CN105713492A - Nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance - Google Patents
Nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance Download PDFInfo
- Publication number
- CN105713492A CN105713492A CN201610182768.4A CN201610182768A CN105713492A CN 105713492 A CN105713492 A CN 105713492A CN 201610182768 A CN201610182768 A CN 201610182768A CN 105713492 A CN105713492 A CN 105713492A
- Authority
- CN
- China
- Prior art keywords
- parts
- antifog
- antifreeze
- silicone resin
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance. The paint comprises raw materials as follows: alkyd resin, epoxy modified organic silicon resin, silicone resin, polyvinyl butyral, 2-(dimethylamino)ethyl methacrylate, isopropanol, acrylamide, vinyl chloride-vinyl ester, polydimethylsiloxane, tartaric acid, benzoic acid, ethyl acetate, titanate coupling agent TMC-TTS, nano zinc oxide, mica powder, zirconia, copper powder, kaolinite, clay, ceramic powder, aluminum powder, polyacrylonitrile-based carbon fibers, a butyl cellosolve, an antifoaming agent, a flame retardant, urea and trimethylolpropane triacrylate. The nano-modified paint has excellent anti-fog, anti-freezing and anti-corrosion performance.
Description
Technical field
The present invention relates to paint field, particularly relate to the modified paint of a kind of antifog antifreeze anticorrosive nano.
Background technology
At present, common antifouling paint mainly reaches antiseptical purpose from two aspects: one is that antifouling paint paint film stops corrosive medium and material surface contact with shielding action, cuts off the path of corrosion cell, increases resistance.Such as epoxy coal asphalt paint, epoxy glass squama antiseptic paint, chlorosulfonated polyethylene paint, polyureas, acrylic polyurethane coating etc.；Another is corrosion inhibition, some pigment of antifouling paint, or the product of itself and film forming matter or moisture, ground metal can play corrosion inhibition (including passivation), such as metal conditioner, phosphatization, zinc-plated chromium plating, epoxy phosphate yellow zinc chromate primer paint etc..But both antifouling paint antiseptic effects are limited; and carry out anticorrosion with cathodic protection effect; antiseptic effect is better; such as zinc rich paint; containing a large amount of zinc powders in zinc rich paint, being in close contact between zinc particles, between zinc particles and steel surface, the current potential of zinc is more negative than ferrum; so zinc atom easily loses electronics and becomes anode in electrolyte solution, iron rule is negative electrode.In anode region, zinc is corroded owing to losing electronics, and on cathode chamber, steel surface is continuously available electronics, thus being protected.After having site tissue damage on film, expose parent metal, can flow to iron and steel exposed portion at less area internal corrosion electric current, then the product of zinc is deposited upon being here formed as layer protecting film, delays corrosion to continue to occur.
The antifog antifreeze Corrosion Protection of paint of the prior art cannot meet the demand in actual production process.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes the modified paint of a kind of antifog antifreeze anticorrosive nano, has the antifog antifreeze Corrosion Protection of excellence.
The modified paint of the antifog antifreeze anticorrosive nano of one that the present invention proposes, its raw material includes by weight: alkyd resin 80-120 part, epoxy modified silicone resin 20-60 part, silicone resin 5-15 part, polyvinyl butyral resin 16-32 part, dimethylaminoethyl methacrylate 2-5 part, isopropanol 3-6 part, acrylamide 2-5 part, vinyl chloride ethylene ester 3-6 part, polydimethylsiloxane 1-5 part, tartaric acid 2-4 part, benzoic acid 3-5 part, ethyl acetate 1-3 part, titanate coupling agent TMC-TTS1-4 part, nano zine oxide 2-5 part, mica powder 1-4 part, zirconium oxide 2-8 part, copper powder 1-4 part, kaolinite 3-6 part, clay 4-8 part, ceramics 1-5 part, aluminium powder 2-5 part, polyacrylonitrile-based carbon fibre 3-6 part, butyl cellosolve 1-4 part, defoamer 1-5 part, fire retardant 2-4 part, carbamide 3-6 part, trimethylolpropane trimethacrylate 1-7 part.
Preferably, nano zine oxide is prepared by following technique: zinc nitrate and hexamethylene tetramine solution mix homogeneously are obtained material a, put into after material a is sealed and the constant temperature water bath of 85-100 DEG C stands 1-3h, after taking-up, room temperature stands 1-2d, then the supernatant is poured out, take out lower floor's liquid and put into dry 20-30h in drying baker, be cooled to room temperature and obtain nano zine oxide.
Preferably, the substance withdrawl syndrome of zinc nitrate is 0.1-0.3mol/L.
Preferably, the substance withdrawl syndrome of hexamethylene tetramine solution is 0.15-0.35mol/L.
Preferably, zinc nitrate and hexamethylene tetramine solution weight are than for 4-8:1-3.
Preferably, the weight ratio of alkyd resin, epoxy modified silicone resin, silicone resin and polyvinyl butyral resin is 85-115:25-55:8-12:18-30.
Preferably, the weight ratio of alkyd resin, titanate coupling agent TMC-TTS, nano zine oxide, mica powder, zirconium oxide, copper powder, kaolinite, clay, ceramics, aluminium powder, polyacrylonitrile-based carbon fibre and butyl cellosolve is 85-115:2-3:3-4:2-3:3-7:2-3:4-5:5-7:2-4:3-5:4-5:2-3.
Preferably, the weight ratio of alkyd resin, epoxy modified silicone resin, silicone resin, polyvinyl butyral resin, titanate coupling agent TMC-TTS and nano zine oxide is 85-115:25-55:8-12:18-30:2-3:3-4.
Preferably, its raw material includes by weight: alkyd resin 85-115 part, epoxy modified silicone resin 25-55 part, silicone resin 8-12 part, polyvinyl butyral resin 18-30 part, dimethylaminoethyl methacrylate 3-4 part, isopropanol 4-5 part, acrylamide 3-4 part, vinyl chloride ethylene ester 4-5 part, polydimethylsiloxane 2-4 part, tartaric acid 2.5-3.5 part, benzoic acid 3.5-4.5 part, ethyl acetate 1.5-2.5 part, titanate coupling agent TMC-TTS2-3 part, nano zine oxide 3-4 part, mica powder 2-3 part, zirconium oxide 3-7 part, copper powder 2-3 part, kaolinite 4-5 part, clay 5-7 part, ceramics 2-4 part, aluminium powder 3-4 part, polyacrylonitrile-based carbon fibre 4-5 part, butyl cellosolve 2-3 part, defoamer 2-4 part, fire retardant 2.5-3.5 part, carbamide 4-5 part, trimethylolpropane trimethacrylate 2-6 part.
Preferably, its raw material includes by weight: alkyd resin 100 parts, epoxy modified silicone resin 40 parts, silicone resin 10 parts, polyvinyl butyral resin 24 parts, dimethylaminoethyl methacrylate 3.5 parts, isopropanol 4.5 parts, acrylamide 3.5 parts, vinyl chloride ethylene ester 4.5 parts, polydimethylsiloxane 3 parts, 3 parts of tartaric acid, 4 parts of benzoic acid, ethyl acetate 2 parts, titanate coupling agent TMC-TTS2.5 part, nano zine oxide 3.5 parts, mica powder 2.5 parts, zirconium oxide 5 parts, copper powder 2.5 parts, 4.5 parts of kaolinite, clay 6 parts, ceramics 3 parts, aluminium powder 3.5 parts, polyacrylonitrile-based carbon fibre 4.5 parts, butyl cellosolve 2.5 parts, defoamer 3 parts, fire retardant 3 parts, 4.5 parts of carbamide, trimethylolpropane trimethacrylate 4 parts.
The modified paint of the antifog antifreeze anticorrosive nano of one of the present invention, its raw material includes its raw material and includes alkyd resin, epoxy modified silicone resin, silicone resin, polyvinyl butyral resin, dimethylaminoethyl methacrylate, isopropanol, acrylamide, vinyl chloride ethylene ester, polydimethylsiloxane, tartaric acid, benzoic acid, ethyl acetate, titanate coupling agent TMC-TTS, nano zine oxide, mica powder, zirconium oxide, copper powder, kaolinite, clay, ceramics, aluminum powder, polyacrylonitrile-based carbon fibre, butyl cellosolve, defoamer, fire retardant, carbamide and trimethylolpropane trimethacrylate.Wherein with alkyd resin and epoxy modified silicone resin for major ingredient, and by adding silicone resin, major ingredient is carried out reinforcement, it is effectively increased the antifog antifreeze and Corrosion Protection of major ingredient, polyvinyl butyral resin, dimethylaminoethyl methacrylate, isopropanol, acrylamide, vinyl chloride ethylene ester, polydimethylsiloxane, tartaric acid, benzoic acid and the ethyl acetate added is as the reinforced additive of major ingredient, its proportioning with major ingredient of conservative control, is effectively increased the antifog antifreeze Corrosion Protection of major ingredient；The titanate coupling agent TMC-TTS, nano zine oxide, mica powder, zirconium oxide, copper powder, kaolinite, clay, ceramics, aluminium powder, polyacrylonitrile-based carbon fibre and the butyl cellosolve that add are as modified and filler, and the proportioning of conservative control and major ingredient, it is effectively increased the antifog antifreeze Corrosion Protection of major ingredient；The epoxy modified silicone resin added, it is possible to by the adjustment effect of Zinc oxide particles, add the roughness on painting layer surface, obtains the painting layer of improvement.The water droplet contact angle on painting layer surface enlarges markedly, and enhances the hydrophobicity of coating, thus improve the water resistance of coating.Changing Zinc oxide particles incorporation, water droplet also there occurs change at the contact angle of coating surface, and coating hydrophobicity is adjusted by coarse structure simultaneously.It is effectively increased the antifog antifreeze Corrosion Protection of nano modification of the present invention paint.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; it is understood that; embodiment is served only for the present invention is described, rather than is used for limiting the invention, any make on basis of the present invention amendment, equivalent replacement etc. is all in protection scope of the present invention.
Embodiment 1
The modified paint of the antifog antifreeze anticorrosive nano of one that the present invention proposes, its raw material includes by weight: alkyd resin 100 parts, epoxy modified silicone resin 40 parts, silicone resin 10 parts, polyvinyl butyral resin 24 parts, dimethylaminoethyl methacrylate 3.5 parts, isopropanol 4.5 parts, acrylamide 3.5 parts, vinyl chloride ethylene ester 4.5 parts, polydimethylsiloxane 3 parts, 3 parts of tartaric acid, 4 parts of benzoic acid, ethyl acetate 2 parts, titanate coupling agent TMC-TTS2.5 part, nano zine oxide 3.5 parts, mica powder 2.5 parts, zirconium oxide 5 parts, copper powder 2.5 parts, 4.5 parts of kaolinite, clay 6 parts, ceramics 3 parts, aluminium powder 3.5 parts, polyacrylonitrile-based carbon fibre 4.5 parts, butyl cellosolve 2.5 parts, defoamer 3 parts, fire retardant 3 parts, 4.5 parts of carbamide, trimethylolpropane trimethacrylate 4 parts.
Nano zine oxide is prepared by following technique: be 0.2mol/L zinc nitrate by 6 parts of substance withdrawl syndrome by weight and 2 parts of substance withdrawl syndrome are that 0.25mol/L hexamethylene tetramine solution mix homogeneously obtains material a, put into after material a is sealed and the constant temperature water bath of 92.5 DEG C stands 2h, after taking-up, room temperature stands 1.5d, then the supernatant is poured out, take out lower floor's liquid and put into dry 25h in drying baker, be cooled to room temperature and obtain nano zine oxide.
Embodiment 2
The modified paint of the antifog antifreeze anticorrosive nano of one that the present invention proposes, its raw material includes by weight: alkyd resin 80 parts, epoxy modified silicone resin 60 parts, silicone resin 5 parts, polyvinyl butyral resin 32 parts, dimethylaminoethyl methacrylate 2 parts, isopropanol 6 parts, acrylamide 2 parts, vinyl chloride ethylene ester 6 parts, polydimethylsiloxane 1 part, 4 parts of tartaric acid, 3 parts of benzoic acid, ethyl acetate 3 parts, titanate coupling agent TMC-TTS1 part, nano zine oxide 5 parts, mica powder 1 part, zirconium oxide 8 parts, copper powder 1 part, 6 parts of kaolinite, clay 4 parts, ceramics 5 parts, aluminium powder 2 parts, polyacrylonitrile-based carbon fibre 6 parts, butyl cellosolve 1 part, defoamer 5 parts, fire retardant 2 parts, 6 parts of carbamide, trimethylolpropane trimethacrylate 1 part.
Nano zine oxide is prepared by following technique: be 0.3mol/L zinc nitrate by 4 parts of substance withdrawl syndrome by weight and 1 part of substance withdrawl syndrome is that 0.35mol/L hexamethylene tetramine solution mix homogeneously obtains material a, put into after material a is sealed and the constant temperature water bath of 85 DEG C stands 3h, after taking-up, room temperature stands 1d, then the supernatant is poured out, take out lower floor's liquid and put into dry 30h in drying baker, be cooled to room temperature and obtain nano zine oxide.
Embodiment 3
The modified paint of the antifog antifreeze anticorrosive nano of one that the present invention proposes, its raw material includes by weight: alkyd resin 120 parts, epoxy modified silicone resin 20 parts, silicone resin 15 parts, polyvinyl butyral resin 16 parts, dimethylaminoethyl methacrylate 5 parts, isopropanol 3 parts, acrylamide 5 parts, vinyl chloride ethylene ester 3 parts, polydimethylsiloxane 5 parts, 2 parts of tartaric acid, 5 parts of benzoic acid, ethyl acetate 1 part, titanate coupling agent TMC-TTS4 part, nano zine oxide 2 parts, mica powder 4 parts, zirconium oxide 2 parts, copper powder 4 parts, 3 parts of kaolinite, clay 8 parts, ceramics 1 part, aluminium powder 5 parts, polyacrylonitrile-based carbon fibre 3 parts, butyl cellosolve 4 parts, defoamer 1 part, fire retardant 4 parts, 3 parts of carbamide, trimethylolpropane trimethacrylate 7 parts.
Nano zine oxide is prepared by following technique: be 0.1mol/L zinc nitrate by 8 parts of substance withdrawl syndrome by weight and 3 parts of substance withdrawl syndrome are that 0.15mol/L hexamethylene tetramine solution mix homogeneously obtains material a, put into after material a is sealed and the constant temperature water bath of 100 DEG C stands 1h, after taking-up, room temperature stands 2d, then the supernatant is poured out, take out lower floor's liquid and put into dry 20h in drying baker, be cooled to room temperature and obtain nano zine oxide.
Embodiment 4
The modified paint of the antifog antifreeze anticorrosive nano of one that the present invention proposes, its raw material includes by weight: alkyd resin 85 parts, epoxy modified silicone resin 55 parts, silicone resin 8 parts, polyvinyl butyral resin 30 parts, dimethylaminoethyl methacrylate 3 parts, isopropanol 5 parts, acrylamide 3 parts, vinyl chloride ethylene ester 5 parts, polydimethylsiloxane 2 parts, 3.5 parts of tartaric acid, 3.5 parts of benzoic acid, ethyl acetate 2.5 parts, titanate coupling agent TMC-TTS2 part, nano zine oxide 4 parts, mica powder 2 parts, zirconium oxide 7 parts, copper powder 2 parts, 5 parts of kaolinite, clay 5 parts, ceramics 4 parts, aluminium powder 3 parts, polyacrylonitrile-based carbon fibre 5 parts, butyl cellosolve 2 parts, defoamer 4 parts, fire retardant 2.5 parts, 5 parts of carbamide, trimethylolpropane trimethacrylate 2 parts.
Nano zine oxide is prepared by following technique: be 0.25mol/L zinc nitrate by 5 parts of substance withdrawl syndrome by weight and 1.5 parts of substance withdrawl syndrome are that 0.32mol/L hexamethylene tetramine solution mix homogeneously obtains material a, put into after material a is sealed and the constant temperature water bath of 86 DEG C stands 2.5h, after taking-up, room temperature stands 1.2d, then the supernatant is poured out, take out lower floor's liquid and put into dry 28h in drying baker, be cooled to room temperature and obtain nano zine oxide.
Embodiment 5
The modified paint of the antifog antifreeze anticorrosive nano of one that the present invention proposes, its raw material includes by weight: alkyd resin 115 parts, epoxy modified silicone resin 25 parts, silicone resin 12 parts, polyvinyl butyral resin 18 parts, dimethylaminoethyl methacrylate 4 parts, isopropanol 4 parts, acrylamide 4 parts, vinyl chloride ethylene ester 4 parts, polydimethylsiloxane 4 parts, 2.5 parts of tartaric acid, 4.5 parts of benzoic acid, ethyl acetate 1.5 parts, titanate coupling agent TMC-TTS3 part, nano zine oxide 3 parts, mica powder 3 parts, zirconium oxide 3 parts, copper powder 3 parts, 4 parts of kaolinite, clay 7 parts, ceramics 2 parts, aluminium powder 4 parts, polyacrylonitrile-based carbon fibre 4 parts, butyl cellosolve 3 parts, defoamer 2 parts, fire retardant 3.5 parts, 4 parts of carbamide, trimethylolpropane trimethacrylate 6 parts.
Nano zine oxide is prepared by following technique: be 0.15mol/L zinc nitrate by 7 parts of substance withdrawl syndrome by weight and 2.5 parts of substance withdrawl syndrome are that 0.18mol/L hexamethylene tetramine solution mix homogeneously obtains material a, put into after material a is sealed and the constant temperature water bath of 99 DEG C stands 1.5h, after taking-up, room temperature stands 1.8d, then the supernatant is poured out, take out lower floor's liquid and put into dry 22h in drying baker, be cooled to room temperature and obtain nano zine oxide.
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention.
Claims (10)
1. the modified paint of antifog antifreeze anticorrosive nano, it is characterized in that, its raw material includes by weight: alkyd resin 80-120 part, epoxy modified silicone resin 20-60 part, silicone resin 5-15 part, polyvinyl butyral resin 16-32 part, dimethylaminoethyl methacrylate 2-5 part, isopropanol 3-6 part, acrylamide 2-5 part, vinyl chloride ethylene ester 3-6 part, polydimethylsiloxane 1-5 part, tartaric acid 2-4 part, benzoic acid 3-5 part, ethyl acetate 1-3 part, titanate coupling agent TMC-TTS1-4 part, nano zine oxide 2-5 part, mica powder 1-4 part, zirconium oxide 2-8 part, copper powder 1-4 part, kaolinite 3-6 part, clay 4-8 part, ceramics 1-5 part, aluminium powder 2-5 part, polyacrylonitrile-based carbon fibre 3-6 part, butyl cellosolve 1-4 part, defoamer 1-5 part, fire retardant 2-4 part, carbamide 3-6 part, trimethylolpropane trimethacrylate 1-7 part.
2. the modified paint of antifog antifreeze anticorrosive nano according to claim 1, it is characterized in that, nano zine oxide is prepared by following technique: zinc nitrate and hexamethylene tetramine solution mix homogeneously are obtained material a, put into after material a is sealed and the constant temperature water bath of 85-100 DEG C stands 1-3h, after taking-up, room temperature stands 1-2d, then the supernatant is poured out, take out lower floor's liquid and put into dry 20-30h in drying baker, be cooled to room temperature and obtain nano zine oxide.
3. the modified paint of antifog antifreeze anticorrosive nano according to claim 1 and 2, it is characterised in that the substance withdrawl syndrome of zinc nitrate is 0.1-0.3mol/L.
4. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-3, it is characterised in that the substance withdrawl syndrome of hexamethylene tetramine solution is 0.15-0.35mol/L.
5. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-4, it is characterised in that zinc nitrate and hexamethylene tetramine solution weight ratio is for 4-8:1-3.
6. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-5, it is characterised in that the weight ratio of alkyd resin, epoxy modified silicone resin, silicone resin and polyvinyl butyral resin is 85-115:25-55:8-12:18-30.
7. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-6, it is characterized in that, the weight ratio of alkyd resin, titanate coupling agent TMC-TTS, nano zine oxide, mica powder, zirconium oxide, copper powder, kaolinite, clay, ceramics, aluminium powder, polyacrylonitrile-based carbon fibre and butyl cellosolve is 85-115:2-3:3-4:2-3:3-7:2-3:4-5:5-7:2-4:3-5:4-5:2-3.
8. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-7, it is characterized in that, the weight ratio of alkyd resin, epoxy modified silicone resin, silicone resin, polyvinyl butyral resin, titanate coupling agent TMC-TTS and nano zine oxide is 85-115:25-55:8-12:18-30:2-3:3-4.
9. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-8, it is characterized in that, its raw material includes by weight: alkyd resin 85-115 part, epoxy modified silicone resin 25-55 part, silicone resin 8-12 part, polyvinyl butyral resin 18-30 part, dimethylaminoethyl methacrylate 3-4 part, isopropanol 4-5 part, acrylamide 3-4 part, vinyl chloride ethylene ester 4-5 part, polydimethylsiloxane 2-4 part, tartaric acid 2.5-3.5 part, benzoic acid 3.5-4.5 part, ethyl acetate 1.5-2.5 part, titanate coupling agent TMC-TTS2-3 part, nano zine oxide 3-4 part, mica powder 2-3 part, zirconium oxide 3-7 part, copper powder 2-3 part, kaolinite 4-5 part, clay 5-7 part, ceramics 2-4 part, aluminium powder 3-4 part, polyacrylonitrile-based carbon fibre 4-5 part, butyl cellosolve 2-3 part, defoamer 2-4 part, fire retardant 2.5-3.5 part, carbamide 4-5 part, trimethylolpropane trimethacrylate 2-6 part.
10. the modified paint of antifog antifreeze anticorrosive nano according to any one of claim 1-9, it is characterized in that, its raw material includes by weight: alkyd resin 100 parts, epoxy modified silicone resin 40 parts, silicone resin 10 parts, polyvinyl butyral resin 24 parts, dimethylaminoethyl methacrylate 3.5 parts, isopropanol 4.5 parts, acrylamide 3.5 parts, vinyl chloride ethylene ester 4.5 parts, polydimethylsiloxane 3 parts, 3 parts of tartaric acid, 4 parts of benzoic acid, ethyl acetate 2 parts, titanate coupling agent TMC-TTS2.5 part, nano zine oxide 3.5 parts, mica powder 2.5 parts, zirconium oxide 5 parts, copper powder 2.5 parts, 4.5 parts of kaolinite, clay 6 parts, ceramics 3 parts, aluminium powder 3.5 parts, polyacrylonitrile-based carbon fibre 4.5 parts, butyl cellosolve 2.5 parts, defoamer 3 parts, fire retardant 3 parts, 4.5 parts of carbamide, trimethylolpropane trimethacrylate 4 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610182768.4A CN105713492A (en) | 2016-03-24 | 2016-03-24 | Nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610182768.4A CN105713492A (en) | 2016-03-24 | 2016-03-24 | Nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105713492A true CN105713492A (en) | 2016-06-29 |
Family
ID=56158092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610182768.4A Pending CN105713492A (en) | 2016-03-24 | 2016-03-24 | Nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105713492A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106637926A (en) * | 2016-11-04 | 2017-05-10 | 南平博士达节能科技有限公司 | Waterborne synthetic leather surface treatment agent and preparation method thereof |
| CN106906655A (en) * | 2016-07-01 | 2017-06-30 | 陆海蓉 | Blend fabric finishing agent |
-
2016
- 2016-03-24 CN CN201610182768.4A patent/CN105713492A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106906655A (en) * | 2016-07-01 | 2017-06-30 | 陆海蓉 | Blend fabric finishing agent |
| CN106637926A (en) * | 2016-11-04 | 2017-05-10 | 南平博士达节能科技有限公司 | Waterborne synthetic leather surface treatment agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6502905B2 (en) | Corrosion prevention coating | |
| CN107459906A (en) | Corrosion-resistant composite layer | |
| CN104098972A (en) | Water-based antirust and antiseptic paint for metal and preparation method thereof | |
| KR101865092B1 (en) | Anti-corrosion water-soluble paint and varnish composition | |
| CN103254755A (en) | Hot-dip Al-Zn-coated steel sheet with excellent weather resistance, corrosion resistance and alkali resistance and preparation method and surface treating agent thereof | |
| CN107177287A (en) | A kind of aqueous high-performance priming paint of super acid resistance salt fog and preparation method thereof | |
| KR100867682B1 (en) | Eco-heavy duty coating system with high weatherability a method for preventing contamination | |
| JP2005314501A (en) | Coating material for highly corrosion-resistant zinc-based alloy-plated steel material | |
| CN108727961A (en) | Heat insulating and corrosion coating and preparation method thereof | |
| KR101130297B1 (en) | Two component zinc type water base paint composition | |
| WO2024002117A1 (en) | Antibacterial fluorine-modified epoxy vinyl ester resin, method for preparing same, and multi-mechanism synergistic universal anti-corrosion coating | |
| CN105713492A (en) | Nano-modified paint with anti-fog, anti-freezing and anti-corrosion performance | |
| CN105038469A (en) | Water-based inorganic anti-corrosive paint added with aluminum stearate | |
| CN105001688A (en) | Water-borne inorganic anti-corrosive paint added with lithium stearate | |
| CN105017965A (en) | Preparation method of carbon nanotube-montmorillonite-silicone modified zinc-rich paint with corrosion resistance | |
| CN103614049A (en) | Zinc-rich epoxy primer and preparation method thereof | |
| CN110467832A (en) | A kind of single-component water-based lithium base zinc-rich coating of environment-friendly type and preparation method thereof | |
| CN105062277A (en) | Sodium stearate-containing inorganic anticorrosive paint and preparation technology thereof | |
| CN111117484A (en) | Anticorrosive composition containing sheet-like carbon material | |
| CN104745044A (en) | Zinc-rich primer using activation technique | |
| KR101779514B1 (en) | Construction method of offshore structure with anticorrosion improved performance | |
| CN101386715A (en) | Environment friendly inorganic zinc silicate shop primer | |
| CN108610693A (en) | A kind of electric power material antirust paint and its preparation process | |
| KR20160127936A (en) | Water base color paint composition containing plate-shaped zinc powder | |
| WO2016024653A1 (en) | Pigment separable type aqueous paint composition mixed with plate-like zinc powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160629 |