CN105754508A - High-watertightness solar module edge-sealing adhesive tape - Google Patents

High-watertightness solar module edge-sealing adhesive tape Download PDF

Info

Publication number
CN105754508A
CN105754508A CN201610146163.XA CN201610146163A CN105754508A CN 105754508 A CN105754508 A CN 105754508A CN 201610146163 A CN201610146163 A CN 201610146163A CN 105754508 A CN105754508 A CN 105754508A
Authority
CN
China
Prior art keywords
adhesive tape
rubber
parts
adhesive
sealing adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610146163.XA
Other languages
Chinese (zh)
Other versions
CN105754508B (en
Inventor
徐孝平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cybrid Technologies Inc
Original Assignee
Cybrid Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cybrid Technologies Inc filed Critical Cybrid Technologies Inc
Priority to CN201610146163.XA priority Critical patent/CN105754508B/en
Publication of CN105754508A publication Critical patent/CN105754508A/en
Application granted granted Critical
Publication of CN105754508B publication Critical patent/CN105754508B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C09J123/22Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/322Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)
  • Sealing Material Composition (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a high-watertightness solar module edge-sealing adhesive tape, comprising a base material layer, a functional adhesive layer and a release material layer arranged in succession from top to bottom.The functional adhesive layer is formed by: dissolving rubber adhesive in an organic solvent to form a solution and applying the solution to the release material layer; the adhesive tape is characterized in that the rubber adhesive is made from the following components according to parts by weight: 80-120 parts of a main agent and 20-30 parts of a viscosifier, wherein the main agent at least comprises butyl rubber.Since the rubber adhesive in the middle functional adhesive layer uses the butyl rubber of high watertightness as the main agent, watertightness of the whole adhesive tape is greatly enhanced; in the adhesive tape compared with original acrylic foam adhesive, the adhesive layer formed by curing of butyl rubber is better in softness and application performance, and thereby, this adhesive layer is imparted same bonding force through only half of usage of original acrylic foam adhesive, helping reduce overall thickness of the adhesive tape.

Description

A kind of high water resistance solar components edge sealing adhesive tape
Technical field
The invention belongs to PSA technology field, be specifically related to a kind of high water resistance solar components edge sealing adhesive tape.
Background technology
Current solar components, for instance be designed with special edge sealing adhesive in all kinds of photovoltaic cell goods and bring reinforcement by connection glass edge.This kind of adhesive tape is all formed by multiple structure lamination, upper strata is substrate layer, lower floor is separated type material layer, acrylic foamed glue is used in centre, has the effect of the water that blocks water, but block-water effect is inconspicuous, and expanded material is thicker also harder, pasting property is bad, yielding after aging, and corner is easily protruding because of overlapping.
Summary of the invention
The problem to be solved in the present invention is: provide the better effects if of a kind of water that blocks water, flexibility and applicating property high water resistance solar components edge sealing adhesive tape more preferably.
For solving the problems referred to above, present invention provide the technical scheme that a kind of high water resistance solar components edge sealing adhesive tape, including the substrate layer set gradually from top to bottom, function glue-line and separated type material layer, described function glue-line be dissolved in organic solvent being formed rubber-like adhesive coat after solution separated type material layer solidifies after formed, it is characterized in that the composition of described rubber-like adhesive comprises by the following component of mass parts: host 80~120 parts and viscosifier 20~30 parts, wherein said host includes at least butyl rubber.
It is further preferred that heretofore described host is 100 parts, and viscosifier are 25 parts.
It is preferred that, heretofore described host also comprises rubber adjuvant, this rubber adjuvant be one or several in ethylene propylene diene rubber, buttress rubber, neoprene by the mixture of any mass ratio, and in described host, the mass percent of butyl rubber is 70~80%, and the mass percent of rubber adjuvant is 20~30%.
Further preferred, in heretofore described host, the mass percent of butyl rubber is 75%, and the mass percent of rubber adjuvant is 25%.
It is further preferred that heretofore described viscosifier are the mixture of one or more in Colophonium esters viscosifier (such as GB-100, GB-75), terpene phenol class viscosifier (such as T-803L) and Petropols class viscosifier (such as FTR6100).
It is further preferred that the thickness of heretofore described function glue-line is 50~100 μm.
The present invention does not do special restriction for the organic solvent of dissolving rubber class adhesive, for instance optional toluene, dimethylbenzene, dehydrated alcohol or ether etc..
The saturating rate WVTR < 8g/m of water of heretofore described function glue-line2.day, the saturating rate of water is more little shows that block-water performance and water seal characteristic are more good.
Heretofore described substrate layer can select the fluorine film of routine, PVC, PET film or various plastic alloy film, certainly the buffer insulation PVC film of preferred 100~400um thickness.
Heretofore described separated type material layer is conventional mould release membrance or release paper.
The invention have the advantage that
This adhesive tape provided by the invention is owing to the function glue line material in the middle of it is with the reasonable butyl rubber of block-water performance for host, therefore greatly strengthen the block-water performance that adhesive tape is overall, compare original acrylic foamed glue simultaneously, flexibility and the applicating property of the glue-line that butyl rubber is formed after solidifying are better, therefore this kind of glue-line reaches same adhesion strength and only needs the consumption of acrylic foamed glue half originally, contributes to the reduction of adhesive tape integral thickness.
2. the intermediate function glue-line of adhesive tape of the present invention is with butyl rubber for host, and resistance to ag(e)ing is better, and edge sealing uses not easily aging deformation after attaching, it is possible to the situation of projection occurs because of overlap to prevent solar components goods corner.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further, but is not limited to these embodiments.
Embodiment, this high water resistance solar components edge sealing adhesive tape provided by the invention is as the prior art, it is made up of the substrate layer (buffer insulation PVC film), function glue-line and the separated type material layer (mould release membrance) that set gradually from top to bottom, the present invention is mainly improved by function glue-line, function glue-line in this example be dissolved in toluene being formed rubber-like adhesive coat after solution separated type material layer solidifies after formed, each embodiment below gives the formula (mass parts meter) of rubber-like adhesive:
Embodiment 1. butyl rubber 100 parts, tackifying resin T-803L25 part, add toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, is transferred in the PVC base (buffer insulation PVC film) that thickness is 100 μm after drying, prepares adhesive tape product.
Embodiment 2. butyl rubber 75 parts, ethylene propylene diene rubber EPDM25 part, tackifying resin FTR610025 part, add toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, is transferred in the PVC base (buffer insulation PVC film) that thickness is 100 μm after drying, prepares adhesive tape product.
Embodiment 3. butyl rubber 75 parts, buttress rubber 25 parts, tackifying resin GB-10025 part, adding toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, it is transferred in the PVC base (buffer insulation PVC film) that thickness is 200 μm after drying, prepares adhesive tape product.
Embodiment 4. butyl rubber 75 parts, neoprene 25 parts, tackifying resin GB-7525 part, adding toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, it is transferred in the PVC base (buffer insulation PVC film) that thickness is 150 μm after drying, prepares adhesive tape product.
Embodiment 5. butyl rubber 75 parts, neoprene 15 parts, ethylene propylene diene rubber 10 parts, tackifying resin GB-7525 part, adding toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, it is transferred in the PVC base (buffer insulation PVC film) that thickness is 100 μm after drying, prepares adhesive tape product.
Embodiment 6. butyl rubber 75 parts, neoprene 15 parts, ethylene propylene diene rubber 10 parts, tackifying resin GB-7525 part, adding toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 100 μm, it is transferred in the PVC base (buffer insulation PVC film) that thickness is 400 μm after drying, prepares adhesive tape product.
Comparative example 1. butyl rubber 40 parts, neoprene 15 parts, ethylene propylene diene rubber 45 parts, tackifying resin GB-7525 part, adds toluene and is dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, is transferred in the PVC base of 100 μ m-thick after drying, prepares adhesive tape product.
Comparative example 2. butyl rubber 50 parts, buttress rubber 50 parts, tackifying resin GB-7525 part, add toluene and be dissolved into solution, on coating mould release membrance, dry glue thickness is 50 μm, is transferred in the PVC base of 100 μ m-thick after drying, prepares adhesive tape product.
It is presented herein below and above-mentioned concrete each embodiment and comparative example adhesive tape are carried out the performance test results sees following table:
Can be seen that from above table, in host in comparative example 1 and 2, the ratio of butyl rubber and rubber adjuvant is provided without this case and preferably limits scope, therefore it is compared with embodiment 1~6, initial peeling force, PCT/48h peeling force and double; two 85 peeling forces are all more weak, and water seal characteristic is poor, the experiment that warps after edge sealing is defective.
Examples detailed above only for technology design and the feature of the present invention are described, its object is to allow person skilled in the art be able to understand present disclosure and implement according to this, can not limit the scope of the invention with this.All equivalent transformations done according to spirit of the invention or modification, all should be encompassed within protection scope of the present invention.

Claims (8)

1. a high water resistance solar components edge sealing adhesive tape, including the substrate layer set gradually from top to bottom, function glue-line and separated type material layer, described function glue-line be dissolved in organic solvent being formed rubber-like adhesive coat after solution separated type material layer solidifies after formed, it is characterized in that the composition of described rubber-like adhesive comprises by the following component of mass parts: host 80~120 parts and viscosifier 20~30 parts, wherein said host includes at least butyl rubber.
2. a kind of high water resistance solar components edge sealing adhesive tape according to claim 1, it is characterised in that described host is 100 parts, and viscosifier are 25 parts.
3. a kind of high water resistance solar components edge sealing adhesive tape according to claim 1 and 2, it is characterized in that described host also comprises rubber adjuvant, this rubber adjuvant be one or several in ethylene propylene diene rubber, buttress rubber, neoprene by the mixture of any mass ratio, and in described host, the mass percent of butyl rubber is 70~80%, and the mass percent of rubber adjuvant is 20~30%.
4. a kind of high water resistance solar components edge sealing adhesive tape according to claim 3, it is characterised in that in described host, the mass percent of butyl rubber is 75%, and the mass percent of rubber adjuvant is 25%.
5. a kind of high water resistance solar components edge sealing adhesive tape according to claim 1, it is characterised in that described viscosifier are Colophonium esters viscosifier, terpene phenol class viscosifier and the mixture of one or more in Petropols class viscosifier.
6. a kind of high water resistance solar components edge sealing adhesive tape according to claim 1, it is characterised in that the thickness of function glue-line is 50~100 μm.
7. a kind of high water resistance solar components edge sealing adhesive tape according to claim 1 or 6, it is characterised in that the saturating rate WVTR < 8g/m of water of described function glue-line2.day。
8. a kind of high water resistance solar components edge sealing adhesive tape according to claim 1, it is characterised in that described substrate layer is the buffer insulation PVC film of 100~400um thickness.
CN201610146163.XA 2016-03-15 2016-03-15 A kind of high water resistance solar components edge sealing adhesive band Active CN105754508B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610146163.XA CN105754508B (en) 2016-03-15 2016-03-15 A kind of high water resistance solar components edge sealing adhesive band

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610146163.XA CN105754508B (en) 2016-03-15 2016-03-15 A kind of high water resistance solar components edge sealing adhesive band

Publications (2)

Publication Number Publication Date
CN105754508A true CN105754508A (en) 2016-07-13
CN105754508B CN105754508B (en) 2018-06-01

Family

ID=56332011

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610146163.XA Active CN105754508B (en) 2016-03-15 2016-03-15 A kind of high water resistance solar components edge sealing adhesive band

Country Status (1)

Country Link
CN (1) CN105754508B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366955A (en) * 2016-08-30 2017-02-01 无锡万能胶粘剂有限公司 Waterproof all-purpose adhesive
CN109504307A (en) * 2017-09-13 2019-03-22 苏州赛伍应用技术股份有限公司 It is a kind of to seal block water adhesive tape and its application

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110214797A1 (en) * 2004-03-03 2011-09-08 Jyoti Seth Three-dimensional reverse tanking membranes
CN104231975A (en) * 2014-08-21 2014-12-24 江苏华侃核电器材科技有限公司 Sealing adhesive tape material for third-generation nuclear power plant and preparation method of sealing adhesive tape material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110214797A1 (en) * 2004-03-03 2011-09-08 Jyoti Seth Three-dimensional reverse tanking membranes
CN104231975A (en) * 2014-08-21 2014-12-24 江苏华侃核电器材科技有限公司 Sealing adhesive tape material for third-generation nuclear power plant and preparation method of sealing adhesive tape material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366955A (en) * 2016-08-30 2017-02-01 无锡万能胶粘剂有限公司 Waterproof all-purpose adhesive
CN109504307A (en) * 2017-09-13 2019-03-22 苏州赛伍应用技术股份有限公司 It is a kind of to seal block water adhesive tape and its application
CN109504307B (en) * 2017-09-13 2022-05-24 苏州赛伍应用技术股份有限公司 Sealing water-blocking adhesive tape and application thereof

Also Published As

Publication number Publication date
CN105754508B (en) 2018-06-01

Similar Documents

Publication Publication Date Title
CN107815259A (en) A kind of compound foam heavy industry adhesive tape and preparation method thereof
US10640684B2 (en) Double coated tape exhibiting improved reworkable capability
CN1861727B (en) Release sheet and adhesive article
WO2009041581A1 (en) Solar cell rear surface sealing sheet and solar cell module using the same
CN113652177B (en) PU foam double-sided adhesive tape and preparation method thereof
CN104393081B (en) A kind of waterproof solar cell panel notacoria and preparation method thereof
CN105969228A (en) High-strength easy pull adhesive tape for batteries
CN105754508A (en) High-watertightness solar module edge-sealing adhesive tape
CN106675431A (en) Two-sided edge sealing adhesive tape arranged between upper glass and lower glass of solar double-glass assembly
CN103660653A (en) Digital inkjet material made from water-borne pressure sensitive adhesive
JP2011054743A (en) Adhesive sealing material for end of solar cell panel, sealing structure of end of the solar cell panel and sealing method, and solar cell module and method for manufacturing the module
CN206619603U (en) Adhesive waterproof tape and double-glass solar energy assembly
KR20160027440A (en) A double-sided Waterproof adhesive tape of 3-layer structure
CN206752942U (en) A kind of water-proof environment protection wood floor
CN202936357U (en) Composite flame-retardant double-sided adhesive tape
KR20130030965A (en) Improved asphalt waterproof sheets and insulation waterproofing method
CN205476208U (en) Concatenation formula fire prevention composite sheet
CN206232658U (en) A kind of antistatic silica gel diaphragm
CN208359616U (en) A kind of anti-exposure high viscosity protective film
CN203055956U (en) Coating type FPC-structure solar cell backboard
CN206204208U (en) A kind of two-sided tape
CN105679865A (en) Anti-aging back film used for solar photovoltaic panel
CN205774274U (en) A kind of antistatic saturating protecting film of diamagnetic scratch resistant height
CN205223086U (en) Double -deck ya keli net protection film of PET
KR102193541B1 (en) Adhesive water-proof tape having porous structure and methods for fabricating the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: 215200, Wujiang economic and Technological Development Zone, Suzhou, Jiangsu Province, No. 369, Hong Kong Road, Tianjin Road

Applicant after: Suzhou competition application technology Limited by Share Ltd

Address before: 215200, Wujiang economic and Technological Development Zone, Suzhou, Jiangsu Province, No. 369, Hong Kong Road, Tianjin Road

Applicant before: Suzhou Saiwu Application Technology Co., Ltd.

GR01 Patent grant
GR01 Patent grant