CN105690903A - 一种抗静电耐湿热的大豆纤维混纺面料 - Google Patents

一种抗静电耐湿热的大豆纤维混纺面料 Download PDF

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CN105690903A
CN105690903A CN201511010685.9A CN201511010685A CN105690903A CN 105690903 A CN105690903 A CN 105690903A CN 201511010685 A CN201511010685 A CN 201511010685A CN 105690903 A CN105690903 A CN 105690903A
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layer
fiber
soybean fiber
blended yarn
agent
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CN105690903B (zh
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赵军伟
林红
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Jiangyin Changjing Garden Wool Textile Co Ltd
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Jiangyin Changjing Garden Wool Textile Co Ltd
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Abstract

本发明涉及一种混纺面料，具体涉及一种抗静电耐湿热的大豆纤维混纺面料，由里层到外层依次由大豆蛋白纤维-纤维素纤维混纺层、羊毛纤维层、纳米竹炭纤维层、菠萝叶纤维层、抗起球纤维层 ，菠萝叶纤维层设有防蚊虫叮咬剂，羊毛纤维层设有抗菌消毒剂，抗起球纤维层设有负热膨胀剂。本发明的一种抗静电耐湿热的大豆纤维混纺面料抗静电，耐湿热，手感柔和，不起毛。

Description

一种抗静电耐湿热的大豆纤维混纺面料
技术领域
本发明涉及一种混纺面料，具体涉及一种抗静电耐湿热的大豆纤维混纺面料。
背景技术
目前，衣服面料很多采用化学纤维制成，由于其在制造过程中，有大量添加剂，如漂白剂，柔顺剂等，如果穿化纤织物内衣，布料上的化学物质易被人体皮肤吸收，时间长了，容易产生刺激，引起湿疹、接触性皮炎、异位性皮炎、荨麻疹等症状。而羊绒或真丝可以弥补上述缺陷，但是其造价高昂。
大豆蛋白纤维由于自身的优异特性，这种廉价的新型再生纤维，可部分替代羊绒和真丝与其他纤维混纺，制作高档家用纺织品面料。
大豆蛋白纤维是以脱去油脂的大豆豆粕作原料，提取植物球蛋白经合成后制成的新型再生植物蛋白纤维，是由我国纺织科技工作者自主开发，并在国际上率先实现了工业化生产的高新技术，也是迄今为止我国获得的唯一完全知识产权的纤维发明。在成为纤维之前，要从大豆中提取蛋白质与高聚物为原料，采用生物工程等高新技术处理，经湿法纺丝而成。这种单丝，细度细、比重轻、拉伸强度高、耐酸耐碱性强、吸湿导湿性好。优于羊绒的手感，光泽能与蚕丝相媲美，棉的保暖性和良好的亲肤性等优良性能，还有明显的抑菌功能，被誉为“新世纪的健康舒适环保纤维”。以50%以上的大豆纤维与长绒棉混纺的高支纱，用于生产春、秋、冬季的薄型绒衫，其滑糯、轻盈、柔软，能保留精纺面料的光泽和细腻感，增加滑糯手感，也是生产轻薄柔软型高级西装和大衣的理想面料。用大豆纤维与真丝交织或与绢丝混纺制成的面料，既能保持丝绸亮泽、飘逸的特点，又能改善其悬垂性，消除产生汗渍及吸湿后贴肤的特点，是制作睡衣、衬衫、晚礼服等高档服装的理想面料。此外，大豆纤维与亚麻等麻纤维混纺，是制作功能性内衣及夏季服装的理想面料；与棉混纺的高支纱，是制造高档衬衫、高级寝卧具的理想材料；或者加入少量氨纶，手感柔软舒适，用于制作T恤、内衣、沙滩装、休闲服、运动服、时尚女装等，极具休闲风格。
但是，大豆纤维较细而滑，易产生起毛现象，易产生细菌，易产生静电，纤维耐湿热性差，且洗多了，衣服容易蓬松，因此，现需要一种含有大豆纤维的面料，能够克服上述缺陷且对皮肤具有保护作用。
发明内容
本发明的目的在于克服现有技术中存在的缺陷，提供一种抗静电耐湿热的大豆纤维混纺面料。
为实现上述目的，本发明的技术方案是：
一种抗静电耐湿热的大豆纤维混纺面料，由里层到外层依次由大豆蛋白纤维-纤维素纤维混纺层、羊毛纤维层、纳米竹炭纤维层、菠萝叶纤维层、抗起球纤维层，所述菠萝叶纤维层设有防蚊虫叮咬剂，所述羊毛纤维层设有抗菌消毒剂，所述抗起球纤维层设有负热膨胀剂，上述组成按照下列重量份制备而成：30-40大豆蛋白纤维-纤维素纤维层混纺层、10-15抗起球纤维层、35-45羊毛纤维层、15-20纳米竹炭纤维层、1-3防蚊虫叮咬剂、20-30菠萝叶纤维层、2-5抗菌消毒剂,3-6负热膨胀剂，所述大豆蛋白纤维-纤维素纤维混纺层中，大豆蛋白纤维的重量份为25-30，纤维素纤维的重量份为5-10，所述大豆蛋白纤维-纤维素纤维混纺层兼备大豆蛋白纤维柔软手感，蚕丝般的柔和光泽，棉的保暖性和良好的亲肤性，还有纤维素纤维的防静电和耐湿热的特性，另外负热膨胀材料设置于抗起球纤维的表面，有效抑制了面料经过清洗后变大的缺陷，抗起球纤维有效防止了面料的起球缺陷，另外面料中添加了防蚊虫叮咬剂和抗菌消毒剂，有效防止蚊虫的叮咬和对皮肤的伤害。
进一步地，所述负热膨胀材料剂由碳纳米管、Mn3Cu0.2Zn0.2Ca0.6N粉体、纤维素粘合剂制备成，其中按照重量份，0.2-0.5碳纳米管、0.3-0.5Mn3Cu0.2Zn0.2Ca0.6N粉体、0.1-0.2纤维素粘合剂，Mn3Cu0.2Zn0.2Ca0.6N为反钙钛矿结构的负热膨胀材料，其在-10℃-50℃温度区间具有很好的负热膨胀性能，其与碳纳米管，纤维素粘结剂结合，能够很好地抑制面料的反复清洗后的膨胀。
进一步地，所述Mn3Cu0.2Zn0.2Ca0.6N粉体的大小为150目-250目，在此大小区间内的粉体材料能够有效地与碳纳米管结合。
进一步地，所述抗菌消毒剂由纳米银、纳米二氧化钛粉末、纳米氧化锌和羟基磷灰石组成，其中按照重量份，0.5-0.9纳米银、1-3二氧化钛粉末，0.2-0.5纳米氧化锌、0.3-0.6羟基磷灰石。
进一步地，所述纳米二氧化钛的大小为50-90nm,所述纳米银的大小为40-50nm，所述纳米氧化锌的大小为50-80nm。
进一步地，所述防蚊虫叮咬剂由二氯二苯三氯乙烷、乙二醇丁醚、乙二醇甲醚和乙二醇乙醚主成，其中按照重量份，0.25-0.6二氯二苯三氯乙烷、0.25-0.7乙二醇丁醚、0.25-0.8乙二醇甲醚和0.25-0.9乙二醇乙醚。
进一步地，所述纤维素纤维为棉纤维或麻纤维。
进一步地，所述抗起球纤维层为抗起球腈纶。
本发明的一种抗静电耐湿热的大豆纤维混纺面料按照以下工艺制备：
S1.将大豆蛋白纤维和纤维素纤维按配方中的重量份比例进行混纺，得到大豆蛋白纤维-纤维素纤维混纺层；
S2.将羊毛纤维层按照配方中的重量份比例纺织成为羊毛纤维层；
S3.按照配方中的重量份比例，配置好抗菌消毒剂，而后喷涂在羊毛纤维层中；
S4.将大豆蛋白纤维-纤维素纤维层的上表面喷涂聚酯树脂浆料，与羊毛纤维层粘接复合；
S5。将纳米竹炭纤维按照配方中的重量份比例纺织成纳米竹炭纤维层；
S6.将菠萝叶纤维按照配方中的重量份比例纺织成菠萝叶纤维层；
S7.将羊毛纤维层中的上表面喷涂聚酯树脂浆料，与纳米竹炭纤维层复合，再将纳米竹炭纤维的下表面喷涂聚酯树脂浆料，与复合好的纳米竹炭纤维层复合；
S8.将抗起球纤维按照配方中的重量份比例纺织成抗起球纤维层，并在抗起球纤维层的表面喷涂负热膨胀材料；
S9.在抗起球纤维层中的下表面喷涂聚酯树脂浆料，与复合好后的纳米竹炭纤维层复合；
S10.将复合好的材料放入烘箱中，烘干，烘箱的温度为40℃-60℃，烘干后取出。
本发明的优点和有益效果在于：
1、大豆蛋白纤维-纤维素纤维混纺层兼备大豆蛋白纤维柔软手感，蚕丝般的柔和光泽，棉的保暖性和良好的亲肤性，还有纤维素纤维的防静电和耐湿热的特性，另外负热膨胀材料设置于抗起球纤维的表面，有效抑制了面料经过清洗后变大的缺陷，抗起球纤维有效防止了面料的起球缺陷，另外面料中添加了防蚊虫叮咬剂和抗菌消毒剂，有效防止蚊虫的叮咬和对皮肤的伤害。
2、Mn3Cu0.2Zn0.2Ca0.6N为反钙钛矿结构的负热膨胀材料，其在-10℃-50℃温度区间具有很好的负热膨胀性能，其与碳纳米管，纤维素粘结剂结合，能够很好地抑制面料的反复清洗后的膨胀，且目前没有关于负热膨胀材料与面料结合的相关技术，有效地填补了这一技术空白。
3、本发明具有舒适保暖、防粘的良好性能，在保证了穿着的舒适性的同时，令使用此面料制作成为的衣服具有良好的保暖性能，绿色环保，健康指数高。
附图说明
附图1：本发明的一种抗静电耐湿热的大豆纤维混纺面料的横截面示意图；
1-大豆蛋白纤维-纤维素纤维混纺层，2-羊毛纤维层，3-纳米竹炭纤维层，4-菠萝叶纤维层，5-抗起球纤维层。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1：
一种抗静电耐湿热的大豆纤维混纺面料，由里层到外层依次由大豆蛋白纤维-纤维素纤维混纺层、羊毛纤维层、纳米竹炭纤维层、菠萝叶纤维层、抗起球纤维层，所述菠萝叶纤维层设有防蚊虫叮咬剂，所述羊毛纤维层设有抗菌消毒剂，所述抗起球纤维层设有负热膨胀剂，上述组成按照下列重量份制备而成：30大豆蛋白纤维-纤维素纤维层混纺层、10抗起球纤维层、35羊毛纤维层、15纳米竹炭纤维层、1防蚊虫叮咬剂、20菠萝叶纤维层、2抗菌消毒剂,3负热膨胀剂，所述大豆蛋白纤维-纤维素纤维混纺层中，大豆蛋白纤维的重量份为25，纤维素纤维的重量份为5，所述负热膨胀材料剂由碳纳米管、Mn3Cu0.2Zn0.2Ca0.6N粉体、纤维素粘合剂制备成，其中按照重量份，0.2碳纳米管、0.3Mn3Cu0.2Zn0.2Ca0.6N粉体、0.1纤维素粘合剂，Mn3Cu0.2Zn0.2Ca0.6N为反钙钛矿结构的负热膨胀材料，其在-10℃-50℃温度区间具有很好的负热膨胀性能，其与碳纳米管，纤维素粘结剂结合，能够很好地抑制面料的反复清洗后的膨胀，所述抗菌消毒剂由纳米银、纳米二氧化钛粉末、纳米氧化锌和羟基磷灰石组成，其中按照重量份，0.5纳米银、1二氧化钛粉末，0.2纳米氧化锌、0.3羟基磷灰石，所述纳米二氧化钛的大小为50nm,所述纳米银的大小为40nm，所述纳米氧化锌的大小为50nm，所述防蚊虫叮咬剂由二氯二苯三氯乙烷、乙二醇丁醚、乙二醇甲醚和乙二醇乙醚主成，其中按照重量份，0.25二氯二苯三氯乙烷、0.25乙二醇丁醚、0.25乙二醇甲醚和0.25乙二醇乙醚，所述纤维素纤维为棉纤维，所述抗起球纤维层为抗起球腈纶。
本发明的一种抗静电耐湿热的大豆纤维混纺面料按照以下工艺制备：
S1.将大豆蛋白纤维和纤维素纤维按配方中的重量份比例进行混纺，得到大豆蛋白纤维-纤维素纤维混纺层；
S2.将羊毛纤维层按照配方中的重量份比例纺织成为羊毛纤维层；
S3.按照配方中的重量份比例，配置好抗菌消毒剂，而后喷涂在羊毛纤维层中；
S4.将大豆蛋白纤维-纤维素纤维层的上表面喷涂聚酯树脂浆料，与羊毛纤维层粘接复合；
S5。将纳米竹炭纤维按照配方中的重量份比例纺织成纳米竹炭纤维层；
S6.将菠萝叶纤维按照配方中的重量份比例纺织成菠萝叶纤维层；
S7.将羊毛纤维层中的上表面喷涂聚酯树脂浆料，与纳米竹炭纤维层复合，再将纳米竹炭纤维的下表面喷涂聚酯树脂浆料，与复合好的纳米竹炭纤维层复合；
S8.将抗起球纤维按照配方中的重量份比例纺织成抗起球纤维层，并在抗起球纤维层的表面喷涂负热膨胀材料；
S9.在抗起球纤维层中的下表面喷涂聚酯树脂浆料，与复合好后的纳米竹炭纤维层复合；
S10.将复合好的材料放入烘箱中，烘干，烘箱的温度为50℃，烘干后取出。
实施例2：
一种抗静电耐湿热的大豆纤维混纺面料，由里层到外层依次由大豆蛋白纤维-纤维素纤维混纺层、羊毛纤维层、纳米竹炭纤维层、菠萝叶纤维层、抗起球纤维层，所述菠萝叶纤维层设有防蚊虫叮咬剂，所述羊毛纤维层设有抗菌消毒剂，所述抗起球纤维层设有负热膨胀剂，上述组成按照下列重量份制备而成：40大豆蛋白纤维-纤维素纤维层混纺层、15抗起球纤维层、45羊毛纤维层、20纳米竹炭纤维层、3防蚊虫叮咬剂、30菠萝叶纤维层、5抗菌消毒剂,6负热膨胀剂，所述大豆蛋白纤维-纤维素纤维混纺层中，大豆蛋白纤维的重量份为30，纤维素纤维的重量份为10，所述负热膨胀材料剂由碳纳米管、Mn3Cu0.2Zn0.2Ca0.6N粉体、纤维素粘合剂制备成，其中按照重量份，00.5碳纳米管、0.5Mn3Cu0.2Zn0.2Ca0.6N粉体、0.2纤维素粘合剂，Mn3Cu0.2Zn0.2Ca0.6N为反钙钛矿结构的负热膨胀材料，其在-10℃-50℃温度区间具有很好的负热膨胀性能，其与碳纳米管，纤维素粘结剂结合，能够很好地抑制面料的反复清洗后的膨胀，所述Mn3Cu0.2Zn0.2Ca0.6N粉体的大小为150目，所述抗菌消毒剂由纳米银、纳米二氧化钛粉末、纳米氧化锌和羟基磷灰石组成，其中按照重量份，0.9纳米银、3二氧化钛粉末，0.5纳米氧化锌、0.6羟基磷灰石，所述纳米二氧化钛的大小为90nm,所述纳米银的大小为50nm，所述纳米氧化锌的大小为80nm，所述防蚊虫叮咬剂由二氯二苯三氯乙烷、乙二醇丁醚、乙二醇甲醚和乙二醇乙醚主成，其中按照重量份，0.6二氯二苯三氯乙烷0.7乙二醇丁醚、0.8乙二醇甲醚和0.9乙二醇乙醚，所述纤维素纤维为麻纤维，所述抗起球纤维层为抗起球腈纶。制备工艺同实施例1.
实施例3：
一种抗静电耐湿热的大豆纤维混纺面料，由里层到外层依次由大豆蛋白纤维-纤维素纤维混纺层、羊毛纤维层、纳米竹炭纤维层、菠萝叶纤维层、抗起球纤维层，所述菠萝叶纤维层设有防蚊虫叮咬剂，所述羊毛纤维层设有抗菌消毒剂，所述抗起球纤维层设有负热膨胀剂，上述组成按照下列重量份制备而成：35大豆蛋白纤维-纤维素纤维层混纺层、12抗起球纤维层、40羊毛纤维层、17纳米竹炭纤维层、2防蚊虫叮咬剂、25菠萝叶纤维层、3抗菌消毒剂,5负热膨胀剂，所述大豆蛋白纤维-纤维素纤维混纺层中，大豆蛋白纤维的重量份为27，纤维素纤维的重量份为7，所述负热膨胀材料剂由碳纳米管、Mn3Cu0.2Zn0.2Ca0.6N粉体、纤维素粘合剂制备成，其中按照重量份，0.3碳纳米管、0.4Mn3Cu0.2Zn0.2Ca0.6N粉体、0.15纤维素粘合剂，所述Mn3Cu0.2Zn0.2Ca0.6N粉体的大小为200目，。
进一步地，所述抗菌消毒剂由纳米银、纳米二氧化钛粉末、纳米氧化锌和羟基磷灰石组成，其中按照重量份，0.6纳米银、2二氧化钛粉末，0.3纳米氧化锌、0.5羟基磷灰石。
进一步地，所述纳米二氧化钛的大小为70nm,所述纳米银的大小为45nm，所述纳米氧化锌的大小为60nm。
进一步地，所述防蚊虫叮咬剂由二氯二苯三氯乙烷、乙二醇丁醚、乙二醇甲醚和乙二醇乙醚主成，其中按照重量份，0.4二氯二苯三氯乙烷、0.4乙二醇丁醚、0.5乙二醇甲醚和0.5乙二醇乙醚，所述纤维素纤维为棉纤维或麻纤维，所述抗起球纤维层为抗起球腈纶。
本发明的优点在于：
1、大豆蛋白纤维-纤维素纤维混纺层兼备大豆蛋白纤维柔软手感，蚕丝般的柔和光泽，棉的保暖性和良好的亲肤性，还有纤维素纤维的防静电和耐湿热的特性，另外负热膨胀材料设置于抗起球纤维的表面，有效抑制了面料经过清洗后变大的缺陷，抗起球纤维有效防止了面料的起球缺陷，另外面料中添加了防蚊虫叮咬剂和抗菌消毒剂，有效防止蚊虫的叮咬和对皮肤的伤害。
2、Mn3Cu0.2Zn0.2Ca0.6N为反钙钛矿结构的负热膨胀材料，其在-10℃-50℃温度区间具有很好的负热膨胀性能，其与碳纳米管，纤维素粘结剂结合，能够很好地抑制面料的反复清洗后的膨胀，且目前没有关于负热膨胀材料与面料结合的相关技术，有效地填补了这一技术空白。
3、本发明具有舒适保暖、防粘的良好性能，在保证了穿着的舒适性的同时，令使用此面料制作成为的衣服具有良好的保暖性能，绿色环保，健康指数高。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (8)

1.一种抗静电耐湿热的大豆纤维混纺面料，其特征在于，由里层到外层依次由大豆蛋白纤维-纤维素纤维混纺层、羊毛纤维层、纳米竹炭纤维层、菠萝叶纤维层、抗起球纤维层，所述菠萝叶纤维层设有防蚊虫叮咬剂，所述羊毛纤维层设有抗菌消毒剂，所述抗起球纤维层设有负热膨胀剂，上述组成按照下列重量份制备而成：30-40大豆蛋白纤维-纤维素纤维层混纺层、10-15抗起球纤维层、35-45羊毛纤维层、15-20纳米竹炭纤维层、1-3防蚊虫叮咬剂、20-30菠萝叶纤维层、2-5抗菌消毒剂,3-6负热膨胀剂，所述大豆蛋白纤维-纤维素纤维混纺层中，大豆蛋白纤维的重量份为25-30，纤维素纤维的重量份为5-10。
2.如权利1所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述负热膨胀材料剂由碳纳米管、Mn3Cu0.2Zn0.2Ca0.6N粉体、纤维素粘合剂制备成，其中按照重量份，0.2-0.5碳纳米管、0.3-0.5Mn3Cu0.2Zn0.2Ca0.6N粉体、0.1-0.2纤维素粘合剂。
3.如权利2所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述Mn3Cu0.2Zn0.2Ca0.6N粉体的大小为150目-250目。
4.如权利要求1或2所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述抗菌消毒剂由纳米银、纳米二氧化钛粉末、纳米氧化锌和羟基磷灰石组成，其中按照重量份，0.5-0.9纳米银、1-3二氧化钛粉末，0.2-0.5纳米氧化锌、0.3-0.6羟基磷灰石。
5.如权利要求3所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述纳米二氧化钛的大小为50-90nm,所述纳米银的大小为40-50nm，所述纳米氧化锌的大小为50-80nm。
6.如权利要求1所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述防蚊虫叮咬剂由二氯二苯三氯乙烷、乙二醇丁醚、乙二醇甲醚和乙二醇乙醚主成，其中按照重量份，0.25-0.6二氯二苯三氯乙烷、0.25-0.7乙二醇丁醚、0.25-0.8乙二醇甲醚和0.25-0.9乙二醇乙醚。
7.如权利要求1所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述纤维素纤维为棉纤维或麻纤维。
8.如权利要求1所述的抗静电耐湿热的大豆纤维混纺面料，其特征在于，所述抗起球纤维层为抗起球腈纶。
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CN108103657A (zh) * 2017-12-29 2018-06-01 浙江真爱时尚家居有限公司 一种三角云纤维毛毯的生产工艺
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