine compound etc..
In the present invention, described auxiliary agent includes the mixture of any one or at least two in silane coupler, titanate coupling agent or dispersant.
In the present invention, described organosilicon resin composition also includes filler.
In the present invention, described filler includes the mixture of any one or at least two in silicon dioxide, aluminium oxide, aluminium hydroxide, boron nitride, aluminium nitride, barium sulfate, mica powder, Firebrake ZB, titanium dioxide, mica powder, silicon nitride or carborundum.
In the present invention, the content of described filler is 0～60 weight portion, for instance 5 weight portions, 10 weight portions, 15 weight portions, 20 weight portions, 25 weight portions, 30 weight portions, 35 weight portions, 40 weight portions, 45 weight portions, 50 weight portions, 55 weight portions, 60 weight portions.
Exemplary a kind of organosilicon resin composition, described organosilicon resin composition includes by weight:
Preferably, described organosilicon resin composition includes by weight:
" including " of the present invention, it is intended that it is except described component, it is also possible to include other components, these other components give the characteristic that described organosilicon resin composition is different.In addition, " including " of the present invention, it is also possible to replace with enclosed " being " or " by ... composition ".
Such as, described organosilicon resin composition can also contain various additives, as concrete example, it is possible to enumerate fire retardant, antioxidant, heat stabilizer, antistatic additive, UV absorbent, pigment, coloring agent or lubricant etc..These various additives can be used alone, it is also possible to two kinds or two or more mixing use.
The two of the purpose of the present invention are in that to provide a kind of resin adhesive liquid, and it is to be dissolved or dispersed in organosilicon resin composition as above in solvent to obtain.
As the solvent in the present invention, it is not particularly limited, as concrete example, the alcohols such as methanol, ethanol, butanol can be enumerated, the ethers such as ethyl cellosolve, butyl cellosolve, ethylene glycol-methyl ether, carbitol, butyl carbitol, the ketones such as acetone, butanone, methyl ethyl ketone, hexone, Ketohexamethylene, toluene, dimethylbenzene, sym-trimethylbenzene. etc. are aromatic hydrocarbon based, the esters such as ethoxyethyl acetate, ethyl acetate, N, the nitrogenous kind solvents such as dinethylformamide, N,N-dimethylacetamide, METHYLPYRROLIDONE.Above-mentioned solvent can be used alone one, can also two kinds or two or more mixing use, it is preferable that the ketone flux such as the aromatic hydrocarbon solvents such as toluene, dimethylbenzene, sym-trimethylbenzene. and acetone, butanone, methyl ethyl ketone, hexone, Ketohexamethylene mix use.
The three of the purpose of the present invention are in that to provide a kind of prepreg, and it includes reinforcing material and by being impregnated with the organosilicon resin composition as above being attached on reinforcing material after drying.
The preparation method of exemplary prepreg is:
With organosilicon resin composition weight as above 100 parts calculating, add the organic solvent such as toluene or dimethylbenzene and make the resin adhesive liquid that solid content is 50～70% (weight ratios), impregnated this resin adhesive liquid by reinforcing material such as glass-fiber-fabric, then at 120～190 DEG C, toast preparation in 2～15 minutes and obtain.
The four of the purpose of the present invention are in that to provide a kind of laminate, and described laminate contains at least one prepreg as above.
The five of the purpose of the present invention are in that to provide a kind of copper-clad laminate, and described copper-clad laminate includes the prepreg as above of at least one overlapping and covers the Copper Foil of one or both sides of the prepreg after overlapping.
The six of the object of the invention are in that to provide a kind of aluminum-based copper-clad plate, are provided with insulating barrier including copper foil layer and aluminum base layer, copper foil layer and aluminium base interlayer, and described insulating barrier is by organosilicon resin composition as above, and adds heat filling and make.
Described heat filling is the mixture of any one or at least two in alchlor, silicon dioxide, carborundum, boron nitride, aluminium nitride or magnesium oxide.
Compared with the prior art, there is advantages that
(1) present invention is by by silicones, catalyst and additive compound, and the organosilicon resin composition obtained has the feature of high heat-resisting (T300 > 60min), non-halogen non-phosphate, low thermal coefficient of expansion (its thermal coefficient of expansion (CTE) is less than 1.0%) and higher peel strength；
(2) organosilicon resin composition of the present invention has the advantages such as non-halogen non-phosphate, low cigarette, low toxicity, self-extinguishment and environmental protection, provides new approaches and new method in flame retardant area for laminate and copper-clad plate；
(3) all of Processes and apparatus of the preparation process of the present invention is that common FR-4 is universal, existing production equipment can be utilized completely to implement the present invention, it is appreciated that in the industrialization of product.
Detailed description of the invention
Technical scheme is further illustrated below by detailed description of the invention.
Embodiment 1
Weighing the methyl silicon resin 100.0 parts of R/Si=1.1 (mol ratio), Ph/ (Ph+Me)=0 (mol ratio), be dissolved in 60.0 parts of toluene solvants, stirring makes it be completely dissolved.Dissolve after completely until silicones, add zinc Isoocatanoate 0.0001 part, silane coupler γ-(2,3-glycidoxy) propyl trimethoxy silicane (U.S., Dow Corning Corporation provides) 0.001 part, be uniformly mixed and obtain glue.Choose smooth bright and clean, E-glass-fiber-fabric that thickness is 0.1mm, be uniformly coated with above-mentioned glue, obtain prepreg with 170 DEG C of baking 5min in an oven.By 8 above-mentioned prepreg superpositions, enclose the Copper Foil of 35 μm up and down, be placed in vacuum hotpressing machine and obtain laminate at 3MPa pressure and 220 DEG C of temperatures 3h.
Embodiment 2
The methyl phenyl silicone resin 100.0 parts weighing R/Si=1.4 (mol ratio), Ph/ (Ph+Me)=0.5 (mol ratio) is dissolved in 70.0 parts of toluene solvants, and stirring makes it be completely dissolved.Dissolve after completely until silicones, add silicon powder 23.0 parts, acetylacetone cobalt 0.1 part, silane coupler γ-methacryloxypropyl trimethoxy silane coupling agent 1.5 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer), stir to obtain glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Embodiment 3
The phenyl polysiloxane 100.0 parts weighing R/Si=1.7 (mol ratio), Ph/ (Ph+Me)=1.0 (mol ratio) is dissolved in 100.0 parts of toluene solvants, and stirring makes it be completely dissolved.Dissolving after completely until silicones, add aluminium oxide 50 parts, titanate esters 1.5 parts, silane coupler γ-methacryloxypropyl trimethoxy silane 8.7 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer), stir to obtain glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Embodiment 4
Weigh R/Si=1.1 (mol ratio), the methyl silicon resin 60.0 parts of Ph/ (Ph+Me)=0 (mol ratio) and R/Si=1.7 (mol ratio), the methyl phenyl silicone resin 40.0 parts of Ph/ (Ph+Me)=0.9 (mol ratio), being dissolved in 85.0 parts of toluene solvants, stirring makes it be completely dissolved.Dissolve after completely until silicones, add aluminium oxide 25.0 parts, silicon powder 10.0 parts, acetylacetone cobalt 0.08 part, silane coupler γ-methacryloxypropyl trimethoxy silane coupling agent 1.5 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer), stir to obtain glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Comparative example 1
Weigh methyl phenyl vinyl polysiloxane 100 parts (contents of ethylene is 1.0%), dissolve in 70 parts of solvents, 3.1 parts of methyl and phenyl hydrogen-containing silicon oils (hydrogen content is 1.2%) are added after being uniformly dissolved, 0.001 part of hexynol is weighed after high-speed stirred is uniform, 0.01 part of platinum-methyl phenyl vinyl complex is added after stirring 30min, silane coupler γ-methacryloxypropyl trimethoxy silane coupling agent 1.5 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer) is added after continuing stirring 30min, 23 parts of silicon powders, 1h is stirred under room temperature, emulsifying 20min, obtain silicones glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Comparative example 2
The methyl phenyl silicone resin 100.0 parts weighing R/Si=1.4 (mol ratio), Ph/ (Ph+Me)=0.5 (mol ratio) is dissolved in 70.0 parts of toluene solvants, and stirring makes it be completely dissolved.Dissolve after completely until silicones, add silicon powder 70.0 parts, acetylacetone cobalt 0.1 part, silane coupler γ-methacryloxypropyl trimethoxy silane coupling agent 1.5 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer), stir to obtain glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Comparative example 3
The phenyl polysiloxane 100.0 parts weighing R/Si=1.7 (mol ratio), Ph/ (Ph+Me)=1.0 (mol ratio) is dissolved in 100.0 parts of toluene solvants, and stirring makes it be completely dissolved.Dissolving after completely until silicones, add aluminium oxide 50 parts, titanate esters 1.5 parts, silane coupler γ-methacryloxypropyl trimethoxy silane 12.0 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer), stir to obtain glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Comparative example 4
The phenyl polysiloxane 100.0 parts weighing R/Si=1.9 (mol ratio), Ph/ (Ph+Me)=1.0 (mol ratio) is dissolved in 100.0 parts of toluene solvants, and stirring makes it be completely dissolved.Dissolving after completely until silicones, add aluminium oxide 50 parts, titanate esters 1.5 parts, silane coupler γ-methacryloxypropyl trimethoxy silane 8.7 parts (Organic Silicon New Material Co. Ltd., Wuhan Univ., Hubei's offer), stir to obtain glue.
Outside except with this resin adhesive liquid, carry out similarly to Example 1, it is thus achieved that prepreg and the double-sided copper-clad laminate that thickness is 1.0mm.
Effect confirms:
(1) test (thermo-mechanical analysis method) of the Z-coefficient of expansion (CTE)
Method of testing: using IPC-TM-6502.4.24, test data are shown in following table.
(2) thermally stratified layer time (T300) (thermo-mechanical analysis method)
Method of testing: using IPC-TM-6502.4.24.1, test data are shown in following table.
(3) burning grade
Method of testing: with reference to U.S.'s UL94 standard, test data are shown in following table.
(4) peel strength test
Method of testing: use IPC-TM-6502.4.8 method to test, test data ask for an interview following table.
Physical Property Analysis:
As can be seen from the above table data, embodiment 1～4 has a low-down thermal coefficient of expansion simultaneously, the high thermally stratified layer time, halogen-free phosphorus-free inflaming retarding and have good peel strength, meets the demand of copper-clad laminate.And comparative example 1 is compared with embodiment 2, owing to silicones is methyl phenyl vinyl polysiloxane, using add-on type curing, after solidification, the coefficient of expansion is big, and peel strength is low, and flame retardant effect does not also highlight；And comparative example 2 is compared with embodiment 2, filer content goes beyond the scope, and causes that the peel strength with Copper Foil reduces, thermally stratified layer time decreased；Comparative example 3 compared with embodiment 3, auxiliary agent make consumption not at protection domain, owing to auxiliary agent mostly is little molecule, addition too much makes laminate at high temperature little molecule release more so that thermal coefficient of expansion increases, and simultaneously separation time shortens；Comparative example 4 is compared with embodiment 3, and R/Si value goes beyond the scope, and R/Si is more big, and resin crosslink density is more low, more tends to thermoplastic resin so that thermal coefficient of expansion rises, and high temperatures declines, and the thermally stratified layer time reduces.
Applicant states, the present invention illustrates the method detailed of the present invention by above-described embodiment, but the invention is not limited in above-mentioned method detailed, does not namely mean that the present invention has to rely on above-mentioned method detailed and could implement.The equivalence of each raw material of product of the present invention, it will be clearly understood that any improvement in the present invention, is replaced and the interpolation of auxiliary element, concrete way choice etc. by person of ordinary skill in the field, all falls within protection scope of the present invention and open scope.

Claims (10)

1. an organosilicon resin composition, it is characterised in that described organosilicon resin composition includes by weight:
Condensed type silicones 100 parts；
Catalyst 0.0001～2 part；
Auxiliary agent 0.001～10 part.
2. organosilicon resin composition as claimed in claim 1, it is characterised in that described condensed type silicones is the mixture of any one or at least two in methyl silicon resin, methyl phenyl silicone resin or phenyl polysiloxane；
Preferably, described condensed type silicones is the mixture of any one or at least two in R/Si=1.0～1.7 (mol ratio) and the methyl silicon resin of Ph/ (Me+Ph)=0～1.0 (mol ratio), methyl phenyl silicone resin or phenyl polysiloxane, wherein Ph represents phenyl group, Me represents methyl group, and R represents organo-functional group-CH3、-Ph、-OCH3、-OCH2CH3,-H or-OH；
Preferably, described condensed type silicones is R/Si=1.2～1.7 (mol ratio) and the methyl phenyl silicone resin of Ph/ (Me+Ph)=0.2-0.6 (mol ratio)；
Preferably, described catalyst is the combination of any one or at least two in zinc naphthenate, aphthenic acids stannum, cobalt naphthenate, iron naphthenate, cerium naphthenate, zinc polycarboxylate, carboxylic acid stannum, carboxylic acid cobalt, ferric carboxylate, cerium carboxylate, perfluorinated sulfonic acid, phosphonitrilic chloride, amine, quaternary ammonium base, zinc octoate, zinc Isoocatanoate, titanate esters or guanidine compound etc.；
Preferably, described auxiliary agent includes the mixture of any one or at least two in silane coupler, titanate coupling agent or dispersant.
3. organosilicon resin composition as claimed in claim 1 or 2, it is characterised in that described organosilicon resin composition also includes filler；
Preferably, described filler includes the mixture of any one or at least two in silicon dioxide, aluminium oxide, aluminium hydroxide, boron nitride, aluminium nitride, barium sulfate, mica powder, Firebrake ZB, titanium dioxide, Pulvis Talci, silicon nitride or carborundum；
Preferably, the content of described filler is 0～60 weight portion.
4. the organosilicon resin composition as described in one of claim 1-3, it is characterised in that described organosilicon resin composition includes by weight:
Preferably, described organosilicon resin composition includes by weight:
5. a resin adhesive liquid, it is characterised in that it is to be dissolved or dispersed in the organosilicon resin composition as described in one of claim 1-4 in solvent to obtain.
6. a prepreg, it is characterised in that it includes reinforcing material and by being impregnated with the organosilicon resin composition as described in one of claim 1-4 being attached on reinforcing material after drying.
7. a laminate, it is characterised in that described laminate contains at least one prepreg as claimed in claim 6.
8. a copper-clad laminate, it is characterised in that described copper-clad laminate includes the prepreg as claimed in claim 6 of at least one overlapping and covers the Copper Foil of one or both sides of the prepreg after overlapping.
9. an aluminum-based copper-clad plate, scribbles insulating barrier including copper foil layer and aluminum base layer, copper foil layer and aluminium base interlayer, it is characterised in that described insulating barrier is by silicon resin composition as described in one of claim 1-4, and adds heat filling and make.
10. the manufacture method of aluminum-based copper-clad plate as claimed in claim 9, comprises the steps:
(1) prepare silicon resin composition by component ratio, and add heat filling, stir, make heat conduction glue；
(2) the heat conduction glue prepared is coated on Copper Foil, toasts 5min with 170 DEG C in an oven and obtain semi-solid preparation coating Copper Foil；
(3) being superimposed together by the coating Copper Foil described in aluminium sheet and (2), being placed under vacuum state substep increasing temperature and pressure prepares aluminum-based copper-clad plate.
CN201410829549.1A 2014-12-25 2014-12-25 A kind of organosilicon resin composition and prepreg, laminate, copper-clad plate and aluminum substrate using it Active CN105778506B (en)

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TW104105267A TWI531617B (en) 2014-12-25 2015-02-16 Organic enamel resin composition and prepreg, laminate, copper clad laminate and aluminum substrate using the same
EP15871611.8A EP3239244B1 (en) 2014-12-25 2015-06-01 Organic silicone resin composition and pre-preg, laminate, copper-clad laminate, and aluminum substrate that use the composition
JP2017533822A JP6514335B2 (en) 2014-12-25 2015-06-01 Silicone resin composition and prepreg using the same, laminate, copper clad laminate, and aluminum substrate
KR1020177020792A KR101887841B1 (en) 2014-12-25 2015-06-01 Organosilicon resin composition and prepreg using it, laminate, copper-clad laminate and aluminum substrate
US15/539,467 US10308808B2 (en) 2014-12-25 2015-06-01 Organic silicone resin composition and pre-preg, laminate, copper-clad laminate, and aluminum substrate that use the composition
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108489630A (en) * 2018-03-22 2018-09-04 首凯汽车零部件（江苏）有限公司 A kind of path thermal sensation portion vehicle exhaust temperature sensor
CN110099508A (en) * 2018-01-29 2019-08-06 铨威技研股份有限公司 Printed circuit board base board and its preparation method
CN110183661A (en) * 2019-06-10 2019-08-30 中山大学 A kind of high heat resistance, the preparation method of High-heat-conductiviinsulation insulation material
CN110272558A (en) * 2019-06-28 2019-09-24 武汉龙顺达新材料有限公司 A kind of Modified Membrane cloth and preparation method thereof
CN111320965A (en) * 2020-03-27 2020-06-23 无锡市百合花胶粘剂厂有限公司 High-temperature-resistant adhesive, and preparation method and application thereof
CN112457496A (en) * 2020-11-20 2021-03-09 西安安聚德纳米科技有限公司 Self-flame-retardant organic silicon resin for PCB (printed Circuit Board), preparation method thereof and composition containing self-flame-retardant organic silicon resin
CN113667162A (en) * 2021-09-18 2021-11-19 哈尔滨工业大学 Method for improving high-temperature resistance of silicone resin and composite material thereof
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CN114953629A (en) * 2022-04-20 2022-08-30 江西鑫远基电子科技有限公司 High-heat-dissipation aluminum-based copper-clad plate and production process thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6615957B1 (en) * 2018-08-06 2019-12-04 日本タングステン株式会社 Method for producing copper clad laminate
KR102400549B1 (en) * 2019-10-22 2022-05-19 주식회사 엘지화학 Thermally conductive composition for thermal pads and thermal pads comprising the same
JP6730503B1 (en) * 2019-11-06 2020-07-29 日本タングステン株式会社 Copper clad laminate
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101712799A (en) * 2008-09-30 2010-05-26 信越化学工业株式会社 Silicone resin composition for optical semiconductor device
CN102757647A (en) * 2012-07-11 2012-10-31 东莞兆舜有机硅新材料科技有限公司 Single-component catalytic dealcoholized room temperature vulcanized (RTV) silicone rubber and preparation method thereof
CN103044922A (en) * 2012-12-31 2013-04-17 上海回天化工新材料有限公司 Halogen-free flame retardant, high-temperature resisting and rapidly solidified deacetone silicon rubber and preparation method thereof
CN103554920A (en) * 2013-11-05 2014-02-05 烟台德邦科技有限公司 Transparent silicone composition
CN104004357A (en) * 2014-06-26 2014-08-27 上海回天新材料有限公司 Transparent, fast-cured and thixotropic dealcoholization one-component silicone rubber

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3018270A (en) * 1960-07-28 1962-01-23 Union Carbide Corp Process for producing silicone resins
JPS5734150A (en) * 1980-08-08 1982-02-24 Toray Silicone Co Ltd Organopolysiloxane resin composition
CA1235245A (en) * 1984-12-26 1988-04-12 Toshifumi Hirose Curable resinous composition comprising epoxy resin and silicon-containing elastomeric polymer
JPS62201242A (en) 1986-02-28 1987-09-04 新興化学工業株式会社 Silicone-resin laminated board and manufacture thereof
JPH0292630A (en) * 1988-09-30 1990-04-03 Wakomu:Kk Metal clad mica plate
US5280098A (en) * 1992-09-30 1994-01-18 Dow Corning Corporation Epoxy-functional silicone resin
JP3121188B2 (en) * 1993-10-26 2000-12-25 信越化学工業株式会社 Room temperature fast-curing organopolysiloxane composition excellent in water resistance, curing method thereof, and cured product obtained thereby
JP3031821B2 (en) * 1994-07-21 2000-04-10 信越化学工業株式会社 Laminates with improved heat resistance
JP3258873B2 (en) * 1995-10-18 2002-02-18 三菱電機株式会社 Silicone varnish, its production method and silicone varnish impregnated prepreg
JP4656616B2 (en) 2000-01-28 2011-03-23 株式会社バンダイナムコゲームス GAME SYSTEM, PROGRAM, AND INFORMATION STORAGE MEDIUM
KR101001121B1 (en) * 2002-10-22 2010-12-14 유겡가이샤 소피아 프로덕트 Sealing composition for optical element, sealing structure, and optical element
WO2004109663A2 (en) * 2003-05-30 2004-12-16 Arkivio, Inc. Techniques for facilitating backup and restore of migrated files
DE102004005222A1 (en) * 2004-02-03 2005-08-18 Degussa Ag Silicone rubber for use e.g. in sealing or coating applications, contains silanised, structurally-modified pyrogenic silica with groups such as dimethylsilyl attached to the surface
US6992440B2 (en) * 2004-02-26 2006-01-31 Asahi Glass Company, Limited Light-emitting device and process for its production
US7732496B1 (en) * 2004-11-03 2010-06-08 Ohio Aerospace Institute Highly porous and mechanically strong ceramic oxide aerogels
JP4569765B2 (en) * 2005-05-13 2010-10-27 信越化学工業株式会社 Room temperature curable silicone rubber composition for protecting electrical and electronic components, mounting circuit board, silver electrode and silver chip resistor
WO2006125182A2 (en) * 2005-05-19 2006-11-23 Danner, Inc. Footwear with a shank system
JP2007012876A (en) * 2005-06-30 2007-01-18 Asahi Glass Co Ltd Laminated material for circuit board and manufacturing method thereof
JP2007106944A (en) * 2005-10-17 2007-04-26 Shin Etsu Chem Co Ltd Room temperature-curable organopolysiloxane composition
DE102006033976A1 (en) 2006-07-22 2008-01-31 Dr.Ing.H.C. F. Porsche Ag Exhaust gas turbocharger for an internal combustion engine
JP5057022B2 (en) * 2006-10-13 2012-10-24 信越化学工業株式会社 Emulsion composition for coating
TWM312864U (en) 2006-11-30 2007-05-21 Leison Technology Company Ltd Improved medium structure for PCB
JP5293598B2 (en) * 2007-04-10 2013-09-18 住友ベークライト株式会社 Resin composition, prepreg, laminate, multilayer printed wiring board, and semiconductor device
JP5266720B2 (en) 2007-10-30 2013-08-21 株式会社デンソー Semiconductor device
US8258251B2 (en) * 2007-11-30 2012-09-04 The United States Of America, As Represented By The Administrator Of The National Aeronautics And Space Administration Highly porous ceramic oxide aerogels having improved flexibility
RU2010127317A (en) * 2007-12-05 2012-01-10 Коринн Джин ГРЕЙЛИНГ (ZA) POLYMERIC HIGH VOLTAGE INSULATOR WITH SOLID HYDROPHOBIC SURFACE
JP4623322B2 (en) * 2007-12-26 2011-02-02 信越化学工業株式会社 White thermosetting silicone resin composition for forming optical semiconductor case, optical semiconductor case and molding method thereof
JP2010021533A (en) * 2008-06-09 2010-01-28 Shin-Etsu Chemical Co Ltd White heat-curable silicone resin composition for forming optical semiconductor case, and optical semiconductor case
JP2010018786A (en) * 2008-06-09 2010-01-28 Shin-Etsu Chemical Co Ltd White heat-curable silicone resin composition for forming optical semiconductor case, and optical semiconductor case
JP5108825B2 (en) * 2009-04-24 2012-12-26 信越化学工業株式会社 Silicone resin composition for optical semiconductor device and optical semiconductor device
EP2272408A1 (en) * 2009-07-08 2011-01-12 Jura Elektroapparate AG Drink preparation machine and method for cleaning same
JP5488326B2 (en) * 2009-09-01 2014-05-14 信越化学工業株式会社 White thermosetting silicone epoxy hybrid resin composition for optical semiconductor device, method for producing the same, pre-mold package and LED device
JP4964928B2 (en) 2009-09-15 2012-07-04 信越化学工業株式会社 Underfill material composition and optical semiconductor device
CN101724268B (en) * 2009-11-27 2012-12-05 佛山市金银河机械设备有限公司 Method for production of silicone adhesive
JP6109569B2 (en) * 2010-05-07 2017-04-05 住友ベークライト株式会社 Epoxy resin composition for circuit board, prepreg, laminate, resin sheet, laminate substrate for printed wiring board, printed wiring board, and semiconductor device
KR20180135079A (en) * 2011-01-18 2018-12-19 히타치가세이가부시끼가이샤 Modified silicone compound, and thermosetting resin composition, prepreg, laminate plate and printed wiring board using same
US9079376B2 (en) * 2011-01-18 2015-07-14 Hitachi Chemical Company, Ltd. Prepreg, laminate obtained with the same and printed-wiring board
US8735733B2 (en) * 2011-01-18 2014-05-27 Hitachi Chemical Company, Ltd. Resin composition, prepreg laminate obtained with the same and printed-wiring board
CN102181264B (en) * 2011-04-15 2013-03-13 东莞兆舜有机硅新材料科技有限公司 High-performance organosilicone sealant for photovoltaic (PV) module and preparation method thereof
JP6026095B2 (en) * 2011-10-31 2016-11-16 太陽インキ製造株式会社 Thermosetting resin composition, cured product thereof, and printed wiring board using the same
US20150056454A1 (en) * 2012-03-13 2015-02-26 Mitsubishi Gas Chemical Company, Inc. Resin composition, prepreg, and metal foil-clad laminate
CN102925055A (en) 2012-11-16 2013-02-13 中国海洋石油总公司 High-color retaining air-dry high temperature-resistant coating
US9663664B2 (en) * 2013-02-27 2017-05-30 Asahi Rubber Inc. Ink for white reflective film, powder coating material for white reflective film, production method of white reflective film, white reflective film, light source mount, and lighting device shade
DE102013216781A1 (en) * 2013-08-23 2015-02-26 Evonik Industries Ag coating materials
CN103497488B (en) * 2013-10-11 2016-05-25 广东生益科技股份有限公司 A kind of compositions of thermosetting resin and uses thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101712799A (en) * 2008-09-30 2010-05-26 信越化学工业株式会社 Silicone resin composition for optical semiconductor device
CN102757647A (en) * 2012-07-11 2012-10-31 东莞兆舜有机硅新材料科技有限公司 Single-component catalytic dealcoholized room temperature vulcanized (RTV) silicone rubber and preparation method thereof
CN103044922A (en) * 2012-12-31 2013-04-17 上海回天化工新材料有限公司 Halogen-free flame retardant, high-temperature resisting and rapidly solidified deacetone silicon rubber and preparation method thereof
CN103554920A (en) * 2013-11-05 2014-02-05 烟台德邦科技有限公司 Transparent silicone composition
CN104004357A (en) * 2014-06-26 2014-08-27 上海回天新材料有限公司 Transparent, fast-cured and thixotropic dealcoholization one-component silicone rubber

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110099508A (en) * 2018-01-29 2019-08-06 铨威技研股份有限公司 Printed circuit board base board and its preparation method
CN108489630A (en) * 2018-03-22 2018-09-04 首凯汽车零部件（江苏）有限公司 A kind of path thermal sensation portion vehicle exhaust temperature sensor
CN110183661A (en) * 2019-06-10 2019-08-30 中山大学 A kind of high heat resistance, the preparation method of High-heat-conductiviinsulation insulation material
CN110272558A (en) * 2019-06-28 2019-09-24 武汉龙顺达新材料有限公司 A kind of Modified Membrane cloth and preparation method thereof
CN111320965A (en) * 2020-03-27 2020-06-23 无锡市百合花胶粘剂厂有限公司 High-temperature-resistant adhesive, and preparation method and application thereof
CN111320965B (en) * 2020-03-27 2022-03-29 无锡市百合花胶粘剂厂有限公司 High-temperature-resistant adhesive, and preparation method and application thereof
CN112457496A (en) * 2020-11-20 2021-03-09 西安安聚德纳米科技有限公司 Self-flame-retardant organic silicon resin for PCB (printed Circuit Board), preparation method thereof and composition containing self-flame-retardant organic silicon resin
CN113956481A (en) * 2021-09-07 2022-01-21 江苏诺德新材料股份有限公司 Resin composition for 5G high-frequency high-speed copper-clad plate, prepreg and laminated plate
CN113667162A (en) * 2021-09-18 2021-11-19 哈尔滨工业大学 Method for improving high-temperature resistance of silicone resin and composite material thereof
CN113667162B (en) * 2021-09-18 2024-03-12 哈尔滨工业大学 Method for improving high temperature resistance of silicone resin and composite material thereof
CN114953629A (en) * 2022-04-20 2022-08-30 江西鑫远基电子科技有限公司 High-heat-dissipation aluminum-based copper-clad plate and production process thereof

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