CN105734685A - Intelligentized ramie degumming technology - Google Patents

Intelligentized ramie degumming technology Download PDF

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Publication number
CN105734685A
CN105734685A CN201610203372.3A CN201610203372A CN105734685A CN 105734685 A CN105734685 A CN 105734685A CN 201610203372 A CN201610203372 A CN 201610203372A CN 105734685 A CN105734685 A CN 105734685A
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parts
degumming
agent
process according
bleaching
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毛亚峰
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Hebei Guoxuan Hemp Fiber Development Co Ltd
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Hebei Guoxuan Hemp Fiber Development Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C1/00Treatment of vegetable material
    • D01C1/02Treatment of vegetable material by chemical methods to obtain bast fibres

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Textile Engineering (AREA)
  • Paper (AREA)

Abstract

The invention discloses an intelligentized ramie degumming technology.The intelligentized ramie degumming technology comprises the following steps that ramie fibers are bound together and then conveyed into a steeping and softening device through a conveyor belt to be steeped and softened, and initial degumming is performed; the softened ramie fibers enter a double-roll extrusion liquid removing machine to recycle a degumming agent; the steeped ramie fibers are washed through a high-frequency jet flow washing system to remove parenchyma cells carried by the ramie fibers; extrusion dewatering is performed for twice through a double-roll dewatering machine; the dewatered ramie fibers enter a bleaching tank for first-stage bleaching and enter a bleaching reduction tank for second-stage bleaching reduction; the ramie fibers are washed again in a low-frequency jet flow washing system to take out residual colloids or parenchyma cells; dewatering treatment is performed through the double-roll dewatering machine, drying treatment is performed through a hot air drying system, and then refined dry ramie fibers are obtained.Accordingly, the intelligentized degumming technology is selected for the fiber characteristic of the ramie fibers, therefore, not only can the degumming time be saved, but also the water using amount can be decreased, and the cost is saved.

Description

A kind of intelligent china grass degumming process
Technical field
The invention belongs to China grass degumming field, be specifically related to a kind of intelligent china grass degumming process.
Background technology
Boehmeria (Boehmerianivea) is Urticaceae perennial root, for herbaceos perennial, original China.China's Boehmeria yield accounts for the 90% of whole world Boehmeria yield, and containing the fiber accounting for Boehmeria weight 70% in Boehmeria, its fiber length, intensity are big, are the important source material in textile industry.In various Plant fiber, Ramie Fiber Quality is best.Ramee is unique in flaxen fiber to exist with ultimate fibre state, and ramee length is long, good springiness, and ultimate fibre length is up to 600MM, and tough and tensile, is rich in gloss, bright, it is not easy to fade.Pure spin or blending becomes various thickness cloth, not only attractive in appearance but also durable.The tension stress intensity of ramee is higher 8-9 times than Cotton Gossypii, it is possible to does aeroplane fabric, the raw material of parachute and manufactures the various ropes such as canvas, the rope of aviation, grenade bracing wire, linen thread.Ramee is when soaking, and intensity increases especially, absorbs and disperses moisture fast, and have corrosion resistant, not easily mouldy characteristic, is the good material manufacturing waterproof cloth, fishnet etc..Ramee heat radiation is also fast, it is not easy to conducts electricity, therefore, it can do the liner of tire, the foreskin of electric wire, the transmission band etc. of machine.Boehmeria chopped fiber can be the raw material of fine paper, gunpowder, artificial silk etc., again can weavening carpet, gunnysack etc..
The physical property of ramee, pliability are to turn the performance such as bent different with other fiber, general content of cellulose is 65-75%, half fiber content 14-16%, pectin 4-5%, water-soluble substances 4-8%, adipocere paper 0.5-1.0%, ash 2-5%, due to the special character of Boehmeria, determine its processing technique and other fiber distinct.
The keen-witted and capable Taro Aso's processing technique of traditional banding has reached 17 procedures, and technological process is long, and production capacity is undesirable, and the mode of production is semi-hand, the semi-mechanization mode of production, and product appropriation of labour power per ton is up to more than hundred people.Originally straight fiber is broken up in flax stamping device, is then subjected to the acutely thin pin of fibre separating machine and steel bar machine.Making to exist in the fiber of combing many Fried Glutinous Rice Balls with Sesame and undercoat, thus the row yielding of degumming and combing only has 56% and 46% respectively, inefficiency, labor productivity is relatively low, causes bigger labour force and consumes, and the processing cost of ramie stripes per ton is more than cotton fine twice.
Domestic more enterprise still adopts traditional chemical steaming or bioanalysis production technology, there is many deficiencies, China fiber crops industrial market seriously delayed, also result in the decline year by year of domestic plantation fiber crops yield, Hunan is Boehmeria main product ground, the cultivated area of peak period breaks through 2,000,000 mu, but taper to now 20-30 ten thousand mu, it is down to current 5-6 unit/kg by original higher price 8-10 unit/kg, raw material economics is caused to be worth on the low side, and the production technology fallen behind also is the major reason that constraints on fiber fiber crops production capacity does not increase, therefore research and development degummed ramie short route, automatization, serialization, zero-emission, high efficiency production and processing technology is urgent problem in current fiber crops industrial chain.
Summary of the invention
For deficiency of the prior art, the present invention provides a kind of intelligent china grass degumming process, and this technique, for the characteristic of Boehmeria, uses special degumming agent, and this technique to have cost little, usually time is short, the feature that water consumption is few.
To achieve these goals, the present invention uses following technical scheme:
A kind of intelligent china grass degumming process, described technique comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is carried out dipping softening by tape transport to dipping demineralizer, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller vacuum press liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;
(5) then through the double; two roller vacuum hydroextractor extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by double; two roller dewaterers subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
In aforementioned intelligent china grass degumming process, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 130~170 parts, the agent 8~10 parts that boils together, 1~3 part of magnesium sulfate, liquid caustic soda 130~170 parts, enzyme 11~15 parts and 655~695 parts of water.
Preferably, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 140~160 parts, the agent 8~10 parts that boils together, 1~3 part of magnesium sulfate, liquid caustic soda 140~160 parts, enzyme 12~14 parts and 665~685 parts of water.
It is highly preferred that described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 150 parts, the agent 10 parts that boils together, 2 parts of magnesium sulfate, liquid caustic soda 150 parts, enzyme 13 parts and 675 parts of water.
Wherein said chelating agen is metal-chelator, it is preferred to citric acid or ethylenediaminetetraacetic acid.
Preferably, the concentration of described liquid caustic soda (i.e. the sodium hydroxide of liquid, also known as Caustic soda, caustic soda) is 30%.
Preferably, described enzyme be cellulase, hemicellulase, lignoenzyme and pectase with (2~4): (1~2): 1:(2~3) mass ratio mix.
In aforementioned intelligent china grass degumming process, described conveyer belt moves with uniform velocity with the speed of 1.5m/min.
In aforementioned intelligent china grass degumming process, the temperature of described dipping softening is 90 DEG C, and the time is 60-90mim.
In aforementioned intelligent china grass degumming process, the temperature of step (8) described drying and processing is 85 DEG C, and the time is 35 minutes.
The adopted degumming system whole process width of the present invention is 1.5m, length is 90~105m, and realize producing continuously, main line installation total capacity 46kw, auxiliary heat exchange general power is about 90kw, water treatment system installation 60~90kw and the water pump etc. less than 35kw are that timesharing starts, full production line general power about 225~255kw, every day worked according to 10~12 hours, produce about 7 tons every day, produce about 2100 tons per year, and the present invention can also utilize photovoltaic generating system to power, reach the degumming production of the ramee really cleaned.
The invention has the beneficial effects as follows:
The present invention is directed to the fiber properties of Boehmeria, select intelligence degumming system in conjunction with suitable degumming tech, be possible not only to save usually time, it is also possible to reduce the consumption of water, save cost, there is higher using value.
Present invention process is divided into three sections or four sections of physical water treatment systems, reach water circulating and recovering, do not discharge, saved labor intensity compared with traditional mode of production mode and saved recruitment more than 80%, reduce energy consumption consuming time with the full-range production cycle, realize automatization, continuous prodution, easily promote scale, enhance production capacities, and product quality and yield can be improved, compared with traditional approach, the yield of product improves about 11%.
Detailed description of the invention
The experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, all commercially obtain.
Specific embodiments of the invention are described in more detail below.Although the present invention closely lists some embodiments, it being understood, however, that may be realized in various forms the present invention and should not limited by embodiments set forth here.On the contrary, it is provided that these embodiments are able to be best understood from the present invention, and complete for the scope of the present invention can be conveyed to those skilled in the art.
It should be noted that " comprising " or " including " as mentioned in the middle of description and claim in the whole text is an open language, therefore " comprise but be not limited to " should be construed to.Description subsequent descriptions is implement the better embodiment of the present invention, and right described description is for the purpose of the rule of description, is not limited to the scope of the present invention.Protection scope of the present invention is when being as the criterion depending on the defined person of claims.
For ease of the understanding to the embodiment of the present invention, it is further explained explanation for several specific embodiments below.
Embodiment 1
A kind of intelligent china grass degumming process, described technique comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is moved with uniform velocity with the speed of 1.5m/min by conveyer belt it is delivered in dipping demineralizer to carry out dipping softening, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller vacuum press liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;The temperature of described dipping softening is 90 DEG C, and the time is 60mim;
(5) then through the double; two roller vacuum hydroextractor extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by double; two roller dewaterers subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
In aforementioned intelligent china grass degumming process, having degumming agent in described dipping demineralizer, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 130 parts, the agent 8 parts that boils together, 3 parts of magnesium sulfate, liquid caustic soda 170 parts, enzyme 11 parts and 678 parts of water.
Wherein said chelator acid citrate;Described liquid paper mill wastewater is 30%;Described enzyme is that cellulase, hemicellulase, lignoenzyme and pectase mix with the mass ratio of 2:2:1:2.
Embodiment 2
A kind of intelligent china grass degumming process, described technique comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is moved with uniform velocity with the speed of 1.5m/min by conveyer belt it is delivered in dipping demineralizer to carry out dipping softening, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller vacuum press liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;The temperature of described dipping softening is 90 DEG C, and the time is 75mim;
(5) then through the double; two roller vacuum hydroextractor extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by double; two roller dewaterers subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
In aforementioned intelligent china grass degumming process, having degumming agent in described dipping demineralizer, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 170 parts, the agent 10 parts that boils together, 1 part of magnesium sulfate, liquid caustic soda 130 parts, enzyme 15 parts and 674 parts of water.
Wherein said chelating agen is ethylenediaminetetraacetic acid.Described liquid paper mill wastewater is 30%.Described enzyme is that cellulase, hemicellulase, lignoenzyme and pectase mix with the mass ratio of 3:1:1:2.
Embodiment 3
A kind of intelligent china grass degumming process, described technique comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is moved with uniform velocity with the speed of 1.5m/min by conveyer belt it is delivered in dipping demineralizer to carry out dipping softening, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller vacuum press liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;The temperature of described dipping softening is 90 DEG C, and the time is 90mim;
(5) then through the double; two roller vacuum hydroextractor extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by double; two roller dewaterers subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
In aforementioned intelligent china grass degumming process, having degumming agent in described dipping demineralizer, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 150 parts, the agent 10 parts that boils together, 2 parts of magnesium sulfate, liquid caustic soda 150 parts, enzyme 13 parts and 675 parts of water.
Wherein said chelating agen is citric acid;Described liquid paper mill wastewater is 30%;Described enzyme is that cellulase, hemicellulase, lignoenzyme and pectase mix with the mass ratio of 3:1:1:3.
Embodiment 4
A kind of intelligent china grass degumming process, described technique comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is moved with uniform velocity with the speed of 1.5m/min by conveyer belt it is delivered in dipping demineralizer to carry out dipping softening, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller vacuum press liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;The temperature of described dipping softening is 90 DEG C, and the time is 70mim;
(5) then through the double; two roller vacuum hydroextractor extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by double; two roller dewaterers subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
In aforementioned intelligent china grass degumming process, having degumming agent in described dipping demineralizer, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 140 parts, the agent 9 parts that boils together, 2 parts of magnesium sulfate, liquid caustic soda 155 parts, enzyme 14 parts and 680 parts of water.
Wherein said chelating agen is ethylenediaminetetraacetic acid;Described liquid paper mill wastewater is 30%;Described enzyme is that cellulase, hemicellulase, lignoenzyme and pectase mix with the mass ratio of 4:1:1:3.
Embodiment 5
A kind of intelligent china grass degumming process, described technique comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is moved with uniform velocity with the speed of 1.5m/min by conveyer belt it is delivered in dipping demineralizer to carry out dipping softening, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller vacuum press liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;The temperature of described dipping softening is 90 DEG C, and the time is 80mim;
(5) then through the double; two roller vacuum hydroextractor extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by double; two roller dewaterers subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
In aforementioned intelligent china grass degumming process, described dipping demineralizer has degumming agent, sodium silicate 160 parts, the agent 8 parts that boils together, 3 parts of magnesium sulfate, liquid caustic soda 150 parts, enzyme 12 parts and 667 parts of water.
Wherein said chelating agen is ethylenediaminetetraacetic acid;Described liquid paper mill wastewater is 30%.Described enzyme is that cellulase, hemicellulase, lignoenzyme and pectase mix with the mass ratio of 3:2:1:2.
The present invention is directed to the fiber properties of Boehmeria, select intelligence degumming system in conjunction with suitable degumming tech, be possible not only to save usually time, it is also possible to reduce the consumption of water, save cost, there is higher using value.
Further, compared with traditional degumming tech, the yield of product on average improves about 11%.

Claims (10)

1. an intelligent china grass degumming process, it is characterised in that described degumming tech comprises the steps:
(1) first by Boehmeria colligation together;
(2) colligation Boehmeria together is carried out dipping softening by tape transport to dipping demineralizer, described dipping demineralizer has degumming agent, initial degumming;
(3) Boehmeria after softening enters in double; two roller extruding liquid remover and is reclaimed by degumming agent;
(4) then then through high-frequency jet washing system, the ramee after dipping is washed, remove the heteroproteose cell that ramee is with;
(5) then through first pair of roller dewaterer extrusion dehydration of twice;
(6) subsequently into bleaching cistern carrying out I section of bleaching and entrance bleaching reduction cell carry out II section of bleaching reduction;
(7) again wash then through in low frequency jet washing system, take out colloid substances or the heteroproteose cell of remaining;
(8), after carrying out processed by second pair of roller dewaterer subsequently, after hot air seasoning system drying and processing, degummed ramie is obtained.
2. intelligent china grass degumming process according to claim 1, it is characterized in that, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 130~170 parts, the agent 8~10 parts that boils together, 1~3 part of magnesium sulfate, liquid caustic soda 130~170 parts, enzyme 11~15 parts and 655~695 parts of water.
3. intelligent china grass degumming process according to claim 2, it is characterized in that, described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 140~160 parts, the agent 8~10 parts that boils together, 1~3 part of magnesium sulfate, liquid caustic soda 140~160 parts, enzyme 12~14 parts and 665~685 parts of water.
4. intelligent china grass degumming process according to claim 2, it is characterised in that described degumming agent is grouped into by the one-tenth of following weight portion: sodium silicate 150 parts, the agent 10 parts that boils together, 2 parts of magnesium sulfate, liquid caustic soda 150 parts, enzyme 13 parts and 675 parts of water.
5. the intelligent china grass degumming process according to any one of claim 2-4, it is characterised in that described in the agent that boils together be citric acid or ethylenediaminetetraacetic acid.
6. the intelligent china grass degumming process according to any one of claim 2-4, it is characterised in that described liquid paper mill wastewater is 30%.
7. the intelligent china grass degumming process according to any one of claim 2-4, it is characterized in that, described enzyme be cellulase, hemicellulase, lignoenzyme and pectase with (2~4): (1~2): 1:(2~3) mass ratio mix.
8. intelligent china grass degumming process according to claim 1, it is characterised in that described conveyer belt moves with uniform velocity with the speed of 1.5m/min.
9. intelligent china grass degumming process according to claim 1, it is characterised in that the temperature of described dipping softening is 90 DEG C, and the time is 60-90mim.
10. intelligent china grass degumming process according to claim 1, it is characterised in that the temperature of step (8) described drying and processing is 85 DEG C, and the time is 35 minutes.
CN201610203372.3A 2016-04-01 2016-04-01 Intelligentized ramie degumming technology Pending CN105734685A (en)

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Publication number Priority date Publication date Assignee Title
CN101096773A (en) * 2006-06-26 2008-01-02 湖南苎麻技术研究中心 Energy-saving environment-friendly type china grass degumming process
CN101358380A (en) * 2008-09-27 2009-02-04 湖南华升洞庭麻业有限公司 Ramie rapid degumming technique for producing high quality ramie top
CN101451274A (en) * 2007-12-07 2009-06-10 李朝康 China grass degumming and carding continues production process
CN102094249A (en) * 2010-04-16 2011-06-15 汉寿鑫源纺织印染有限责任公司 Method for degumming ramie by weakly alkaline liquid biological enzyme
CN103774245A (en) * 2014-02-25 2014-05-07 武汉纺织大学 Ramie chain type continuous waste-free degumming fiber separation method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101096773A (en) * 2006-06-26 2008-01-02 湖南苎麻技术研究中心 Energy-saving environment-friendly type china grass degumming process
CN101451274A (en) * 2007-12-07 2009-06-10 李朝康 China grass degumming and carding continues production process
CN101358380A (en) * 2008-09-27 2009-02-04 湖南华升洞庭麻业有限公司 Ramie rapid degumming technique for producing high quality ramie top
CN102094249A (en) * 2010-04-16 2011-06-15 汉寿鑫源纺织印染有限责任公司 Method for degumming ramie by weakly alkaline liquid biological enzyme
CN103774245A (en) * 2014-02-25 2014-05-07 武汉纺织大学 Ramie chain type continuous waste-free degumming fiber separation method

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Title
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Application publication date: 20160706