CN105694862A - Luminescent material [Zn(tibc)2]n and synthetic method - Google Patents
Luminescent material [Zn(tibc)2]n and synthetic method Download PDFInfo
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- CN105694862A CN105694862A CN201610171237.5A CN201610171237A CN105694862A CN 105694862 A CN105694862 A CN 105694862A CN 201610171237 A CN201610171237 A CN 201610171237A CN 105694862 A CN105694862 A CN 105694862A
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- tibc
- htibc
- analytically pure
- dissolved
- amino
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- 239000000463 material Substances 0.000 title claims abstract description 10
- 238000010189 synthetic method Methods 0.000 title claims abstract description 9
- 239000011701 zinc Substances 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002262 Schiff base Substances 0.000 claims abstract description 6
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000003321 amplification Effects 0.000 claims abstract description 5
- 239000012153 distilled water Substances 0.000 claims abstract description 5
- 238000003199 nucleic acid amplification method Methods 0.000 claims abstract description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004246 zinc acetate Substances 0.000 claims abstract description 5
- 239000013078 crystal Substances 0.000 claims description 14
- JHZOXYGFQMROFJ-UHFFFAOYSA-N 3,5-dibromo-2-hydroxybenzaldehyde Chemical compound OC1=C(Br)C=C(Br)C=C1C=O JHZOXYGFQMROFJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000005286 illumination Methods 0.000 claims description 7
- -1 4 triazole schiff bases Chemical class 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims description 4
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 claims description 4
- 230000001476 alcoholic effect Effects 0.000 claims description 4
- 238000004020 luminiscence type Methods 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 3
- FMCUPJKTGNBGEC-UHFFFAOYSA-N 1,2,4-triazol-4-amine Chemical compound NN1C=NN=C1 FMCUPJKTGNBGEC-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000011835 investigation Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002189 fluorescence spectrum Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1003—Carbocyclic compounds
- C09K2211/1007—Non-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1059—Heterocyclic compounds characterised by ligands containing three nitrogen atoms as heteroatoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1408—Carbocyclic compounds
- C09K2211/1425—Non-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1441—Heterocyclic
- C09K2211/1466—Heterocyclic containing nitrogen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
Abstract
Description
Zn1—O3 | 2.015(6) | N9—N17 | 1.367(10) |
Zn1—O3i | 2.015(6) | N9—C10 | 1.313(10) |
Zn1—N6 | 2.201(7) | N15—N6iii | 1.428(9) |
Zn1—N6i | 2.201(7) | N15—C0AA | 1.360(11) |
Zn1—N9 | 2.195(7) | N15—C10 | 1.321(11) |
Zn1—N9i | 2.195(7) | N17—C0AA | 1.304(11) |
Br5—C11 | 1.891(9) | C6—C7 | 1.422(14) |
Br8—C16 | 1.894(11) | C6—C16 | 1.375(14) |
O3—C5 | 1.282(10) | C7—C5 | 1.426(13) |
N6—C8i | 1.279(11) | C5—C11 | 1.428(11) |
N6—N15ii | 1.428(9) | C11—C20 | 1.358(14) |
C8—N6i | 1.279(11) | C16—C20 | 1.395(15) |
C8—C7 | 1.453(12) | ||
O3—Zn1—O3i | 180.0(4) | C10—N9—N17 | 107.4(7) |
O3—Zn1—N6i | 84.1(2) | C0AA—N15—N6iii | 126.9(7) |
O3—Zn1—N6 | 95.9(2) | C10—N15—N6iii | 126.5(7) |
O3i—Zn1—N6i | 95.9(2) | C10—N15—C0AA | 106.5(7) |
O3i—Zn1—N6 | 84.1(2) | C0AA—N17—N9 | 107.3(7) |
O3—Zn1—N9 | 87.9(3) | C16—C6—C7 | 119.8(10) |
O3—Zn1—N9i | 92.1(3) | C6—C7—C8 | 115.1(8) |
O3i—Zn1—N9i | 87.9(3) | C6—C7—C5 | 121.3(8) |
O3i—Zn1—N9 | 92.1(3) | C5—C7—C8 | 123.6(8) |
N6—Zn1—N6i | 179.999(1) | N17—C0AA—N15 | 109.0(8) |
N9—Zn1—N6 | 95.1(3) | O3—C5—C7 | 124.5(7) |
N9i—Zn1—N6i | 95.1(3) | O3—C5—C11 | 120.7(8) |
N9—Zn1—N6i | 84.9(3) | C7—C5—C11 | 114.7(8) |
N9i—Zn1—N6 | 84.9(3) | N9—C10—N15 | 109.8(7) |
N9—Zn1—N9i | 180.0 | C5—C11—Br5 | 116.9(7) |
C5—O3—Zn1 | 125.0(5) | C20—C11—Br5 | 119.1(7) |
C8i—N6—Zn1 | 123.2(6) | C20—C11—C5 | 124.0(9) |
C8i—N6—N15ii | 111.0(7) | C6—C16—Br8 | 120.6(9) |
N15ii—N6—Zn1 | 122.3(5) | C6—C16—C20 | 120.5(10) |
N6i—C8—C7 | 124.4(8) | C20—C16—Br8 | 118.8(8) |
N17—N9—Zn1 | 123.0(5) | C11—C20—C16 | 119.6(9) |
C10—N9—Zn1 | 129.5(6) |
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610171237.5A CN105694862B (en) | 2016-03-23 | 2016-03-23 | Luminescent material [Zn (tibc)2]nAnd synthetic method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610171237.5A CN105694862B (en) | 2016-03-23 | 2016-03-23 | Luminescent material [Zn (tibc)2]nAnd synthetic method |
Publications (2)
Publication Number | Publication Date |
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CN105694862A true CN105694862A (en) | 2016-06-22 |
CN105694862B CN105694862B (en) | 2017-12-12 |
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CN201610171237.5A Active CN105694862B (en) | 2016-03-23 | 2016-03-23 | Luminescent material [Zn (tibc)2]nAnd synthetic method |
Country Status (1)
Country | Link |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102503963A (en) * | 2011-09-13 | 2012-06-20 | 江西师范大学 | Zinc metal-organic coordination polymer and preparation method thereof |
JP2014152114A (en) * | 2013-02-05 | 2014-08-25 | Nippon Shokubai Co Ltd | Organometallic complex |
-
2016
- 2016-03-23 CN CN201610171237.5A patent/CN105694862B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102503963A (en) * | 2011-09-13 | 2012-06-20 | 江西师范大学 | Zinc metal-organic coordination polymer and preparation method thereof |
JP2014152114A (en) * | 2013-02-05 | 2014-08-25 | Nippon Shokubai Co Ltd | Organometallic complex |
Non-Patent Citations (2)
Title |
---|
MUHAMMAD HANIF等: "Design, spectral characterization and biological studies of transition metal(II) complexes with triazole Schiff bases", 《SPECTROCHIMICA ACTA PART A: MOLECULAR AND BIOMOLECULAR SPECTROSCOPY》 * |
ZAHID H. CHOHAN等: "Synthesis and characterization of biologically active new Schiff bases containing 3-functionalized 1,2,4-triazoles and their zinc(II) complexes: crystal structure of 4-bromo-2-[(E)-(1H-1,2,4-triazol-3-ylimino)- methyl]phenol", 《APPL. ORGANOMETAL. CHEM.》 * |
Also Published As
Publication number | Publication date |
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CN105694862B (en) | 2017-12-12 |
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Effective date of registration: 20201218 Address after: 11 / F, Jingang building, south of Lianyungang Road, Sheyang Economic Development Zone, Sheyang County, Yancheng City, Jiangsu Province 224300 Patentee after: Li Zaigao Address before: 541004 the Guangxi Zhuang Autonomous Region Guilin Construction Road No. 12 Patentee before: GUILIN University OF TECHNOLOGY |
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Application publication date: 20160622 Assignee: Yancheng Aipinyue Network Technology Co.,Ltd. Assignor: Li Zaigao Contract record no.: X2023980047070 Denomination of invention: Luminescent material [Zn (tibc)2]nand synthesis method Granted publication date: 20171212 License type: Common License Record date: 20231120 |
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Assignee: Yancheng Aipinyue Network Technology Co.,Ltd. Assignor: Li Zaigao Contract record no.: X2023980047070 Date of cancellation: 20240416 |
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