CN105695975A - Bacteriostatic, wear-resistant and corrosion-resistant metal surface treatment agent - Google Patents
Bacteriostatic, wear-resistant and corrosion-resistant metal surface treatment agent Download PDFInfo
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- CN105695975A CN105695975A CN201610069606.XA CN201610069606A CN105695975A CN 105695975 A CN105695975 A CN 105695975A CN 201610069606 A CN201610069606 A CN 201610069606A CN 105695975 A CN105695975 A CN 105695975A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/43—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also hexavalent chromium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a bacteriostatic, wear-resistant and corrosion-resistant metal surface treatment agent which comprises the raw materials of a silane solution, sodium alkyl benzene sulfonate, titanium dioxide, methylene dichloride, calcium hydroxide, polyglycerol fatty acid ester, zinc dihydrogen phosphate, sodium borate, 1,3-di(o-tolyl)thiourea, sodium alcohol ether sulphate, a surfactant, a metal detergent, an OP emulsifier, ammonium molybdate, sodium metasilicate, phytic acid, potassium dichromate and auxiliaries. The metal surface treated by the agent provided by the invention is excellent in antibacterial and corrosion-resistant performance.
Description
Technical field
The present invention relates to a kind of metal conditioner, particularly relate to a kind of antibacterial wear-resistant noncorroding metal surface conditioning agent。
Background technology
At present, application is wide variety of anti-corrosion method in Treatment of Metal Surface。Coating Pretreatment is the requisite preliminary processes of application; its effect is to set up one on protected metal works to receive on-metallic protective coating; make metal works that paint film to have good adhesive force, in order to the two is more firmly attached on together, thus improving the anti-corrosion capability of coating。
After metal conditioner of the prior art processes metal, the antibacterial and corrosion resistance of metal surface can not meet the demand of prior art。
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of antibacterial wear-resistant noncorroding metal surface conditioning agent, has the antibacterial corrosion resistance of excellence through the metal surface that the present invention processed。
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one that the present invention proposes, its raw material includes by weight: solution of silane 80-120 part, sodium alkyl benzene sulfonate 40-60 part, titanium dioxide 10-30 part, dichloromethane 5-15 part, calcium hydroxide 2-8 part, polyglyceryl fatty acid ester 10-40 part, zinc dihydrogen phosphate 5-15 part, sodium borate 6-9 part, o-xylene thiourea 5-15 part, polyoxyethylenated alcohol sodium sulfate 1-5 part, surfactant 2-8 part, metal cleaner 1-5 part, OP emulsifying agent 2-8 part, ammonium molybdate 3-9 part, sodium metasilicate 4-8 part, phytic acid 1-4 part, potassium dichromate 2-6 part, auxiliary agent 4-8 part。
Preferably, the raw material of auxiliary agent includes by weight: polyvinyl alcohol 2-8 part, glycyrrhizic acid dipotassium 1-8 part, tea saponin 2-9 part, chlorinated paraffin 4-8 part, lithium base grease 3-9 part, ferrocenecarboxylic acid 1-5 part, hexahydro phthalic anhydride 2-9 part, potassium sorbate 3-6 part, hexamethyl phosphoramide 4-8 part, sodium sulfite 2-5 part, boric acid 1-5 part, methyl benzotriazazole 3-9 part, deionized water 4-12 part。
Preferably, the raw material of auxiliary agent includes by weight: polyvinyl alcohol 3-7 part, glycyrrhizic acid dipotassium 2-7 part, tea saponin 3-8 part, chlorinated paraffin 5-7 part, lithium base grease 4-8 part, ferrocenecarboxylic acid 2-4 part, hexahydro phthalic anhydride 3-8 part, potassium sorbate 4-5 part, hexamethyl phosphoramide 5-7 part, sodium sulfite 3-4 part, boric acid 2-4 part, methyl benzotriazazole 4-8 part, deionized water 5-11 part。
Preferably, the raw material of auxiliary agent includes by weight: polyvinyl alcohol 5 parts, glycyrrhizic acid dipotassium 4.5 parts, tea saponin 5.5 parts, chlorinated paraffin 6 parts, lithium base grease 6 parts, ferrocenecarboxylic acid 3 parts, hexahydro phthalic anhydride 5.5 parts, potassium sorbate 4.5 parts, hexamethyl phosphoramide 6 parts, sodium sulfite 3.5 parts, boric acid 3 parts, methyl benzotriazazole 6 parts, deionized water 8 parts。
Preferably, solution of silane is prepared by following technique: deionized water, ethanol and hydridovinyldichlorosilane mix homogeneously are obtained material a, and then adding second acid for adjusting pH is 4-5, stirs 2-4h, until the transparent shape of solution, obtains solution of silane。
Preferably, the weight ratio of hydridovinyldichlorosilane drunk by deionized water, ethanol is 2-8:2-8:85-95。
Preferably, its raw material includes by weight: solution of silane 85-115 part, sodium alkyl benzene sulfonate 45-55 part, titanium dioxide 15-25 part, dichloromethane 8-12 part, calcium hydroxide 3-7 part, polyglyceryl fatty acid ester 15-35 part, zinc dihydrogen phosphate 8-12 part, sodium borate 7-8 part, o-xylene thiourea 8-12 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, surfactant 3-7 part, metal cleaner 2-4 part, OP emulsifying agent 3-7 part, ammonium molybdate 4-8 part, sodium metasilicate 5-7 part, phytic acid 2-3 part, potassium dichromate 3-5 part, auxiliary agent 5-7 part。
Preferably, its raw material includes by weight: solution of silane 100 parts, sodium alkyl benzene sulfonate 50 parts, titanium dioxide 20 parts, dichloromethane 10 parts, calcium hydroxide 5 parts, polyglyceryl fatty acid ester 25 parts, zinc dihydrogen phosphate 10 parts, sodium borate 7.5 parts, o-xylene thiourea 10 parts, polyoxyethylenated alcohol sodium sulfate 3 parts, 5 parts of surfactant, metal cleaner 3 parts, OP emulsifying agent 5 parts, ammonium molybdate 6 parts, sodium metasilicate 6 parts, phytic acid 2.5 parts, potassium dichromate 4 parts, auxiliary agent 6 parts。
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one of the present invention, its raw material includes solution of silane, sodium alkyl benzene sulfonate, titanium dioxide, dichloromethane, calcium hydroxide, polyglyceryl fatty acid ester, zinc dihydrogen phosphate, sodium borate, o-xylene thiourea, polyoxyethylenated alcohol sodium sulfate, surfactant, metal cleaner, OP emulsifying agent, ammonium molybdate, sodium metasilicate, phytic acid, potassium dichromate and auxiliary agent, wherein with solution of silane for major ingredient, auxiliary adds sodium alkyl benzene sulfonate, titanium dioxide, dichloromethane, calcium hydroxide, polyglyceryl fatty acid ester, zinc dihydrogen phosphate and sodium borate are as the auxiliary material of major ingredient, the antibacterial hole that metal conditioner of the present invention has excellence is made to grind erosion-resisting performance, wherein solution of silane is effectively increased resistance to corrosion after treatment, further increase the metallic surface that metal conditioner of the present invention processed and there is the corrosion resistance of excellence。
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; it is understood that; embodiment is served only for the present invention is described, rather than is used for limiting the invention, any make on basis of the present invention amendment, equivalent replacement etc. is all in protection scope of the present invention。
Embodiment 1
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one that the present invention proposes, its raw material includes by weight: solution of silane 100 parts, sodium alkyl benzene sulfonate 50 parts, titanium dioxide 20 parts, dichloromethane 10 parts, calcium hydroxide 5 parts, polyglyceryl fatty acid ester 25 parts, zinc dihydrogen phosphate 10 parts, sodium borate 7.5 parts, o-xylene thiourea 10 parts, polyoxyethylenated alcohol sodium sulfate 3 parts, 5 parts of surfactant, metal cleaner 3 parts, OP emulsifying agent 5 parts, ammonium molybdate 6 parts, sodium metasilicate 6 parts, phytic acid 2.5 parts, potassium dichromate 4 parts, auxiliary agent 6 parts。
The raw material of auxiliary agent includes by weight: polyvinyl alcohol 5 parts, glycyrrhizic acid dipotassium 4.5 parts, tea saponin 5.5 parts, chlorinated paraffin 6 parts, lithium base grease 6 parts, ferrocenecarboxylic acid 3 parts, hexahydro phthalic anhydride 5.5 parts, potassium sorbate 4.5 parts, hexamethyl phosphoramide 6 parts, sodium sulfite 3.5 parts, boric acid 3 parts, methyl benzotriazazole 6 parts, deionized water 8 parts。
Solution of silane is prepared by following technique: by weight 5 parts of deionized waters, 5 parts of ethanol and 90 parts of hydridovinyldichlorosilane mix homogeneously are obtained material a, and then adding second acid for adjusting pH is 4.5, stirs 3h, until the transparent shape of solution, obtains solution of silane。
Embodiment 2
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one that the present invention proposes, its raw material includes by weight: solution of silane 80 parts, sodium alkyl benzene sulfonate 60 parts, titanium dioxide 10 parts, dichloromethane 15 parts, calcium hydroxide 2 parts, polyglyceryl fatty acid ester 40 parts, zinc dihydrogen phosphate 5 parts, sodium borate 9 parts, o-xylene thiourea 5 parts, polyoxyethylenated alcohol sodium sulfate 5 parts, 2 parts of surfactant, metal cleaner 5 parts, OP emulsifying agent 2 parts, ammonium molybdate 9 parts, sodium metasilicate 4 parts, phytic acid 4 parts, potassium dichromate 2 parts, auxiliary agent 8 parts。
The raw material of auxiliary agent includes by weight: polyvinyl alcohol 2 parts, glycyrrhizic acid dipotassium 8 parts, tea saponin 2 parts, chlorinated paraffin 8 parts, lithium base grease 3 parts, ferrocenecarboxylic acid 5 parts, hexahydro phthalic anhydride 2 parts, potassium sorbate 6 parts, hexamethyl phosphoramide 4 parts, sodium sulfite 5 parts, boric acid 1 part, methyl benzotriazazole 9 parts, deionized water 4 parts。
Solution of silane is prepared by following technique: by weight 2 parts of deionized waters, 8 parts of ethanol and 85 parts of hydridovinyldichlorosilane mix homogeneously are obtained material a, and then adding second acid for adjusting pH is 5, stirs 2h, until the transparent shape of solution, obtains solution of silane。
Embodiment 3
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one that the present invention proposes, its raw material includes by weight: solution of silane 120 parts, sodium alkyl benzene sulfonate 40 parts, titanium dioxide 30 parts, dichloromethane 5 parts, calcium hydroxide 8 parts, polyglyceryl fatty acid ester 10 parts, zinc dihydrogen phosphate 15 parts, sodium borate 6 parts, o-xylene thiourea 15 parts, polyoxyethylenated alcohol sodium sulfate 1 part, 8 parts of surfactant, metal cleaner 1 part, OP emulsifying agent 8 parts, ammonium molybdate 3 parts, sodium metasilicate 8 parts, phytic acid 1 part, potassium dichromate 6 parts, auxiliary agent 4 parts。
The raw material of auxiliary agent includes by weight: polyvinyl alcohol 8 parts, glycyrrhizic acid dipotassium 1 part, tea saponin 9 parts, chlorinated paraffin 4 parts, lithium base grease 9 parts, ferrocenecarboxylic acid 1 part, hexahydro phthalic anhydride 9 parts, potassium sorbate 3 parts, hexamethyl phosphoramide 8 parts, sodium sulfite 2 parts, boric acid 5 parts, methyl benzotriazazole 3 parts, deionized water 12 parts。
Solution of silane is prepared by following technique: by weight 8 parts of deionized waters, 2 parts of ethanol and 95 parts of hydridovinyldichlorosilane mix homogeneously are obtained material a, and then adding second acid for adjusting pH is 4, stirs 4h, until the transparent shape of solution, obtains solution of silane。
Embodiment 4
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one that the present invention proposes, its raw material includes by weight: solution of silane 85 parts, sodium alkyl benzene sulfonate 55 parts, titanium dioxide 15 parts, dichloromethane 12 parts, calcium hydroxide 3 parts, polyglyceryl fatty acid ester 35 parts, zinc dihydrogen phosphate 8 parts, sodium borate 8 parts, o-xylene thiourea 8 parts, polyoxyethylenated alcohol sodium sulfate 4 parts, 3 parts of surfactant, metal cleaner 4 parts, OP emulsifying agent 3 parts, ammonium molybdate 8 parts, sodium metasilicate 5 parts, phytic acid 3 parts, potassium dichromate 3 parts, auxiliary agent 7 parts。
The raw material of auxiliary agent includes by weight: polyvinyl alcohol 3 parts, glycyrrhizic acid dipotassium 7 parts, tea saponin 3 parts, chlorinated paraffin 7 parts, lithium base grease 4 parts, ferrocenecarboxylic acid 4 parts, hexahydro phthalic anhydride 3 parts, potassium sorbate 5 parts, hexamethyl phosphoramide 5 parts, sodium sulfite 4 parts, boric acid 2 parts, methyl benzotriazazole 8 parts, deionized water 5 parts。
Solution of silane is prepared by following technique: by weight 3 parts of deionized waters, 7 parts of ethanol and 88 parts of hydridovinyldichlorosilane mix homogeneously are obtained material a, and then adding second acid for adjusting pH is 4.8, stirs 2.5h, until the transparent shape of solution, obtains solution of silane。
Embodiment 5
The antibacterial wear-resistant noncorroding metal surface conditioning agent of one that the present invention proposes, its raw material includes by weight: solution of silane 115 parts, sodium alkyl benzene sulfonate 45 parts, titanium dioxide 25 parts, dichloromethane 8 parts, calcium hydroxide 7 parts, polyglyceryl fatty acid ester 15 parts, zinc dihydrogen phosphate 12 parts, sodium borate 7 parts, o-xylene thiourea 12 parts, polyoxyethylenated alcohol sodium sulfate 2 parts, 7 parts of surfactant, metal cleaner 2 parts, OP emulsifying agent 7 parts, ammonium molybdate 4 parts, sodium metasilicate 7 parts, phytic acid 2 parts, potassium dichromate 5 parts, auxiliary agent 5 parts。
The raw material of auxiliary agent includes by weight: polyvinyl alcohol 7 parts, glycyrrhizic acid dipotassium 2 parts, tea saponin 8 parts, chlorinated paraffin 5 parts, lithium base grease 8 parts, ferrocenecarboxylic acid 2 parts, hexahydro phthalic anhydride 8 parts, potassium sorbate 4 parts, hexamethyl phosphoramide 7 parts, sodium sulfite 3 parts, boric acid 4 parts, methyl benzotriazazole 4 parts, deionized water 11 parts。
Solution of silane is prepared by following technique: by weight 7 parts of deionized waters, 3 parts of ethanol and 92 parts of hydridovinyldichlorosilane mix homogeneously are obtained material a, and then adding second acid for adjusting pH is 4.2, stirs 3.5h, until the transparent shape of solution, obtains solution of silane。
The above; it is only the present invention preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; any those familiar with the art is in the technical scope that the invention discloses; it is equal to replacement according to technical scheme and inventive concept thereof or is changed, all should be encompassed within protection scope of the present invention。
Claims (8)
1. an antibacterial wear-resistant noncorroding metal surface conditioning agent, it is characterized in that, its raw material includes by weight: solution of silane 80-120 part, sodium alkyl benzene sulfonate 40-60 part, titanium dioxide 10-30 part, dichloromethane 5-15 part, calcium hydroxide 2-8 part, polyglyceryl fatty acid ester 10-40 part, zinc dihydrogen phosphate 5-15 part, sodium borate 6-9 part, o-xylene thiourea 5-15 part, polyoxyethylenated alcohol sodium sulfate 1-5 part, surfactant 2-8 part, metal cleaner 1-5 part, OP emulsifying agent 2-8 part, ammonium molybdate 3-9 part, sodium metasilicate 4-8 part, phytic acid 1-4 part, potassium dichromate 2-6 part, auxiliary agent 4-8 part。
2. antibacterial wear-resistant noncorroding metal surface conditioning agent according to claim 1, it is characterized in that, the raw material of auxiliary agent includes by weight: polyvinyl alcohol 2-8 part, glycyrrhizic acid dipotassium 1-8 part, tea saponin 2-9 part, chlorinated paraffin 4-8 part, lithium base grease 3-9 part, ferrocenecarboxylic acid 1-5 part, hexahydro phthalic anhydride 2-9 part, potassium sorbate 3-6 part, hexamethyl phosphoramide 4-8 part, sodium sulfite 2-5 part, boric acid 1-5 part, methyl benzotriazazole 3-9 part, deionized water 4-12 part。
3. antibacterial wear-resistant noncorroding metal surface conditioning agent according to claim 1 and 2, it is characterized in that, the raw material of auxiliary agent includes by weight: polyvinyl alcohol 3-7 part, glycyrrhizic acid dipotassium 2-7 part, tea saponin 3-8 part, chlorinated paraffin 5-7 part, lithium base grease 4-8 part, ferrocenecarboxylic acid 2-4 part, hexahydro phthalic anhydride 3-8 part, potassium sorbate 4-5 part, hexamethyl phosphoramide 5-7 part, sodium sulfite 3-4 part, boric acid 2-4 part, methyl benzotriazazole 4-8 part, deionized water 5-11 part。
4. the antibacterial wear-resistant noncorroding metal surface conditioning agent according to any one of claim 1-3, it is characterized in that, the raw material of auxiliary agent includes by weight: polyvinyl alcohol 5 parts, glycyrrhizic acid dipotassium 4.5 parts, tea saponin 5.5 parts, chlorinated paraffin 6 parts, lithium base grease 6 parts, ferrocenecarboxylic acid 3 parts, hexahydro phthalic anhydride 5.5 parts, potassium sorbate 4.5 parts, hexamethyl phosphoramide 6 parts, sodium sulfite 3.5 parts, boric acid 3 parts, methyl benzotriazazole 6 parts, deionized water 8 parts。
5. the antibacterial wear-resistant noncorroding metal surface conditioning agent according to any one of claim 1-4, it is characterized in that, solution of silane is prepared by following technique: deionized water, ethanol and hydridovinyldichlorosilane mix homogeneously are obtained material a, then adding second acid for adjusting pH is 4-5, stirring 2-4h, until the transparent shape of solution, obtain solution of silane。
6. the antibacterial wear-resistant noncorroding metal surface conditioning agent according to any one of claim 1-5, it is characterised in that the weight ratio of hydridovinyldichlorosilane drunk by deionized water, ethanol is 2-8:2-8:85-95。
7. the antibacterial wear-resistant noncorroding metal surface conditioning agent according to any one of claim 1-6, it is characterized in that, its raw material includes by weight: solution of silane 85-115 part, sodium alkyl benzene sulfonate 45-55 part, titanium dioxide 15-25 part, dichloromethane 8-12 part, calcium hydroxide 3-7 part, polyglyceryl fatty acid ester 15-35 part, zinc dihydrogen phosphate 8-12 part, sodium borate 7-8 part, o-xylene thiourea 8-12 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, surfactant 3-7 part, metal cleaner 2-4 part, OP emulsifying agent 3-7 part, ammonium molybdate 4-8 part, sodium metasilicate 5-7 part, phytic acid 2-3 part, potassium dichromate 3-5 part, auxiliary agent 5-7 part。
8. the antibacterial wear-resistant noncorroding metal surface conditioning agent according to any one of claim 1-7, it is characterized in that, its raw material includes by weight: solution of silane 100 parts, sodium alkyl benzene sulfonate 50 parts, titanium dioxide 20 parts, dichloromethane 10 parts, calcium hydroxide 5 parts, polyglyceryl fatty acid ester 25 parts, zinc dihydrogen phosphate 10 parts, sodium borate 7.5 parts, o-xylene thiourea 10 parts, polyoxyethylenated alcohol sodium sulfate 3 parts, 5 parts of surfactant, metal cleaner 3 parts, OP emulsifying agent 5 parts, ammonium molybdate 6 parts, sodium metasilicate 6 parts, phytic acid 2.5 parts, potassium dichromate 4 parts, auxiliary agent 6 parts。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610069606.XA CN105695975A (en) | 2016-01-28 | 2016-01-28 | Bacteriostatic, wear-resistant and corrosion-resistant metal surface treatment agent |
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| CN201610069606.XA CN105695975A (en) | 2016-01-28 | 2016-01-28 | Bacteriostatic, wear-resistant and corrosion-resistant metal surface treatment agent |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319506A (en) * | 2016-08-29 | 2017-01-11 | 常熟市诺信达机械设备有限公司 | Roller conveyer for industrial production |
| CN107311736A (en) * | 2017-05-12 | 2017-11-03 | 天长市翔净蔬菜种植发展有限公司 | A kind of high slow release compoiste fertilizer of black mustard high yield |
| CN109024075A (en) * | 2018-07-12 | 2018-12-18 | 江苏金大包装材料科技有限公司 | A kind of antibacterial release paper and preparation method thereof |
| CN110560343A (en) * | 2019-08-30 | 2019-12-13 | 江苏亚一智能装备有限公司 | Paint spraying process for automobile parts |
-
2016
- 2016-01-28 CN CN201610069606.XA patent/CN105695975A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319506A (en) * | 2016-08-29 | 2017-01-11 | 常熟市诺信达机械设备有限公司 | Roller conveyer for industrial production |
| CN107311736A (en) * | 2017-05-12 | 2017-11-03 | 天长市翔净蔬菜种植发展有限公司 | A kind of high slow release compoiste fertilizer of black mustard high yield |
| CN109024075A (en) * | 2018-07-12 | 2018-12-18 | 江苏金大包装材料科技有限公司 | A kind of antibacterial release paper and preparation method thereof |
| CN110560343A (en) * | 2019-08-30 | 2019-12-13 | 江苏亚一智能装备有限公司 | Paint spraying process for automobile parts |
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