CN105731584A - 一种去除水中微污染物布洛芬的方法 - Google Patents
一种去除水中微污染物布洛芬的方法 Download PDFInfo
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- CN105731584A CN105731584A CN201610179197.9A CN201610179197A CN105731584A CN 105731584 A CN105731584 A CN 105731584A CN 201610179197 A CN201610179197 A CN 201610179197A CN 105731584 A CN105731584 A CN 105731584A
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- ibuprofen
- graphene
- graphite oxide
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- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 229960001680 ibuprofen Drugs 0.000 title claims abstract description 116
- 238000000034 method Methods 0.000 title claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 96
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000000463 material Substances 0.000 claims abstract description 50
- 239000002131 composite material Substances 0.000 claims abstract description 47
- 239000002351 wastewater Substances 0.000 claims abstract description 34
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- 229910002804 graphite Inorganic materials 0.000 claims description 74
- 239000010439 graphite Substances 0.000 claims description 74
- 238000006555 catalytic reaction Methods 0.000 claims description 38
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 28
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- 239000005446 dissolved organic matter Substances 0.000 claims description 26
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 19
- 239000004021 humic acid Substances 0.000 claims description 19
- 239000000725 suspension Substances 0.000 claims description 18
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- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000004587 chromatography analysis Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201610179197.9A CN105731584B (zh) | 2016-03-25 | 2016-03-25 | 一种去除水中微污染物布洛芬的方法 |
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CN201610179197.9A CN105731584B (zh) | 2016-03-25 | 2016-03-25 | 一种去除水中微污染物布洛芬的方法 |
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CN105731584A true CN105731584A (zh) | 2016-07-06 |
CN105731584B CN105731584B (zh) | 2018-04-17 |
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CN201610179197.9A Expired - Fee Related CN105731584B (zh) | 2016-03-25 | 2016-03-25 | 一种去除水中微污染物布洛芬的方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106732611A (zh) * | 2016-11-29 | 2017-05-31 | 郑州航空工业管理学院 | 一种去除废水中有机磷农药的方法 |
CN107500405A (zh) * | 2017-09-16 | 2017-12-22 | 济南大学 | 一种去除布洛芬的序批式厌氧颗粒污泥的方法 |
CN108203142A (zh) * | 2017-12-28 | 2018-06-26 | 盛世生态环境股份有限公司 | 一种光催化复合电极及其制备方法、和在废水处理中的应用 |
CN110496627A (zh) * | 2018-12-07 | 2019-11-26 | 郑州航空工业管理学院 | 一种高活性的WS2/MoS2-RGO复合光催化剂及其制备方法和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103263910A (zh) * | 2013-05-20 | 2013-08-28 | 聊城大学 | 一种钒酸铋-石墨烯复合光催化剂及其制备和应用 |
CN103877971A (zh) * | 2014-03-07 | 2014-06-25 | 中国科学院东北地理与农业生态研究所 | 高效可见光催化剂及其制备方法 |
KR20140085869A (ko) * | 2012-12-28 | 2014-07-08 | 전자부품연구원 | 수처리용 복합체 멤브레인 및 그 제조방법 |
CN104324713A (zh) * | 2014-11-20 | 2015-02-04 | 熊菊莲 | 一种石墨烯-钛酸铋复合材料的光催化剂 |
CN104437460A (zh) * | 2014-11-20 | 2015-03-25 | 熊菊莲 | 基于单相钛酸铋制备的光催化剂纳米复合材料 |
CN105363433A (zh) * | 2015-11-17 | 2016-03-02 | 河海大学 | 石墨烯基钨酸铋复合光催化剂及其制备方法和应用 |
-
2016
- 2016-03-25 CN CN201610179197.9A patent/CN105731584B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20140085869A (ko) * | 2012-12-28 | 2014-07-08 | 전자부품연구원 | 수처리용 복합체 멤브레인 및 그 제조방법 |
CN103263910A (zh) * | 2013-05-20 | 2013-08-28 | 聊城大学 | 一种钒酸铋-石墨烯复合光催化剂及其制备和应用 |
CN103877971A (zh) * | 2014-03-07 | 2014-06-25 | 中国科学院东北地理与农业生态研究所 | 高效可见光催化剂及其制备方法 |
CN104324713A (zh) * | 2014-11-20 | 2015-02-04 | 熊菊莲 | 一种石墨烯-钛酸铋复合材料的光催化剂 |
CN104437460A (zh) * | 2014-11-20 | 2015-03-25 | 熊菊莲 | 基于单相钛酸铋制备的光催化剂纳米复合材料 |
CN105363433A (zh) * | 2015-11-17 | 2016-03-02 | 河海大学 | 石墨烯基钨酸铋复合光催化剂及其制备方法和应用 |
Non-Patent Citations (1)
Title |
---|
SAMIRA YOUSEFZADEH,ET AL.: "Constructing BiVO 4 /Graphene/TiO 2 nanocomposite photoanode for photoelectrochemical conversion applications", 《JOURNAL OF ELECTROANALYTICAL CHEMISTRY》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106732611A (zh) * | 2016-11-29 | 2017-05-31 | 郑州航空工业管理学院 | 一种去除废水中有机磷农药的方法 |
CN106732611B (zh) * | 2016-11-29 | 2019-05-10 | 郑州航空工业管理学院 | 一种去除废水中有机磷农药的方法 |
CN107500405A (zh) * | 2017-09-16 | 2017-12-22 | 济南大学 | 一种去除布洛芬的序批式厌氧颗粒污泥的方法 |
CN108203142A (zh) * | 2017-12-28 | 2018-06-26 | 盛世生态环境股份有限公司 | 一种光催化复合电极及其制备方法、和在废水处理中的应用 |
CN110496627A (zh) * | 2018-12-07 | 2019-11-26 | 郑州航空工业管理学院 | 一种高活性的WS2/MoS2-RGO复合光催化剂及其制备方法和应用 |
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CN105731584B (zh) | 2018-04-17 |
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Inventor after: Zheng Binguo Inventor after: Fan Xiaolong Inventor after: Li Xiaojing Inventor after: Yao Jiaojiao Inventor after: Li Chunguang Inventor after: Liang Lizhen Inventor after: Zhang Xusheng Inventor after: Jia Xiaofeng Inventor after: Wang Ronghong Inventor after: Chen Chaoyue Inventor before: Zheng Binguo Inventor before: Wang Ronghong Inventor before: Li Chunguang Inventor before: Fan Wenxue Inventor before: Xu Jilei Inventor before: Zeng Xiaoxi Inventor before: Li Liuxing Inventor before: Chen Chaoyue Inventor before: Cheng Wenbo |
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Effective date of registration: 20180316 Address after: No. 2, middle section of University Road, Zhengzhou, Henan Province, Henan Applicant after: Zhengzhou Institute of Aeronautical Industry Management Applicant after: Zhengzhou Engineering Institute Address before: 450015 No. 2, middle section, University of Henan, Zhengzhou Applicant before: Zhengzhou Institute of Aeronautical Industry Management |
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