CN105711208B - A kind of polyurethane-modified inorganic material insulation and decoration integrated plate and its production method - Google Patents

A kind of polyurethane-modified inorganic material insulation and decoration integrated plate and its production method Download PDF

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Publication number
CN105711208B
CN105711208B CN201610063020.2A CN201610063020A CN105711208B CN 105711208 B CN105711208 B CN 105711208B CN 201610063020 A CN201610063020 A CN 201610063020A CN 105711208 B CN105711208 B CN 105711208B
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polyurethane
mold
parts
material layer
inorganic material
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CN105711208A (en
Inventor
王耀西
王浩臻
高迎弟
何文龙
王晓明
刘兴洲
钟云
刘访艺
刘江斌
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WANHUA ENERGY SAVING TECHNOLOGY (YANTAI) Co.,Ltd.
Wanhua Building Technology Yantai Co Ltd
Wanhua Energysav Science and Technology Group Co Ltd
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Wanhua Energy Saving Technology (yantai) Co Ltd
Wanhua Energysav Science and Technology Group Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0871Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0875Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Laminated Bodies (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Building Environments (AREA)

Abstract

The present invention relates to a kind of polyurethane-modified inorganic heat-insulating decorative material integrated board and its production methods, belong to construction material structure and its production method technical field.Including following production technology:1), it is by the way of glue spraying or brush coating that decoration plane material and inorganic material layer is mutually compound, it is spare;2), the decoration plane material for being compounded with inorganic material layer is placed in the constant temperature mold of closing, with fire prevention coiled material layer above mold;3), with polyurethane combined material mold is poured into a mould, polyurethane combined material completes the molding and curing of polyurethane combined material in a mold, forms polyurethane foam, and polyurethane foam, inorganic material layer, decoration plane material and fire prevention coiled material layer are complex as a whole;4), spray in polyurethane foam, inorganic material layer, decoration plane material and the plank surrounding that is complex as a whole of fire prevention coiled material layer the waterproof coating of 0.5 2mm.Present invention process is simple and easy to do, and when construction is not required to do it interface processing, and production efficiency is high.

Description

A kind of polyurethane-modified inorganic material insulation and decoration integrated plate and its production method
Technical field
The present invention relates to a kind of polyurethane-modified inorganic heat preservation package material integrated board and its production methods, belong to Building wood Expect structure and its production method technical field.
Background technology
Rock wool, foamed glass, expanded and vitrified small ball etc. as traditional thermal insulation material there are A grades of flame retardant properties extensively should For exterior insulation field, the hard-foam polyurethane brand-new material best as heat insulation effect is in the great hair in exterior insulation field Exhibition prospect.Publication No.:202866195U, it is entitled:Novel wall rock wool heat-preservation decoration integrated board provides a kind of new Type wall rock wool heat-preservation decoration integrated board, including insulating layer and decorative layer, the insulating layer be rock-wool heat insulation plate, the decoration Layer is cement fibrolite plate, and rock-wool heat insulation plate is complex as a whole with cement fibrolite plate by Nian Jie;Publication No.: CN203383444U, it is entitled:Modified hard foam polyurethane heat insulation decoration integrated board provides a kind of modified hard-foam polyurethane and protects Warm decoration integrated board, including insulating layer, adhesive linkage and decorative layer, insulating layer is integrated by adhesive linkage and decorative layer bonding, The insulating layer is modified hard-foam polyurethane thermal insulation board, and the adhesive linkage is polyurethane glue-line, and the decorative layer is Cement fibre Plate.The thermal insulation material of both different form heat insulating decorative boards is compared, though the former has good anti-flammability as inorganic material, But it is higher with thermal conductivity factor as other traditional inorganic material, to reach the thicker insulating layer of corresponding heat insulation effect needs;Afterwards Although A grades of fire prevention are not achieved in person in flame retardant property, it is substantially reduced than traditional inorganic material thermal conductivity factor.In addition, due to certain Characteristic on a little performance of heat protective material(As rock wool easily absorbs water), need during construction individually do insulating layer in interface processing ability Wall increases working procedure and cost.
Invention content
The purpose of the present invention is that the advantage for making full use of rock wool in terms of preventing fires with heat preservation, overcomes above-mentioned existing product In place of the deficiencies of flame retardant effect and poor thermal insulation property existing in terms of production technology and construction technology, production technology is complicated, provide A kind of product quality is stably and controllable, performance safety reliably polyurethane-modified inorganic material insulation and decoration integrated plate and, work Skill is simple and easy to do, and coiled material layer and cement have a good compatibility, and when construction is not required to do it interface processing, and production efficiency is high Polyurethane-modified inorganic material insulation and decoration integrated plate production method.
Above-mentioned purpose to realize the present invention, the present invention use following technical scheme:
A kind of polyurethane-modified inorganic material insulation and decoration integrated plate is characterized in that including playing decoration and fire prevention The decoration plane material 1 of effect, the back side of decoration plane material 1 stick one or more inorganic material layer 2 separately, inorganic material layer 2 opposite side is equipped with fire prevention coiled material layer 4, and decoration plane material 1, inorganic material layer 2, fire prevention coiled material layer 4 are multiple by polyurethane foam 3 It is integrated to form a whole plate, the surrounding of whole plate is coated with waterproof coating 8;
The decoration plane material 1 is stone material, calcium silicate board with microporous, ceramic thin plate, metal decking, porcelain tendre, flexible sheet material, Cement fibre pressure Any one of power plate, plasterboard, pottery clay plates, face brick, acrylic board;
The inorganic material layer 2 is in the inorganic heat insulation material such as rock wool, foamed glass, foam cement, expanded and vitrified small ball Any or several complex;
The fire prevention coiled material layer 4 is the type interface sheet material being prepared by flame-proof type polyalcohol rubber cement, and base material is glass, net Any one in Ge Bu, non-woven fabrics;
The decoration plane material 1 is cement fibre pressure plate, and the outer surface of cement fibre pressure plate is coated with the true stone of F-C paint Paint or water-in-water multicolor coating.
A kind of production method of polyurethane-modified inorganic material insulation and decoration integrated plate, is as follows:
1), it is by the way of glue spraying or brush coating that decoration plane material 1 and inorganic material layer 2 is mutually compound, it is spare;
2), the decoration plane material 1 for being compounded with inorganic material layer 2 is placed in the constant temperature mold of closing, have above mold Fire prevention coiled material layer 4;
3), with polyurethane combined material mold is poured into a mould, polyurethane combined material completes polyurethane combined material in a mold Molding and curing, formed polyurethane foam 3, polyurethane foam 3, inorganic material layer 2, decoration plane material 1 and fireproof rolling Material layer 4 is complex as a whole;
4), in polyurethane foam 3, inorganic material layer 2, decoration plane material 1 and the plate that is complex as a whole of fire prevention coiled material layer 4 Material surrounding sprays the waterproof coating 8 of 0.5-2mm;
The waterproof coating is made of the raw material of following mass parts:30-40 parts of asphalt, polyoxypropyleneglycol 0.3-0.6 parts, 3-8 parts of nano-titanium dioxide, 1-4 parts of epoxy resin, 35-37 parts of water, 0.5-1 parts of PH conditioning agents;
The mold includes rectangular mould ontology 7 and is articulated with the mold upper cover 9 of 7 side of die ontology, die ontology 7 and Mold upper cover 9 is hollow structure, and water inlet 10, water outlet 5, die ontology 7 are equipped on die ontology 7 and mold upper cover 9 And hinge 6 is installed in mold upper cover 9;
The polyurethane combined material is A material and B material, and A expects and the mass ratio of B material is 1:(0.9-2.4).
The A material(It is commonly called as white material), main component and mass ratio are:
The polyalcohol is polyester polyol and/or polyether polyol, and quality is 100 parts, the master that polyalcohol is reacted with B material Body;
Catalyst is amines catalyst and/or metal-based catalysts, and quality is 2-5 parts, adjusts A, B and expects mixed reaction Speed;
Fire retardant is nitrogenous, phosphorus, the liquid of halogen or solid-state fire retardant, and quality is 10-25 parts, for improving the anti-of foam Fiery performance;
Foaming agent is any one in liquid blowing agent 141b, 245fa, pentane, and quality is 15-35 parts, and foaming agent leads to Physically or chemically generated reactive gas is crossed, is the main source of gas in foam;
Foam stabiliser uses the amphiprotic substance for playing emulsification, nucleation, foam stabilizing to foaming process, is silicone oil, tween, silk Any one in disk, quality is 2-5 part, such as AK8803, and foam stabiliser is used for adjusting cell size, exquisiteness degree, makes The foam stabilization of generation;
Other auxiliary agents are any one in antioxidant or color inhibition agent, and mass parts are 0-5 parts;
The B material(It is commonly called as black material):B material refer to isocyanates and its modified product, in hard bubble mainly with PM200, PM400,5005 etc., the different manufacturers trade mark are different, but its ingredient is all poly methylene poly phenyl poly isocyanate, English abbreviation PAPI;
The B material refer to isocyanates and its modified product, for any one in PM200, PM400,5005.
Step 3)Described in polyurethane combined material cast when temperature control at 10-40 DEG C.
Step 3)Described in mold temperature control at 15-80 DEG C,
Step 3)Described in polyurethane foam curing time in a mold control in 5-60min.
A kind of polyurethane-modified inorganic material insulation and decoration integrated plate and its production method of the present invention, provides one kind It is new using nothing/organic material or metal material as exterior finish, using polyurethane-modified inorganic material as a kind of polyurethane of insulating layer Modified inorganic material insulation and decoration integrated plate and its production method, the method are set using simple die or polyurethane Batch Process It is standby to be produced, using nothing/organic material or metal material as exterior finish, using polyurethane-modified inorganic material as insulating layer, to prevent Fiery coiled material is boundary layer, produces a kind of polyurethane-modified inorganic material insulation and decoration integrated plate using die methods, is produced A kind of good flame retardant effect of polyurethane-modified inorganic material insulation and decoration integrated plate collection inorganic material and hard-foam polyurethane are excellent Different heat-insulating property is integrated, stable and controllable for quality, and performance safety is reliable, and simple process is easy, and coiled material layer has with cement Good compatibility, when construction, are not required to do interface processing to it.
Description of the drawings
Fig. 1:The structure diagram of the polyurethane-modified inorganic material insulation and decoration integrated plate embodiment 1 of the present invention;
Fig. 2:The structure diagram of the polyurethane-modified inorganic material insulation and decoration integrated plate embodiment 2 of the present invention;
Fig. 3:The structure diagram of the polyurethane-modified inorganic material insulation and decoration integrated plate embodiment 3 of the present invention;
Fig. 4:The structural representation of mold in the polyurethane-modified inorganic material insulation and decoration integrated plate production method of the present invention Figure.
Specific embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel all other embodiments obtained under the premise of no creative work, shall fall within the protection scope of the present invention.
Embodiment 1
Polyurethane-modified inorganic material insulation and decoration integrated plate in the present embodiment, the dress including playing decoration and fireproofing function Veneer material 1, the back side of decoration plane material 1 stick organic and/or inorganic materials layer 2, and the opposite side of inorganic material layer 2 is equipped with fire prevention coiled material layer 4, Decoration plane material 1, inorganic material layer 2, fire prevention coiled material layer 4 are complex as a whole by polyurethane foam 3.
Decoration plane material 1 uses marble plate, and inorganic material layer 2 is the foamed glass of 3cm thickness, and production technology is specific Operating procedure is:
Use first the mode of brush coating by specification for the foamed glass of 0.6m × 0.45m be compounded in specification be 0.695m × On the marble plate of 0.540m, the marble plate of compound good foamed glass is then placed in deep 6cm, temperature is 50 DEG C And attach above in the constant temperature mold of fire prevention coiled material layer 4, mold uses 52 DEG C of recirculated water temperature controls, finally uses polyurethane combined material Mold to be poured into a mould, combination material temperature degree is 45 DEG C, always pours fluence as 790g, wherein, polyurethane combined material includes A material and B material, A is expected with the B mass ratioes expected:1:1.4, wherein A material include following raw material:Polyalcohol, catalyst, fire retardant, foaming agent, foam Stabilizer, mass ratio are:100:4.5:22:26:2 ;Wherein, polyalcohol is to include polyester polyol and/or polyether polyol, For example, the polyester polyols that the trade mark that polyester polyol can select Nanjing Nanjing Si Taipan Chemical Co., Ltd.s to produce is 3152 Alcohol, the polyether polyol that the trade mark that polyether polyol can select Zibo Nuo Li Chemical Co., Ltd.s to produce is 635;Catalyst is Amines catalyst and/or metal-based catalysts, for example, amines catalyst can select what air chemical products Co., Ltd produced The trade mark is the amines catalyst of PC5, and it is pungent that metal-based catalysts can select Yangzhou great river chemical industry Industrial Co., Ltd. to produce Sour potassium, fire retardant is nitrogenous, phosphorus, the liquid of halogen or solid-state fire retardant, for example, Jiangsu Daming Technology Co., Ltd. can be selected The TCPP liquid combustion inhibitors of production or the solid flame retardant melamine of Qingdao Tianyuan chemical inc production;Hair Infusion is any one in liquid blowing agent 141b, 245fa, pentane;Foam stabiliser use to foaming process rise emulsification, into Core, the amphiprotic substance of foam stabilizing effect, are any one in silicone oil, tween, wire tray;B material refer to isocyanates and its modified production Object, mainly with PM200, PM400,5005 etc. in hard bubble, the different manufacturers trade mark is different, but its ingredient is all polymethylene Polyphenyl polyisocyanate, English abbreviation PAPI.Guan Bi mould after casting complete,(Close hinge 6)Polyurethane combined material penetrates into In marble plate and foamed glass micropore and start to rise, in foaming process, polyurethane combined material by its own The molding of polyurethane foam is completed in reaction, is realized and marble plate, foaming glass by the permeability of its own, cementability Glass and the compound of coiled material layer 4 of preventing fires, finally provide the synergistic effect of pressure caused by temperature and foaming process in mold Under, complete a kind of molding of polyurethane-modified inorganic material insulation and decoration integrated plate.
Embodiment 2
The present embodiment and embodiment 1 the difference lies in:Decoration plane material 1 uses aluminum plate facing plate, and inorganic material layer 2 is The rock wool of 4cm thickness, production technology concrete operation step are:
Using the mode of brush coating first, specification is compounded in specification for the rock wool of 0.75m × 0.5m is 0.75m × 0.6m's On aluminum plate facing plate, the aluminum plate facing plate of compound good rock wool is then placed in deep 6cm, temperature as 50 DEG C and attaches good fire prevention above In the constant temperature mold of coiled material layer 4, mold uses 52 DEG C of recirculated water temperature controls, and finally mold is poured into a mould with polyurethane combined material, It is 45 DEG C to combine material temperature degree, always pours fluence as 900g, Guan Bi mould after casting complete.Polyurethane combined material penetrates into aluminum plate facing plate 1 with 2 micropore of rock wool in and start to rise, in foaming process, polyurethane combined material pass through its own reaction complete polyurethane The molding of froth bed 3 is realized and aluminum plate facing plate, rock wool and coiled material fire prevention coiled material by the permeability of its own, cementability Layer 4 it is compound, finally in the case where mold provides the synergistic effect of pressure caused by temperature and foaming process, a kind of poly- ammonia of completion The molding of ester modified inorganic material insulation and decoration integrated plate finally sprays waterproof coating layer 8 in the both sides of exposed rock wool, into Divide and mass fraction is as follows:40 parts of asphalt, 0.3 part of polyoxypropyleneglycol, 8 parts of nano-titanium dioxide, epoxy resin 4 parts, 35 parts of water, 0.5 part of PH conditioning agents.
Embodiment 3
The difference lies in decoration plane material 1 uses acrylic decoration panel, inorganic material to the present embodiment with embodiment 1 or 2 Expanded and vitrified small ball of the layer 2 for three 5cm thickness, production technology concrete operation step are:
It uses the mode of glue spraying that specification is compounded in specification for three expanded and vitrified small balls of 1.05m × 0.15m first to be On the acrylic decoration panel of 1.2m × 0.6m, then by the acrylic decoration panel 1 of compound good expanded and vitrified small ball be placed in deep 9cm, For temperature for 40 DEG C and in the constant temperature mold above for attaching fire prevention coiled material layer 4, mold uses 42 DEG C of recirculated water temperature controls, finally with poly- Urethane combination material pours into a mould mold, and combination material temperature degree is 30 DEG C, always pours fluence as 2500g.Polyurethane combined material penetrates into sub- Gram force decoration panel is interior with expanded and vitrified small ball micropore and starts to rise, and in foaming process, polyurethane combined material passes through its own Reaction complete polyurethane foam molding, pass through the permeability of its own, cementability realize with acrylic decoration panel, expansion Glass bead and the compound of coiled material layer 4 of preventing fires, finally provide the association of pressure caused by temperature and foaming process in mold Under same-action, a kind of molding of polyurethane-modified inorganic material insulation and decoration integrated plate is completed.
A kind of polyurethane-modified inorganic material insulation and decoration integrated plate and its production method of the present invention, provides one kind It is new using nothing/organic material or metal material as exterior finish, using polyurethane-modified inorganic material as a kind of polyurethane of insulating layer Modified inorganic material insulation and decoration integrated plate and its production method, the method are set using simple die or polyurethane Batch Process It is standby to be produced, using nothing/organic material or metal material as exterior finish, using polyurethane-modified inorganic material as insulating layer, to prevent Fiery coiled material is boundary layer, produces a kind of polyurethane-modified inorganic material insulation and decoration integrated plate using die methods, is produced A kind of good flame retardant effect of polyurethane-modified inorganic material insulation and decoration integrated plate collection inorganic material and hard-foam polyurethane are excellent Different heat-insulating property is integrated, stable and controllable for quality, and performance safety is reliable, and simple process is easy, and coiled material layer has with cement Good compatibility, when construction, are not required to do interface processing to it.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (3)

1. a kind of production method of polyurethane-modified inorganic material insulation and decoration integrated plate, is as follows:
1), by the way of glue spraying or brush coating by decoration plane material(1)With inorganic material layer(2)It is mutually compound, it is spare;
2), inorganic material layer will be compounded with(2)Decoration plane material (1) be placed in the constant temperature mold of closing, have above mold Fire prevention coiled material layer(4);
3), with polyurethane combined material mold is poured into a mould, polyurethane combined material complete in a mold polyurethane combined material into Type and curing, form polyurethane foam(3), polyurethane foam(3), inorganic material layer(2), decoration plane material(1)It is and anti- Fiery coiled material layer(4)It is complex as a whole;
4), in polyurethane foam(3), inorganic material layer(2), decoration plane material(1)And fire prevention coiled material layer(4)It is complex as a whole Plank surrounding spraying 0.5-2mm waterproof coating(8);
The waterproof coating( 8)It is made of the raw material of following mass parts:30-40 parts of asphalt, polyoxypropyleneglycol 0.3-0.6 parts, 3-8 parts of nano-titanium dioxide, 1-4 parts of epoxy resin, 35-37 parts of water, 0.5-1 parts of PH conditioning agents;
The polyurethane combined material is A material and B material, and A expects and the mass ratio of B material is 1:(0.9-2.4);
The A expects that its main component and mass fraction are:
Polyalcohol is polyester polyol and/or polyether polyol, and quality is 100 parts;
Catalyst is amines catalyst and/or metal-based catalysts, and quality is 2-5 parts;
Fire retardant is nitrogenous, phosphorus, the liquid of halogen or solid-state fire retardant, and quality is 10-25 parts;
Foaming agent is any one in liquid blowing agent 141b, 245fa, pentane, and quality is 15-35 parts;
Foam stabiliser uses the amphiprotic substance for playing emulsification, nucleation, foam stabilizing to foaming process, is in silicone oil, tween, wire tray Any one, quality be 2-5 parts;
Other auxiliary agents are any one in antioxidant or color inhibition agent, and mass parts are 0-5 parts;
The B material refer to isocyanates and its modified product, for any one in PM200, PM400,5005.
2. a kind of production method of polyurethane-modified inorganic material insulation and decoration integrated plate described in accordance with the claim 1, It is characterized in that:
The mold includes rectangular mould ontology(7)And it is articulated with die ontology(7)The mold upper cover of side(9), die ontology (7)And mold upper cover(9)It is hollow structure, die ontology(7)And mold upper cover(9)On be equipped with water inlet(10), water outlet Mouthful(5), die ontology(7)And mold upper cover(9)On hinge is installed(6).
3. a kind of production method of polyurethane-modified inorganic material insulation and decoration integrated plate described in accordance with the claim 1, It is characterized in that:
Step 3)Described in polyurethane combined material cast when temperature control at 10-40 DEG C;
Step 3)Described in mold temperature control at 15-80 DEG C;
Step 3)Described in polyurethane foam curing time in a mold control in 5-60min.
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