CN105766984A - Biocide of marine organisms - Google Patents
Biocide of marine organisms Download PDFInfo
- Publication number
- CN105766984A CN105766984A CN201610185884.1A CN201610185884A CN105766984A CN 105766984 A CN105766984 A CN 105766984A CN 201610185884 A CN201610185884 A CN 201610185884A CN 105766984 A CN105766984 A CN 105766984A
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- Prior art keywords
- alkyl
- biocide
- ammonium
- bromide
- ammonium salt
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds only one oxygen atom attached to the nitrogen atom
Abstract
The invention discloses a biocide of marine organisms. The biocide is prepared from the following components by mass percent: 20-60% of polyquaternium, 10-60% of hyamine, and the balance of water. A preparation method of the biocide comprises the following steps: dissolving the hyamine in the water, adding the polyquaternium while stirring, and sufficiently and evenly stirring after all the polyquaternium is added to obtain the biocide of the marine organisms. According to the biocide of the marine organisms, the polyquaternium and the hyamine are compounded to use, biological slime and biomass can be effectively stripped by aid of the fast permeation effect of single-molecule hyamine, and a better biocidal effect can be achieved as the active ingredients of the hyamine can act on biological tissues more effectively; in addition, as the polyquaternium is not apt to bubble, generation of bubbles can be reduced during use, and the good biocidal effect can be kept even when the sea water quality is heavily turbid.
Description
Technical field
The present invention relates to a kind of marine growth biocide.
Background technology
In recent years, along with expanding economy, China is newly-built many power plant in coastal area, and in order to save the water resource of preciousness, what many power plant all adopted is direct cooling technology.Direct cooling technology is the cooling technology that the current whole world is comparatively popularized, with sea water directly as cooling medium, complete after once cooling through heat-exchange apparatus, directly discharge, advantages such as there is water intaking temperature is low, good cooling results, system operational management are simple, but it is subject to seawater corrosion and sea organism attachment due to equipment, often affects the properly functioning of equipment.
The harm major embodiment of sea organism attachment is in the following areas: easily adhering to substantial amounts of marine organisms on the pipeline of cooling water system and heat transmission equipment, these marine growths can affect safe operation and the work efficiency of unit in varying degrees in system；nullThe ovum of marine growth、Larva can pour in sea water in mating period，Due to these marine organisms such as blue or green shellfish、Brown shellfish、Concha Ostreae、Barnacle、Bivalves、Angle a species of small clam living in fresh water and the same hydroid etc. of similar hay，All there is stronger adhesiveness，And like gregarious，Once there be small part biology to survive in systems，When suitable water temperature and nutritious，Understand breeding of quickly growing up in systems，Form substantial amounts of biocenose assemble and live in peace in system，The production run of generating set can be caused serious potential safety hazard，Once condenser tube is by toxicity bioassay，Cooling water inflow is not enough，Recirculated water inlet pressure is caused to increase，Enter、The pressure reduction of the port of export increases，Cooling effectiveness declines，Clean reaching to a certain degree to need afterwards to carry out half side isolation，Under bad working environments，Even can cause unit outage，Marine growth also can secrete substantial amounts of biological cement while growth attachment，Corrosion pipeline equipment，Reduce the heat exchanger effectiveness of condenser；Rotary sieve and circulating water pipeline also easily gather a large amount of green snail, barnacle etc., and cleaning work amount is very big, costly.Therefore, solve the infringement that causes of sea biological pollution, be once-though cooling technology a great problem in the urgent need to address.
At present, domestic and international sea biological pollution control technology is essentially all the method adopting physical control and Chemical Control to combine.Chemical control method is broadly divided into Electrolyzed sea water chlorination (or chlorate) and directly adds chemistry biocide two kinds.
U.S.'s backman Business Name is the marine growth biocide product of Bulab6002 is composite with 2-thiocyanomethylthio benzothiazole (TCMTB) with polyhexamethylene guanidine, and wherein polyquaternary ammonium salt plays the effect of killing livestock.The shortcoming being used alone polyquaternary ammonium salt is in that owing to its molecular weight is relatively large, poor permeability, when turbidity of sea water is higher, and meeting strong adsorption silt, produce flocculation, it is impossible to be applied to marine growth tissue, do not have effect of killing livestock.
Quaternary ammonium salt is unimolecule compound, has permeability strong, and energy rapid osmotic is to cell wall, and drug action is fast.Meanwhile, quaternary ammonium salt also has that toxicity is low, wide spectrum, the performance such as efficient, and bacterium algae mud is had release effect.Its shortcoming is in that it belongs to unimolecule structure, and cationic strength is low, and absorption affinity is not enough, and marine growth is easily replaced with sea water and made medicament free, and loses effect of killing livestock, it is easy to when developing immunity to drugs and use, foam is many etc..
Compared with quaternary ammonium salt, the cationic degree of polyquaternary ammonium salt is higher, absorption affinity is higher, better effects if of therefore killing livestock, and the zest of polyquaternary ammonium salt is low, the marine growth such as shellfish, barnacle can be made to adsorb enough medicaments in automatic situation, the macromolecule chain section of polyquaternary ammonium salt also can cover marine growth tissue surface, hinders marine growth to breathe, improves effect of killing livestock, and it is not easy to foaming, foundry loam is had stronger stripping and peptizaiton.
Summary of the invention
It is an object of the invention to provide a kind of marine growth biocide and preparation method thereof.
The technical solution used in the present invention is:
A kind of marine growth biocide, its composition is by mass percentage:
Polyquaternary ammonium salt: 20～60%；
Quaternary ammonium salt: 10～60%；
Water: surplus.
Described polyquaternary ammonium salt is at least one in poly (hexamethylene) hydrochloride, hexamethylene, polyoxyethylene groups halo diformazan imonium, PDDA, poly dimethyl allyl ammonium bromide.
The structural formula of described polyoxyethylene groups halo diformazan imonium is shown below:
,
In formula, n is the natural number of 4～15, and X is Cl or Br.
nullDescribed quaternary ammonium salt is C8～C12 zephiran、C8～C12 alkyl dimethyl ethyl ammonium chloride、C8～C12 alkyl dioctyl benzyl ammonium chloride、C8～C12 alkyl didecyl benzyl ammonium chloride、The double; two dodecylbenzyl ammonium chloride of C8～C12 alkyl、C8～C12 alkyl octyl-decyl benzyl ammonium chloride、C8～C12 alkyl dioctyl Benzylphosphonium Bromide ammonium、C8～C12 alkyl didecyl Benzylphosphonium Bromide ammonium、The double; two dodecylbenzyl ammonium bromide of C8～C12 alkyl、C8～C12 alkyl octyl-decyl Benzylphosphonium Bromide ammonium、Double-track suspended self-propelled conveyor、Double; two dodecyl dimethyl ammonium chloride、Octyl decyl dimethyl ammonium chloride、Bisoctyl dimethyl ammonium bromide、Double; two decyl dimethyl ammonium bromide、Didodecyldimethylammbromide bromide、Octyl decyl dimethyl ammonium bromide、Double; two (dodecyl dimethyl) the ethylene diammonium of bromination、2-(2-phenoxy group) at least one in ethyl-trimethyl salmiac.
The preparation method of above-mentioned marine growth biocide, comprises the following steps: quaternary ammonium salt is first dissolved in water, then adds polyquaternary ammonium salt while stirring, stir, obtain marine growth biocide after adding.
The invention has the beneficial effects as follows: the marine growth biocide of the present invention is by by composite to polyquaternary ammonium salt and quaternary ammonium salt use, the rapid osmotic effect of quarternium salt can be utilized, it is effectively peeled off biological clay and biomass, make polyquaternary ammonium salt active component significantly more efficient can act on biological tissue, play effect of better killing livestock, and polyquaternary ammonium salt is not easy to foaming, foam can be reduced during use and produce, when the seawater quality of higher turbidity, remain to keep good effect of killing livestock.
Accompanying drawing explanation
Fig. 1 is the effect contrast figure that kills livestock of the biocide of embodiment 1 and comparative example 1～3.
Detailed description of the invention
A kind of marine growth biocide, its composition is by mass percentage:
Polyquaternary ammonium salt: 20～60%；
Quaternary ammonium salt: 10～60%；
Water: surplus.
Preferably, a kind of marine growth biocide, its composition is by mass percentage:
Polyquaternary ammonium salt: 20～50%；
Quaternary ammonium salt: 10～30%；
Water: surplus.
Preferably, described polyquaternary ammonium salt is at least one in poly (hexamethylene) hydrochloride, hexamethylene, polyoxyethylene groups halo diformazan imonium, PDDA, poly dimethyl allyl ammonium bromide.
Preferably, the structural formula of described polyoxyethylene groups halo diformazan imonium is shown below:
,
In formula, n is the natural number of 4～15, and X is Cl or Br.
nullPreferably，Described quaternary ammonium salt is C8～C12 zephiran、C8～C12 alkyl dimethyl ethyl ammonium chloride、C8～C12 alkyl dioctyl benzyl ammonium chloride、C8～C12 alkyl didecyl benzyl ammonium chloride、The double; two dodecylbenzyl ammonium chloride of C8～C12 alkyl、C8～C12 alkyl octyl-decyl benzyl ammonium chloride、C8～C12 alkyl dioctyl Benzylphosphonium Bromide ammonium、C8～C12 alkyl didecyl Benzylphosphonium Bromide ammonium、The double; two dodecylbenzyl ammonium bromide of C8～C12 alkyl、C8～C12 alkyl octyl-decyl Benzylphosphonium Bromide ammonium、Double-track suspended self-propelled conveyor、Double; two dodecyl dimethyl ammonium chloride、Octyl decyl dimethyl ammonium chloride、Bisoctyl dimethyl ammonium bromide、Double; two decyl dimethyl ammonium bromide、Didodecyldimethylammbromide bromide、Octyl decyl dimethyl ammonium bromide、Double; two (dodecyl dimethyl) the ethylene diammonium of bromination、2-(2-phenoxy group) at least one in ethyl-trimethyl salmiac.
Preferably, described " C8～C12 alkyl " is the alkyl containing 8～12 carbon atoms.
The preparation method of the marine growth biocide of corresponding above-mentioned formula or optimization formula, comprises the following steps: quaternary ammonium salt is first dissolved in water, then adds polyquaternary ammonium salt while stirring, stir, obtain marine growth biocide after adding.
Preferably, the preparation method of the marine growth biocide of corresponding above-mentioned formula or optimization formula, comprise the following steps: first quaternary ammonium salt is dissolved in water, then is slowly added to polyquaternary ammonium salt while stirring, continue stirring 20～30 minutes after adding, obtain marine growth biocide.
Below in conjunction with specific embodiment, the present invention is made further explanation and description.
Embodiment 1:
A kind of marine growth biocide, its composition is by mass percentage: poly (hexamethylene) hydrochloride: 20%；Double-track suspended self-propelled conveyor: 10%；Dodecyl dimethyl benzyl ammonium chloride: 20%；Surplus is water.
Embodiment 2:
A kind of marine growth biocide, its composition is by mass percentage: poly (hexamethylene) hydrochloride: 30%；Double-track suspended self-propelled conveyor: 7%；Dodecyl dimethyl benzyl ammonium chloride: 13%；Surplus is water.
Embodiment 3:
A kind of marine growth biocide, its composition is by mass percentage: polyoxyethylene groups chloro diformazan imonium: 50%；Didodecyldimethylammbromide bromide: 10%；Surplus is water.
Embodiment 4:
A kind of marine growth biocide, its composition is by mass percentage: polyoxyethylene groups chloro diformazan imonium: 20%；Bisoctyl dimethyl ammonium bromide: 10%；Dodecyl dimethyl benzyl ammonium chloride: 15%；Surplus is water.
Comparative example 1:
A kind of marine growth biocide, its composition is by mass percentage: poly (hexamethylene) hydrochloride: 60%；Surplus is water.
Comparative example 2:
A kind of marine growth biocide, its composition is by mass percentage: double-track suspended self-propelled conveyor: 60%；Surplus is water.
Comparative example 3:
A kind of marine growth biocide, its composition is by mass percentage: double-track suspended self-propelled conveyor: 20%；Dodecyl dimethyl benzyl ammonium chloride: 30%；Surplus is water.
Test case:
With blue or green mouth for experimental subject, adding consistency is 10ppm, and experimental water takes from the sea water in marine site, Hengqin, the effect of killing livestock of the biocide of detection embodiment 1 and comparative example 1～3, kills livestock Experimental Comparison result as shown in Figure 1.
As shown in Figure 1: polyquaternary ammonium salt and the composite biocide (embodiment 1 obtained of quaternary ammonium salt, working substance content 50%) although total working substance content reduces, but it is killed livestock, effect is better than independent polyquaternary ammonium salt biocide (comparative example 1, working substance content is 60%) and independent quaternary ammonium salt biocide (comparative example 2, working substance content 60%)；Composite biocide (the comparative example 3 obtained of quaternary ammonium salt, working substance content 50%) effect of killing livestock better than polyquaternary ammonium salt and quaternary ammonium salt Compositional type biocide at the beginning, but it is long-lasting poorer than polyquaternary ammonium salt and quaternary ammonium salt Compositional type biocide, is primarily due between polyquaternary ammonium salt and quaternary ammonium salt and there is synergistic function.
Above-described embodiment is the present invention preferably embodiment; but embodiments of the present invention are also not restricted to the described embodiments; the change made under other any spirit without departing from the present invention and principle, modification, replacement, combination, simplification; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (5)
1. a marine growth biocide, it is characterised in that: its composition is by mass percentage:
Polyquaternary ammonium salt: 20～60%；
Quaternary ammonium salt: 10～60%；
Water: surplus.
2. marine growth biocide according to claim 1, it is characterised in that: described polyquaternary ammonium salt is at least one in poly (hexamethylene) hydrochloride, hexamethylene, polyoxyethylene groups halo diformazan imonium, PDDA, poly dimethyl allyl ammonium bromide.
3. marine growth biocide according to claim 2, it is characterised in that: the structural formula of described polyoxyethylene groups halo diformazan imonium is shown below:
,
In formula, n is the natural number of 4～15, and X is Cl or Br.
null4. the marine growth biocide according to any one in claims 1 to 3，It is characterized in that: described quaternary ammonium salt is C8～C12 zephiran、C8～C12 alkyl dimethyl ethyl ammonium chloride、C8～C12 alkyl dioctyl benzyl ammonium chloride、C8～C12 alkyl didecyl benzyl ammonium chloride、The double; two dodecylbenzyl ammonium chloride of C8～C12 alkyl、C8～C12 alkyl octyl-decyl benzyl ammonium chloride、C8～C12 alkyl dioctyl Benzylphosphonium Bromide ammonium、C8～C12 alkyl didecyl Benzylphosphonium Bromide ammonium、The double; two dodecylbenzyl ammonium bromide of C8～C12 alkyl、C8～C12 alkyl octyl-decyl Benzylphosphonium Bromide ammonium、Double-track suspended self-propelled conveyor、Double; two dodecyl dimethyl ammonium chloride、Octyl decyl dimethyl ammonium chloride、Bisoctyl dimethyl ammonium bromide、Double; two decyl dimethyl ammonium bromide、Didodecyldimethylammbromide bromide、Octyl decyl dimethyl ammonium bromide、Double; two (dodecyl dimethyl) the ethylene diammonium of bromination、2-(2-phenoxy group) at least one in ethyl-trimethyl salmiac.
5. the preparation method of the marine growth biocide described in claim 4, it is characterised in that: comprise the following steps: first quaternary ammonium salt is dissolved in water, then adds polyquaternary ammonium salt while stirring, stir after adding, obtain marine growth biocide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610185884.1A CN105766984A (en) | 2016-03-28 | 2016-03-28 | Biocide of marine organisms |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610185884.1A CN105766984A (en) | 2016-03-28 | 2016-03-28 | Biocide of marine organisms |
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| CN105766984A true CN105766984A (en) | 2016-07-20 |
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| CN201610185884.1A Pending CN105766984A (en) | 2016-03-28 | 2016-03-28 | Biocide of marine organisms |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857659A (en) * | 2017-04-01 | 2017-06-20 | 江西凝盛生物科技有限公司 | A kind of thing table thimerosal of asepsis environment-protecting and preparation method thereof |
| CN111226929A (en) * | 2020-03-06 | 2020-06-05 | 吉林云飞医药有限公司 | Glutaraldehyde disinfectant, and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1377230A (en) * | 1999-11-16 | 2002-10-30 | 约翰逊商业贸易公司 | Fast acting disinfectant and cleaner |
| CN101548678A (en) * | 2009-05-06 | 2009-10-07 | 青岛天兰电力实业有限公司 | Highly efficient composite bactericidal algaecide and preparation method |
| CN101601409A (en) * | 2009-05-26 | 2009-12-16 | 兰州华星高科技开发有限公司 | Sterilization and alga-killing remover for circulating water |
| CN101637155A (en) * | 2009-08-26 | 2010-02-03 | 北京拓凯化工技术有限公司 | Bactericidal and algaecidal composition for intermediate water system, preparation method and application thereof |
| CN105129931A (en) * | 2015-07-06 | 2015-12-09 | 安徽省蓝天能源环保科技有限公司 | Bactericidal scale and corrosion inhibitor for seawater desalination |
| CN105165835A (en) * | 2015-10-15 | 2015-12-23 | 西安西热电站化学科技有限公司 | Ocean water once-through cooling system marine organism inhibitor and preparation method |
-
2016
- 2016-03-28 CN CN201610185884.1A patent/CN105766984A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1377230A (en) * | 1999-11-16 | 2002-10-30 | 约翰逊商业贸易公司 | Fast acting disinfectant and cleaner |
| CN101548678A (en) * | 2009-05-06 | 2009-10-07 | 青岛天兰电力实业有限公司 | Highly efficient composite bactericidal algaecide and preparation method |
| CN101601409A (en) * | 2009-05-26 | 2009-12-16 | 兰州华星高科技开发有限公司 | Sterilization and alga-killing remover for circulating water |
| CN101637155A (en) * | 2009-08-26 | 2010-02-03 | 北京拓凯化工技术有限公司 | Bactericidal and algaecidal composition for intermediate water system, preparation method and application thereof |
| CN105129931A (en) * | 2015-07-06 | 2015-12-09 | 安徽省蓝天能源环保科技有限公司 | Bactericidal scale and corrosion inhibitor for seawater desalination |
| CN105165835A (en) * | 2015-10-15 | 2015-12-23 | 西安西热电站化学科技有限公司 | Ocean water once-through cooling system marine organism inhibitor and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 张跃军等: "季铵盐杀生剂杀生性能与机理研究进展", 《精细化工》 * |
| 赵小芳等: "双季铵盐对海水中异养菌的杀菌性能及构效关系", 《工业水处理》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106857659A (en) * | 2017-04-01 | 2017-06-20 | 江西凝盛生物科技有限公司 | A kind of thing table thimerosal of asepsis environment-protecting and preparation method thereof |
| CN111226929A (en) * | 2020-03-06 | 2020-06-05 | 吉林云飞医药有限公司 | Glutaraldehyde disinfectant, and preparation method and application thereof |
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Application publication date: 20160720 |