CN105778283A - Waterproof and environment-friendly cable material - Google Patents
Waterproof and environment-friendly cable material Download PDFInfo
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- CN105778283A CN105778283A CN201610186153.9A CN201610186153A CN105778283A CN 105778283 A CN105778283 A CN 105778283A CN 201610186153 A CN201610186153 A CN 201610186153A CN 105778283 A CN105778283 A CN 105778283A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H1/00—Macromolecular products derived from proteins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Spectroscopy & Molecular Physics (AREA)
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Abstract
The invention discloses a waterproof and environment-friendly cable material, prepared from the following raw materials in parts by weight: 20-35 parts of carboxyl nitrile rubber, 15-28 parts of phenyl silicone rubber, 20-40 parts of polypropylene, 0.8-1.6 parts of dioctyl terephthalate, 1.5-1.6 parts of trioctyl phosphate, 0.2-0.9 part of palm wax, 45-58 parts of white carbon black, 10-20 parts of graphene, 20-30 parts of nano calcium carbonate, 20-30 parts of modified soybean protein, 5-12 parts of glass beads, 1-2 parts of polyvinyl alcohol, 2-4 parts of dibutyl phthalate, 1-3 parts of liquid coumarone resin, 0.5-1.2 parts of an antioxidant AT-215, 0.4-1 part of stearic acid, 1-2 parts of epoxidized soybean oil, 1-3 parts of di-tert-butyl peroxide, 0.2-0.6 part of tert-butyl perbenzoate, 0.2-0.6 part of sodium ammonium dichromate, 0.1-0.6 part of an accelerant M and 0.5-1.2 parts of an accelerant TMTD. The cable material provided by the invention is waterproof and environment-friendly as well as free from environmental pollution.
Description
Technical field
The present invention relates to CABLE MATERIALS technical field, particularly relate to a kind of water-proof environmental protection cable material.
Background technology
CABLE MATERIALS belongs to a kind of composite, and it is typically to be equipped with suitable filler by matrix resin and forms,
Require in addition to there is higher physical and mechanical properties, also should have the waterproof and environmental-protecting performance that comparison is excellent,
Typically do not have waterproof and environmental-protecting performance due to matrix resin itself, therefore the CABLE MATERIALS under prior art is anti-
Water poor performance, causes to reduce service life, even causes sheath to ftracture, the hidden danger that formation accident occurs,
After simultaneously discarded big to environmental hazard, how can improve the waterproof of CABLE MATERIALS and environmental-protecting performance simultaneously, to become
For those skilled in the art institute problem demanding prompt solution.
Summary of the invention
The present invention proposes a kind of water-proof environmental protection cable material, waterproof, and environmental protection is free from environmental pollution.
A kind of water-proof environmental protection cable material that the present invention proposes, its raw material includes by weight: carboxy terminated nitrile rubber
20-35 part, phenyl siloxane rubber 15-28 part, polypropylene 20-40 part, DOTP 0.8-1.6
Part, trioctyl phosphate 1.5-1.6 part, palm wax 0.2-0.9 part, white carbon 45-58 part, Graphene 10-20
Part, nano-calcium carbonate 20-30 part, modified soy-bean protein 20-30 part, glass microballoon 5-12 part, polyethylene
Alcohol 1-2 part, dibutyl phthalate 2-4 part, liquid coumarone indene resin 1-3 part, antioxidant AT-215
0.5-1.2 part, stearic acid 0.4-1 part, epoxy soybean oil 1-2 part, di-t-butyl peroxide 1-3 part, mistake
T-butyl perbenzoate 0.2-0.6 part, Ammonium bichromate. sodium 0.2-0.6 part, captax 0.1-0.6 part, promote
Enter agent TMTD 0.5-1.2 part.
Preferably, modified soy-bean protein uses following technique to prepare: weigh 15-30 part Semen sojae atricolor egg by weight
In vain, 150-200 part concentration be 50-70% ethanol solution, 5-15 part stearic acid mix and blend 40-80min, stir
Mix temperature and be 60-70 DEG C, microwave radiation processing 5-15min, filters, is dried, add 1-5 part sweet after grinding
Oil, 1-3 part propanoic acid, 20-40 part water mix and blend 15-30min, whipping temp is 110-118 DEG C, stirring
Pressure is 4-10MPa, and cooling is sent into after adding 50-60 part Gypsum Fibrosum, 1-3 part titanate coupling agent mix homogeneously
In still kettle, in still kettle, steam pressure is 0.8-1MPa, and vapor (steam) temperature is 150-170 DEG C, the steam pressure time
For 15-20h, being dried to content of water in system is 20-30wt%, stirs, mixing speed 5000-6000r/min,
Whipping temp is 100-120 DEG C, dry, pulverize and obtains modified soy-bean protein.
Preferably, carboxy terminated nitrile rubber, phenyl siloxane rubber, polypropylene, the weight ratio of modified soy-bean protein are
25-30:22-24:30-35:25-28.
Preferably, the weight of white carbon, Graphene, nano-calcium carbonate, modified soy-bean protein, glass microballoon
Ratio is 48-52:14-18:21-25:25-28:8-10.
Preferably, the weight of DOTP, trioctyl phosphate, palm wax, modified soy-bean protein
Ratio is 1.2-1.4:1.55-1.58:0.3-0.5:25-28.
Preferably, di-t-butyl peroxide, t-butyl perbenzoate, Ammonium bichromate. sodium, captax, promotion
The weight ratio of agent TMTD is 1.2-1.8:0.3-0.5:0.3-0.35:0.2-0.4:0.6-0.8.
Preferably, described water-proof environmental protection cable material, its raw material includes by weight: carboxy terminated nitrile rubber 25-30
Part, phenyl siloxane rubber 22-24 part, polypropylene 30-35 part, DOTP 1.2-1.4 part,
Trioctyl phosphate 1.55-1.58 part, palm wax 0.3-0.5 part, white carbon 48-52 part, Graphene 14-18
Part, nano-calcium carbonate 21-25 part, modified soy-bean protein 25-28 part, glass microballoon 8-10 part, polyethylene
Alcohol 1.4-1.8 part, dibutyl phthalate 2.5-3 part, liquid coumarone indene resin 1.2-1.8 part is anti-
Oxygen agent AT-215 0.6-1 part, stearic acid 0.6-0.8 part, epoxy soybean oil 1.2-1.5 part, peroxidating two
Tert-butyl group 1.2-1.8 part, t-butyl perbenzoate 0.3-0.5 part, Ammonium bichromate. sodium 0.3-0.35 part, promote
Enter agent M 0.2-0.4 part, Vulcanization accelerator TMTD 0.6-0.8 part.
The present invention uses the preparation technology of common cable material to prepare.
The present invention, soybean protein can promote soybean protein intramolecular through microwave radiation processing and intermolecular hand over
Connection reaction, reacts with the stearic acid of follow-up addition, is effectively reduced the hydrophilic group quantity that soybean protein exposes,
Goods compactness and hot strength significantly improve, and water absorption rate is extremely low, and the propanoic acid added and soybean protein
Water suction radical reaction, not only can reduce goods water absorbing properties further, and can slacken soybean protein further and divide
Active force between son, goods elongation at break is high, further with the Gypsum Fibrosum added, titanate coupling agent one
React under fixed condition, can be grafted on gypsum surface, goods and carboxy terminated nitrile rubber, phenyl siloxane rubber, poly-third
Alkene mating reaction, goods water resistance is fabulous, and elongation at break is high, and ageing-resistant performance is the most excellent, because
Soybean protein is natural materials, is easier to degraded after discarded, and environmental pollution is little.Additionally white carbon, stone
Ink alkene, nano-calcium carbonate, glass microballoon and modified soy-bean protein mating reaction, goods not only compactness progress
Strengthening, hot strength is high, and water resistance further enhances；And DOTP, tricresyl phosphate are pungent
Ester, palm wax and modified soy-bean protein mating reaction, promote toughness reach with hardness Jun Heng on the premise of,
Goods elongation at break is higher, and di-t-butyl peroxide, t-butyl perbenzoate, Ammonium bichromate. sodium, rush
Entering agent M and Vulcanization accelerator TMTD synergism as vulcanizing system, cure is good, and mechanical property is good, goods
Waterproof and ageing-resistant performance is the most excellent.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of water-proof environmental protection cable material, its raw material includes by weight: carboxy terminated nitrile rubber 35 parts, phenyl silicon
Rubber 15 parts, polypropylene 40 parts, DOTP 0.8 part, trioctyl phosphate 1.6 parts, palm fibre
0.2 part of palmitic acid wax, white carbon 58 parts, Graphene 10 parts, nano-calcium carbonate 30 parts, modified soy-bean protein 20
Part, glass microballoon 12 parts, polyvinyl alcohol 1 part, dibutyl phthalate 4 parts, liquid coumarone indene resin
1 part, antioxidant AT-215 1.2 parts, stearic acid 0.4 part, epoxy soybean oil 2 parts, the tertiary fourth of peroxidating two
1 part of base, t-butyl perbenzoate 0.6 part, 0.2 part of Ammonium bichromate. sodium, captax 0.6 part, promote
Agent TMTD 0.5 part.
Embodiment 2
A kind of water-proof environmental protection cable material, its raw material includes by weight: carboxy terminated nitrile rubber 20 parts, phenyl silicon
Rubber 28 parts, polypropylene 20 parts, DOTP 1.6 parts, trioctyl phosphate 1.5 parts, palm fibre
0.9 part of palmitic acid wax, white carbon 45 parts, Graphene 20 parts, nano-calcium carbonate 20 parts, modified soy-bean protein 30
Part, glass microballoon 5 parts, polyvinyl alcohol 2 parts, dibutyl phthalate 2 parts, liquid coumarone indene resin 3
Part, antioxidant AT-215 0.5 part, stearic acid 1 part, epoxy soybean oil 1 part, di-t-butyl peroxide 3
Part, t-butyl perbenzoate 0.2 part, 0.6 part of Ammonium bichromate. sodium, captax 0.1 part, Vulcanization accelerator TMTD
1.2 part.
Embodiment 3
A kind of water-proof environmental protection cable material, its raw material includes by weight: carboxy terminated nitrile rubber 25 parts, phenyl silicon
Rubber 24 parts, polypropylene 30 parts, DOTP 1.4 parts, trioctyl phosphate 1.55 parts, palm fibre
0.5 part of palmitic acid wax, white carbon 48 parts, Graphene 18 parts, nano-calcium carbonate 21 parts, modified soy-bean protein 28
Part, glass microballoon 8 parts, polyvinyl alcohol 1.8 parts, dibutyl phthalate 2.5 parts, liquid coumarone
Resin 1.8 parts, antioxidant AT-215 0.6 part, stearic acid 0.8 part, epoxy soybean oil 1.2 parts, peroxide
Change di-t-butyl 1.8 parts, t-butyl perbenzoate 0.3 part, 0.35 part of Ammonium bichromate. sodium, captax 0.2
Part, Vulcanization accelerator TMTD 0.8 part.
Modified soy-bean protein use following technique prepare: weigh by weight 15 portions of soybean proteins, 200 parts dense
Degree is 50% ethanol solution, 15 parts of stearic acid mix and blend 40min, and whipping temp is 70 DEG C, microwave radiation
Process 5min, filter, be dried, after grinding, add 5 parts of glycerol, 1 part of propanoic acid, 40 parts of water mix and blend 15min,
Whipping temp is 118 DEG C, and stirring pressure is 4MPa, and cooling adds 60 parts of Gypsum Fibrosum, 1 part of titanate coupling agent
Sending in still kettle after mix homogeneously, in still kettle, steam pressure is 1MPa, and vapor (steam) temperature is 150 DEG C, steams
The pressure time is 20h, and being dried to content of water in system is 20wt%, stirs, mixing speed 6000r/min, stirring
Temperature is 100 DEG C, dry, pulverize and obtains modified soy-bean protein.
Embodiment 4
A kind of water-proof environmental protection cable material, its raw material includes by weight: carboxy terminated nitrile rubber 30 parts, phenyl silicon
Rubber 22 parts, polypropylene 35 parts, DOTP 1.2 parts, trioctyl phosphate 1.58 parts, palm fibre
0.3 part of palmitic acid wax, white carbon 52 parts, Graphene 14 parts, nano-calcium carbonate 25 parts, modified soy-bean protein 25
Part, glass microballoon 10 parts, polyvinyl alcohol 1.4 parts, dibutyl phthalate 3 parts, liquid coumarone tree
1.2 parts of fat, antioxidant AT-215 1 part, stearic acid 0.6 part, epoxy soybean oil 1.5 parts, peroxidating two
The tert-butyl group 1.2 parts, t-butyl perbenzoate 0.5 part, 0.3 part of Ammonium bichromate. sodium, captax 0.4 part,
Vulcanization accelerator TMTD 0.6 part.
Modified soy-bean protein use following technique prepare: weigh by weight 30 portions of soybean proteins, 150 parts dense
Degree is 70% ethanol solution, 5 parts of stearic acid mix and blend 80min, and whipping temp is 60 DEG C, at microwave radiation
Reason 15min, filters, and is dried, and adds 1 part of glycerol, 3 parts of propanoic acid, 20 parts of water mix and blend 30min after grinding,
Whipping temp is 110 DEG C, and stirring pressure is 10MPa, and cooling adds 50 parts of Gypsum Fibrosum, 3 parts of titanate coupling agents
Sending in still kettle after mix homogeneously, in still kettle, steam pressure is 0.8MPa, and vapor (steam) temperature is 170 DEG C,
The steam pressure time is 15h, and being dried to content of water in system is 30wt%, stirs, mixing speed 5000r/min, stirs
Mixing temperature is 120 DEG C, dry, pulverize and obtains modified soy-bean protein.
Embodiment 5
A kind of water-proof environmental protection cable material, its raw material includes by weight: carboxy terminated nitrile rubber 28 parts, phenyl silicon
Rubber 23 parts, polypropylene 32 parts, DOTP 1.3 parts, trioctyl phosphate 1.56 parts, palm fibre
0.42 part of palmitic acid wax, white carbon 51 parts, Graphene 15 parts, nano-calcium carbonate 23 parts, modified soy-bean protein
26 parts, glass microballoon 9 parts, polyvinyl alcohol 1.6 parts, dibutyl phthalate 2.8 parts, liquid Gu horse
Grand resin 1.4 parts, antioxidant AT-215 0.82 part, stearic acid 0.72 part, epoxy soybean oil 1.32 parts,
Di-t-butyl peroxide 1.4 parts, t-butyl perbenzoate 0.41 part, 0.32 part of Ammonium bichromate. sodium, promote
Agent M 0.25 part, Vulcanization accelerator TMTD 0.72 part.
Modified soy-bean protein use following technique prepare: weigh by weight 24 portions of soybean proteins, 165 parts dense
Degree is 62% ethanol solution, 12 parts of stearic acid mix and blend 60min, and whipping temp is 64 DEG C, microwave radiation
Process 10min, filter, be dried, after grinding, add 2 parts of glycerol, 2 parts of propanoic acid, 32 parts of water mix and blends
20min, whipping temp is 112 DEG C, and stirring pressure is 6MPa, and cooling adds 55 parts of Gypsum Fibrosum, 2 parts of titanate esters
Sending in still kettle after coupling agent mix homogeneously, in still kettle, steam pressure is 0.9MPa, and vapor (steam) temperature is
162 DEG C, the steam pressure time is 18h, and being dried to content of water in system is 24wt%, stirs, mixing speed 5200r/min,
Whipping temp is 112 DEG C, dry, pulverize and obtains modified soy-bean protein.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (7)
1. a water-proof environmental protection cable material, it is characterised in that its raw material includes by weight: carboxyl butyronitrile rubber
Glue 20-35 part, phenyl siloxane rubber 15-28 part, polypropylene 20-40 part, DOTP 0.8-1.6
Part, trioctyl phosphate 1.5-1.6 part, palm wax 0.2-0.9 part, white carbon 45-58 part, Graphene 10-20
Part, nano-calcium carbonate 20-30 part, modified soy-bean protein 20-30 part, glass microballoon 5-12 part, polyethylene
Alcohol 1-2 part, dibutyl phthalate 2-4 part, liquid coumarone indene resin 1-3 part, antioxidant AT-215
0.5-1.2 part, stearic acid 0.4-1 part, epoxy soybean oil 1-2 part, di-t-butyl peroxide 1-3 part,
T-butyl perbenzoate 0.2-0.6 part, Ammonium bichromate. sodium 0.2-0.6 part, captax 0.1-0.6 part,
Vulcanization accelerator TMTD 0.5-1.2 part.
Water-proof environmental protection cable material the most according to claim 1, it is characterised in that modified soy-bean protein is adopted
Prepare by following technique: weigh 15-30 part soybean protein by weight, 150-200 part concentration is 50-70%
Ethanol solution, 5-15 part stearic acid mix and blend 40-80min, whipping temp is 60-70 DEG C, microwave radiation
Process 5-15min, filter, be dried, after grinding, add 1-5 part glycerol, 1-3 part propanoic acid, 20-40 part water
Mix and blend 15-30min, whipping temp is 110-118 DEG C, and stirring pressure is 4-10MPa, and cooling adds
Send into after 50-60 part Gypsum Fibrosum, 1-3 part titanate coupling agent mix homogeneously in still kettle, vapour pressure in still kettle
Power is 0.8-1MPa, and vapor (steam) temperature is 150-170 DEG C, and the steam pressure time is 15-20h, is dried to system aqueous
Amount is 20-30wt%, stirring, mixing speed 5000-6000r/min, and whipping temp is 100-120 DEG C, dry
Dry, pulverize and obtain modified soy-bean protein.
Water-proof environmental protection cable material the most according to claim 1 and 2, it is characterised in that carboxyl butyronitrile rubber
Glue, phenyl siloxane rubber, polypropylene, the weight ratio of modified soy-bean protein are 25-30:22-24:30-35:
25-28。
4. according to the water-proof environmental protection cable material described in any one of claim 1-3, it is characterised in that white carbon,
Graphene, nano-calcium carbonate, modified soy-bean protein, the weight ratio of glass microballoon are 48-52:14-18:21-25:
25-28:8-10.
5. according to the water-proof environmental protection cable material described in any one of claim 1-4, it is characterised in that to benzene two
Formic acid dioctyl ester, trioctyl phosphate, palm wax, the weight ratio of modified soy-bean protein are 1.2-1.4:
1.55-1.58:0.3-0.5:25-28.
6. according to the water-proof environmental protection cable material described in any one of claim 1-5, it is characterised in that peroxidating
Di-t-butyl, t-butyl perbenzoate, Ammonium bichromate. sodium, captax, the weight ratio of Vulcanization accelerator TMTD are
1.2-1.8:0.3-0.5:0.3-0.35:0.2-0.4:0.6-0.8.
7. according to the water-proof environmental protection cable material described in any one of claim 1-6, it is characterised in that its raw material
Include by weight: carboxy terminated nitrile rubber 25-30 part, phenyl siloxane rubber 22-24 part, polypropylene 30-35
Part, DOTP 1.2-1.4 part, trioctyl phosphate 1.55-1.58 part, palm wax 0.3-0.5
Part, white carbon 48-52 part, Graphene 14-18 part, nano-calcium carbonate 21-25 part, modified soy-bean protein
25-28 part, glass microballoon 8-10 part, polyvinyl alcohol 1.4-1.8 part, dibutyl phthalate 2.5-3
Part, liquid coumarone indene resin 1.2-1.8 part, antioxidant AT-215 0.6-1 part, stearic acid 0.6-0.8 part,
Epoxy soybean oil 1.2-1.5 part, di-t-butyl peroxide 1.2-1.8 part, t-butyl perbenzoate 0.3-0.5
Part, Ammonium bichromate. sodium 0.3-0.35 part, captax 0.2-0.4 part, Vulcanization accelerator TMTD 0.6-0.8 part.
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| CN201610186153.9A CN105778283A (en) | 2016-03-25 | 2016-03-25 | Waterproof and environment-friendly cable material |
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| CN201610186153.9A CN105778283A (en) | 2016-03-25 | 2016-03-25 | Waterproof and environment-friendly cable material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106543509A (en) * | 2016-10-19 | 2017-03-29 | 安徽吉思特智能装备有限公司 | A kind of tension small-sized electric tool cable jacket |
| CN106750689A (en) * | 2016-12-15 | 2017-05-31 | 天长市康宁甘油科技有限公司 | A kind of environmentally friendly crude glycerine XNBR material |
| CN108198649A (en) * | 2017-11-29 | 2018-06-22 | 安徽华天电缆有限公司 | A kind of tensile cable sheath |
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| CN102816439A (en) * | 2012-06-28 | 2012-12-12 | 河南工业大学 | Composite modified soybean protein plastic and its preparation method |
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| CN105199166A (en) * | 2015-09-29 | 2015-12-30 | 安徽蓝德集团股份有限公司 | Flame-retardant computer cable sheath material with excellent mechanical properties |
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| CN101987902A (en) * | 2009-07-31 | 2011-03-23 | 索肯（上海）科技有限公司 | Halogen-free thermoplastic elastomer and manufacturing method thereof and environment-friendly electric wires and cables using halogen-free thermoplastic elastomer |
| CN102816439A (en) * | 2012-06-28 | 2012-12-12 | 河南工业大学 | Composite modified soybean protein plastic and its preparation method |
| CN104008807A (en) * | 2014-04-23 | 2014-08-27 | 晶锋集团股份有限公司 | Low-smoke power cable for ship |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106543509A (en) * | 2016-10-19 | 2017-03-29 | 安徽吉思特智能装备有限公司 | A kind of tension small-sized electric tool cable jacket |
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| CN108198649A (en) * | 2017-11-29 | 2018-06-22 | 安徽华天电缆有限公司 | A kind of tensile cable sheath |
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Application publication date: 20160720 |
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