CN105777040B - Ceramic tile bond and preparation method thereof - Google Patents

Ceramic tile bond and preparation method thereof Download PDF

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Publication number
CN105777040B
CN105777040B CN201610203817.8A CN201610203817A CN105777040B CN 105777040 B CN105777040 B CN 105777040B CN 201610203817 A CN201610203817 A CN 201610203817A CN 105777040 B CN105777040 B CN 105777040B
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China
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parts
ceramic tile
tile bond
bentonite
ether
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CN105777040A (en
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胡岛蜻
孟安树
胡佳豪
杨文书
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CHONGQING CITY HUTE BUILDING MATERIALS Ltd Co
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CHONGQING CITY HUTE BUILDING MATERIALS Ltd Co
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/147Calcium sulfate hemi-hydrate with a specific crystal form beta-hemihydrate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of novel ceramic tile bond, the novel ceramic tile bond includes following components by weight:1.52 2.72 parts of 20 35 parts of cement, 25 30 parts of powdered whiting, 15 20 parts of plaster of Paris, 6 15 parts of bentonite, 9.6 12.5 parts of redispersable latex powder, 4.53 7.24 parts of polypropylene fibre, 2.12 4.53 parts of calcium formate, 3.26 5.63 parts of cellulose ether, 2.31 3.64 parts of starch ether, 1.26 2.68 parts of water reducer, 2.44 3.52 parts of defoamer and thixotropic lubricant.The ceramic tile bond cohesive force of the present invention is strong.Meanwhile, ceramic tile bond of the invention has excellent water-fast, heatproof, freeze-thaw resistance property, and service life is strong.

Description

Ceramic tile bond and preparation method thereof
Technical field
The present invention relates to building material field, and in particular to a kind of novel ceramic tile bond and preparation method thereof.
Background technology
Tile decorative surface system is one of the most frequently used decorative encasing in China's architectural engineering, has strong shock resistance, resistance to Long property is good, easy cleaning the features such as;But the puzzlement of several big persistent ailments such as also it is often accompanied with infiltration, hollowing, comes off.Make porcelain in the current country The conventional bonding of brick facing, pointing have:Neat slurry, cement mortar, ceramic tile bond, silica gel etc..Ceramic tile bond is The material of cementation, also referred to as binder for face brick or glue for tile are played between ceramic tile and metope, ground etc., by cement, Filler, polymer latex ramming material are equipped with multiple additives and uniformly formed through mechanical mixture.
The cohesive force of existing ceramic tile bond is weak, easily comes off.
The content of the invention
In view of this, it is an object of the invention to provide a kind of novel ceramic tile bond.The novel ceramic tile bond cohesive force By force.
To achieve the above object, the technical solution adopted by the present invention is as follows:
Novel ceramic tile bond, by weight including following components:20-35 parts of cement, 25-30 parts of powdered whiting, build Build 15-20 parts of gypsum, 6-15 parts of bentonite, 9.6-12.5 parts of redispersable latex powder, 4.53-7.24 parts of polypropylene fibre, first Sour calcium 2.12-4.53 parts, 3.26-5.63 parts of cellulose ether, 2.31-3.64 parts of starch ether, 1.26-2.68 parts of water reducer, froth breaking 1.52-2.72 parts of 2.44-3.52 parts of agent and thixotropic lubricant.
Further, the novel ceramic tile bond includes following components by weight:28 parts of cement, powdered whiting 27 Part, 18 parts of plaster of Paris, 12 parts of bentonite, 11.6 parts of redispersable latex powder, 5.85 parts of polypropylene fibre, calcium formate 3.33 Part, 4.45 parts of cellulose ether, 2.92 parts of starch ether, 1.98 parts of water reducer, 2.96 parts of defoamer and 2.12 parts of thixotropic lubricant.
The plaster of Paris is dihydrate gypsum thermal dehydration at a certain temperature, and it is levigate be made using β-semi-hydrated gypsum as The air hardening cementitious materials mainly constituted.Beta-type semi-hydrated gypsum production gypsum raw material be mainly the natural gypsum of sulfur acid calcium (again Claim gypsum) or the waste residue such as the chemical by-product and ardealite of sulfur acid calcium, fluorgypsum, boron gypsum, its chemical formula is CaSO4· 2H2O, also referred to as dihydrate gypsum.Natural dihydrate gypsum is calcined at different temperature and can obtain different gypsum kinds.Will be natural Dihydrate gypsum is heated under 107-170 DEG C of drying condition can obtain plaster of Paris.
The redispersable latex powder is the spray-dried rear powder formed of polymer emulsion, also referred to as dry powder glue.It is this Powder can be reduced into emulsion rapidly after contact with water, and keep and initial latex identical property, i.e., after moisture evaporation, this Planting film has high-flexibility, high-weatherability and the high-adhesion to various base materials.
The calcium formate is also referred to as formic acid calcium, and molecular formula is C2H204Ca, as feed addictive, it is adaptable to all kinds of animals, The effects such as with acidifying, mould proof, antibacterial, industrially it is also used for concrete, grout additive, the tanning of leather or as preservative Use.
The water reducer is a kind of under conditions of maintaining concrete slump constant, can reduce the coagulation of mixing water amount Native additive.Belong to anion surfactant mostly, there is lignosulfonates, naphthalene sulphonate formaldehyde polymer etc..Add mixed There is peptizaiton to cement granules after solidifying soil mixture, its workability can be improved, unit consumption of water is reduced, improve concrete mixing The mobility of thing;Or unit cement consumption is reduced, save cement.
Further, the particle diameter of the powdered whiting is 80-120 μm.The powdered whiting abbreviation coarse whiting, by natural carbon Hydrochlorate mineral such as calcite, marble, lime stone, which are ground, to be formed, and is conventional powdery inorganic filler, high, lazy with chemical purity Property it is big, be difficult that chemical reaction, heat endurance are good, do not decompose less than 400 DEG C, whiteness height, oil absorbency is low, index of refraction is low, matter is soft, Dry, without the crystallization water, small, nontoxic, the tasteless low wearing valve of hardness, odorless, good dispersion the advantages of.
Further, the bentonite by sodium bentonite and calcium-base bentonite according to quality proportioning 4-5:2-3 is mixed. The bentonite is the nonmetallic minerals using montmorillonite as main mineral constituent, and smectite structure is pressed from both sides by two silicon-oxy tetrahedrons The 2 of one layer of alumina octahedral composition:1 type crystal structure, due to montmorillonite structure cell formation layer structure exist it is some sun from Son, such as Cu, Mg, Na, K, and the effect of these cations and montmorillonite structure cell is very unstable, is easily partially or completely exchanged by other cations, Therefore with preferable ion exchangeable.Interlayer cation is Na+When claim sodium bentonite;Interlayer cation is Ca2+When claim calcium base Bentonite;Interlayer cation is H+When claim hydrogen-based bentonite (atlapulgite, natural bleaching soil-Emathlite);Interlayer cation Claim organobentonite during for organic cation.
Further, the fibre length of the polypropylene fibre is 6-9mm.The polypropylene fibre is obtained with propylene polymerization Isotactic polypropylene be raw material spin synthetic fibers.
Further, it is characterised in that the cellulose ether is hydroxyethyl ether cellulose or hydroxypropylcelluloether ether.
Further, the defoamer is aqueous alkyd resin class defoamer.
Further, the thixotropic lubricant is aluminium-magnesium silicate thixotropic lubricant.The thixotropic lubricant is added by special Work processing, it is adaptable to the powdery rheologic additive of mineral base (dry mash) system and paste system.Thixotropic lubricant is mainly For the performance of the improvement of application property, open hour and uniformity in cement based system, increase mortar, plaster, bottom ash, plaster The workability and sag resistance of mortar and adhesive, prevent self-leveling cement to be layered.
The second object of the present invention is the preparation method for providing the novel ceramic tile bond agent, and it is concretely comprised the following steps:
A. the cement of above-mentioned mass parts, powdered whiting, plaster of Paris and bentonite are put into mixer and stir 15-18 Minute;
B. the redispersable latex powder of above-mentioned mass parts is added in mixture described in step A and stirred 3-5 minutes;
C. the polypropylene fibre, cellulose ether and starch ether of above-mentioned mass parts are added in mixture obtained by step B and stirred Ground 4-7 minutes after 10-15 minutes;
D. the calcium formate of above-mentioned mass parts, defoamer, thixotropic lubricant and water reducer are sequentially added into the mixing after grinding Stirred 3-5 minutes in thing, produce the ceramic tile bond.
The present invention also aims to protect the novel ceramic tile bond viscous in concrete mortar metope and floor surface Tie the application in ceramic tile work progress.
The beneficial effects of the invention are as follows:
The novel ceramic tile bond cohesive force of the present invention is strong.Meanwhile, ceramic tile bond of the invention has excellent resistance to Water, heatproof, freeze-thaw resistance property, service life are strong.
Embodiment
Embodiment 1
Novel ceramic tile bond, consisting of:Powdered whiting 25kg, the plaster of Paris of cement 35kg, particle diameter for 120 μm 20kg, bentonite 6kg, redispersable latex powder 12.5kg, fibre length are 9mm polypropylene fibre 4.53kg, calcium formate 4.53kg, hydroxyethyl ether cellulose 5.63kg, starch ether 3.64kg, water reducer 1.26kg, aqueous alkyd resin class defoamer 3.52kg and aluminium-magnesium silicate thixotropic lubricant 1.52kg.
The bentonite is by sodium bentonite and calcium-base bentonite according to quality proportioning 4:3 mix.
The preparation method of the novel ceramic tile bond agent is:
A. cement, powdered whiting, plaster of Paris and bentonite are put into mixer and stirred 18 minutes;
B. redispersable latex powder is added in mixture described in step A and stirred 3 minutes;
C. polypropylene fibre, hydroxyethyl ether cellulose and starch ether are added in mixture obtained by step B and stirred 15 minutes Grind 4 minutes afterwards;
D. calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer are sequentially added and ground Stirred 3 minutes in mixture after mill, produce the ceramic tile bond.
Embodiment 2
Novel ceramic tile bond, consisting of:Powdered whiting 30kg, the plaster of Paris of cement 20kg, particle diameter for 80 μm 15kg, bentonite 15kg, redispersable latex powder 9.6kg, fibre length are 6mm polypropylene fibre 7.24kg, calcium formate 2.12kg, hydroxypropylcelluloether ether 3.26kg, starch ether 2.31kg, water reducer 2.68kg, aqueous alkyd resin class defoamer 2.44kg and aluminium-magnesium silicate thixotropic lubricant 2.72kg.
The bentonite is by sodium bentonite and calcium-base bentonite according to quality proportioning 5:2 mix.
The preparation method of the novel ceramic tile bond agent is:
A. cement, powdered whiting, plaster of Paris and bentonite are put into mixer and stirred 15 minutes;
B. redispersable latex powder is added in mixture described in step A and stirred 5 minutes;
C. polypropylene fibre, hydroxypropylcelluloether ether and starch ether are added in mixture obtained by step B and stirred 10 minutes Grind 7 minutes afterwards;
D. calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer are sequentially added and ground Stirred 5 minutes in mixture after mill, produce the ceramic tile bond.
Embodiment 3
Novel ceramic tile bond, consisting of:Powdered whiting 27kg, the plaster of Paris of cement 28kg, particle diameter for 100 μm 18kg, bentonite 12kg, redispersable latex powder 11.6kg, fibre length are 8mm polypropylene fibre 5.85kg, calcium formate 3.33kg, hydroxypropylcelluloether ether 4.45kg, starch ether 2.92kg, water reducer 1.98kg, aqueous alkyd resin class defoamer 2.96kg and aluminium-magnesium silicate thixotropic lubricant 2.12kg.
The bentonite is by sodium bentonite and calcium-base bentonite according to quality proportioning 4:2 mix.
The preparation method of the novel ceramic tile bond agent is:
A. cement, powdered whiting, plaster of Paris and bentonite are put into mixer and stirred 156 minutes;
B. redispersable latex powder is added in mixture described in step A and stirred 4 minutes;
C. polypropylene fibre, hydroxypropylcelluloether ether and starch ether are added in mixture obtained by step B and stirred 12 minutes Grind 6 minutes afterwards;
D. calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer are sequentially added and ground Stirred 4 minutes in mixture after mill, produce the ceramic tile bond.
Comparative example 1
Novel ceramic tile bond, consisting of:Powdered whiting 26kg, the plaster of Paris of cement 21kg, particle diameter for 84 μm 19kg, bentonite 7kg, redispersable latex powder 10.2kg, fibre length are 7mm polypropylene fibre 4.62kg, calcium formate 4.51kg, hydroxyethyl ether cellulose 3.45kg, starch ether 2.43kg, water reducer 1.36kg and aluminium-magnesium silicate thixotropic lubricant 1.68kg。
The bentonite is by sodium bentonite and calcium-base bentonite according to quality proportioning 5:3 mix.
The preparation method of the novel ceramic tile bond agent is:
A. cement, powdered whiting, plaster of Paris and bentonite are put into mixer and stirred 16 minutes;
B. redispersable latex powder is added in mixture described in step A and stirred 5 minutes;
C. polypropylene fibre, hydroxyethyl ether cellulose and starch ether are added in mixture obtained by step B and stirred 11 minutes Grind 5 minutes afterwards;
D. calcium formate, aluminium-magnesium silicate thixotropic lubricant and water reducer are sequentially added in the mixture after grinding and stirs 3 points Clock, produces the ceramic tile bond.
Comparative example 2
Novel ceramic tile bond, consisting of:Powdered whiting 29kg, the plaster of Paris of cement 33kg, particle diameter for 115 μm 19kg, bentonite 14kg, redispersable latex powder 12.4kg, fibre length are 8mm polypropylene fibre 7.19kg, calcium formate 2.18kg, hydroxypropylcelluloether ether 3.26-5.63kg, starch ether 3.57kg, water reducer 2.55kg, aqueous alkyd resin class froth breaking Agent 2.53kg and aluminium-magnesium silicate thixotropic lubricant 2.74kg.
The bentonite is by sodium bentonite and calcium-base bentonite according to quality proportioning 4:2 mix.
The preparation method of the novel ceramic tile bond agent is:
A. cement, powdered whiting, plaster of Paris and bentonite are put into mixer and stirred 17 minutes;
B. redispersable latex powder is added in mixture described in step A and stirred 3 minutes;
C. hydroxypropylcelluloether ether and starch ether are added into stirring in mixture obtained by step B to grind 6 minutes after 14 minutes;
D. by polypropylene fibre, calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer Sequentially add in the mixture after grinding and stir 4 minutes, produce the ceramic tile bond.
Comparative example 3
Ceramic tile is carried out with formula described in Publication No. CN104860601A application for a patent for invention embodiment 1 and conventional method It is prepared by binding agent.Specifically, a kind of ceramic tile bond, is by mass fraction ratio:60 parts of portland cement, 45 parts of quartz sand, carbon Sour 28 parts of calcium powder, 3 parts of redispersible latex powder, 0.8 part of polypropylene fibre, 2 parts of hydroxypropyl methyl cellulose ether, wood fibre 2 parts of element, 5 parts of desulfurated plaster, 3 parts of rubber powder.Said components are put into mixer and mixed 15 minutes, the ceramic tile is produced Binding agent.
Ceramic tile bond performance test
The porcelain prepared to embodiment 1-3 (being respectively experimental group 1-3) and comparative example 1-3 (being respectively control group 1-3) Tile adhesive carries out performance detection, and testing result is as shown in the table:
Thus prove, ceramic tile bond cohesive force of the invention is strong.Meanwhile, ceramic tile bond of the invention has excellent Water-fast, heatproof, freeze-thaw resistance property, service life are strong.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to skill of the invention Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover at this Among the right of invention.

Claims (9)

1. ceramic tile bond, it is characterised in that by weight including following components:20-35 parts of cement, powdered whiting 25-30 Part, 15-20 parts of plaster of Paris, 6-15 parts of bentonite, 9.6-12.5 parts of redispersable latex powder, polypropylene fibre 4.53-7.24 Part, 2.12-4.53 parts of calcium formate, 3.26-5.63 parts of cellulose ether, 2.31-3.64 parts of starch ether, 1.26-2.68 parts of water reducer, 1.52-2.72 parts of 2.44-3.52 parts of defoamer and thixotropic lubricant;The bentonite is pressed by sodium bentonite and calcium-base bentonite According to quality proportioning 4-5:2-3 is mixed.
2. ceramic tile bond according to claim 1, it is characterised in that by weight including following components:28 parts of cement, 27 parts of powdered whiting, 18 parts of plaster of Paris, 12 parts of bentonite, 11.6 parts of redispersable latex powder, 5.85 parts of polypropylene fibre, 3.33 parts of calcium formate, 4.45 parts of cellulose ether, 2.92 parts of starch ether, 1.98 parts of water reducer, 2.96 parts of defoamer and thixotroping lubrication 2.12 parts of agent.
3. ceramic tile bond according to claim 1, it is characterised in that the particle diameter of the powdered whiting is 80-120 μ m。
4. ceramic tile bond according to claim 1, it is characterised in that the fibre length of the polypropylene fibre is 6- 9mm。
5. ceramic tile bond according to claim 1, it is characterised in that the cellulose ether be hydroxyethyl ether cellulose or Hydroxypropylcelluloether ether.
6. ceramic tile bond according to claim 1, it is characterised in that the defoamer is aqueous alkyd resin class froth breaking Agent.
7. ceramic tile bond according to claim 1, it is characterised in that the thixotropic lubricant is aluminium-magnesium silicate thixotroping Lubricant.
8. the preparation method of the ceramic tile bond described in claim 1, it is characterised in that concretely comprise the following steps:
A. the cement of above-mentioned mass parts, powdered whiting, plaster of Paris and bentonite are put into mixer and stir 15-18 points Clock;
B. the redispersable latex powder of above-mentioned mass parts is added in mixture described in step A and stirred 3-5 minutes;
C. the polypropylene fibre, cellulose ether and starch ether of above-mentioned mass parts are added in mixture obtained by step B and stirs 10-15 Ground 4-7 minutes after minute;
D. the calcium formate of above-mentioned mass parts, defoamer, thixotropic lubricant and water reducer are sequentially added in the mixture after grinding Stirring 3-5 minutes, produces the ceramic tile bond.
9. the ceramic tile bond described in claim any one of 1-7 bonds ceramic tile construction in concrete mortar metope and floor surface During application.
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CN110028269A (en) * 2019-05-17 2019-07-19 郭保军 A kind of strength glue for tile essence
CN110683814A (en) * 2019-11-21 2020-01-14 江门大光明粘胶有限公司 Ceramic tile dry powder gum and preparation method thereof
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CN112062519A (en) * 2020-09-03 2020-12-11 北京华阳众信建材有限公司 High-weather-resistance ceramic tile binder and preparation method and construction method thereof
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CN104108917A (en) * 2014-06-19 2014-10-22 广东省建筑科学研究院 Low-alkalinity tile glue

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CN101182139A (en) * 2007-11-12 2008-05-21 华南理工大学 Masonry cement having higher strength and water retention
CN102153327A (en) * 2010-12-24 2011-08-17 上海大学 Ceramic tile adhesive
CN104108917A (en) * 2014-06-19 2014-10-22 广东省建筑科学研究院 Low-alkalinity tile glue

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