CN105714578B - A kind of colouring method of fruit button - Google Patents
A kind of colouring method of fruit button Download PDFInfo
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- CN105714578B CN105714578B CN201410721120.0A CN201410721120A CN105714578B CN 105714578 B CN105714578 B CN 105714578B CN 201410721120 A CN201410721120 A CN 201410721120A CN 105714578 B CN105714578 B CN 105714578B
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Abstract
The invention provides a kind of dyeability modifier for fruit button, including the ammoniacal liquor of 15~25 parts by weight, the base catalyst of 2.0~8.0 parts by weight, the acid dyes of the fluorescent whitening agent of 5.0~15 parts by weight and 1.0~5.0 parts by weight.Present invention also offers a kind of preparation method of the dyeability modifier for fruit button, after ammoniacal liquor is mixed with base catalyst first, mixed liquor is obtained;Then after again mixing mixed liquor, fluorescent whitening agent again with acid dyes, the dyeability modifier for fruit button is obtained.The present invention is soaked fruit button blank using the dyeability modifier of above-mentioned fruit button, can effectively improve dyestuff in the uniform diffusivity of fruit button and coloring in bleaching process, when effectively reducing bright color button, the aberration problem existed.
Description
Technical field
The invention belongs to garment production technical field, more particularly to a kind of colouring method of fruit button.
Background technology
Button is exactly to be used for the fastener that the both sides hem are connected on clothes, and its initial effect is for connection to the door of clothes
The flap, gradually developed into and artistry and dicoration had more in addition to its original function is kept, be also dress ornament it is personalized and
The representative of multifunction.
Button presses the classification of its material, can be divided into natural class, chemical and other materials, wherein natural class button master
To be shell button, fruit button, ox horn button, ox bone button etc..In the last few years, fruit button, also known as ivory nut, because it is special
The natural color and quality having, has obtained concern more in the industry.
Fruit button be TAGUA coco fruits gelatin it is ripe after, become like the white hard material of ivory.Its
Texture, hardness, color are similar to ivory, thus are referred to as in the industry " vegetable ivory " again.The COROZO NUT dried completely can
For substituting real ivory product, the Ecuador in South America is originated from its main blank more, using shell as base base, processed.
The manufacturing process of kernel button is different from the manufacture craft that conventional resins are buckled completely, is characterized in that quality is hard, texture is good, resistance to presses
Scald, rapid laser carving can be used, be the first choice of current domestic high-grade men's clothing, meet and wearing the clothes for natural green environmental protection is advocated now
Lead.
It is in the field of business, fruit button be often used as it is single buckle, it is radium-shine buckle, it is burning hot buckle, burn buckle, wire drawing is buckled, dye class button.
With requiring to improve constantly to the sample color of fruit button in field, the demand of the fruit button to dyeing class was increasingly carried in the last few years
It is high.And due to the natural characteristic of fruit button, have higher requirement to coloring in the fabrication process, at present, use in the industry
Fruit button is dyed with the mode of direct dyes or reactive dye color fixing at high temperature.It is generally divided into bleaching-cleaning-weigh
The step of dyestuff-dyeing-cleaning-fixation-cleaning-dehydration-drying, realizes the dyeing flow of whole fruit button.
But, in existing actual production when contaminating bright-colored to fruit button, due to the fruit knob of different batches
Detain raw material to differ to what Dye Adsorption was showed in dyeing course so that during bright color fruit button, often
There is aberration problem.
Therefore, with further requirement of the consumer to fruit button color, a kind of fruit of uniform in color how is obtained
Toggle, is always technical problem urgently to be resolved hurrily in the industry.
The content of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of colouring method of fruit button, the present invention
The colouring method of offer so that the fruit button after dyeing has uniform diffusivity and coloring, and causes bright face
Aberration when color button has less.
The invention discloses a kind of dyeability modifier for fruit button, it is characterised in that including:
It is preferred that, the base catalyst is the one or more in sodium carbonate and potassium carbonate.
It is preferred that, the fluorescent whitening agent is the one or more in talan and double triazine amino-stilbenes.
It is preferred that, the acid dyes is one or more in acid black, Indian yellow and acid red.
It is preferred that, the mass concentration of the ammoniacal liquor is 10%~22%.
The invention discloses a kind of preparation method of the dyeability modifier for fruit button, it is characterised in that including with
Lower step:
A after) ammoniacal liquor is mixed with base catalyst, mixed liquor is obtained;
B after mixed liquor that) above-mentioned steps are obtained, fluorescent whitening agent are mixed again with acid dyes, obtain being used for fruit knob
The dyeability modifier of button.
It is preferred that, the pH value of the mixed liquor is 6.5~8.5.
It is preferred that, the temperature of the mixed liquor is 65~85 DEG C.
The invention also discloses a kind of colouring method of fruit button, it is characterised in that comprises the following steps:
A) fruit button is bleached, and added after dyeability modifier, the button after being bleached;
B) after button, dyestuff after the bleaching for obtaining above-mentioned steps is mixed with water, the button after just being contaminated;
C) by the button after above-mentioned dyeing is through over cleaning fixation, cleaning and is dehydrated, then after drying, the fruit after being dyed
Button;
The dyeability modifier is the dyeability modifier or above-mentioned any one skill described in above-mentioned any one technical scheme
Dyeability modifier prepared by art scheme.
It is preferred that, the temperature of the mixing is 75~95 DEG C.
The invention discloses a kind of dyeability modifier for fruit button, including 15~25 parts by weight ammoniacal liquor, 2.0~
The acid dyes of the base catalyst of 8.0 parts by weight, the fluorescent whitening agent of 5.0~15 parts by weight and 1.0~5.0 parts by weight.
Present invention also offers a kind of preparation method of the dyeability modifier for fruit button, ammoniacal liquor is mixed with base catalyst first
After conjunction, mixed liquor is obtained;Then after again mixing mixed liquor, fluorescent whitening agent again with acid dyes, obtain being used for fruit knob
The dyeability modifier of button.Compared with prior art, the present invention is in bleaching process, using the dyeability modifier of above-mentioned fruit button
To soak fruit button blank, dyestuff can be effectively improved in the uniform diffusivity of fruit button and coloring, effectively reduced
During bright color button, the aberration problem existed.Test result indicates that, detected by precise colorimeter, use the present invention
Button prepared by the dyeability modifier of the fruit button of offer, vision can not distinguishing colours difference, its Δ E values are 0.55, surface
Diffusion is good in the fruit button of dyestuff after dyeing, and aberration is small.
Brief description of the drawings
Fig. 1 is the outward appearance photo of fruit button prepared by comparative example 1;
Fig. 2 is the outward appearance photo of fruit button prepared by embodiment 1;
Fig. 3 is the outward appearance photo of fruit button prepared by embodiment 2;
Fig. 4 is the outward appearance photo of fruit button prepared by embodiment 3.
Embodiment
In order to further appreciate that the present invention, the preferred embodiments of the invention are described with reference to embodiment, but
It is it should be appreciated that these descriptions are simply to further illustrate the features and advantages of the present invention rather than to patent requirements of the present invention
Limitation.
All raw materials of the present invention, originate to it and are not particularly limited, commercially buying or according to people in the art
Known to member prepared by conventional method.
All raw materials of the present invention, its purity is not particularly limited, pure present invention preferably employs analyzing.
The invention discloses a kind of dyeability modifier for fruit button, it is characterised in that including:
In dyeability modifier of the present invention, the addition of the ammoniacal liquor is preferably 15~25 parts by weight, more preferably 18
~23 parts by weight, most preferably 20~21 parts by weight;The addition of the base catalyst is preferably 2.0~8.0 parts by weight, more
Preferably 3.0~7.0 parts by weight, most preferably 4.0~6.0 parts by weight;The addition of the fluorescent whitening agent is preferably 5.0~
15.0 parts by weight, more preferably 8.0~12.0 parts by weight, most preferably 9.0~11.0 parts by weight;The addition of the acid dyes
Amount is preferably 1.0~5.0 parts by weight, most preferably more preferably 2.0~4.0 parts by weight, 2.5~3.5 parts by weight.
The concentration of ammoniacal liquor of the present invention is preferably 10%~22%, more preferably 13%~18%, most preferably 15%
~16%;The base catalyst is preferably the one or more in sodium carbonate and potassium carbonate, more preferably sodium carbonate or carbonic acid
Potassium, most preferably sodium carbonate;The fluorescent whitening agent be preferably talan and one kind in double triazine amino-stilbenes or
A variety of, more preferably talan or double triazine amino-stilbenes are most preferably double triazine amino-stilbenes;The present invention is right
Described pair of triazine amido diphenyl ethylene fluorescent bleaches are not particularly limited, with well known to those skilled in the art pair of triazine ammonia
Base diphenyl ethylene fluorescent bleaches, the present invention is preferably 33# fluorescent whitening agents (Shanghai Jin Yue Chemical Co., Ltd.s);This
The acid dyes is not particularly limited for invention, with the acid dyes well known to those skilled in the art dyed for button,
Or the acid dyes allocated according to needs of production, the present invention is preferably one kind in acid black, Indian yellow and acid red
Or it is a variety of.
Present invention also offers a kind of preparation method of the dyeability modifier for fruit button, it is characterised in that including
Following steps:
A after) ammoniacal liquor is mixed with base catalyst, mixed liquor is obtained;
B after mixed liquor that) above-mentioned steps are obtained, fluorescent whitening agent are mixed again with acid dyes, obtain being used for fruit knob
The dyeability modifier of button.
In the above-mentioned preparation method of the present invention, raw materials used optimum principle and addition with it is excellent in foregoing dyeability modifier
Select principle consistent with addition, this is no longer going to repeat them.
The present invention is first mixed ammoniacal liquor with base catalyst, obtains mixed liquor;The pH value of the mixed liquor is preferred
For 6.5~8.5, more preferably 6.8~8.3, more preferably 7.0~8.0, most preferably 7.3~7.6;The temperature of the mixed liquor
Degree is preferably 65~85 DEG C, more preferably 68~82 DEG C, most preferably more preferably 70~80 DEG C, 73~76 DEG C;The present invention is right
The hybrid mode is not particularly limited, with hybrid mode well known to those skilled in the art, and the present invention is preferably to stir
Mixing;The other conditions of the mixing are not particularly limited the present invention, are with mixing condition well known to those skilled in the art
Can, the present invention is preferably uniform mixing.
After the present invention and then the mixed liquor, the fluorescent whitening agent that obtain above-mentioned steps are mixed again with acid dyes, obtain
Dyeability modifier for fruit button;The present invention is improves mixing uniformity, preferably first by above-mentioned mixed liquor and fluorescent brightening
After agent is mixed, add acid dyes and carry out second of mixing;The present invention is mixed to above-mentioned mixed liquor and fluorescent whitening agent
The conjunction time is not particularly limited, and those skilled in the art adjust according to actual mixing situation, and the present invention is preferably 5~20 points
Clock, more preferably 10~15 minutes;The hybrid mode of above-mentioned mixed liquor and fluorescent whitening agent is not particularly limited the present invention, with
Hybrid mode well known to those skilled in the art, preferably stirring mixing;The rotating speed of the stirring mixing is preferably 100~
200rpm, more preferably 140~160rpm;Above-mentioned second of incorporation time is not particularly limited the present invention, art technology
Personnel are preferably 20~40 minutes, more preferably 25~35 minutes according to actual mixing situation adjustment, the present invention;The present invention
Hybrid mode to above-mentioned second of mixing is not particularly limited, excellent with hybrid mode well known to those skilled in the art
Elect stirring mixing as.
Present invention also offers a kind of colouring method of fruit button, it is characterised in that comprises the following steps:
A) fruit button is bleached, and added after dyeability modifier, the button after being bleached;
B) after button, dyestuff after the bleaching for obtaining above-mentioned steps is mixed with water, the button after just being contaminated;
C) by the button after above-mentioned dyeing is through over cleaning fixation, cleaning and is dehydrated, then after drying, the fruit after being dyed
Button.
In the above-mentioned colouring method of the present invention, the dyeability modifier is that the dyeing described in above-mentioned any one technical scheme changes
Dyeability modifier prepared by property agent or above-mentioned any one technical scheme.
The present invention is bleached to fruit button first, and adds dyeability modifier in bleaching process, is obtained after bleaching
Button;The bleaching is not particularly limited the present invention, with button bleaching process well known to those skilled in the art, sheet
Invention is preferred to use hydrogen peroxide and bleached as bleaching liquid, and the concentration of the hydrogen peroxide is preferably 0.8%~1.0%, more excellent
Elect 0.85%~0.95% as;The pH value of solution is preferably greater than to be equal to 10 in the bleaching process, is more preferably higher than equal to
11;In bleaching process, the temperature of the bleaching is preferably 40~60 DEG C, more preferably 45~55 DEG C;The time of the bleaching is excellent
Elect 4~6 hours, more preferably 4.5~5.5 hours as.
After the present invention mixes the button after above-mentioned bleaching, dyestuff with water, the button after just being contaminated;The temperature of the mixing
Degree is preferably 75~95 DEG C, more preferably 80~90 DEG C;The present invention, preferably before combination, first will be upper to ensure the effect of just dye
State the button after bleaching and carry out cleaning and acid neutralization;The cleaning fluid of the cleaning is not particularly limited the present invention, with ability
Cleaning fluid known to field technique personnel, the present invention is preferably water;The present invention is not special to the cleaning way of the cleaning
Limitation, with cleaning way well known to those skilled in the art;The present invention is not special to the acid neutralizer neutralized
Limitation, with the neutralizer well known to those skilled in the art being used in button dyeing course, the present invention is preferably acetic acid, institute
The concentration for stating acetic acid is preferably 1%~5%, and more preferably 1%~3%;The present invention is contaminated the ratio of the dyestuff and water water
The concentration of color liquid is not particularly limited, and with normal dyeing liquid concentration well known to those skilled in the art, the present invention is preferably
2%~4%, more preferably 2.5%~3.5%;The time of the just dye is not particularly limited the present invention, with art technology
Normal dyeing time known to personnel, the present invention is preferably 10~30 minutes, more preferably 15~25 minutes.
Button after the present invention first dye that obtains above-mentioned steps, through over cleaning fixation, cleaning and is dehydrated, then after drying,
Fruit button after being dyed;To ensure that the color of finished product fruit button is suitable, the present invention is preferably first by the button after first dye
Carry out after color verification, then carry out subsequently cleaning the steps such as fixation;Color verification is not particularly limited the present invention, with this
The mode of verification color, color verification is carried out present invention preferably employs standard color card known to art personnel.
The above-mentioned button after the first dye of verification through over cleaning and fixation, then is cleaned and is dehydrated by the present invention, most
After drying afterwards, the fruit button after being dyed.The cleaning fluid of the cleaning is not particularly limited the present invention, with this area skill
Cleaning fluid known to art personnel, the present invention is preferably water;The cleaning way of the cleaning is not particularly limited the present invention,
With cleaning way well known to those skilled in the art;The fixation liquid of the fixation is not particularly limited the present invention, with this
Fixation liquid known to art personnel, the mass concentration of the fixation liquid is preferably 1%~4%, more preferably 2%~
3%;The fixation time is not particularly limited the present invention, with the fixation time well known to those skilled in the art or according to reality
The condition of production is formulated, and the present invention is preferably 10~30 minutes, more preferably 15~25 minutes;The present invention is to the fixation
Mode is not particularly limited, in fixation mode well known to those skilled in the art;The present invention does not have to the dewatering time
Especially limitation, is formulated with the time of dehydration well known to those skilled in the art or according to practical condition;The present invention is right
The mode of the dehydration is not particularly limited, with dewatering type well known to those skilled in the art, the present invention be preferably from
Scheming is dehydrated;The drying time is not particularly limited the present invention, with drying time well known to those skilled in the art or root
Formulated according to practical condition, the present invention is preferably 7~11 hours, more preferably 8~10 hours;The present invention is to described de-
The mode of water is not particularly limited, with dewatering type well known to those skilled in the art
Dyeability modifier disclosed by the invention for fruit button, including 15~25 parts by weight ammoniacal liquor, 2.0~8.0
The acid dyes of the base catalyst of parts by weight, the fluorescent whitening agent of 5.0~15 parts by weight and 1.0~5.0 parts by weight.This hair
It is bright first to be bleached fruit button, add after above-mentioned dyeability modifier, the button after being bleached, then by the knob after bleaching
Button, after dyestuff mix with water, the button after just being contaminated eventually passes cleaning fixation, cleaning and dehydration, then after drying, obtains
Fruit button after dyeing;The present invention soaks fruit knob in bleaching process using the dyeability modifier of above-mentioned fruit button
Blank is detained, dyestuff can be effectively improved in the uniform diffusivity of fruit button and coloring, bright color is effectively reduced
During button, the aberration problem existed.
Fruit button after the dyeing obtained to above-mentioned steps of the present invention detects that the present invention is to detection method without spy
Do not limit, with button detection method well known to those skilled in the art, present invention preferably employs following scheme progress,
Specimen size:φ15.3mm*4mm
Detection device:Precise colorimeter
Detection method:L, a, b value at modification liquid stoste and surface of test piece are measured with precise colorimeter.
Computational methods:
L:Whiteness a:Red green axle chromaticity index b:Yellowish green axle chromaticity index
Δ L=L sample-L standards
Δ a=a sample-a standards
Δ b=b sample-b standards
Δ E represents the size of total color difference, and vision can not identify difference during usual Δ E≤3.0;
L is big to represent partially white, and L is small to represent partially black;
A is big to represent partially red, and a is small to represent partially green;
B is big, and expression is partially yellow, and b is small to represent partially green.
Test result indicates that, detected by above-mentioned precise colorimeter, the dyeing of the fruit button provided using the present invention is changed
Property agent prepare button, vision can not distinguishing colours difference, its Δ E values be 0.55, the fruit button of surface dye after dyeing
Middle diffusion is good, and aberration is small.
For a further understanding of the present invention, the dyeability modifier of the fruit button provided with reference to embodiment the present invention
And preparation method thereof, colouring method illustrate, protection scope of the present invention is not limited by the following examples.
Comparative example 1
Fruit button (ivory nut) is bleached for 0.8% hydrogen peroxide first by mass concentration, bleaching process
Temperature control is at 40 DEG C, and pH value is that the button after bleaching is cleaned with water after 10,4 hours, and use quality concentration is 1%
Acetum is neutralized.
Then by 5g acid dyes (acid black, Indian yellow, acid red composition, can according to needed for actual production color
Carry out any proportioning) and water mixed, and control temperature at 90 DEG C, be stirred simultaneously, after stirring, the above-mentioned fruit of addition
Real button is dyed, the button after just being contaminated after 10 minutes.
After button after the first dye that above-mentioned steps are obtained, with standard color card verification, then by water cleaning, mass concentration is
1% fixation liquid fixation and water cleaning, after centrifuge dewatering, after finally drying 7 hours, the fruit button after being dyed.
The fruit button obtained to above-mentioned steps is detected.
Specimen size:φ15.3mm*4mm
Detection device:Precise colorimeter
Detection method:L, a, b value at modification liquid stoste and surface of test piece are measured with precise colorimeter.
Computational methods:
L:Whiteness a:Red green axle chromaticity index b:Yellowish green axle chromaticity index
Δ L=L sample-L standards
Δ a=a sample-a standards
Δ b=b sample-b standards
Δ E represents the size of total color difference, and vision can not identify difference during usual Δ E≤3.0;
L is big to represent partially white, and L is small to represent partially black;
A is big to represent partially red, and a is small to represent partially green;
B is big, and expression is partially yellow, and b is small to represent partially green.
As a result referring to table 1, table 1 is the color characteristics detection number for the fruit button that the embodiment of the present invention is prepared with comparative example
According to, it can be seen from data in table 1 dye after fruit button, test specimen 1mm place Δ E values be 3.42, vision can differentiate face
Aberration is different, and button integral color is uneven, and edge color is shallower, and central area color is deeper, and left side color is deeper, the right color
It is shallower.Thus, diffusion is poor in the fruit button of dyestuff after dyeing, and aberration is bigger than normal.
Embodiment 1
The ammoniacal liquor that 200g mass concentrations are 16%, 5g base catalyst sodium carbonate, 15g fluorescent whitening agents double three are prepared first
(acid black, Indian yellow, the composition of acid red, can be according to needed for actual production for piperazine amino-stilbene and 5g acid dyes
Color carries out any proportioning).
Then first ammoniacal liquor is added in reactor, and is warming up to 70 DEG C, then with base catalyst sodium carbonate regulation pH value to
7.5, double triazine amido diphenyl ethylene fluorescent bleaches 33# (Shanghai Jin Yue Chemical Co., Ltd.s) are added, are turned with 130rpm
Speed stirring 10min;Acid dyes is eventually adding, continues to stir after 30min, is cooled to 30 DEG C of dischargings, obtains dyeability modifier.
The dyeability modifier obtained to above-mentioned steps carries out Coloration experiment.
Colouring method:Fruit button (ivory nut) is bleached for 0.8% hydrogen peroxide first by mass concentration, floated
The temperature control of white process is at 40 DEG C, and pH value is 10, then adds above-mentioned dyeability modifier, after 4 hours with water to bleaching after
Button is cleaned, and use quality concentration is that 1% acetum is neutralized.
Then the dyestuff and water that are dyed will be needed to be mixed, and controls temperature at 90 DEG C, be stirred, stir simultaneously
After mixing uniformly, add above-mentioned fruit button and dyed, the button after just being contaminated after 10 minutes.
After button after the first dye that above-mentioned steps are obtained, with standard color card verification, then by water cleaning, mass concentration is
1% fixation liquid fixation and water cleaning, after centrifuge dewatering, after finally drying 7 hours, the fruit button after being dyed.
The fruit button obtained to above-mentioned steps is detected.
Specimen size:φ15.3mm*4mm
Detection device:Precise colorimeter
Detection method:L, a, b value at modification liquid stoste and surface of test piece are measured with precise colorimeter.
Computational methods:
L:Whiteness a:Red green axle chromaticity index b:Yellowish green axle chromaticity index
Δ L=L sample-L standards
Δ a=a sample-a standards
Δ b=b sample-b standards
Δ E represents the size of total color difference, and vision can not identify difference during usual Δ E≤3.0;
L is big to represent partially white, and L is small to represent partially black;
A is big to represent partially red, and a is small to represent partially green;
B is big, and expression is partially yellow, and b is small to represent partially green.
As a result referring to table 1, table 1 is the color characteristics detection number for the fruit button that the embodiment of the present invention is prepared with comparative example
According to using the dyeability modifier prepared by the present embodiment, the fruit button after dyeing, test specimen it can be seen from data in table 1
Δ E values at 1mm are 0.78, vision can not distinguishing colours difference, thus, diffusion in the fruit button of dyestuff after dyeing
Well, aberration is small.
Embodiment 2
The ammoniacal liquor that 200g mass concentrations are 16%, 5g base catalyst sodium carbonate, 12g fluorescent whitening agents double three are prepared first
(acid black, Indian yellow, the composition of acid red, can be according to needed for actual production for piperazine amino-stilbene and 4g acid dyes
Color carries out any proportioning).
Then first ammoniacal liquor is added in reactor, and is warming up to 70 DEG C, then with base catalyst sodium carbonate regulation pH value to
7.5, double triazine amido diphenyl ethylene fluorescent bleaches 33# (Shanghai Jin Yue Chemical Co., Ltd.s) are added, are turned with 130rpm
Speed stirring 10min;Acid dyes is eventually adding, continues to stir after 30min, is cooled to 30 DEG C of dischargings, obtains dyeability modifier.
The dyeability modifier obtained to above-mentioned steps carries out Coloration experiment.
Colouring method:Fruit button (ivory nut) is bleached for 0.8% hydrogen peroxide first by mass concentration, floated
The temperature control of white process is at 40 DEG C, and pH value is 10, then adds above-mentioned dyeability modifier, after 4 hours with water to bleaching after
Button is cleaned, and use quality concentration is that 1% acetum is neutralized.
Then the dyestuff and water that are dyed will be needed to be mixed, and controls temperature at 90 DEG C, be stirred, stir simultaneously
After mixing uniformly, add above-mentioned fruit button and dyed, the button after just being contaminated after 10 minutes.
After button after the first dye that above-mentioned steps are obtained, with standard color card verification, then by water cleaning, mass concentration is
1% fixation liquid fixation and water cleaning, after centrifuge dewatering, after finally drying 7 hours, the fruit button after being dyed.
The fruit button obtained to above-mentioned steps is detected.
Specimen size:φ15.3mm*4mm
Detection device:Precise colorimeter
Detection method:L, a, b value at modification liquid stoste and surface of test piece are measured with precise colorimeter.
Computational methods:
L:Whiteness a:Red green axle chromaticity index b:Yellowish green axle chromaticity index
Δ L=L sample-L standards
Δ a=a sample-a standards
Δ b=b sample-b standards
Δ E represents the size of total color difference, and vision can not identify difference during usual Δ E≤3.0;
L is big to represent partially white, and L is small to represent partially black;
A is big to represent partially red, and a is small to represent partially green;
B is big, and expression is partially yellow, and b is small to represent partially green.
As a result referring to table 1, table 1 is the color characteristics detection number for the fruit button that the embodiment of the present invention is prepared with comparative example
According to using the dyeability modifier prepared by the present embodiment, the fruit button after dyeing, test specimen it can be seen from data in table 1
Δ E values at 1mm are 0.55, vision can not distinguishing colours difference, thus, diffusion in the fruit button of dyestuff after dyeing
Well, aberration is small.
Embodiment 3
The ammoniacal liquor that 200g mass concentrations are 16%, 5g base catalyst sodium carbonate, 10g fluorescent whitening agents double three are prepared first
(acid black, Indian yellow, the composition of acid red, can be according to needed for actual production for piperazine amino-stilbene and 3g acid dyes
Color carries out any proportioning).
Then first ammoniacal liquor is added in reactor, and is warming up to 70 DEG C, then with base catalyst sodium carbonate regulation pH value to
7.5, double triazine amido diphenyl ethylene fluorescent bleaches 33# (Shanghai Jin Yue Chemical Co., Ltd.s) are added, are turned with 130rpm
Speed stirring 10min;Acid dyes is eventually adding, continues to stir after 30min, is cooled to 30 DEG C of dischargings, obtains dyeability modifier.
The dyeability modifier obtained to above-mentioned steps carries out Coloration experiment.
Colouring method:Fruit button (ivory nut) is bleached for 0.8% hydrogen peroxide first by mass concentration, floated
The temperature control of white process is at 40 DEG C, and pH value is 10, then adds above-mentioned dyeability modifier, after 4 hours with water to bleaching after
Button is cleaned, and use quality concentration is that 1% acetum is neutralized.
Then the dyestuff and water that are dyed will be needed to be mixed, and controls temperature at 90 DEG C, be stirred, stir simultaneously
After mixing uniformly, add above-mentioned fruit button and dyed, the button after just being contaminated after 10 minutes.
After button after the first dye that above-mentioned steps are obtained, with standard color card verification, then by water cleaning, mass concentration is
1% fixation liquid fixation and water cleaning, after centrifuge dewatering, after finally drying 7 hours, the fruit button after being dyed.
The fruit button obtained to above-mentioned steps is detected.
Specimen size:φ15.3mm*4mm
Detection device:Precise colorimeter
Detection method:L, a, b value at modification liquid stoste and surface of test piece are measured with precise colorimeter.
Computational methods:
L:Whiteness a:Red green axle chromaticity index b:Yellowish green axle chromaticity index
Δ L=L sample-L standards
Δ a=a sample-a standards
Δ b=b sample-b standards
Δ E represents the size of total color difference, and vision can not identify difference during usual Δ E≤3.0;
L is big to represent partially white, and L is small to represent partially black;
A is big to represent partially red, and a is small to represent partially green;
B is big, and expression is partially yellow, and b is small to represent partially green.
As a result referring to table 1, table 1 is the color characteristics detection number for the fruit button that the embodiment of the present invention is prepared with comparative example
According to using the dyeability modifier prepared by the present embodiment, the fruit button after dyeing, test specimen it can be seen from data in table 1
Δ E values at 1mm are 0.22, vision can not distinguishing colours difference, thus, diffusion in the fruit button of dyestuff after dyeing
Well, aberration is small.
The color characteristics for the fruit button that the embodiment of table 1 is prepared with comparative example are detected
Above to provided by the present invention a kind of for dyeability modifier of fruit button and preparation method thereof, colouring method
It is described in detail.Specifically individual example used herein is set forth to the principle and embodiment of the present invention, the above
The explanation of embodiment is only intended to the method and its core concept for helping to understand the present invention.It should be pointed out that for the art
Those of ordinary skill for, under the premise without departing from the principles of the invention, can also to the present invention carry out it is some improvement and repair
Decorations, these are improved and modification is also fallen into the protection domain of the claims in the present invention.
Claims (10)
1. a kind of dyeability modifier for fruit button, it is characterised in that consist of the following composition:
2. dyeability modifier according to claim 1, it is characterised in that the base catalyst is sodium carbonate and potassium carbonate
In one or more.
3. dyeability modifier according to claim 1, it is characterised in that the fluorescent whitening agent is talan and double three
One or more in piperazine amino-stilbene.
4. dyeability modifier according to claim 1, it is characterised in that the acid dyes be acid black, Indian yellow and
It is one or more in acid red.
5. dyeability modifier according to claim 1, it is characterised in that the mass concentration of the ammoniacal liquor is 10%~
22%.
6. the preparation method of a kind of dyeability modifier for fruit button, it is characterised in that comprise the following steps:
A after) ammoniacal liquor is mixed with base catalyst, mixed liquor is obtained;
B after mixed liquor that) above-mentioned steps are obtained, fluorescent whitening agent are mixed again with acid dyes, obtain for fruit button
Dyeability modifier.
7. preparation method according to claim 6, it is characterised in that the pH value of the mixed liquor is 6.5~8.5.
8. preparation method according to claim 6, it is characterised in that the temperature of the mixed liquor is 65~85 DEG C.
9. a kind of colouring method of fruit button, it is characterised in that comprise the following steps:
A) fruit button is bleached, and added after dyeability modifier, the button after being bleached;
B) after button, dyestuff after the bleaching for obtaining above-mentioned steps is mixed with water, the button after just being contaminated;
C) by the button after above-mentioned dyeing is through over cleaning fixation, cleaning and is dehydrated, then after drying, the fruit knob after being dyed
Button;
The dyeability modifier is that dyeability modifier or claim 6~8 described in Claims 1 to 5 any one are any one
Dyeability modifier prepared by.
10. preparation method according to claim 9, it is characterised in that the temperature of the mixing is 75~95 DEG C.
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CN106496618B (en) * | 2016-10-18 | 2022-02-08 | 浙江伟星实业发展股份有限公司 | Laser hollow-out processing liquid for fruit buttons and laser hollow-out fruit buttons |
CN107326702B (en) * | 2017-07-28 | 2019-11-26 | 浙江伟星实业发展股份有限公司 | A kind of fruit button surface layer colouring method and fruit button |
CN107604633A (en) * | 2017-08-31 | 2018-01-19 | 王露 | A kind of underwear whitening treatment methods |
CN109137462B (en) * | 2018-08-07 | 2020-01-03 | 江南大学 | Method for improving blackness of stock solution coloring viscose fibers |
WO2020096538A2 (en) * | 2018-09-05 | 2020-05-14 | Skalanova Eti̇ket Ve Teksti̇l Aksesuarlari San Ve Ti̇c Ltd Şti̇. | Full automatic water-based button and accessory painting machine |
CN110578260B (en) * | 2019-08-16 | 2022-03-01 | 浙江伟星实业发展股份有限公司 | Fruit button with ripple grain effect and preparation process thereof |
CN112277114B (en) * | 2020-10-09 | 2022-03-01 | 浙江伟星实业发展股份有限公司 | Contrast ivory nut button and preparation method thereof |
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CN1672886A (en) * | 2005-03-28 | 2005-09-28 | 高凯 | Log dyeing method |
CN101439530A (en) * | 2008-12-24 | 2009-05-27 | 赵斌 | Dyeing liquor capable of transparently dying lumber or bamboo wood and dyeing method thereof |
CN103173066A (en) * | 2011-12-26 | 2013-06-26 | 永港伟方(北京)科技股份有限公司 | Wood dyeing modifier and preparation method thereof |
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CN1672886A (en) * | 2005-03-28 | 2005-09-28 | 高凯 | Log dyeing method |
CN101439530A (en) * | 2008-12-24 | 2009-05-27 | 赵斌 | Dyeing liquor capable of transparently dying lumber or bamboo wood and dyeing method thereof |
CN103173066A (en) * | 2011-12-26 | 2013-06-26 | 永港伟方(北京)科技股份有限公司 | Wood dyeing modifier and preparation method thereof |
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