CN105742675B - Membrane electrode and the fuel cell for including it - Google Patents
Membrane electrode and the fuel cell for including it Download PDFInfo
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- CN105742675B CN105742675B CN201610109351.5A CN201610109351A CN105742675B CN 105742675 B CN105742675 B CN 105742675B CN 201610109351 A CN201610109351 A CN 201610109351A CN 105742675 B CN105742675 B CN 105742675B
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- 239000012528 membrane Substances 0.000 title claims abstract description 54
- 239000000446 fuel Substances 0.000 title claims abstract description 31
- 239000003054 catalyst Substances 0.000 claims abstract description 163
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 34
- 238000009792 diffusion process Methods 0.000 claims abstract description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 3
- 238000011160 research Methods 0.000 abstract description 14
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 238000006731 degradation reaction Methods 0.000 abstract description 4
- 230000009467 reduction Effects 0.000 description 11
- 239000002699 waste material Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003570 air Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
This application provides a kind of membrane electrodes and the fuel cell for including it.The membrane electrode includes the cathode diffusion layer, cathode catalysis layer, proton membrane, anode catalyst layer and the anode diffusion layer that are sequentially stacked, cathod catalyst is provided in cathode catalysis layer, anode catalyst is provided in anode catalyst layer, wherein, using stacked direction as first direction, the direction vertical with first direction is second direction, in cathode catalysis layer the content of cathod catalyst second direction distribution and cathode-current density second direction distribution positive correlation；And/or the content of anode catalyst layer researches on anode catalysts second direction distribution and anodic current density second direction distribution positive correlation.The membrane electrode can solve the problems, such as the degradation of fuel cell caused by being uniformly distributed by catalyst.
Description
Technical field
This application involves chemical cell field, in particular to a kind of membrane electrode and the fuel cell for including it.
Background technology
Fuel cell is a kind of power generator that chemical energy is converted into electric energy using on-fuel mode, has environment friend
The advantages that good, safe and reliable and easily operated.Due to not limited by Carnot cycle, direct generation of electricity efficiency is hot up to 45%
Point alliance efficiency can be widely applied to the multiple fields such as stand-by power supply, distributed power station and automobile power up to more than 90%.Combustion
Expect that the type of battery is more, wherein, Proton Exchange Membrane Fuel Cells have that current density is big, specific power is high and can room temperature quickly open
The advantages such as dynamic, have very deep development potentiality.
But all there are the problem of poor-performing and relatively low service life substantially for fuel cell of the prior art.
Invention content
The main purpose of the application is to provide a kind of membrane electrode and includes its fuel cell, to solve in the prior art
The problem of poor-performing of fuel cell.
To achieve these goals, according to the one side of the application, a kind of membrane electrode is provided, above-mentioned membrane electrode includes
Cathode diffusion layer, cathode catalysis layer, proton membrane, anode catalyst layer and the anode diffusion layer being sequentially stacked, above-mentioned cathode catalysis layer
In be provided with cathod catalyst, be provided with anode catalyst in above-mentioned anode catalyst layer, wherein, using above-mentioned stacked direction as
One direction, the direction vertical with above-mentioned first direction are second direction, and above-mentioned cathod catalyst contains in above-mentioned cathode catalysis layer
Measure the distribution positive correlation of distribution and cathode-current density in second direction in above-mentioned second direction；It is and/or above-mentioned anode-catalyzed
In layer the content of above-mentioned anode catalyst above-mentioned second direction distribution and anodic current density above-mentioned second direction point
Cloth positive correlation.
Further, above-mentioned second direction is parallel with a line boundary line of above-mentioned membrane electrode, third direction and above-mentioned first
Direction is vertical, and above-mentioned third direction is vertical with above-mentioned second direction, and above-mentioned cathod catalyst contains in above-mentioned cathode catalysis layer
Measure the distribution positive correlation being distributed with above-mentioned cathode-current density in above-mentioned third direction in third direction.
Further, in above-mentioned cathode catalysis layer the content of above-mentioned cathod catalyst and above-mentioned cathode-current density into just
Than.
Further, above-mentioned second direction is parallel with a line boundary line of above-mentioned membrane electrode, third direction and above-mentioned first
Direction is vertical, and above-mentioned third direction is vertical with above-mentioned second direction, and above-mentioned cathod catalyst contains in above-mentioned anode catalyst layer
Measure the distribution positive correlation being distributed with above-mentioned anodic current density in above-mentioned third direction in third direction.
Further, in above-mentioned anode catalyst layer the content of above-mentioned anode catalyst and above-mentioned anodic current density into just
Than.
Further, between 1~100 μm of the thickness of above-mentioned anode catalyst layer, the thickness 1 of preferably above-mentioned cathode catalysis layer~
Between 100 μm.
Further, above-mentioned anode catalyst is Pt/C catalyst, and preferably above-mentioned cathod catalyst is Pt/C catalyst.
To achieve these goals, according to further aspect of the application, a kind of fuel cell is provided, the fuel cell
Including at least one membrane electrode, which is above-mentioned membrane electrode.
Using the technical solution of the application, point of the content of cathod catalyst and/or anode catalyst in a second direction
Cloth is uneven, and current density corresponding in second direction distribution positive correlation so that catalyst content and current density pair
The demand of catalyst forms appropriate matching, so not only can to avoid or alleviate due to catalyst content it is less caused by cause combustion
The problem of the problem of expecting the degradation of battery and service life reduction, and in the smaller position of corresponding current density, catalyst
It is less, so as to which the waste of catalyst will not be caused.
Description of the drawings
The accompanying drawings which form a part of this application are used for providing further understanding of the present application, and the application's shows
Meaning property embodiment and its explanation do not form the improper restriction to the application for explaining the application.In the accompanying drawings：
Fig. 1 shows the structure diagram of membrane electrode provided according to a kind of typical embodiment of the application；
Fig. 2 shows a kind of distribution schematic diagrams for the current density for implementing to provide；And
Fig. 3 shows a kind of distribution schematic diagram for the current density for implementing to provide.
Wherein, above-mentioned attached drawing is marked including the following drawings：
10th, cathode diffusion layer；20th, cathode catalysis layer；30th, proton membrane；40th, anode catalyst layer；50th, anode diffusion layer.
Specific embodiment
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.It is unless another
It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field
The identical meanings of understanding.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root
According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singulative
It is also intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet
Include " when, indicate existing characteristics, step, operation, device, component and/or combination thereof.
As background technology is introduced, fuel cell of the prior art relatively low is asked there are poor-performing and service life
Topic, the technical issues of in order to solve as above, applicant has carried out numerous studies to influencing fuel battery performance and the factor in service life,
And it has been surprisingly found that, kinetic current density (abbreviation current density) not only has relationship, but also with urging with the concentration of reaction gas
How much the dosage of agent has direct relation, and relationship therebetween directly affects performance and the service life of fuel cell.Herein
On the basis of, relationship of the present inventor between current density and catalyst amount has made intensive studies, and finds following
Rule：The amount of catalyst that the big position of current density needs is more, and the amount of catalyst that the small position of current density needs is few.But
It is that membrane electrode researches on anode catalysts layer of the prior art and the catalyst in cathode catalyst layer are equally distributed, if
According to the amount of the larger position setting catalyst of current density, for the small position of current density, the wave of catalyst will be led to
Take；If according to the amount of the smaller position setting catalyst of current density, for the big part of current density, since catalyst contains
It measures relatively low, and fuel battery performance is caused to be deteriorated and the problem of service life reduction.To solve the above-mentioned problems, present applicant proposes one
Kind membrane electrode is with including its fuel cell.
A kind of typical embodiment of the application provides a kind of membrane electrode, as shown in Figure 1, the membrane electrode includes folding successively
Cathode diffusion layer 10, cathode catalysis layer 20, proton membrane 30, anode catalyst layer 40 and the anode diffusion layer 50 put, cathode catalysis layer
Cathod catalyst is provided in 20, anode catalyst is provided in anode catalyst layer 40, wherein, using stacked direction as first party
It is second direction to, the direction vertical with first direction, the content of cathod catalyst is in second direction in cathode catalysis layer 20
It is distributed the distribution positive correlation in second direction with cathode-current density；And/or the content of 40 researches on anode catalysts of anode catalyst layer
Second direction distribution and anodic current density second direction distribution positive correlation.
In above-mentioned membrane electrode, there are three types of different situations for the content distribution of catalyst.In the first situation, only cathode
Cathode catalysis agent content in Catalytic Layer 20 second direction distribution and cathode-current density second direction distribution positive
It closes；In the second situation, only distribution and anode current of the content of 40 researches on anode catalysts of anode catalyst layer in second direction
Density is in the distribution positive correlation of second direction；In the third situation, distribution and cathode of the cathode catalysis agent content in second direction
Current density second direction distribution positive correlation, meanwhile, the content of anode catalyst is in the distribution of second direction and anode electricity
Current density is in the distribution positive correlation of second direction.
By taking the first above-mentioned situation as an example, point of cathode catalysis agent content in a second direction in cathode catalysis layer 20
Cloth is uneven, and is distributed positive correlation with the cathode-current density in second direction, that is to say, that the big position of cathode-current density
It puts, the content of catalyst is also more, and in this way in the violent position of gas reaction, the cathod catalyst of more content can ensure gas
The progress of precursor reactant is avoided the problem that or is alleviated due to the less caused degradation for causing fuel cell of cathode catalysis agent content
The problem of with service life reduction.In the smaller position of cathode-current density, catalyst is also less, reduces the wave for causing catalyst in this way
Take.
Similarly, the second situation and the third situation can also solve catalyst distribution it is uniform caused by catalyst waste,
The problem of poor-performing and service life reduction of battery.
Previously mentioned second direction is the direction vertical with first direction, and the practical direction is not that some is specific
Direction, it refers to all directions in the plane vertical with first direction.
In a kind of embodiment of the application, second direction is parallel with a line boundary line of membrane electrode, third direction and first party
To vertical, and third direction is vertical with second direction, and the content of cathod catalyst is not only in second direction in cathode catalysis layer 20
Distribution and cathode-current density in the distribution positive correlation of second direction, and exist in the distribution of third direction with cathode-current density
The distribution positive correlation of third direction.The size trend of the distribution of cathod catalyst and the distribution of cathode-current density is only needed upper
State in both direction it is consistent, can be solved in this way using simple catalyst distribution mode catalyst distribution it is uniform caused by
The problem of catalyst waste, the poor-performing of battery and service life reduction.
In order to enable the content of cathod catalyst and the distribution of cathode-current density in different directions are consistent, Jin Ergeng
Solve the problems, such as well catalyst distribution it is uniform caused by catalyst waste, the poor-performing of battery and service life reduction.The application
It is preferred that the content of cathod catalyst is directly proportional to cathode-current density in cathode catalysis layer 20, it is practical just to refer to cathod catalyst
Content is directly proportional in each direction to cathode-current density.
Similarly, catalyst waste, the poor-performing of battery and service life caused by further solution catalyst distribution is uniform
The problem of reduction.The preferred second direction of the application is parallel with a line boundary line of membrane electrode, and third direction is vertical with first direction,
And third direction is vertical with second direction, the distribution and anode of the content of 40 researches on anode catalysts of anode catalyst layer in third direction
Current density is in the distribution positive correlation of third direction.
The content distribution situation of anode catalyst can be combined with the content distribution situation of cathod catalyst, can also be single
Solely realize.Situation about individually occurring is distribution and cathode of the content of cathod catalyst in second direction in cathode catalysis layer 20
Current density is in the distribution positive correlation of second direction；And/or the content of 40 researches on anode catalysts of anode catalyst layer is in second direction
Distribution and anodic current density in the distribution positive correlation of second direction, the content of 40 researches on anode catalysts of anode catalyst layer exists
The distribution of third direction and anodic current density are in the distribution positive correlation of third direction.
With reference to situation there are two types of, Yi Zhongshi：The content of cathod catalyst is in point of second direction in cathode catalysis layer 20
Cloth and cathode-current density are in the distribution positive correlation of second direction；And/or the content of 40 researches on anode catalysts of anode catalyst layer exists
The distribution of second direction and anodic current density are in the distribution positive correlation of second direction, and cathod catalyst in cathode catalysis layer 20
Content third direction distribution and cathode-current density third direction distribution positive correlation, meanwhile, anode catalyst layer 40
The content of researches on anode catalysts third direction distribution and anodic current density third direction distribution positive correlation.
Another situation is：Distribution and cathode current of the content of cathod catalyst in second direction in cathode catalysis layer 20
Density is in the distribution positive correlation of second direction；And/or the content of 40 researches on anode catalysts of anode catalyst layer is in point of second direction
Cloth and anodic current density second direction distribution positive correlation, and in cathode catalysis layer 20 cathod catalyst content and cathode
Current density is directly proportional, and the content of 40 researches on anode catalysts of anode catalyst layer exists in the distribution of third direction with anodic current density
The distribution positive correlation of third direction.
Similarly, in order to enable the content of anode catalyst and the distribution of anodic current density in different directions are uniform
Cause, so preferably solve catalyst distribution it is uniform caused by catalyst waste, the poor-performing of battery and service life reduction ask
Topic.The content of 40 researches on anode catalysts of the application preferred anodes Catalytic Layer is directly proportional to anodic current density.Similary such anode
The content distribution situation of catalyst can be combined with the content distribution situation of cathod catalyst, can also be implemented separately.
Situation about individually occurring is：Distribution and cathode of the content of cathod catalyst in second direction in cathode catalysis layer 20
Current density is in the distribution positive correlation of second direction；And/or the content of 40 researches on anode catalysts of anode catalyst layer is in second direction
Distribution and anodic current density second direction distribution positive correlation.And the content of 40 researches on anode catalysts of anode catalyst layer with
Anodic current density is directly proportional.
With reference to appearance situation also there are two types of, and the combination of both of these case and the content of anode catalyst are
The combination of the distribution situation in three directions is identical, is just repeated no more herein.
In order to preferably control the content of catalyst so that the content of anode catalyst is preferably matched with anodic current density
It closes, and then avoids the waste of anode catalyst, avoid under the performance due to the less caused fuel cell of anode-catalyzed agent content
Drop and the problem of service life reduction, between 1~100 μm of the thickness of the application sun anode catalyst layer 40.
Similarly, in order to enable the content of cathod catalyst preferably coordinates with cathode-current density, the application is preferably cloudy
Between 1~100 μm of the thickness of pole Catalytic Layer 20.
What cathod catalyst in the application and anode catalyst can be applied in prior art fuel cell any urges
Agent, preferably Pt/C catalyst or other multicomponent catalysts, for example, the alloy of Pt and other metals.This field
Technical staff can select suitable cathod catalyst and anode catalyst according to actual conditions.
In a kind of embodiment of the application, above-mentioned anode catalyst is Pt/C catalyst.The catalytic effect of the catalyst compared with
It is good.
In another embodiment, cathod catalyst is Pt/C catalyst.Anode catalyst can be phase with cathod catalyst
Same catalyst or different catalyst.Those skilled in the art can select suitable catalysis according to actual conditions
Agent.
It is hydrogen and air by the reaction gas of membrane electrode in the another embodiment of the application, hydrogen and air slave phase
Equidirectional gas access respectively enters anode plate and cathode plate, then by diffusing into membrane electrode, fuel battery inside
Current density distribution situation is：Distance is follow-up gradually to increase to be smaller at 0 position (gas access position is corresponded on membrane electrode)
Greatly, as shown in Figure 2.In order to enable the content of catalyst preferably coordinates with the current density, the anode catalyst of corresponding position
And/or the content of cathod catalyst and current density positive correlation, that is to say, that anode catalyst and/or cathod catalyst contain
The variation tendency of amount is consistent with the plots changes of Fig. 2.
When carrying out membrane electrode preparation, it can design what is matched according to the distribution situation of current density when carrying out catalyst spraying
Quantity for spray, the quantitative relation of quantity for spray distribution can be identical with current density distribution situation, can also be according to fuel electricity
The response characteristic in pond and the difference of design make corresponding modification.
In another embodiment, the reaction gas by membrane electrode is hydrogen and air, and hydrogen is with air respectively from opposite two
The gas access of side enters anode plate and cathode plate, and the entrance of hydrogen is known as hydrogen inlet, and the entrance of air is known as air intake,
Hydrogen and air are by diffusing into membrane electrode, the current density distribution situation of fuel battery inside：As shown in figure 3, film is electric
It is smaller at extremely upper end positions corresponding with air intake (the maximum position of distance) with hydrogen inlet (distance is 0 position),
Centre position is larger.In order to enable the content of catalyst preferably coordinates with the current density, the anode catalyst of corresponding position
And/or the content of cathod catalyst and current density positive correlation, that is to say, that anode catalyst and/or cathode catalysis agent content
Variation tendency it is consistent with the plots changes of Fig. 3.
In order to adapt to above-mentioned figure current density distribution, when carrying out membrane electrode preparation, can press during catalyst spraying
The quantity for spray that distribution situation design according to current density matches, the quantitative relation of quantity for spray distribution can be with current density point
Cloth situation is identical, can also the response characteristic of fuel cell and the difference of design make corresponding modification.
In the application in another typical embodiment, a kind of fuel cell is provided, which is included at least
One membrane electrode, the membrane electrode are above-mentioned membrane electrode.
Cathod catalyst and/or anode catalyst in the cathode catalysis layer of membrane electrode in above-mentioned fuel cell contain
The distribution of amount is distributed in positive correlation on some direction or certain several direction with corresponding current density, in this way can to avoid or delay
Solution in the prior art the catalyst distribution in Catalytic Layer uniformly caused catalyst waste problem, deterioration of cell properties the problem of with
The problem of service life reduction of battery.
It can be seen from the above description that the application the above embodiments realize following technique effect：
1), the content of the cathod catalyst in the application and/or anode catalyst being unevenly distributed in a second direction,
And the distribution positive correlation of corresponding in second direction current density, in this way can to avoid or alleviate since catalyst content is less
The problem of the problem of degradation of caused cause fuel cell and service life reduction.In the smaller position of corresponding current density,
Catalyst is also less, will not cause the waste of catalyst in this way.
2), the fuel cell in the application includes above-mentioned membrane electrode, and catalyst waste problem is not tight in the fuel cell
Weight, and the better performances of the battery, last a long time.
The foregoing is merely the preferred embodiments of the application, are not limited to the application, for the skill of this field
For art personnel, the application can have various modifications and variations.It is all within spirit herein and principle, made any repair
Change, equivalent replacement, improvement etc., should be included within the protection domain of the application.
Claims (10)
1. a kind of membrane electrode, the membrane electrode includes the cathode diffusion layer (10), cathode catalysis layer (20), the proton membrane that are sequentially stacked
(30), anode catalyst layer (40) and anode diffusion layer (50) are provided with cathod catalyst in the cathode catalysis layer (20), described
Anode catalyst layer is provided with anode catalyst in (40), which is characterized in that and described using the stacked direction as first direction
The vertical direction of first direction is second direction, and the content of cathod catalyst is in second party described in the cathode catalysis layer (20)
To distribution and cathode-current density the second direction distribution positive correlation；And/or institute in the anode catalyst layer (40)
State the content of anode catalyst the second direction distribution and anodic current density the second direction distribution positive
It closes.
2. membrane electrode according to claim 1, which is characterized in that the second direction and a line circle of the membrane electrode
Line is parallel, and third direction is vertical with the first direction, and the third direction is vertical with the second direction, and the cathode is urged
The content of cathod catalyst described in change layer (20) is in the distribution of third direction and the cathode-current density in the third party
To distribution positive correlation.
3. membrane electrode according to claim 1, which is characterized in that cathod catalyst described in the cathode catalysis layer (20)
Content it is directly proportional to the cathode-current density.
4. membrane electrode according to claim 1, which is characterized in that the second direction and a line circle of the membrane electrode
Line is parallel, and third direction is vertical with the first direction, and the third direction is vertical with the second direction, and the anode is urged
The content of anode catalyst described in change layer (40) is in the distribution of third direction and the anodic current density in the third party
To distribution positive correlation.
5. membrane electrode according to claim 1, which is characterized in that anode catalyst described in the anode catalyst layer (40)
Content it is directly proportional to the anodic current density.
6. membrane electrode according to claim 1, which is characterized in that 1~100 μm of the thickness of the anode catalyst layer (40) it
Between.
7. membrane electrode according to claim 1, which is characterized in that 1~100 μm of the thickness of the cathode catalysis layer (20) it
Between.
8. membrane electrode according to claim 1, which is characterized in that the anode catalyst is Pt/C catalyst.
9. membrane electrode according to claim 1, which is characterized in that the cathod catalyst is Pt/C catalyst.
10. a kind of fuel cell, including at least one membrane electrode, which is characterized in that the membrane electrode is in claim 1 to 9
Any one of them membrane electrode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610109351.5A CN105742675B (en) | 2016-02-26 | 2016-02-26 | Membrane electrode and the fuel cell for including it |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610109351.5A CN105742675B (en) | 2016-02-26 | 2016-02-26 | Membrane electrode and the fuel cell for including it |
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| CN105742675A CN105742675A (en) | 2016-07-06 |
| CN105742675B true CN105742675B (en) | 2018-07-06 |
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| CN111463442A (en) * | 2020-04-13 | 2020-07-28 | 上海电气集团股份有限公司 | Catalyst layer, fuel cell membrane electrode and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101098009A (en) * | 2006-06-30 | 2008-01-02 | 比亚迪股份有限公司 | Method for activating membrane electrode of fuel cell |
| CN101212054A (en) * | 2006-12-31 | 2008-07-02 | 比亚迪股份有限公司 | Fuel cell membrane electrode and its preparation method |
| CN102082280A (en) * | 2011-01-04 | 2011-06-01 | 常州大学 | Membrane permeation electrode for electrochemical process |
| CN104852003A (en) * | 2014-02-17 | 2015-08-19 | 三星Sdi株式会社 | Polymer electrolyte membrane, membrane electrode assembly and fuel cell including the same |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070119905A (en) * | 2006-06-16 | 2007-12-21 | 삼성에스디아이 주식회사 | Membrane-electrode assembly for fuel cell and fuel cell system comprising same |
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- 2016-02-26 CN CN201610109351.5A patent/CN105742675B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101098009A (en) * | 2006-06-30 | 2008-01-02 | 比亚迪股份有限公司 | Method for activating membrane electrode of fuel cell |
| CN101212054A (en) * | 2006-12-31 | 2008-07-02 | 比亚迪股份有限公司 | Fuel cell membrane electrode and its preparation method |
| CN102082280A (en) * | 2011-01-04 | 2011-06-01 | 常州大学 | Membrane permeation electrode for electrochemical process |
| CN104852003A (en) * | 2014-02-17 | 2015-08-19 | 三星Sdi株式会社 | Polymer electrolyte membrane, membrane electrode assembly and fuel cell including the same |
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