CN105734960A - Mosquito repellent and anti-acarien socks and preparation method thereof - Google Patents
Mosquito repellent and anti-acarien socks and preparation method thereof Download PDFInfo
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- CN105734960A CN105734960A CN201610119488.9A CN201610119488A CN105734960A CN 105734960 A CN105734960 A CN 105734960A CN 201610119488 A CN201610119488 A CN 201610119488A CN 105734960 A CN105734960 A CN 105734960A
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- China
- Prior art keywords
- socks
- anophelifuge
- demodicid mite
- mite
- demodicid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000077 insect repellent Substances 0.000 title abstract 4
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 229920002334 Spandex Polymers 0.000 claims abstract description 8
- 239000004759 spandex Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- 159000000000 sodium salts Chemical class 0.000 claims description 16
- 230000000149 penetrating effect Effects 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 9
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 claims description 9
- 229940120146 EDTMP Drugs 0.000 claims description 8
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000007796 conventional method Methods 0.000 claims description 3
- 241000744766 Cymbopogon winterianus Species 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 239000004744 fabric Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 238000007493 shaping process Methods 0.000 abstract description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 13
- 238000012360 testing method Methods 0.000 description 10
- 244000032014 Java citronella Species 0.000 description 6
- 241001465754 Metazoa Species 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- 241000255925 Diptera Species 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 210000002683 foot Anatomy 0.000 description 3
- -1 methene Phosphonic acids Chemical class 0.000 description 3
- 210000003371 toe Anatomy 0.000 description 3
- 206010049244 Ankyloglossia congenital Diseases 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 2
- 241000699670 Mus sp. Species 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 241000283973 Oryctolagus cuniculus Species 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 210000003423 ankle Anatomy 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 231100000013 eye irritation Toxicity 0.000 description 2
- 210000003128 head Anatomy 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 240000000047 Gossypium barbadense Species 0.000 description 1
- 235000009429 Gossypium barbadense Nutrition 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- RZHBMYQXKIDANM-UHFFFAOYSA-N dioctyl butanedioate;sodium Chemical compound [Na].CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC RZHBMYQXKIDANM-UHFFFAOYSA-N 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000003304 gavage Methods 0.000 description 1
- 210000001255 hallux Anatomy 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- HLLFAOOLQATURQ-UHFFFAOYSA-M sodium;1,4-di(octan-2-yloxy)-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CCCCCCC(C)OC(=O)CC(S([O-])(=O)=O)C(=O)OC(C)CCCCCC HLLFAOOLQATURQ-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B11/00—Hosiery; Panti-hose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/236—Esters of carboxylic acids; Esters of carbonic acid containing halogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/453—Phosphates or phosphites containing nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses mosquito repellent and anti-acarien socks and a preparation method thereof. The mosquito repellent and anti-acarien socks are woven from the following raw materials in percentage by weight: 60-80 wt% of cotton fiber and 20-40 wt% of spandex. The mosquito repellent and anti-acarien socks provided by the invention are stable in process, good in selected and used raw material, stable in quality by guarantee of the various processes, visually uniform in fabric density, chunky, pure in color, and good in shaping and forming effect, thereby being an ideal chose for health home life.
Description
Technical field
The present invention relates to a kind of socks, be specifically related to a kind of anophelifuge anti-demodicid mite socks and preparation method thereof.
Background technology
" socks " word sees " China notes at all times " the earliest, says: " three generations and week write angle, lie in band
Ankle "." three generations " refers to China's summer the most on the books, business, period in week, away from the present existing 3000 or four thousand years history.
" angle " should be the original socks made of animal skin, so writing " ".Later, along with textile
Occurring, socks are developed into make of cloth, fiber crops, silk by beast cloth again, and " " the most correspondingly changes " socks " into,
Last be reduced to step by step today we described " socks ".The transmutation process of " socks " word, has contained China in fact
The development process of civilization.
Ancient times socks shape system about can divide three-chip type craft socks for have legging, frenulum socks, panty hose,
Divide toe socks, shaven head socks and bottomless sock etc. six kinds.The stocking leg wherein having legging is different in size, and some length is to abdomen
Portion, have only between ankle.Frenulum socks are in order that difficult drop-off when wearing.Point toe socks be by big toe with additionally
Four toes separate, shape such as bifurcation shape.Shaven head socks and bottomless sock are used for the women of foot-binding in ancient times, are commonly called as half socks.
Now, the kind of socks is a lot, divides by the length of the stocking leg, has stocking, Knee-socks and short legging
With ship socks (invisible socks)；Divide by stocking blank kind, have registered permanent residence socks, rib cuff socks and elastic top hosiery；By using object
Point, there are men's socks, female's socks and Children's Socks.Circular knit hosiery is by stocking blank, the stocking leg and stocking foot 3 portion of tissue.The rule of socks
Lattice, represent with socks size, and socks number are a size of standards of the physical length with the stocking sole, institute
Just can choose, after knowing oneself foot length, the socks fitted.The raw material used due to socks is different, its
In socks series the most different.
Along with healthy living pursuit is improved constantly by people, the performance of socks is not limited solely to warming,
Attractive in appearance etc., also it is aided with more massage, demodicid mite antibacterial, anti-, moisture absorbing and sweat releasing, antistatic, uvioresistant etc. each
Plant health care and safeguard function.
The invention provides a kind of anophelifuge anti-demodicid mite socks, meet the people's multi-functional demand to socks.
Summary of the invention
For deficiencies of the prior art, one of the technical problem to be solved is to provide
A kind of anophelifuge anti-demodicid mite socks.
The two of the technical problem to be solved are to provide the preparation method of above-mentioned anophelifuge anti-demodicid mite socks.
The technical problem of the present invention, is achieved by following technical proposals:
A kind of anophelifuge anti-demodicid mite socks, are weaved by the raw material of following weight parts and form: 60-80wt% cotton fiber and
20-40wt% spandex.
Preferably, described anophelifuge anti-demodicid mite socks process step through the anti-demodicid mite of anophelifuge again and obtain.
Preferably, the anti-demodicid mite of described anophelifuge processes step is at anophelifuge anti-mite finishing agent by anti-for described anophelifuge demodicid mite socks
Middle dipping, described anophelifuge anti-mite finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part lavandula angustifolia
Quintessence oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.005-0.05 part Envidor, 0.1-0.5 part penetrating agent, 5-15 part
Ethanol, 0.1-0.5 part chelating agen, 95-105 part water.
Preferably, described penetrating agent is by 40-60wt% aerosol OT and 40-60wt% fourth
Diacid-1,4-two (1-first heptyl) ester sodium sulfonate mixes.
Preferably, described chelating agen by 40-60wt% ethylene diamine tetra methylene phosphonic acid five sodium-salt and
40-60wt% ATMP five sodium-salt mixes.
Present invention also offers the preparation method of above-mentioned anophelifuge anti-demodicid mite socks, comprise the following steps:
(1) conventional method is used cotton fiber and spandex to be weaved, be processed into socks；
(2) above-mentioned socks carry out the anti-demodicid mite of anophelifuge process.
Preferably, described step (2) is under the conditions of 65-85 DEG C, by socks at anophelifuge anti-mite finishing agent
Middle dipping 20-30min, after dehydration, dries 5-10min under the conditions of 70-90 DEG C.
Described anophelifuge anti-mite finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil,
0.1-0.3 part oil of Cymbopogon winterianus, 0.005-0.05 part Envidor, 0.1-0.5 part penetrating agent, 5-15 part ethanol,
0.1-0.5 part chelating agen, 95-105 part water.
Concrete, in the present invention:
Herba Lysimachiae foenum-graeci quintessence oil, No. CAS: 8000-28-0.
Oil of Cymbopogon winterianus, No. CAS: 73049-78-2.
Envidor, No. CAS: 148477-71-8.
Aerosol OT, No. CAS: 577-11-7.
Succinic acid-Isosorbide-5-Nitrae-two (1-first heptyl) ester sodium sulfonate, No. CAS: 20727-33-7.
Ethylene diamine tetra methylene phosphonic acid five sodium-salt, No. CAS: 7651-99-2.
ATMP five sodium-salt, No. CAS: 2235-43-0.
1-propanol, No. CAS: 71-23-8.
The anophelifuge anti-demodicid mite socks of the present invention, process stabilizing, select raw material good, by checking on of each procedure,
Steady quality, shows in appearance, and Density is uniform, abundant, pure color, forming of shaping,
It it is the ideal chose of healthy life staying idle at home.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, only to the present invention
Preferred embodiment, not does the restriction of other forms, any technology being familiar with this specialty to the present invention
Personnel are changed to the Equivalent embodiments changed on an equal basis possibly also with the technology contents of the disclosure above.Every
Without departing from the present invention program content, any letter following example done according to the technical spirit of the present invention
Single amendment or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Anophelifuge anti-demodicid mite socks raw material (percentage by weight): 70wt% cotton fiber (cotton fiber is long-staple cotton, its
A length of 40mm, fineness is 7200nm) and 30wt% spandex (using Du Pont's spandex thread, 70D).
Anophelifuge anti-mite finishing agent raw material (weight portion): 0.2 part of Herba Lysimachiae foenum-graeci quintessence oil, 0.2 part of oil of Cymbopogon winterianus,
0.01 part of Envidor, 0.3 part of penetrating agent, 10 parts of 1-propanol, 0.3 part of chelating agen, 100 parts of deionized waters.
Described penetrating agent is by 50wt% aerosol OT and 50wt% succinic acid-1,4-two (1-
First heptyl) ester sodium sulfonate is uniformly mixed and obtains.
Described chelating agen is by 50wt% ethylene diamine tetra methylene phosphonic acid five sodium-salt and 50wt% amino three methene phosphine
Acid five sodium-salt is uniformly mixed and obtains.
Present invention also offers the preparation method of above-mentioned anophelifuge anti-demodicid mite socks, comprise the following steps:
(1) use braider, according to a conventional method cotton fiber and spandex are woven into socks blank cloth (grammes per square metre
It is 160 grams/m), according to technique and the requirement of making socks, after socks blank cloth cutting, add
Work becomes socks；
(2) Herba Lysimachiae foenum-graeci quintessence oil, oil of Cymbopogon winterianus, Envidor, penetrating agent, 1-propanol, chelating agen are added
Deionized water is uniformly mixed, obtains anophelifuge anti-mite finishing agent；It is 75 DEG C that socks are placed on temperature
Impregnating 25min in anophelifuge anti-mite finishing agent, wherein socks are 1:10 with the mass ratio of anophelifuge anti-mite finishing agent
(i.e. 1kg socks 10kg anophelifuge anti-mite finishing agent impregnates), after dehydration, dries under the conditions of 80 DEG C
8min；Obtain anophelifuge anti-demodicid mite socks.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described penetrating agent is only dioctyl succinate
Sodium sulfonate.Obtain the anophelifuge anti-demodicid mite socks of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described penetrating agent is only succinic acid-Isosorbide-5-Nitrae-two
(1-first heptyl) ester sodium sulfonate.Obtain the anophelifuge anti-demodicid mite socks of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described chelating agen is only ethylenediamine tetraacetic methene
Phosphonic acids five sodium-salt.Obtain the anophelifuge anti-demodicid mite socks of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described chelating agen is only amino three methene phosphine
Acid five sodium-salt.Obtain the anophelifuge anti-demodicid mite socks of embodiment 5.
Test case 1
The anophelifuge anti-demodicid mite socks of embodiment 1-5 are carried out anti-demodicid mite test, uses " the anti-demodicid mite of FZ/T62012-2009
Bedding " standard, test.Test data are shown in Table 1.
Table 1: anti-demodicid mite performance test table
Comparing embodiment 1-3, embodiment 1 (aerosol OT, succinic acid-Isosorbide-5-Nitrae-two (1-first heptan
Base) ester sodium sulfonate compound) anti-demodicid mite effect, hence it is evident that be better than embodiment 2-3 (aerosol OT,
Single raw material in succinic acid-1,4-two (1-first heptyl) ester sodium sulfonate)；Comparing embodiment 1 and embodiment 4-5,
Embodiment 1 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt are compounding) anti-demodicid mite effect
Really, hence it is evident that be better than embodiment 4-5 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium
Single raw material in salt).
Test case 2
The anophelifuge anti-demodicid mite socks of embodiment 1-5 are carried out anophelifuge test,
Test 18:00-20:00 between the lights to carry out, white mice is fixed on three conjunctions of one piece of 10cm × 15cm
On plate, Mus surface covers silk stocking, and fixes in surrounding with elastic, then puts it into and has raised 1000
In the mosquito cage of mosquito, timing 3 minutes, observe and record mosquito stopping on sample cloth cover during this period
Fall number of times, and in triplicate, embodiment uses color identical with comparative example.Test data are shown in Table 2.
Table 2: synthesis test table
Comparing embodiment 1-3, embodiment 1 (aerosol OT, succinic acid-Isosorbide-5-Nitrae-two (1-first heptan
Base) ester sodium sulfonate compound) repelling effect, hence it is evident that be better than embodiment 2-3 (aerosol OT,
Single raw material in succinic acid-1,4-two (1-first heptyl) ester sodium sulfonate)；Comparing embodiment 1 and embodiment 4-5,
Embodiment 1 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt are compounding) anophelifuge effect
Really, hence it is evident that be better than embodiment 4-5 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium
Single raw material in salt).
Test case 3
Embodiment 1 anophelifuge anti-mite finishing agent (anophelifuge anti-mite finishing agent raw material (weight portion): 0.2 part smokes
Clothing grass quintessence oil, 0.2 part of oil of Cymbopogon winterianus, 0.01 part of Envidor, 0.3 part of penetrating agent, 10 parts of 1-propanol, 0.3
Part chelating agen, 100 parts of deionized waters) toxicity test:
(1) anophelifuge anti-mite finishing agent per os acute toxicity；Take anophelifuge anti-mite finishing agent to 40 empty stomach 16h
Kunming kind standard white mice disposable per os gavage, anophelifuge anti-mite agent dose is up to 1000mg/kg.
Observing animal and poisoning manifestations every day, seven days terminate experiment, and respectively group laboratory animal is in whole experimentation,
All normal without any poisoning manifestations, diet and motion, none animal dead.
(2) to skin irritation: by 10 Japan's big ear tag quasi experiments with the spinal column diamond wool of rabbit respectively
Cut, the gauze of anophelifuge anti-mite finishing agent will be impregnated, apply ointment or plaster on the skin that right side exposes.24 hours
, all there is not the irritation such as erythema and edema, according to skin irritation intensity in rear observation application site skin
Grade scale, this anophelifuge anti-mite finishing agent belongs to non-stimulated material to skin.
(3) to eye irritation: by anophelifuge anti-mite finishing agent, directly instill the big ear tag quasi experiment of Japan and use
The right eye of rabbit, left eye compares, passive Guan Bi 5 seconds, and then clean with normal saline flushing, 24 is little
Observing time after, eyes are the most without exception, according to eye irritation strength grading standard, and this anophelifuge anti-mite finishing agent
Eyes are belonged to non-stimulated material.
Claims (8)
1. anophelifuge anti-demodicid mite socks, it is characterised in that weaved by the raw material of following weight parts and form:
60-80wt% cotton fiber and 20-40wt% spandex.
2. anophelifuge anti-demodicid mite socks as claimed in claim 1, it is characterised in that described anophelifuge anti-demodicid mite socks warp again
Cross the anti-demodicid mite of anophelifuge to process step and obtain.
3. anophelifuge anti-demodicid mite socks as claimed in claim 2, it is characterised in that the anti-demodicid mite of described anophelifuge processes step
Rapid is to be impregnated in anophelifuge anti-mite finishing agent by anti-for described anophelifuge demodicid mite socks, described anophelifuge anti-mite finishing agent by
The raw material composition of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.005-0.05
Part Envidor, 0.1-0.5 part penetrating agent, 5-15 part ethanol, 0.1-0.5 part chelating agen, 95-105 part water.
4. anophelifuge anti-demodicid mite socks as claimed in claim 3, it is characterised in that described penetrating agent by
40-60wt% aerosol OT and 40-60wt% succinic acid-1,4-two (1-first heptyl) ester sodium sulfonate
Mix.
5. the anophelifuge anti-demodicid mite socks as described in claim 3 or 4, it is characterised in that described chelating agen by
40-60wt% ethylene diamine tetra methylene phosphonic acid five sodium-salt and the mixing of 40-60wt% ATMP five sodium-salt
Form.
6., according to the preparation method of the anti-demodicid mite socks of the anophelifuge according to any one of claim 1-5, its feature exists
In, comprise the following steps:
(1) conventional method is used cotton fiber and spandex to be weaved, be processed into socks；
(2) above-mentioned socks carry out the anti-demodicid mite of anophelifuge process.
The preparation method of anophelifuge the most according to claim 6 anti-demodicid mite socks, it is characterised in that described step
Suddenly (2) are under the conditions of 65-85 DEG C, and socks impregnate in anophelifuge anti-mite finishing agent 20-30min, de-
After water, under the conditions of 70-90 DEG C, dry 5-10min.
The preparation method of anophelifuge the most according to claim 7 anti-demodicid mite socks, it is characterised in that described
Anophelifuge anti-mite finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part Herba Lysimachiae foenum-graeci quintessence oil, 0.1-0.3 part
Oil of Cymbopogon winterianus, 0.005-0.05 part, 0.005-0.05 part Envidor, 0.1-0.5 part penetrating agent, 5-15 part second
Alcohol, 0.1-0.5 part chelating agen, 95-105 part water.
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| CN104594056A (en) * | 2013-10-31 | 2015-05-06 | 青岛鑫益发工贸有限公司 | Environmentally-friendly anti-mite fabric production method |
| CN105231503A (en) * | 2015-11-20 | 2016-01-13 | 上海喜眠服饰有限公司 | Sweat removing pajama fabric and manufacturing method thereof |
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| CN102277744A (en) * | 2011-06-10 | 2011-12-14 | 东华大学 | Antibiotic and anti-asthma finishing liquid, preparation method thereof and application thereof on fabrics |
| CN103668548A (en) * | 2012-09-21 | 2014-03-26 | 江苏蓝品纤维科技发展有限公司 | Lukens fiber and functional fiber prepared therefrom |
| CN104594056A (en) * | 2013-10-31 | 2015-05-06 | 青岛鑫益发工贸有限公司 | Environmentally-friendly anti-mite fabric production method |
| CN104499273A (en) * | 2014-11-17 | 2015-04-08 | 浙江梦娜袜业股份有限公司 | Mosquito-repelling and mite-resisting finishing agent for silk stockings and silk stocking production technology |
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| CN105734960B (en) | 2018-03-09 |
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Address after: 274300 East Outer Ring Road East, shunshi Road, Shan county, Heze City, Shandong Province Patentee after: Xu Mengkui Address before: 311825 Zhejiang city of Shaoxing province Zhuji Paitou Zhen Keng Xi Cun township government Patentee before: Xu Mengkui |
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Effective date of registration: 20210402 Address after: 321000 1788 Jingang Avenue, Jindong Economic Development Zone, Jinhua City, Zhejiang Province Patentee after: Zhejiang Yusi socks Co.,Ltd. Address before: 274300 East Outer Ring Road, shunshi Road, Shan county, Heze City, Shandong Province Patentee before: Xu Mengkui |