CN105777209B - Glass-ceramic clad plate with border crystallization texture and preparation method thereof - Google Patents
Glass-ceramic clad plate with border crystallization texture and preparation method thereof Download PDFInfo
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- CN105777209B CN105777209B CN201610074338.0A CN201610074338A CN105777209B CN 105777209 B CN105777209 B CN 105777209B CN 201610074338 A CN201610074338 A CN 201610074338A CN 105777209 B CN105777209 B CN 105777209B
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- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 121
- 238000002425 crystallisation Methods 0.000 title claims abstract description 53
- 230000008025 crystallization Effects 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 49
- 239000000919 ceramic Substances 0.000 claims abstract description 69
- 241000446313 Lamella Species 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims description 33
- 239000004744 fabric Substances 0.000 claims description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
- 210000003298 dental enamel Anatomy 0.000 claims description 26
- 239000000047 product Substances 0.000 claims description 23
- 238000010304 firing Methods 0.000 claims description 20
- 235000015895 biscuits Nutrition 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000011265 semifinished product Substances 0.000 claims description 15
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229910021532 Calcite Inorganic materials 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 9
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 9
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 9
- 239000010459 dolomite Substances 0.000 claims description 9
- 229910000514 dolomite Inorganic materials 0.000 claims description 9
- 239000010433 feldspar Substances 0.000 claims description 9
- 239000010436 fluorite Substances 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000004576 sand Substances 0.000 claims description 9
- 229910052845 zircon Inorganic materials 0.000 claims description 9
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004327 boric acid Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000003825 pressing Methods 0.000 claims description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- 238000004040 coloring Methods 0.000 claims description 6
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 5
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 5
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 5
- 239000000834 fixative Substances 0.000 claims description 5
- 239000010453 quartz Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 229960004643 cupric oxide Drugs 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000012216 screening Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 18
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 230000004927 fusion Effects 0.000 abstract description 4
- 239000002365 multiple layer Substances 0.000 abstract description 3
- 239000011449 brick Substances 0.000 description 13
- 239000002131 composite material Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 8
- 239000003317 industrial substance Substances 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 238000010791 quenching Methods 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 238000009966 trimming Methods 0.000 description 5
- 229910052788 barium Inorganic materials 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000005355 lead glass Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- -1 quartzy 18.8 parts Substances 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 241000984082 Amoreuxia Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000002419 bulk glass Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical group [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of glass-ceramic clad plate with border crystallization texture and preparation method thereof, which includes ceramic adobe, is compounded in the coloured ground glaze layer of ceramic adobe upper surface and the glass ceramics frit lamella of compound coloured ground glaze layer upper surface.The present invention is by preparing a kind of glass ceramics frit piece of new block polygon, utilize glass ceramics frit piece melt binding at high temperature, and in its appearance crystallization, form natural border texture, since semi-transparent state is presented in crystallization, and the inside of block polygon crystallite frit then remain on it is transparent glassy, under the fusion of this semi-transparent and multiple-layer overlapped of full impregnated, form colorful effect of shadow, translucency is greatly improved, so that the decorative art aesthetic feeling of glass-ceramic clad plate is lifted to a new height.
Description
Technical field
The present invention relates to Ceramic Tiles manufacturing technology field, more specifically to a kind of micro- with border crystallization texture
Crystal glass ceramic clad plate and preparation method thereof.
Background technology
Glass-ceramic clad plate be devitrified glass with Ceramic Tiles by once or double sintering be compounded in it is ceramics vitrified
The novel environment-friendly top-grade building ceramic tile that brick surface forms.Glass-ceramic clad plate combines vitrified tile and glass board material
Advantage, its mechanical strength is big, and impact resistance is good, and chemical resistance is high, completely not soil pick-up, and maintenance convenient for cleaning, its is wear-resisting
Property, case hardness, flexural strength etc. are superior to granite and marble.The crystallite glass of glass-ceramic clad plate at the same time
Glass deck structure is fine and close, crystal is uniform, clean mark, has dress glittering and translucent as gentle soft texture as beautiful matter and ice and snow
Effect is adornd, is one of modern building decoration building material product the most high-grade, is widely used in luxurious hotel, club, not
The high-end place such as villa.
In the production technology of existing glass-ceramic clad plate, the preparation of crystallite frit is all to enter to melt in powder
After being melted in block kiln, by water quenching, then dry, is broken, sieving is prepared into the little particle frit pellet that granularity is 6-30 mesh.So
The fine grain crystallite frit of 6-30 mesh is carried out to cloth on ceramic body surface afterwards, semi-finished product are made into burning till in roller kilns,
Glass-ceramic clad plate finished product is made by process such as polishing, sortings in last semi-finished product.
Glass-ceramic clad plate product currently on the market is melted by the fine grained of the 6-30 mesh sizes after water quenching
What block was prepared, what 6-30 mesh fine grained frits can produce 10-30% in the process such as broken, sieving is less than 30 mesh
Frit fine powder, these frit fine powder materials can pollute environment, or even cannot recycle, and cause great waste.And
6-30 mesh fine grained water quenching frit causes that crystallite frit crystallization when burning till is more, and decorative pattern is small, causes since particle is small, interface
The translucency of product glass-ceramic layer is poor, and texture effect is not notable enough.
The content of the invention
The technical problem to be solved in the present invention is, is melted for crystallite existing for present glass-ceramic clad plate product
Block crystallization is excessive, and decorative pattern is small, the defects of causing product permeability poor, there is provided it is a kind of it is with brand-new texture and texture, with side
The glass-ceramic clad plate of boundary's crystallization texture.The present invention is melted by preparing a kind of devitrified glass of new block polygon
Block piece, using glass ceramics frit piece melt binding at high temperature, and in its appearance crystallization, forms natural border texture,
Since crystallization is presented semi-transparent state, and the inside of block polygon crystallite frit then remain on it is transparent glassy, at this
Under the semi-transparent fusion with the multiple-layer overlapped of full impregnated of kind, colorful effect of shadow is formed, translucency is greatly improved, so that crystallite
The decorative art aesthetic feeling of glass ceramic composite boards is lifted to a new height.
The technical solution adopted by the present invention to solve the technical problems is：A kind of crystallite with border crystallization texture is provided
Glass ceramic composite boards, wherein, including ceramic adobe, be compounded in ceramic adobe upper surface coloured ground glaze layer and compound coloured bottom
The glass ceramics frit lamella of glaze layer upper surface.
Glass-ceramic clad plate of the present invention with border crystallization texture, wherein, the thickness of the ceramic adobe
Spend for 11.0-12.0mm, the thickness of the coloured ground glaze layer is 0.01-0.1mm, and the thickness of the glass ceramics frit lamella is
1.5-3.0mm。
The present invention also provides a kind of preparation method such as the above-mentioned glass-ceramic clad plate with border crystallization texture,
Include the following steps：
1) preparation of glass ceramics frit piece：Include the following steps：
1.1) dispensing：Dispensing, 5-25 parts of potassium feldspar, 5-30 parts of lithium feldspar, stone are carried out according to the component of following parts by weight
5-20 parts of English, 5-15 parts of aluminium oxide, 10-25 parts of dolomite, 5-15 parts of calcite, 5-12 parts of barium carbonate, 3-10 parts of zircon sand, boron
3-12 parts sour, 3-10 parts of fluorite；0-10 parts of coloring oxide；
1.2) it is melted：Each component in step 1.1) is melted at a temperature of 1450-1580 DEG C, obtains frit
Glass metal；
1.3) it is compressing：Frit glass metal made from step 1.2) is suppressed, it is more that bulk is made after then cooling down
The glass ceramics frit piece of side shape；
2) preparation of the biscuit of ceramics with coloured ground-coat enamel：By conventional ceramic powder pressing into adobe, and it is dried, Shi Yi
The coloured ground-coat enamel of layer strong covering power, subsequently into being fired in roller kilns, is made the ceramic adobe with color ground-coat enamel, stand-by；
3) cloth of glass ceramics frit piece：One made from surface charity step 1) in ceramic adobe prepared by step 2)
The glass ceramics frit piece of kind or a variety of different colours, obtains the Ceramic Tiles of the good glass ceramics frit piece of cloth；
4) it is fired into finished product：By Ceramic Tiles made from step 3), spray fixative and be fixed, be again introduced into roller kilns
Burnt till, semi-finished product are made, then polish, sorted and packaged is compound up to the devitrified glass ceramics with border crystallization texture
Plate.
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
1) coloring oxide is one kind in cerium oxide, titanium oxide, chromium oxide, cupric oxide, iron oxide, manganese oxide, nickel oxide.
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
1) in the size of the obtained glass ceramics frit piece be the length of side be 5-50mm, thickness 1-10mm.
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
2) enter in roller kilns and fire, the temperature range of firing is 1150-1200 DEG C, and firing time is 50-100 minutes.
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
2) water absorption rate of obtained ceramic adobe is 0.02-0.12% in, and flatness is (- 1.0)-(+1.5) mm.
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
2) color of coloured ground-coat enamel described according to the color of the glass ceramics frit piece come select white, yellow, green, it is orange in
One kind.
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
3) the cloth doses of the glass ceramics frit piece of charity is 8-15Kg/m in2。
The preparation method of glass-ceramic clad plate of the present invention with border crystallization texture, wherein, step
4) burnt till described in roller kilns, the temperature burnt till is 1100-1150 DEG C, and firing time is 90-150 minutes.
Implement glass-ceramic clad plate with border crystallization texture of the present invention and preparation method thereof, have following
Beneficial effect：
(1) present invention utilizes the devitrified glass by preparing a kind of glass ceramics frit piece of new block polygon
Frit piece melt binding at high temperature, and in its appearance crystallization, natural border texture is formed, since semi-transparent shape is presented in crystallization
State, and the inside of block polygon crystallite frit then remain on it is transparent glassy, in this semi-transparent and multilayer weight of full impregnated
Under folded fusion, colorful effect of shadow is formed, translucency is greatly improved, so that the decoration of glass-ceramic clad plate
Aesthetic is lifted to a new height；
(2) further, since frit piece used in the present invention does not use traditional water quenching, drying, crushing procedure,
This undoubtedly saves the energy consumption with water, drying course of water quenching process, reduces dust pollution caused by shattering process, frit
Utilization rate reaches more than 99%, is a kind of environmentally protective new process, new technology.
Brief description of the drawings
Below in conjunction with accompanying drawings and embodiments, the invention will be further described, in attached drawing：
Fig. 1 is the surface texture design sketch of the microcrystallite glass-ceramic composite brick prepared by presently preferred embodiments of the present invention；
Fig. 2 is close-up schematic view in Fig. 1；
Fig. 3 is the surface texture of another angle of the microcrystallite glass-ceramic composite brick prepared by presently preferred embodiments of the present invention
Design sketch；
Fig. 4 is the enlarged diagram of a-quadrant in Fig. 3；
Wherein, 1, glass ceramics frit lamella；2nd, coloured ground glaze layer；3rd, ceramic adobe；4th, transparent region；5th, devitrified glass
Frit piece crystallization boundary lines；6th, the semi-transparent region of crystallization.
Embodiment
In the following, with reference to attached drawing and embodiment, the present invention is described further：
As shown in Figs 1-4, a kind of glass-ceramic clad plate with border crystallization texture, it is characterised in that including
The devitrified glass of ceramic adobe 1, the coloured ground glaze layer 2 for being compounded in ceramic adobe upper surface and compound coloured ground glaze layer upper surface melts
Block piece layer 3.Wherein, the thickness of the ceramic adobe is 11.0-12.0mm, and the thickness of the coloured ground glaze layer is 0.01-
0.1mm, the thickness of the glass ceramics frit lamella is 1.5-3.0mm.
The present invention utilizes the glass ceramics frit by preparing a kind of glass ceramics frit piece of new block polygon
Piece melt binding at high temperature, and in its appearance crystallization, forming natural border texture, (glass ceramics frit piece is analysed in such as Fig. 4
Shown in brilliant boundary lines 5), since semi-transparent state (as shown in the semi-transparent region 6 of crystallization in Fig. 4) is presented in crystallization, and it is block polygon
The inside of shape crystallite frit then remains on transparent glassy (as shown in transparent region 4 in Fig. 4), in this semi-transparent and full impregnated
Multiple-layer overlapped fusion under, form colorful effect of shadow, translucency is greatly improved, so that devitrified glass ceramics is compound
The decorative art aesthetic feeling of plate is lifted to a new height.
It is another object of the present invention to provide a kind of as the above-mentioned devitrified glass ceramics with border crystallization texture is answered
The preparation method of plywood, includes the following steps：
1) preparation of glass ceramics frit piece：Include the following steps：
1.1) dispensing：Dispensing, 5-25 parts of potassium feldspar, 5-30 parts of lithium feldspar, stone are carried out according to the component of following parts by weight
5-20 parts of English, 5-15 parts of aluminium oxide, 10-25 parts of dolomite, 5-15 parts of calcite, 5-12 parts of barium carbonate, 3-10 parts of zircon sand, boron
3-12 parts sour, 3-10 parts of fluorite；0-10 parts of coloring oxide；The coloring oxide is coloured oxide, such as cerium oxide, oxygen
Change one kind in titanium, chromium oxide, cupric oxide, iron oxide, manganese oxide, nickel oxide, but be not limited to above-mentioned colored oxide.
1.2) it is melted：Each component in step 1.1) is melted at a temperature of 1450-1580 DEG C, obtains frit
Glass metal；
1.3) it is compressing：Frit glass metal made from step 1.2) is suppressed, it is more that bulk is made after then cooling down
The glass ceramics frit piece of side shape；Preferably, the size of the glass ceramics frit piece be the length of side be 5-50mm, thickness 1-
10mm。
2) preparation of the biscuit of ceramics with coloured ground-coat enamel：By conventional ceramic powder pressing into adobe, and it is dried, Shi Yi
The coloured ground-coat enamel of layer strong covering power, subsequently into being fired in roller kilns, the temperature range of firing is 1150-1200 DEG C, when burning till
Between be 50-100 minutes；The ceramic adobe with color ground-coat enamel is made, the water absorption rate of the ceramic adobe is 0.02-0.12%, smooth
Spend for (- 1.0)-(+1.5) mm, it is stand-by；Wherein coloured ground-coat enamel generally will be according to selected by glass-ceramic clad plate product
The color of glass ceramics frit piece selects corresponding color, frequently with color have a color and luster such as white, yellow, green, orange
Chromatic colour, by strengthening the background color of glass-ceramic layer, to lift the level of product and texture.
3) cloth of glass ceramics frit piece：Block made from surface charity step 1) in ceramic adobe prepared by step 2)
Shape polygon glass ceramics frit piece, wherein, during charity can a kind of color of cloth block polygon glass ceramics frit piece,
Can also the mixing of cloth a variety of different colours block polygon glass ceramics frit piece, the cloth doses of the glass ceramics frit piece is
8-15Kg/m2, obtain the Ceramic Tiles of the good glass ceramics frit piece of cloth；
4) it is fired into finished product：By Ceramic Tiles made from step 3), spray fixative and be fixed, be again introduced into roller kilns
To be burnt till, the temperature burnt till is 1100-1150 DEG C, and firing time is 90-150 minutes, and semi-finished product are made, then polish, point
Choosing is packed up to having the glass-ceramic clad plate of border crystallization texture.Fixative of the present invention is normal in industry
Fixative.
Embodiment 1
A kind of glass-ceramic clad plate with border crystallization texture, its preparation method are as follows：
1) preparation of water white transparency sheet-like crystallite frit：Glass ceramics frit preparation process routinely, selects good
8.2 parts of potassium feldspar, 20.6 parts of lithium feldspar, 12.5 parts of quartz, 6.5 parts of aluminium oxide, 20.5 parts of dolomite, 6.3 parts of calcite, carbonic acid
6.1 parts of 5.6 parts of barium, 6.4 parts of zircon sand, 7.3 parts of boric acid, fluorite industrial chemicals, prepare glass ceramics frit piece, will after dispensing
Raw material is melted at a temperature of 1520 DEG C, and the frit glass metal after being melted is flowed into molding die, is carried out to roller mould
Compressing, after supercooling, it is 5-12mm that the length of side, which is made, thickness 2.5mm, the devitrified glass of block polygon clear, colorless
Frit piece；
2) preparation of whiteware biscuit：By conventional ceramic powder pressing into adobe, and it is dried, applies one layer of covering power
Strong white ground-coat enamel, subsequently into being fired in roller kilns, firing temperature is 1195 DEG C, and firing time is 65 minutes, biscuit of ceramics
Water absorption rate be 0.06%, flatness be (- 0.3)-(+1.2) mm scopes, thickness 11.2mm, and the general of white ground-coat enamel is made
Logical biscuit of ceramics；
3) cloth of glass ceramics frit piece：By the block glass ceramics frit piece of the water white transparency prepared, pass through cloth
Expect equipment, apply the conventional ceramic biscuit surface for being distributed in white ground-coat enamel, cloth doses is 12Kg/m2；
4) finished product is made：By the ceramic body of the good water white transparency bulk crystallite frit piece of surface cloth, roller kilns are then fed into
In stove, burnt till.The maximum temperature burnt till is 1135 DEG C, and firing time is 140 minutes so that the edge of the micro- frit of sheet goes out
The crystallization of existing white, while sheet-like crystallite glass frit is fused into an entirety, and with ceramic body strong bonded, thus make
Into devitrified glass composite brick semi-finished product.Last semi-finished product are 14.2mm by polishing, trimming, finished product thickness, and background color is
White, the microcrystallite glass-ceramic composite brick finished product of the translucent bulk texture being interweaved with transparent part.
Embodiment 2
A kind of glass-ceramic clad plate with border crystallization texture, its preparation method are as follows：
1) preparation of yellow transparent sheet-like crystallite frit：Glass ceramics frit preparation process routinely, selects good
8.2 parts of potassium feldspar, 18.4 parts of lithium feldspar, 18.9 parts of quartz, 7.2 parts of aluminium oxide, 16.6 parts of dolomite, 7.5 parts of calcite, carbonic acid
The industrial chemicals such as 7.3 parts of barium, 4.6 parts of zircon sand, 5.7 parts of boric acid, 4.2 parts of fluorite, 0.6 part of cerium oxide, 0.8 part of titanium oxide, system
Standby glass ceramics frit piece, after dispensing, is melted, the frit glass metal after being melted flows into shaping at a temperature of 1530 DEG C
In mould, carry out compressing to roller mould, after cooling, it is 8-20mm that the length of side, which is made, thickness 3.5mm, and block polygon is shallow
The glass ceramics frit piece of yellow transparent；
2) preparation of light yellow biscuit of ceramics：By conventional ceramic powder pressing into adobe, and it is dried, applies one layer of covering
The strong yellow ground-coat enamel of power, subsequently into being fired in roller kilns, firing temperature is 1185 DEG C, and firing time is 72 minutes, and suction is made
Water rate is 0.058%, and flatness be (- 0.4)-(+1.3) mm, thickness for 11.5mm scopes commonly making pottery for light yellow ground-coat enamel
Porcelain biscuit；
3) cloth of glass ceramics frit piece：By the block glass ceramics frit piece of the yellow transparent prepared, pass through cloth
Expect equipment, apply the conventional ceramic biscuit surface for being distributed in yellow ground-coat enamel, cloth doses is 14.2Kg/m2。
4) finished product is made：By the ceramic body of the good yellow transparent bulk crystallite frit piece of surface cloth, roller kilns are then fed into
In stove, burnt till, the maximum temperature burnt till is 1140 DEG C, and firing time is 120 minutes so that the edge of the micro- frit of sheet goes out
Existing crystallization, while glass ceramics frit piece is fused into an entirety, and with ceramic body strong bonded, it is compound that devitrified glass is made
Brick semi-finished product.For last semi-finished product by polishing, trimming, it is 14.8mm that finished product thickness, which is made, background color be it is light yellow, it is translucent with
The yellow microcrystalline glass ceramics composite brick finished product for the bulk texture that transparent part is interweaved.
Embodiment 3
A kind of glass-ceramic clad plate with border crystallization texture, its preparation method are as follows：
1) preparation of green transparent sheet-like crystallite frit：Glass ceramics frit preparation process routinely, selects good
6.6 parts of potassium feldspar, 23.3 parts of lithium feldspar, 19.1 parts of quartz, 8.7 parts of aluminium oxide, 14.5 parts of dolomite, 5.6 parts of calcite, carbonic acid
The industrial chemicals such as 8.2 parts of barium, 3.6 parts of zircon sand, 5.1 parts of boric acid, 4.8 parts of fluorite, 0.5 part of chromium oxide, prepare devitrified glass and melt
Block piece, after dispensing, is melted at a temperature of 1530 DEG C, and the frit glass metal after being melted is flowed into molding die, is carried out
Compressing to roller mould, after cooling, it is 7-32mm that the length of side, which is made, thickness 2.2mm, block polygon greenish transparent it is micro-
Crystal glass frit piece；
By above-mentioned identical method, good 6.5 parts of potassium feldspar, 24.6 parts of lithium feldspar, quartzy 18.8 parts, aluminium oxide are selected
8.2 parts, 12.2 parts of dolomite, 5.8 parts of calcite, 6.7 parts of barium carbonate, 3.7 parts of zircon sand, 5.9 parts of boric acid, 5.5 parts of fluorite, oxygen
Change 0.6 part of copper, the industrial chemicals such as 1.5 parts of chromium oxide, prepare glass ceramics frit piece, after dispensing, at a temperature of 1530 DEG C into
Row is melted, and the frit glass metal after being melted is flowed into special molding die, is pressed, after cooling, the length of side is made
For 7-32mm, thickness 2.2mm, the transparent glass ceramics frit piece of bulk polygon bottle green is made；
2) preparation of light green color biscuit of ceramics：By conventional ceramic powder pressing into adobe, and it is dried, applies one layer of covering
The strong green ground-coat enamel of power, subsequently into being fired in roller kilns, firing temperature is 1195 DEG C, and firing time is 78 minutes, and suction is made
Water rate is 0.084%, and flatness is (- 0.4)-(+1.1) mm, and thickness the conventional ceramic biscuit of light green color ground-coat enamel for 11.8mm；
3) cloth of glass ceramics frit piece：The greenish transparent bulk glass ceramics frit piece and bottle green that will be prepared
Transparent cake glass ceramics frit piece presses 1：1 proportioning collocation mixing, by apparatus for distributing, applies and is distributed in the common of green ground-coat enamel
Biscuit of ceramics surface, cloth doses are 11.5Kg/m2；
4) finished product is made：By the ceramic body of the good green transparent bulk crystallite frit piece of surface cloth, roller kilns are then fed into
In stove, burnt till, the maximum temperature burnt till is 1130 DEG C, and firing time is 145 minutes so that the side of the micro- frit of sheet green
There is crystallization in edge, while glass ceramics frit piece is fused into an entirety, and with ceramic body strong bonded, the micro- of green is made
Crystal glass composite brick semi-finished product.Last semi-finished product are by polishing, trimming, and it is 14.6mm that thickness, which is made, and background color is light green color, semi-transparent
The depth green of the bright bulk texture being interweaved with transparent part interacts the microcrystallite glass-ceramic composite brick finished product to shine.
Embodiment 4
A kind of glass-ceramic clad plate with border crystallization texture, its preparation method are as follows：
1) it is 5-12mm to utilize the length of side in embodiment 1, thickness 2.5mm, the crystallite glass of block polygon clear, colorless
Glass frit piece, and the length of side in embodiment 2 is 8-20mm, thickness 3.5mm, block polygon light yellow clear sheet-like crystallite
Glass frit come prepare background color for white；
2) ceramic body use in embodiment 1 white ground-coat enamel, thickness be the ceramic body of 11.2mm；
3) wherein the ratio of water white transparency sheet-like crystallite glass frit and the bright sheet-like crystallite glass frit of light yellow show is 1：
3.By apparatus for distributing, the conventional ceramic biscuit surface for being distributed in white ground-coat enamel is applied, cloth doses is 10.6Kg/m2；
4) by good yellow, the transparent cake crystallite frit piece matched somebody with somebody that has no use the ceramic body of surface cloth, it is then fed into roller way kiln
In, burnt till, the maximum temperature burnt till is 1135 DEG C, and firing time is 128 minutes so that the yellowish-white alternate crystallite of sheet melts
There is crystallization in the edge of block, while glass ceramics frit piece is fused into an entirety, and with ceramic body strong bonded, be made green
The devitrified glass composite brick semi-finished product of color.For last semi-finished product by polishing, trimming, obtained thickness is 14.0mm, and background color is white,
The yellowish-white alternate microcrystallite glass-ceramic composite brick finished product of the translucent bulk texture being interweaved with transparent part.
Embodiment 5
A kind of glass-ceramic clad plate with border crystallization texture, its preparation method are as follows：
1) preparation of coffee color transparent sheet-like crystallite frit：Glass ceramics frit preparation process routinely, selects good
21.3 parts of potassium feldspar, 5.2 parts of lithium feldspar, 10.6 parts of quartz, 8.4 parts of aluminium oxide, 15.2 parts of dolomite, 8.5 parts of calcite, carbonic acid
6.4 parts of barium, 3.6 parts of zircon sand, 5.8 parts of boric acid, 6.9 parts of fluorite, 1.0 parts of nickel oxide, iron oxide part 2.4,4.7 parts of manganese oxide etc.
Industrial chemicals, prepares glass ceramics frit piece, after dispensing, is melted at a temperature of 1560 DEG C, the frit glass after being melted
Liquid is flowed into molding die, carries out compressing to roller mould, and after cooling, it is 7-32mm, thickness 2.2mm that the length of side, which is made,
The glass ceramics frit piece of block polygon depth coffee color；
By above-mentioned identical method, good 23.4 parts of potassium feldspar, 5.1 parts of lithium feldspar, quartzy 8.6 parts, aluminium oxide are selected
9.8 parts, 16.8 parts of dolomite, 7.5 parts of calcite, 6.9 parts of barium carbonate, 5.0 parts of zircon sand, 5.9 parts of boric acid, 5.5 parts of fluorite, oxygen
Change 0.4 part of nickel, 1.8 parts of iron oxide, the industrial chemicals such as 3.3 parts of manganese oxide, prepare glass ceramics frit piece, after dispensing, block is made
The transparent glass ceramics frit piece of the shallow coffee color of shape polygon；
2) preparation of brown biscuit of ceramics：By conventional ceramic powder pressing into adobe, and it is dried, applies one layer of covering power
Strong brown ground-coat enamel, subsequently into being fired in roller kilns, firing temperature is 1190 DEG C, and the time is 68 minutes, and water absorption rate, which is made, is
0.086%, flatness is (- 0.5)-(+1.3) mm, thickness be 11.3mm the conventional ceramic biscuit of brown ground-coat enamel；
3) cloth of block glass ceramics frit piece：By the deep coffee color transparent cake glass ceramics frit piece prepared with it is shallow
Coffee color transparent cake glass ceramics frit piece presses 3：1 proportioning collocation mixing, by apparatus for distributing, applies and is distributed in brown ground-coat enamel
Conventional ceramic biscuit surface, cloth doses are 11.8Kg/m2；
4) finished product is made：By the ceramic body of the good deep coffee color of surface cloth and shallow coffee color transparent cake crystallite frit piece, then
It is sent into roller way kiln, is burnt till, the maximum temperature burnt till is 1145 DEG C, and firing time is 135 minutes so that sheet coffee color
There is crystallization in the edge of crystallite frit, while glass ceramics frit piece is fused into an entirety, and with ceramic body strong bonded,
The devitrified glass composite brick semi-finished product of coffee color are made.Last semi-finished product are by polishing, trimming, and finished product thickness is 14.5mm,
Background color is coffee color, and deep coffee, the shallow coffee color of the translucent bulk texture being interweaved with transparent part interact the micro- of superposition intertexture
Crystal glass ceramic composite brick finished product.
It will be apparent to those skilled in the art that technical solution that can be as described above and design, make other various
Corresponding change and deformation, and all these changes and deformation should all belong to the protection domain of the claims in the present invention
Within.
Claims (9)
- A kind of 1. preparation method of the glass-ceramic clad plate with border crystallization texture, it is characterised in that the crystallite glass Glass ceramic clad plate, including ceramic adobe, be compounded in the coloured ground glaze layer of ceramic adobe upper surface and be compounded in coloured ground glaze layer The glass ceramics frit lamella of upper surface；The preparation method specifically comprises the following steps：1）The preparation of glass ceramics frit piece：Include the following steps：1.1）Dispensing：Dispensing, 5-25 parts of potassium feldspar, 5-30 parts of lithium feldspar, quartz 5- are carried out according to the component of following parts by weight 20 parts, 5-15 parts of aluminium oxide, 10-25 parts of dolomite, 5-15 parts of calcite, 5-12 parts of barium carbonate, 3-10 parts of zircon sand, boric acid 3- 12 parts, 3-10 parts of fluorite；0-10 parts of coloring oxide；1.2）It is melted：By step 1.1）In each component be melted at a temperature of 1450-1580 DEG C, obtain frit glass Liquid；1.3）It is compressing：By step 1.2）Obtained frit glass metal is suppressed, and block polygon is made after then cooling down Glass ceramics frit piece；2）The preparation of biscuit of ceramics with coloured ground-coat enamel：By conventional ceramic powder pressing into adobe, and it is dried, applies one layer of screening The strong coloured ground-coat enamel of lid power, subsequently into being fired in roller kilns, is made the ceramic adobe with color ground-coat enamel, stand-by；3）The cloth of glass ceramics frit piece：In step 2）The surface charity step 1 of the ceramic adobe of preparation）It is obtained a kind of or The glass ceramics frit piece of a variety of different colours, obtains the Ceramic Tiles of the good glass ceramics frit piece of cloth；4）It is fired into finished product：By step 3）Obtained Ceramic Tiles, spray fixative and are fixed, and are again introduced into roller kilns and carry out Burn till, semi-finished product are made, then polish, sorted and packaged is up to the glass-ceramic clad plate with border crystallization texture.
- 2. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 1）Described in coloring oxide for cerium oxide, titanium oxide, chromium oxide, cupric oxide, iron oxide, manganese oxide, oxidation One kind in nickel.
- 3. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 1）In the obtained glass ceramics frit piece size be the length of side be 5-50mm, thickness 1-10mm.
- 4. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 2）Fired in middle entrance roller kilns, the temperature range of firing is 1150-1200 DEG C, firing time 50-100 Minute.
- 5. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 2）In the water absorption rate of obtained ceramic adobe be 0.02-0.12%, flatness is（-1.0） - （+1.5）mm.
- 6. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 2）Described in coloured ground-coat enamel color according to the color of the glass ceramics frit piece come select white, yellow, One kind in green, orange.
- 7. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 3）The cloth doses of the glass ceramics frit piece of middle charity is 8-15kg/m2。
- 8. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is, step 4）In burnt till in roller kilns, the temperature burnt till is 1100-1150 DEG C, and firing time is 90-150 point Clock.
- 9. the preparation method of the glass-ceramic clad plate according to claim 1 with border crystallization texture, it is special Sign is that the thickness of the ceramic adobe is 11.0-12.0mm, and the thickness of the coloured ground glaze layer is 0.01-0.1mm, described The thickness of glass ceramics frit lamella is 1.5-3.0mm.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708851A (en) * | 2013-12-21 | 2014-04-09 | 湖南立发釉彩科技有限公司 | Microcrystalline zirconium glaze and preparation technology of efficient microcrystalline zirconium glaze glass polishing powder thereof |
| CN104744077A (en) * | 2015-02-06 | 2015-07-01 | 佛山石湾鹰牌陶瓷有限公司 | Flaky frit microcrystallite glass ceramic composite plate and preparation method thereof |
| CN105218170A (en) * | 2015-09-17 | 2016-01-06 | 广东博德精工建材有限公司 | A kind of high-hardness, wearable exempts from polishing iron microcrystalline glass in series ceramic clad plate and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103708851A (en) * | 2013-12-21 | 2014-04-09 | 湖南立发釉彩科技有限公司 | Microcrystalline zirconium glaze and preparation technology of efficient microcrystalline zirconium glaze glass polishing powder thereof |
| CN104744077A (en) * | 2015-02-06 | 2015-07-01 | 佛山石湾鹰牌陶瓷有限公司 | Flaky frit microcrystallite glass ceramic composite plate and preparation method thereof |
| CN105218170A (en) * | 2015-09-17 | 2016-01-06 | 广东博德精工建材有限公司 | A kind of high-hardness, wearable exempts from polishing iron microcrystalline glass in series ceramic clad plate and preparation method thereof |
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