CN105749883A - Adsorbent for adsorbing harmful substances in cigarette smoke - Google Patents
Adsorbent for adsorbing harmful substances in cigarette smoke Download PDFInfo
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- CN105749883A CN105749883A CN201610180968.6A CN201610180968A CN105749883A CN 105749883 A CN105749883 A CN 105749883A CN 201610180968 A CN201610180968 A CN 201610180968A CN 105749883 A CN105749883 A CN 105749883A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/202—Polymeric adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses an adsorbent for adsorbing harmful substances in cigarette smoke. The adsorbent is prepared from raw materials in parts by weight as follows: 40-60 parts of lignin, 10-15 parts of tea seed powder, 4-6 parts of tea polyphenol, 20-30 parts of starch, 3-5 parts of chitosan, 10-20 parts of polyacrylamide, 5-10 parts of polyacrylic acid and 100-150 parts of water. The adsorbent prepared from the raw materials including the lignin, the tea seed powder, the tea polyphenol, the starch, the chitosan and the like can effectively remove harmful substances such as nicotine, tar, carbon monoxide and the like in cigarette smoke and has the advantages that the adsorbent performance is good, the cost is lower, the source of the raw materials is wide, the preparation process is simple, and the adsorbent can be degraded and the like. The removal rate of nicotine is 6.3% or above, the removal rate of tar is 5.8% or above, the removal rate of carbon monoxide is 4.9% or above, and the removal rate of benzopyrene is 5.7% or above after the adsorbent is applied to cigarettes.
Description
Technical field
The invention belongs to sorbing material technical field, specifically one and be used for adsorbing nicotine in cigarette gas, tar, an oxidation
The adsorbent of the harmful substances such as carbon.
Background technology
Smoking, to the breathing of human body, cardiovascular, stomach and intestine, nervous system and the organ such as liver, kidney, has the damage that degree is different
Evil.Long-term a large amount of smokings can cause multiple disease, and first reason such as lung cancer is exactly smoking, other some cancers of human body
Disease is as also closely related with smoking in cancer of the esophagus, carcinoma of urinary bladder, cancer of pancreas, colorectal cancer, laryngocarcinoma, lip cancer etc..Main being harmful in cigarette
Composition is the harmful substances such as nicotine, tar, carbon monoxide, benzene pyrene, along with the public pass day by day to the problem of " smoking is with healthy "
Note, and the development of global Tobacco Control campaign, the research and development of Less harmful cigarette product and production and sales have become tobacco row
The inexorable trend of industry development.Therefore, it is effectively reduced the content of harmful substance in tobacco cigarette gas, for reducing what smoking caused
Environmental pollution, protection smoker and surrounding population healthy, tool is of great significance.
At present, the filter tip material that China's tobacco business absorption nicotine uses is mainly two acetic acid (CA) cellulose and polypropylene
(PP) fiber.Obvious, the comfortable taste in Jiaozhuo drops in CA fiber, is suitable in medium-to-high grade cigarette using.But its raw material sources are limited,
Price is high, and complex manufacturing is seriously polluted, is difficult to biodegradable after using.PP fiber is cheap, stable chemical performance,
But owing to this material polarity is little, smooth surface, poor to the adsorption capacity of nicotine and tar relatively CA fiber in cigarette gas so that it is only
Can be used in low-grade cigarette.Therefore, developing low-cost, efficient novel nicotine adsorbent, it has also become the emphasis of current research.
Summary of the invention
The present invention is directed to the problem that existing adsorbent exists, it is provided that one is used for adsorbing nicotine in cigarette gas, tar, an oxygen
Changing the adsorbent of the harmful substance such as carbon, this adsorbent has that absorption property is good, cost is relatively low, raw material sources are extensive, preparation technology
Simply, the advantage such as degradable.
In order to realize object above, the technical solution used in the present invention is as follows:
A kind of adsorbent for adsorbing fragrant harmful substances from flue gases, is made up of the raw material of following parts by weight: lignin 40-60
Part, tea seed powder 10-15 part, Tea Polyphenols 4-6 part, starch 20-30 part, shitosan 3-5 part, polyacrylamide 10-20 part, polypropylene
Acid 5-10 part and water 100-150 part.
Further, the above is for adsorbing the adsorbent of fragrant harmful substances from flue gases, former by following parts by weight
Material composition: 50 parts of lignin, 13 parts of tea seed powder, Tea Polyphenols 5 parts, starch 25 parts, shitosan 5 parts, polyacrylamide 18 parts, poly-third
Olefin(e) acid 8 parts and 120 parts of water.
Further, the above is for adsorbing the adsorbent of fragrant harmful substances from flue gases, former by following parts by weight
Material composition: 60 parts of lignin, 12 parts of tea seed powder, Tea Polyphenols 6 parts, starch 25 parts, shitosan 5 parts, polyacrylamide 18 parts, poly-third
Olefin(e) acid 8 parts and 135 parts of water.
The preparation method of a kind of adsorbent for adsorbing fragrant harmful substances from flue gases, comprises the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 200-300 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 20-30 minute under rotating speed is 300-500rpm, glued
Thick shape adsorbent；
(3) thick adsorbent uniformly being brushed the shaping body paper surface cigarette, forming thickness is 0.03-0.05mm's
Adsorption layer.
Compared with prior art, beneficial effects of the present invention:
1, the adsorbent that the present invention makes with raw materials such as quality, tea seed powder, Tea Polyphenols, starch, shitosans, it is possible to effectively remove perfume (or spice)
The harmful substance such as nicotine, tar, carbon monoxide in flue gas, this adsorbent has that absorption property is good, cost is relatively low, raw material sources are wide
The advantages such as general, preparation technology simple, degradable.
2, adsorbent of the present invention adds Tea Polyphenols and tea seed powder, more can effectively reduce the harmful substance of flue gas.
3, adsorbent of the present invention is applied in cigarette, and nicotine clearance reaches more than 6.3%, tar clearance reaches 5.8%
Above, carbon monoxide removal rate reach more than 4.9%, BaP clearance reaches more than 5.7%.Show through sensory evaluating smoking, add
Substantially the original fragrance of cigarette can be kept after adding adsorbent.
4, the preparation of adsorbent of the present invention is without high-temperature roasting, and it is excellent to have that technique is simple, it is low to consume energy, production efficiency is high etc.
Point.
Detailed description of the invention
Below in conjunction with specific embodiment to the detailed description of the invention, but it is not limited to protection scope of the present invention.
Embodiment 1
A kind of adsorbent for adsorbing fragrant harmful substances from flue gases, is made up of the raw material of following parts by weight: 40 parts of lignin,
12 parts of tea seed powder, Tea Polyphenols 4 parts, starch 20 parts, shitosan 3 parts, polyacrylamide 10 parts, polyacrylic acid 7 parts and 100 parts of water.
Preparation method, comprises the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 200 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 30 minutes under rotating speed is 300rpm, obtain thick suction
Attached dose；
(3) thick adsorbent is uniformly being brushed the shaping body paper surface cigarette, forming the absorption that thickness is 0.03mm
Layer.
Embodiment 2
A kind of adsorbent for adsorbing fragrant harmful substances from flue gases, is made up of the raw material of following parts by weight: 45 parts of lignin,
10 parts of tea seed powder, Tea Polyphenols 4 parts, starch 22 parts, shitosan 4 parts, polyacrylamide 15 parts, polyacrylic acid 5 parts and 100 parts of water.
Preparation method, comprises the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 250 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 30 minutes under rotating speed is 350rpm, obtain thick suction
Attached dose；
(3) thick adsorbent is uniformly being brushed the shaping body paper surface cigarette, forming the absorption that thickness is 0.03mm
Layer.
Embodiment 3
A kind of adsorbent for adsorbing fragrant harmful substances from flue gases, is made up of the raw material of following parts by weight: 50 parts of lignin,
13 parts of tea seed powder, Tea Polyphenols 5 parts, starch 25 parts, shitosan 5 parts, polyacrylamide 18 parts, polyacrylic acid 8 parts and 120 parts of water.
Preparation method, comprises the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 300 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 20 minutes under rotating speed is 500rpm, obtain thick suction
Attached dose；
(3) thick adsorbent is uniformly being brushed the shaping body paper surface cigarette, forming the absorption that thickness is 0.02mm
Layer.
Embodiment 4
A kind of adsorbent for adsorbing fragrant harmful substances from flue gases, is made up of the raw material of following parts by weight: 55 parts of lignin,
15 parts of tea seed powder, Tea Polyphenols 5 parts, starch 30 parts, shitosan 4 parts, polyacrylamide 20 parts, polyacrylic acid 10 parts and 150 parts of water.
Preparation method, comprises the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 250 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 25 minutes under rotating speed is 350rpm, obtain thick suction
Attached dose；
(3) thick adsorbent is uniformly being brushed the shaping body paper surface cigarette, forming the absorption that thickness is 0.01mm
Layer.
Embodiment 5
A kind of adsorbent for adsorbing fragrant harmful substances from flue gases, is made up of the raw material of following parts by weight: 60 parts of lignin,
12 parts of tea seed powder, Tea Polyphenols 6 parts, starch 25 parts, shitosan 5 parts, polyacrylamide 18 parts, polyacrylic acid 8 parts and 135 parts of water.
Preparation method, comprises the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 200 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 30 minutes under rotating speed is 300rpm, obtain thick suction
Attached dose；
(3) thick adsorbent is uniformly being brushed the shaping body paper surface cigarette, forming the absorption that thickness is 0.03mm
Layer.
The forming paper that above example 1-5 has adsorption layer is applied on cigarette, wherein removes nicotine, Jiao in cigarette gas
Oil, carbon monoxide and the effect of BaP, see table.
| Nicotine clearance (%) | Tar clearance (%) | Carbon monoxide removal rate (%) | BaP clearance (%) | |
| Embodiment 1 | 6.7 | 6.1 | 4.9 | 5.9 |
| Embodiment 2 | 6.3 | 5.8 | 5.3 | 5.7 |
| Embodiment 3 | 8.7 | 6.9 | 6.3 | 6.4 |
| Embodiment 4 | 7.2 | 6.5 | 5.6 | 6.8 |
| Embodiment 5 | 8.4 | 6.7 | 5.8 | 6.7 |
The above results shows, adsorbent of the present invention is applied in cigarette, and nicotine clearance reaches more than 6.3%, tar is removed
Rate reaches more than 5.8%, carbon monoxide removal rate reaches more than 5.8%, and BaP clearance reaches more than 5.7%.It is then passed through sense
Official smokes panel test and shows, substantially can keep the original fragrance of cigarette after adding this programme adsorbent.
Claims (4)
1. the adsorbent being used for adsorbing fragrant harmful substances from flue gases, it is characterised in that: by the raw material group of following parts by weight
Become: lignin 40-60 part, tea seed powder 10-15 part, Tea Polyphenols 4-6 part, starch 20-30 part, shitosan 3-5 part, polyacrylamide
10-20 part, polyacrylic acid 5-10 part and water 100-150 part.
The most according to claim 1 for adsorbing the adsorbent of fragrant harmful substances from flue gases, it is characterised in that: by following weight
The raw material composition of number: 50 parts of lignin, 13 parts of tea seed powder, Tea Polyphenols 5 parts, starch 25 parts, shitosan 5 parts, polyacrylamide
18 parts, polyacrylic acid 8 parts and 120 parts of water.
The most according to claim 1 for adsorbing the adsorbent of fragrant harmful substances from flue gases, it is characterised in that: by following weight
The raw material composition of number: 60 parts of lignin, 12 parts of tea seed powder, Tea Polyphenols 6 parts, starch 25 parts, shitosan 5 parts, polyacrylamide
18 parts, polyacrylic acid 8 parts and 135 parts of water.
The preparation method of a kind of adsorbent for adsorbing fragrant harmful substances from flue gases, its feature exists
In: comprise the following steps:
(1) lignin, tea seed powder, Tea Polyphenols, starch, shitosan, polyacrylamide and poly-third are weighed according to above parts by weight
Olefin(e) acid, adds pulverizer and is crushed to 200-300 mesh, obtain powder raw material；
(2) powder raw material is added mixer, add water, stir 20-30 minute under rotating speed is 300-500rpm, glued
Thick shape adsorbent；
(3) thick adsorbent uniformly being brushed the shaping body paper surface cigarette, forming thickness is 0.03-0.05mm's
Adsorption layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610180968.6A CN105749883A (en) | 2016-03-28 | 2016-03-28 | Adsorbent for adsorbing harmful substances in cigarette smoke |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610180968.6A CN105749883A (en) | 2016-03-28 | 2016-03-28 | Adsorbent for adsorbing harmful substances in cigarette smoke |
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| Publication Number | Publication Date |
|---|---|
| CN105749883A true CN105749883A (en) | 2016-07-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610180968.6A Pending CN105749883A (en) | 2016-03-28 | 2016-03-28 | Adsorbent for adsorbing harmful substances in cigarette smoke |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110192495A (en) * | 2019-06-27 | 2019-09-03 | 贵州省贵福菌业发展有限公司 | A kind of methods and applications using tobacco rod preparation oil tea mushroom culture medium |
| CN110813078A (en) * | 2019-11-26 | 2020-02-21 | 许达勇 | Nicotine decomposer and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5409021A (en) * | 1992-04-22 | 1995-04-25 | Safaev; Radzhab D. | Cigarette filter |
| CN1696401A (en) * | 2005-03-31 | 2005-11-16 | 玉溪红塔烟草(集团)有限责任公司 | Shaped paper with activated adsorption layer in use for filter plug of cigarette |
| CN101716492A (en) * | 2009-12-17 | 2010-06-02 | 云南恩典科技产业发展有限公司 | Antibacterial adsorbent selectively adsorbing nicotine and carbon monoxide in smoke and application in wrap paper thereof |
| CN101822425A (en) * | 2010-04-16 | 2010-09-08 | 云南正邦生物技术有限公司 | Preparation method of cigarette absorption type flavor compensation material |
| CN102499480A (en) * | 2011-10-10 | 2012-06-20 | 云南恩典科技产业发展有限公司 | Functional agent containing Pu-erh tea extracts and cigarette filter stick prepared with same |
| CN102987555A (en) * | 2012-12-14 | 2013-03-27 | 吴伟銮 | Method for manufacturing cigarette filters with tea seed powder |
-
2016
- 2016-03-28 CN CN201610180968.6A patent/CN105749883A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5409021A (en) * | 1992-04-22 | 1995-04-25 | Safaev; Radzhab D. | Cigarette filter |
| CN1696401A (en) * | 2005-03-31 | 2005-11-16 | 玉溪红塔烟草(集团)有限责任公司 | Shaped paper with activated adsorption layer in use for filter plug of cigarette |
| CN101716492A (en) * | 2009-12-17 | 2010-06-02 | 云南恩典科技产业发展有限公司 | Antibacterial adsorbent selectively adsorbing nicotine and carbon monoxide in smoke and application in wrap paper thereof |
| CN101822425A (en) * | 2010-04-16 | 2010-09-08 | 云南正邦生物技术有限公司 | Preparation method of cigarette absorption type flavor compensation material |
| CN102499480A (en) * | 2011-10-10 | 2012-06-20 | 云南恩典科技产业发展有限公司 | Functional agent containing Pu-erh tea extracts and cigarette filter stick prepared with same |
| CN102987555A (en) * | 2012-12-14 | 2013-03-27 | 吴伟銮 | Method for manufacturing cigarette filters with tea seed powder |
Non-Patent Citations (3)
| Title |
|---|
| 张晓阳等: "《纤维素生物质水解与应用》", 31 December 2012 * |
| 李和平等: "《精细化工工艺学》", 31 August 1997, 科学出版社 * |
| 潘祖仁: "《高分子化学》", 31 May 2007 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110192495A (en) * | 2019-06-27 | 2019-09-03 | 贵州省贵福菌业发展有限公司 | A kind of methods and applications using tobacco rod preparation oil tea mushroom culture medium |
| CN110813078A (en) * | 2019-11-26 | 2020-02-21 | 许达勇 | Nicotine decomposer and preparation method thereof |
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