CN105702579B - Manufacturing method of epitaxial channel on fin and fin field effect transistor - Google Patents

Manufacturing method of epitaxial channel on fin and fin field effect transistor Download PDF

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Publication number
CN105702579B
CN105702579B CN201410681972.1A CN201410681972A CN105702579B CN 105702579 B CN105702579 B CN 105702579B CN 201410681972 A CN201410681972 A CN 201410681972A CN 105702579 B CN105702579 B CN 105702579B
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fin
manufacturing
chamber
gas
layer
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CN105702579A (en
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秦长亮
殷华湘
李俊峰
赵超
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Institute of Microelectronics of CAS
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Institute of Microelectronics of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66787Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
    • H01L29/66795Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/785Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • H01L29/7853Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET the body having a non-rectangular crossection
    • H01L29/7854Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET the body having a non-rectangular crossection with rounded corners

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The invention discloses a method for manufacturing a fin of a fin field effect transistor, which comprises the following steps: providing a substrate, wherein fins which are mutually isolated are formed in the substrate; performing pre-baking before fin epitaxy to remove a natural oxide layer on the fin, and reflowing the fin in a pre-baking chamber; an epitaxial layer is grown on the fin. In the invention, after reflow, the height of the fin is reduced, the original doping residue in the channel region can move downwards to the lower part of the fin, and the regrown epitaxial layer is used as a part or a new channel, so that the device has better device characteristics.

Description

The manufacturing method of epi channels, fin formula field effect transistor on fin
Technical field
The invention belongs to epi channels in field of semiconductor manufacture more particularly to a kind of fin formula field effect transistor, fin Manufacturing method.
Background technology
Highly integrated with semiconductor devices, the short-channel effect of the MOSFET element of plane is more notable, is degrading The performance of device.
Currently, in order to solve the problems, such as short-channel effect, it is proposed that the three-dimensional device of fin formula field effect transistor (Fin-FET) Part structure, Fin-FET are the transistors for having fin channel structure, it using several surfaces of thin fin as raceway groove, so as to To prevent the short-channel effect in conventional transistor, while operating current can be increased.
In Fin-FET device fabrications, due to PTSL (Punch Though Stop Layer, break-through stop-layer) Deng the doping in channel region so that channel region remains unwanted impurity, increases the scattering of channel region, influences the performance of device.
Invention content
It is an object of the invention to overcome deficiency in the prior art, a kind of fin formula field effect transistor, outer on fin is provided The manufacturing method for prolonging raceway groove improves the stress of source-drain area.
To achieve the above object, the technical scheme is that:
The manufacturing method of epi channels on a kind of fin, including step:
Substrate is provided, mutually isolated fin is formed in substrate;
Ion implanting is carried out, to form break-through stop-layer;
The front baking before fin extension is carried out, to remove the natural oxidizing layer on fin, and fin is returned in the chamber of front baking Stream, makes the height of fin reduce, and the original doping residual of channel region is displaced downwardly to the lower part of fin;
In fin growing epitaxial layers;
Front baking refers to reacting to generate compound with the natural oxidizing layer on fin by the gas in chamber, and compound is gasifying It is detached afterwards from fin surface;
Reflux refers to changing gas pressure intensity and/or temperature in chamber, so that the height of fin is reduced, the atom of fin rearranges.
Optionally, the mobility for stating epitaxial layer is more than the mobility of fin.
Optionally, the substrate is SOI or GOI substrates.
Optionally, the gas of front baking is H2Or H2With HCl, NH4F or GeH4Mixed gas or HF and N2Mixing Gas.
Optionally, when removing removing natural oxidizing layer, the pressure of chamber indoor gas holds in the palm for 20-2000, and the temperature of cavity is 450- 1150℃。
Optionally, when flowing back to fin, the pressure of chamber indoor gas is -200 support of 50 millitorr, and the temperature of cavity is 450- 1150℃。
Optionally, when removing removing natural oxidizing layer, the pressure of chamber indoor gas holds in the palm for 250-1000, and the temperature of cavity is 700- 850℃。
Optionally, when flowing back to fin, the pressure of chamber indoor gas holds in the palm for 1-100, and the temperature of cavity is 700-850 ℃。
Optionally, the thickness range of epitaxial layer is 1-100nm.
Optionally, the thickness range of epitaxial layer is 5-40nm.
In addition, the present invention also provides a kind of manufacturing method of fin formula field effect transistor, any of the above-described manufacturer is utilized Method forms epi channels on fin.
The manufacturing method of epi channels on the fin formula field effect transistor of the embodiment of the present invention, fin, before being carried out to whole fin It dries, and flows back to fin in the chamber of front baking, then, carry out the extension of fin, so that the height of fin reduces after reflux, raceway groove The original doping residual in area can be displaced downwardly to the lower part of fin, and the epitaxial layer to regrow has more preferable as part or new raceway groove Device property.Meanwhile the atom for the skeg that flows back rearranges, and reduces the defects of fin, to improve subsequent epitaxial layer Quality.
Further, the fin after reflux is easy to the higher-quality epitaxial layer of extension, the epitaxial layer of extension mobility bigger, The carrier mobility that will further improve raceway groove improves the speed of device.
Description of the drawings
It, below will be to attached drawing needed in the embodiment in order to illustrate more clearly of the technical solution that the present invention is implemented It is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, general for this field For logical technical staff, without creative efforts, other drawings may also be obtained based on these drawings.
Fig. 1 is the flow chart according to the manufacturing method of the fin formula field effect transistor source-drain area of the present invention;
Fig. 2A-Fig. 6 B are the solid in each manufacturing process for manufacture fin formula field effect transistor according to the embodiment of the present invention Structural schematic diagram, wherein Fig. 2A -6A are the schematic cross-section of the transistor of the cross-sectional direction along fin, and Fig. 2 B-6B are along fin The diagrammatic cross-section of the transistor of length direction;
The epitaxial layer of the fin of Fig. 7 A and 7B respectively conventional manufacturing process, the formation of the manufacturing process of the embodiment of the present invention exists Schematic cross-section under microscope.
Specific implementation mode
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, below in conjunction with the accompanying drawings to the present invention Specific implementation mode be described in detail.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still the present invention can be with Implemented different from other manner described here using other, those skilled in the art can be without prejudice to intension of the present invention In the case of do similar popularization, therefore the present invention is not limited by following public specific embodiment.
Secondly, combination schematic diagram of the present invention is described in detail, when describing the embodiments of the present invention, for purposes of illustration only, table Show that the sectional view of device architecture can disobey general proportion and make partial enlargement, and the schematic diagram is example, is not answered herein Limit the scope of protection of the invention.In addition, three-dimensional space that should be comprising length, width and depth in actual fabrication.
The present invention proposes a kind of manufacturing method of fin formula field effect transistor fin, including:Substrate is provided, is formed in substrate There is mutually isolated fin;The front baking before fin extension is carried out, to remove the natural oxidizing layer on fin, and to fin in the chamber of front baking It flows back;In fin growing epitaxial layers.
In the present invention, front baking is carried out to whole fin, and flowed back to fin in the chamber of front baking, then, carry out fin Extension, so that the height of fin reduces after reflux, the original doping residual of channel region can be displaced downwardly to the lower part of fin, regrow Epitaxial layer has better device property as part or new raceway groove, undoped residual.Meanwhile the atom for the skeg that flows back It rearranges, reduces the defects of fin, to improve the quality of subsequent epitaxial layer.
It should be noted that in the attached drawing of the present invention, the attached drawing of same sequence number is same manufacture such as Fig. 2A and Fig. 2 B The schematic cross-section of the different directions of transistor in the process, wherein Fig. 2A -6A are cutting for the transistor of the cross-sectional direction along fin Face schematic diagram, i.e. Fig. 2 B-6B are the cross-sectional view of the transistor along fin extending direction.
Technical solution in order to better understand the present invention and technique effect, below with reference to specific flow diagram figure 1 pair of specific embodiment is described in detail.
First, in step S01, provide substrate 100, mutually isolated fin 110 be formed in substrate 100, with reference to figure 4A and Shown in Fig. 4 B.
In the present invention, the substrate 100 can be Si substrates, Ge substrates, SiGe substrate, SOI (silicon-on-insulator, Silicon On Insulator) or GOI (germanium on insulator, Germanium On Insulator) etc., the substrate may be used also Think that the substrate including other elements semiconductor or compound semiconductor, such as GaAs, InP or SiC etc. can also be lamination knot Structure, such as Si/SiGe etc. can be with other epitaxial structures, such as SGOI (silicon germanium on insulator) etc..In the present embodiment, institute It is body silicon substrate to state substrate, with reference to shown in figure 2A.
In a specific embodiment, fin 110 and isolation 120 can be provided as follows.
First, the first hard mask 104 is formed on the substrate 100 of body silicon, such as silicon nitride;Then, using lithographic technique, example Such as the method for RIE (reactive ion etching), etched substrate 100 forms fin 102, so as to form the fin 102 on substrate 100, As shown in Figure 2 A and 2B.
Then, as shown in Figure 3A and Figure 3B, the filling of isolated material 106 is carried out, isolated material for example can be titanium dioxide Silicon is then planarized, until exposing the upper surface of fin 102, then, can use wet etching, such as use hydrofluoric acid The isolated material of the certain thickness silica of erosion removal, the isolated material of member-retaining portion between fin 102, so as to form Isolation 110, with reference to shown in figure 4A and Fig. 4 B.
Then, in step S02, the front baking before fin extension is carried out, to remove the natural oxidizing layer on fin, and in the chamber of front baking It flows back to fin in room, with reference to shown in figure 6A and Fig. 6 B.
In the manufacturing process of body silicon substrate, is formed after fin, as shown in Figure 4 A and 4 B shown in FIG., usually to carry out ion note Enter, to form break-through stop-layer (Punch Though Stop Layer, PTSL) 108 under the raceway groove of fin.Normally, PTSL The angular range of ion implanting is 0-45 °, and dosage range is 1E12 to 1E14cm-2, energy range is 10 to 150KEV.In this reality It applies in example, the angular range of PTSL ion implantings is 0-7 °, and dosage range is 5E12 to 5E13cm-2, energy range be 30 to 80KEV.Normally, PTSL ion implantings use the ion that opposite types are injected with source and drain, and for N-type device, implanting p-type is miscellaneous Matter, such as B etc.;For P-type device, N-type impurity, for example, As or P etc. are injected.Break-through is formed in the ion implanting for forming PTSL After stop-layer, in channel region, there is also non-uniform doping concentrations for meeting, this makes the knot between channel region and source-drain area Pattern tilt, the working condition of device is had an impact, the deterioration of device performance is caused.
In the present embodiment, after forming break-through stop-layer, front baking and reflux technique are carried out.Front baking before fin extension In processing step, the natural oxidizing layer on fin is removed, so as to subsequently in fin growing epitaxial layers, in front baking technique, usually It is that compound is generated with oxidation pasc reaction by the gas in chamber, the melting point compound of generation is low, is easy gasification, after gasification It is detached from fin surface, to achieve the purpose that remove fin oxide on surface, the gas of front baking can be H2、H2With the gaseous mixture of HCl Body, H2With NH4The mixed gas of F, H2With GeH4Mixed gas or HF and N2Mixed gas etc..
Removal and the reflow step of natural oxidizing layer are carried out in the chamber for the front baking for removing removing natural oxidizing layer.Specifically , first, the removal of natural oxidizing layer is carried out in the chamber of front baking, the gas of front baking can be H2、H2With the gaseous mixture of HCl Body, H2With NH4The mixed gas of F, H2With GeH4Mixed gas or HF and N2Mixed gas, in the process, in chamber The pressure of gas is that 20-2000 holds in the palm (torr), and the temperature of cavity is 450-1150 DEG C, in a preferred embodiment, chamber Indoor Air The pressure of body holds in the palm for 250-1000, and the temperature of cavity is 700-850 DEG C;Then, in the chamber, change the indoor pressure of chamber And/or temperature, the reflux (re-flow) of fin is carried out, in the process, the pressure of chamber indoor gas is -200 support of 50 millitorr, chamber The temperature of body is 450-1150 DEG C, and in preferred embodiment, the pressure of chamber indoor gas holds in the palm for 1-100, and the temperature of cavity is 700-850℃.Upon reflowing, with reference to shown in figure 5A and Fig. 5 B, the height of fin reduces, and the original doping residual of channel region can move down To the lower part of fin, the atom of fin rearranges, and reduces the defects of fin, is conducive to the quality for improving subsequent epitaxial.
In the present embodiment, H is used in the chamber of front baking2Or H2With the mixed gas of HCl, after reflux, with reference to figure 7B institutes Show, fin forms the polyhedron with (111) face, and the polyhedron is shorter wider.
In step S03, in fin growing epitaxial layers 103, with reference to shown in figure 6A and 6B.
Selective epitaxial process may be used, carry out the growth of the epitaxial layer of fin, the thickness of epitaxial layer can be 1- The atom of 100nm, the fin after being flowed back have re-started arrangement, more conducively improve the quality of epitaxial layer, meanwhile, channel region is former Some doping residuals can be displaced downwardly to the lower part of fin, and the epitaxial layer to regrow is as partly or new raceway groove, undoped residual, With better device property.
In a preferred embodiment, epitaxial layer selection mobility is formed higher than the material of fin, and thickness range can be 5- 40nm in this way, will further improve the carrier mobility of raceway groove, and then improves the speed of device.Such as the fin for silicon, outside Prolong the material or two or more compound-materials constituted that the single-element that layer can be four races is constituted, such as germanium silicon, carbon silicon Deng;Can also be three-five material single-element constitute material or two or more constitute compound-materials, such as GaAs, InP etc..
With reference to shown in figure 7A and 7B, Fig. 7 A and 7B are respectively the manufacturing process of routine, the manufacturing process of the embodiment of the present invention The schematic cross-section of the epitaxial layer of the fin of formation under the microscope, it can be seen that the epitaxial layer of the embodiment of the present invention has better Epitaxial quality and pattern.
So far, the fin with epitaxial layer of the embodiment of the present invention is formd, then, the follow-up manufacture work of device can be completed Skill, such as gate dielectric layer, grid and side wall and source-drain area etc. are continuously formed on epitaxial layer.
Although the present invention has been disclosed in the preferred embodiments as above, however, it is not intended to limit the invention.It is any to be familiar with ability The technical staff in domain, without departing from the scope of the technical proposal of the invention, all using in the methods and techniques of the disclosure above Appearance makes many possible changes and modifications to technical solution of the present invention, or is revised as the equivalent embodiment of equivalent variations.Therefore, Every content without departing from technical solution of the present invention is made to the above embodiment any simple according to the technical essence of the invention Modification, equivalent variations and modification, in the range of still falling within technical solution of the present invention protection.

Claims (11)

1. the manufacturing method of epi channels on a kind of fin, which is characterized in that including step:
Substrate is provided, mutually isolated fin is formed in substrate;
Ion implanting is carried out, to form break-through stop-layer;
The front baking before fin extension is carried out, to remove the natural oxidizing layer on fin, and flows back, makes to fin in the chamber of front baking The height of fin reduces, and the original doping residual of channel region is displaced downwardly to the lower part of fin;
In fin growing epitaxial layers;
Front baking refer to reacted with the natural oxidizing layer on fin by the gas in chamber generate compound, compound after gasification from Fin surface detaches;
Reflux refers to changing gas pressure intensity and/or temperature in chamber, so that the height of fin is reduced, the atom of fin rearranges.
2. manufacturing method according to claim 1, which is characterized in that the mobility of the epitaxial layer is more than the migration of fin Rate.
3. manufacturing method according to claim 1, which is characterized in that the substrate is SOI or GOI substrates.
4. manufacturing method according to claim 1, which is characterized in that the gas of front baking is H2Or H2With HCl, NH4F or GeH4Mixed gas or HF and N2Mixed gas.
5. manufacturing method according to claim 1, which is characterized in that when removing removing natural oxidizing layer, the pressure of chamber indoor gas It is held in the palm for 20-2000 by force, the temperature of cavity is 450-1150 DEG C.
6. manufacturing method according to claim 1, which is characterized in that when flowing back to fin, the pressure of chamber indoor gas Temperature for -200 support of 50 millitorr, cavity is 450-1150 DEG C.
7. manufacturing method according to claim 1, which is characterized in that when removing removing natural oxidizing layer, the pressure of chamber indoor gas It is held in the palm for 250-1000 by force, the temperature of cavity is 700-850 DEG C.
8. manufacturing method according to claim 7, which is characterized in that when flowing back to fin, the pressure of chamber indoor gas It is held in the palm for 1-100, the temperature of cavity is 700-850 DEG C.
9. manufacturing method according to claim 1, which is characterized in that the thickness range of epitaxial layer is 1-100nm.
10. manufacturing method according to claim 1, which is characterized in that the thickness range of epitaxial layer is 5-40nm.
11. a kind of manufacturing method of fin formula field effect transistor, which is characterized in that described in any one of claim 1-10 Fin on epi channels manufacturing method.
CN201410681972.1A 2014-11-24 2014-11-24 Manufacturing method of epitaxial channel on fin and fin field effect transistor Active CN105702579B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102496574A (en) * 2011-11-17 2012-06-13 上海华力微电子有限公司 Pretreatment method for SiGe selective epitaxial growth
CN103227200A (en) * 2012-01-31 2013-07-31 台湾积体电路制造股份有限公司 Finfet and method of fabricating the same
CN104022037A (en) * 2013-02-28 2014-09-03 中芯国际集成电路制造(上海)有限公司 Fin type field effect transistor and forming method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102496574A (en) * 2011-11-17 2012-06-13 上海华力微电子有限公司 Pretreatment method for SiGe selective epitaxial growth
CN103227200A (en) * 2012-01-31 2013-07-31 台湾积体电路制造股份有限公司 Finfet and method of fabricating the same
CN104022037A (en) * 2013-02-28 2014-09-03 中芯国际集成电路制造(上海)有限公司 Fin type field effect transistor and forming method thereof

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