CN105688982B - A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production - Google Patents

A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production Download PDF

Info

Publication number
CN105688982B
CN105688982B CN201610026449.4A CN201610026449A CN105688982B CN 105688982 B CN105688982 B CN 105688982B CN 201610026449 A CN201610026449 A CN 201610026449A CN 105688982 B CN105688982 B CN 105688982B
Authority
CN
China
Prior art keywords
alcohol
extract
branch
hydrogen
rush
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610026449.4A
Other languages
Chinese (zh)
Other versions
CN105688982A (en
Inventor
黄翔
黄丽莎
覃林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanjou International New Energy Technology Co., Ltd
Original Assignee
Guangxi Sanjiu New Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Sanjiu New Energy Technology Co Ltd filed Critical Guangxi Sanjiu New Energy Technology Co Ltd
Priority to CN201610026449.4A priority Critical patent/CN105688982B/en
Publication of CN105688982A publication Critical patent/CN105688982A/en
Application granted granted Critical
Publication of CN105688982B publication Critical patent/CN105688982B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/003—Catalysts comprising hydrides, coordination complexes or organic compounds containing enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1088—Non-supported catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1223—Methanol
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1229—Ethanol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a kind of bioactivity catalyst for making alcohol water system reformation hydrogen production, it is made of mulberry branch extract, apricot branch extract, rush extract, bioactivity catalyst is placed in gas generator, reforming reaction occurs and generates the hydrogen-rich gas of high-purity and then drives engine work；This bioactivity catalyst can be applied to car-mounted device, rotor machine or hydrogen-rich aerating station arrangement；The bioactivity catalyst source of the present invention is in plant extracts, abundant raw material, and extraction process is simple, with the bioactivity catalyst of the present invention, hydrogen purity improves, closer to theoretical value, alcohol consumption is significantly reduced, and is current more advanced, the stronger hydrogen production process of applicability.

Description

A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production
Technical field
The present invention relates to environmentally protective regenerative resource research and development technology field, specially one kind makes alcohol water system reform system The bioactivity catalyst and its preparation and application of hydrogen.
Background technology
Two hang-up of facing mankind energy crisis and environmental pollution.
Oil, natural gas, coal are the main bodys of high-grade energy and current energy resource structure that the Nature is presented to the mankind, It is non-renewable resource.But it is estimated that whole world petroleum reserves is about 150,000,000,000 tons；Gas reserves is about 15,000,000,000 cubes Rice；Increase according to Global Oil 2%/year of consumption；5%/year of gas consumption increases, and Global Oil will be exhausted in 2032, Natural gas will be exhausted in 2028, and there are energy crises by the mankind.Meanwhile the serious threat of facing mankind environmental pollution, to obtain Economic and society sustainable development, it is necessary to research and develop alternative new energy.
Hydrogen Energy has high inflammability, low ignition energy, homogenous combustion, high-octane rating, high-energy density, adapts to higher pressure Contracting ratio, engine thermal efficiency are high, undoubtedly a kind of ideal cleaning, efficient, the reproducible energy.In twentieth century 70 years Generation, the U.S., Germany and Japan all successively have developed the automobile using liquid hydrogen as fuel.Right Hydrogen Energy is because producing difficulty, storage, fortune Defeated and hydrogenation stations danger coefficient is high, along with hydrogen manufacturing cost it is excessively high the problems such as so that Hydrogen Energy fails to be generalizable.
Fortunately, the mankind being full of resource never stopped exploration, people have found a low price, cleaning, efficiently, can Regeneration, environmentally protective, the alternative strong alcohol water system method for preparing hydrogen by reforming that can generate Hydrogen Energy moment, disposably solve Hydrogen Energy The problems such as producing, store, transporting makes Hydrogen Energy popularization and application come true.
Existing alcohol water system method for preparing hydrogen by reforming is after being mixed in a certain ratio methanol/ethanol and water, to be filled in reaction In putting, by catalyst action under certain temperature or pressure condition or magneticaction, reform methanol/ethanol aqueous solution Reaction is obtained with hydrogen（H2）Based on, while also contain carbon monoxide（CO）, carbon dioxide（CO2）, methane（CH4）And water （H2O）Hydrogen-rich gas.The reforming reaction formula being directed to is as follows：
Methanol-water systems reform hydrogen production reaction formula：
1）Main reaction formula：CH3OH→→→→CO+2H2
CO+ H2O→→→→CO2+H2
2）Overall reaction：CH3OH+H2O→→→→CO2+3H2
3）Side reaction CO+3H2→→→→CH4+H2O
Ethanol water systems reform hydrogen production reaction formula：
1）Main reaction formula：C2H5OH→→→→CO+3H2+C
CO+ H2O→→→→CO2+H2
C+2H2O→→→→CO2+2H2
2）Overall reaction：C2H5OH +3H2O→→→→2CO2+6H2
3）Side reaction CO+3H2→→→→CH4+H2O
Reforming reaction is more abundant, and alcohol conversion is higher, and side reaction is fewer, and hydrogen-rich gas hydrogen content is higher.Publication 201210083938.5（A kind of method of hydrogen production from methanol-steam reforming）, publication 201510055497.1（It is vehicle-mounted aqueous Ethyl alcohol low-temperature reformate hydrogen production process and its device and application system）, publication 201510363608.5（A kind of methanol-water is reformed Hydrogen making machine and its hydrogen production process）And the mechanism of hydrogen generation of publication 201510553870.6 is such.So above-mentioned patent institute is public The rare metal catalyst that the reforming reaction of the hydrogen preparation method opened uses, reforming reaction process are contacted because of alcohol water with catalyst Insufficient, alcohol consumption is big, and side reaction product is more, and hydrogen purity is much lower compared with theoretical value, is used as and urged using rare metal Agent is promoted the use of and is restricted, and reaction temperature is high in addition（It is required that 600 DEG C of reaction temperature or more）So that Hydrogen Energy manufacturing cost It is high.
Invention content
It is an object of the invention to：For existing alcohol water system method for preparing hydrogen by reforming alcohol consumption height, hydrogen purity and reason By value compared to it is much lower, because metallic catalyst limitation and reaction temperature it is high-leveled and difficult with it is universal the problems such as, a kind of alcohol water system weight is provided The bioactivity catalyst of whole hydrogen manufacturing, by the way that bioactivity catalyst is added in alcohol water system in advance and is uniformly mixed it, Alcohol water is made to transform into cerebroysin alcohol.Cerebroysin alcohol becomes hydrogen-rich gas by certain device, at low temperature catalytic pyrolysis.Pass through utilization The bioactivity catalyst of the present invention, hydrogen purity improve, and closer to theoretical value, alcohol consumption is significantly reduced, and is current More advanced, the stronger hydrogen production process of applicability.
Realization that the present invention adopts the following technical solutions：
The active catalyst made used in the bioactivity antigravity system biology of alcohol water system reformation hydrogen production of the present invention, by The raw material of following parts by weight is made：
30-40 parts of mulberry branch extract；Apricot branch extract 20-30；10-25 parts of rush extract.
Mulberry branch extract, apricot branch extract and the rush extract be by mulberry branch, apricot branch and The second extract of the water extract of rush, water and organic solvent.
The mulberry branch extract is to shred mulberry branch, and the boiling for adding in branch weight 5-10 weight is boiled 2-4 hours, Filtering, the boiling that filter residue adds 2-3 times of weight are boiled 1-2 hours, merge filtrate twice, are concentrated into the relative density that 6O DEG C of heat is surveyed It is 1.1, obtains mulberry branch extract.
Equally, apricot branch water extract is the chopping of apricot branch, and the boiling boiling 2-4 for adding in branch weight 5-10 weight is small When, filtering, the boiling that filter residue adds 2-3 times of weight is boiled 1-2 hour, merges filtrate twice, is concentrated into the opposite of 6O DEG C of heat survey Density is 1.1, obtains apricot extract.
Rush water extract is rush chopping, and the boiling for adding in branch weight 5-10 weight is boiled 2-4 hours, filtering, The boiling that filter residue adds 2-3 times of weight is boiled 1-2 hours, merges filtrate twice, is concentrated into the relative density that 6O DEG C of heat is surveyed and is 1.1, obtain rush extract.
The second extract of mulberry branch organic solvent is to shred mulberry branch, is first extracted 1-2 hours with organic solvent, respectively Liquid and mulberry branch slag are taken out, mulberry branch slag adds 3-5 times of boiling to boil 1-2 hours, merges organic solvent extracting solution and Aqueous extracts.
The second extract of apricot branch organic solvent is to shred apricot branch, is first extracted 1-2 hours with organic solvent, Liquid and apricot branch slag are taken out respectively, and apricot branch slag adds 3-5 times of boiling to boil 1-2 hours, merges organic solvent extracting solution And Aqueous extracts.
The second extract of rush organic solvent is to shred rush, is first extracted 1-2 hours with organic solvent, respectively Liquid and rush slag are taken out, rush slag adds 3-5 times of boiling to boil 1-2 hours, merges organic solvent extracting solution and Aqueous extracts.
The organic solvent is methanol, ethyl alcohol, ether, petroleum ether, benzene, toluene, chloroform, ethyl acetate and two chloroethenes Alkane；Or the mixture of methanol and ethyl alcohol；Or the mixture of benzene and toluene.
Above-mentioned mulberry branch extract, apricot extract and rush extract does not have to be condensed into dry when concentration Cream.
Above-described mulberry branch, for the dry twig of moraceae plants mulberry tree, latin name：Morus alba L.Originate in me In the middle part of state, there is the cultivation history of nearly 4,000 years, cultivation is in extensive range, and northeast is from the south Harbin；Northwest is from Southern Nei Mongol to new Boundary, Qinghai, Gansu, Shaanxi；South to Guangdong, Guangxi, to the east of Taiwan；West to Sichuan, Yunnan；With the cultivation of middle and lower reach of Yangtze River various regions most It is more.Vertical distribution is mostly below height above sea level 1200m.In addition, also there are cultivation in Korea, Mongolia, Japan, Russia, Europe and North America.
Mulberry branch is also the traditional Chinese medicine in China, herbal nature：Spray part, taste is poor, is slightly cold, nontoxic.Ramulus mori head： Bitter, it is cold in nature, it is nontoxic.
In the chemical analysis of mulberry branch extraction, containing tannin（tannin）[1], sucrose（sucrose）, fructose （fructose）, stachyose（stachyose）, glucose（glucose）, maltose（maltose）, gossypose （raffinose）, arabinose（arabinose）, xylose（xylose）；Stem contains flavones ingredient：Mulberrin（mulberrin）, Mulberrochromene（mulbel-rochromene）, cyclomulberrin（cyclomulberrin）, cyclomulberrochromene（cyclomulbel- rochromene）.Timber contains morin（morin）, three-bristle cudrania tree element（cudranin）, 2,4,4 ', 6- tetrahydroxybenzophenones（2,4, 4 ', 6-tetrahydroxybenzoph-none), 2,3 ', 4,4 ', 6- pentahydroxybenzophenones（2,3 ', 4,4 ', 6- Pentahydrox-ybenzophenone, maclurin）；Heartwood contains dihydromorin（dihydromo-rin）, dihydro kaempferia galanga Phenol（dihydro kaempferol）, 2,4,3 ', 5 '-tetrahydroxystilbene（2,4,3 ', 5 '-tetrahydroxystilbene) [6], Eight alcohol of white mulberry（alboctalol）, moracinC, D（moracin C,D）, 2,4,4 ', 6- tetrahydroxybenzophenones（2,4,4 ', 6- tetrahydrox-ybenzophenone）And 2,3 ', 4,4 ', 6- pentahydroxybenzophenones（Maclurin, 2,3 ', 4,4 ', 6- pentrahydrox-ybenzophenone）, resvertrol（Black false hellebore phenol, resera-trol）, Oxyresveratrol （oxyresveratrol）, dihydro Oxyresveratrol（dihydrooxyresveratrol）, Moracin A, B, E, F, G, H, （moracin A,B,E,F,G,H）, morusin（mulberrin）, mulberrochromene（mulberrochromene）, cyclomorusin （cyclomulberrin）, cyclomulberrochromene（cyclomulberrochromene）And birch skin acid.
There are many kinds for mulberry tree, and the mulberry branch selected by the present invention is the kind that can raise silkworm.
Apricot branch, is limb and the leaf of plant apricot, apricot Latin literary fame：Armeniaca vulgaris Lam. Alias：Apricot, northern plum.Section belongs to：The rose family, Prunus.The place of production is distributed：Xinjiang native to China, it is widely distributed to North China various regions. Ecological habit：For heliophilous species, deep-rootedness, light, drought-enduring, cold-resistant, wind resistance lasts a long time, and is low massif more than a century The Main Cultivation fruit tree in mound area.Horticultural use：Early spring blooms, and first spends rear leaf；Can be planted with green pine, Chinese incense cedar by the pond lakeside or Before planting Yushan Hill Shi Ya sides, garden hall, great ornamental value.
Apricot is deciduous tree, all over China to have cultivation more.High reachable 5-8m, diameter of a cross-section of a tree trunk 1.3 meters above the ground 30cm.Dry hide taupe, no top Bud, 2-3 pieces of fasciation of hibernaculum.Single leaf alternate, leaf are avette to subcircular, long 5-9cm, wide 4-8cm, apex tool mucro, base portion circle Shape is near heart-shaped, edge tool round blunt sawtooth, pinnate vein, 4-6 pairs of lateral vein, and leaf mass color is slided, blade back hairiness between arteries and veins sometimes, petiole light It slides, long 2-3cm, has 1-6 bodies of gland at nearly phyllopodium, flower both sexes, single flower is without stalk or closely without stalk；The narrow cylindrical shape of calyx, sepal are anti-when spending Folding；Grey color is micro- red, 25-45 pieces of stamen, shorter than petal, and fruit is spherical or avette, how shallow when ripe to split or yellowish red color, micro- hairiness. Seed nucleus flattened round, more bitter tastes or sweet taste；March at florescence, the fruit ripe 6-7 months.
It after apricot harvesting, needs to carry out branch pulling and angle opening to prosperous branch, be promoted with mitigating tree vigo(u)r into flower；Young sprout is plucked twice The heart to inspire branch, cultivates branch group；It suitably to be bounced back to weak sagging fruitful branch notable after result；To being sprouted in tree crown Raw excessive growth branch will take pinching, turn round the measures such as the tip, control its nutrient growth；To the branch of excessive growth of no growing space, and When remove.So there is a large amount of apricot branch in annual orchard, it is generally used for making a fire in the past cooking, now due to rural area also makes With natural gas, so apricot branch can only be allowed to rot in orchard.
Apricot branch chemical analysis：
Apricot bark protease containing tool inhibits and the tannin of the former Cyanidin type of antiviral activity.
Apricot leaf is containing rutin (rutin), Quercetin -3- sandlwood glycosides (quercetin-3- Rhamnoglucoside), prunase（prunase）, chlorogenic acid (chlorogenic acid), neochlorogenic acid (neochlorogenic acid)。
Wild apricot leaf, containing quercitrin (quercitrin), rhamnetin -3-O- rhamnosides (rhamnetin-3-O- Rhamnoside), rhamnocitrin -3-O- rhamnosides (rhamnocitrin-3-O-rhamnoside).
Ansu apricot leaf (phlorizin) containing phloridzin.
More containing flavonoids in underdone fruit, flavonoids plays the role of preventing heart disease and reduces myocardial infarction；
Semen armeniacae amarae can be relieving cough and asthma, relaxes bowel, and can treat the diseases such as tuberculosis, cough；
Also containing abundant vitamin C and polyphenol components, this ingredient is not only able to reduce cholesterol in human body almond Content, moreover it is possible to significantly reduce the onset risk of heart disease and many chronic diseases.
Semen armeniacae amarae chemical composition, containing amygdalin（amygdalin）, fat oil, emulsin（emulsin）, cyaniding glucoside, Amygdalase（amygdalase）, prunase（prunase）, oestrone, alpha-estradiol, desmosterol etc..
Rush, Chinese medicine name are rush family plant rushMedulla JunciDrying stem marrow.Alias：Wick Grass, Lin's grass, Chinese alpine rush, wild seat grass, horse palm fibre root, wild horse palm fibre；It is perennial herb water plant, subterranean stem is short, crawling property, stalk clump Raw upright, cylindrical shape is solid, and basal part of stem tool brown is degenerated in flakey first sheathing leaf, spike, basidixed, given birth on stem in false side Shape, the extension of base portion bract spend 2 pieces of squamellas of lower tool, 6 pieces of perianth sliver, 3 pieces of stamen, 3 disagreement of pistil stigma in bulbous.Brown Huang Color capsule, elliptical or oval shape, seed yellow are in obovate.Rush late summer to autumn extracts stem, dries, and takes out stem marrow, reason Directly, it is bundled into wisp.This product is in thin cylinder, up to 2250px, 0.1~7.5px of diameter.Superficial white or yellowish white have thin Longitudinal grin.Body is light, and matter is soft, slightly elastic, easily breaks.
Rush is also traditional Chinese herbal medicine, and effect is classified：Sharp water medicine；Antipyretic；Stranguria-relieving diuretic, meridian distribution of property and flavor are micro- It is cold；It is sweet, light；The thoughts of returning home；Lung；Small intestine；Bladder warp, effect promoting diuresis for stranguria；Clearing heart fire.It cures mainly：Gonorrhoea；Oedema；Urine is not Profit, the puckery pain of oliguria；Jaundice with damp-heat pathogen；Dysphoria and insomnia；Nocturnal fretfulness in infants；Larynx numbness；Aphthae；Wound.
[pharmacological action]:Promoting diuresis for stranguria；Clearing heart fire.It cures mainly：Gonorrhoea；Oedema；Difficult urination, the puckery pain of oliguria；Damp and hot Huang Subcutaneous ulcer；Dysphoria and insomnia；Nocturnal fretfulness in infants；Larynx numbness；Aphthae；Wound.
[chemical composition]:Containing araban（araban）, xylan（xylan）, methylpentosan（methyl pentosan）, tan acid anhydride（phlobaphene）, cyanidenon（luteolin）, luteolin-7-glucoside（luteolin- 7-glucoside）Deng.
The extraction of rush also had some document reports, for example, rush phenanthrene effective kind part and preparation method thereof and Purposes Chinese Patent Application No.：201410106877.9 applicant：Beijing University of Chinese Medicine：Inventor：Huang builds plum Li Gui clouds The gorgeous Wang Yang of Duan Tianxuan Zhan Xue；Rush phenanthrene effective kind part and preparation method thereof and its use in anxiolytic drugs is prepared On the way, the active component includes effusol, dehydroeffusol, juncusol and the dehydroujunation higher than 50%, the preparation Method includes the following steps：Lampwick grass blade marrow is taken, with ethanol water refluxing extraction；By obtained extracting solution merge and it is dense Contracting then with ethyl acetate ultrasonic extraction, merges extracting solution, the extracting solution after merging is concentrated, dry, obtains dry acetic acid second Ester crude extract；Dry ethyl acetate extract is taken, is detached by silica gel column chromatography or high speed adverse current chromatogram, you can obtains luxuriant and rich with fragrance class Active component.
There are many kinds of rushes, as long as but having medulla（That is lampwick）It can use.
The mechanism of the bioactivity catalyst of the present invention is, due to mulberry branch extract, apricot branch extract and wick Careless extract contains carbohydrate, ketone, phenols, olefines, leaf enzyme, peroxidase, chlorogenic acid, glucosides, mixed with first/ethyl alcohol with Afterwards, the various hydroxyls of catalyst, phenolic group, ketone group, alkylene, phytoenzyme make the hydroxy combining of moisture subbase group and first/ethyl alcohol Cracking reaction can also be accelerated when first/ethanol water is in low temperature by obtaining.The application method of the bioactivity catalyst of the present invention is such as Under：
（1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain biology Active catalyst；
（2）By the organic solvent of weight content 55-80%, such as methanol or ethyl alcohol（Water content 20-45%）It is upper with 2-5% It states bioactivity catalyst and is uniformly mixed acquisition cerebroysin alcohol.
（3）Cerebroysin alcohol treats that temperature is increased to 180 DEG C or more in gas generator（180-400℃）Weight can occur moment Whole reaction generates the hydrogen-rich gas of high-purity.
（4）Gas generator can be car-mounted device, rotor machine or hydrogen-rich aerating station arrangement, but be not limited to be carried The device arrived.
The car-mounted device is that an alcohol is disposed to decompose generator A on automobile, and alcohol is equipped with charging before decomposing generator A Device, alcohol-water solution and bioactivity catalyst inject alcohol by feeder and decompose in generator A, and the alcohol decomposes generator A Equipped with blender and heating device, alcohol-water solution catalysis reaction generation hydrogen, carbon dioxide and a small amount of carbon monoxide and methane； Alcohol decomposes generator A gas vents and meets hydrogen-rich bottle A, and by pressure reducing valve and controller, hydrogen-rich gas is sprayed into engine from nozzle A combusted cylinders do work；Lack of gas after engine A burnings connect the heat exchanger in feeder A, to alcohol-water solution and catalyzer temperature-elevating. The cerebroysin alcohol of the present invention is added to the automotive oil tank for having installed above device additional, using engine valve waste heat, the cracking and catalyzing outside cylinder Into hydrogen-rich gas, cylinder combustion is entered under engine negative pressure state, instead of gasoline as motor vehicle fuel.
The rotor machine is one feeder B of placement in engine export, and decomposing generator B with alcohol connect, Alcohol is injected after alcohol-water solution and catalyst heating by feeder B to decompose in generator B, the alcohol decomposes generator B and is equipped with Blender and heating device, alcohol-water solution catalysis reaction generation hydrogen, carbon dioxide and a small amount of carbon monoxide and methane；Alcohol point Solution generator B gas vents connect hydrogen-rich bottle, and by pressure reducing valve and controller, hydrogen-rich gas is sprayed into engine cylinder combustion from nozzle Burn acting；Engine output shaft is connect with generator shaft.Alcohol-water solution can be catalytically conveted to richness by the engine exhaust heat of the present apparatus Hydrogen provides the energy for engine, is converted into electric energy, can be developed into small-sized power station, and cost of electricity-generating is fired less than tradition Fry dried food ingredients motor.
The hydrogen-rich aerating station arrangement can be by the use of solar energy as heating source；The heat or electricity of solar panels output are to alcohol It decomposes the alcohol-water solution of generator C and bioactivity catalyst carries out heat resolve, alcohol decomposition generator C, which is equipped with, to be stirred Mix device and heating device, alcohol-water solution catalysis reaction generation hydrogen, carbon dioxide and a small amount of carbon monoxide and methane；Alcohol decomposes Generator C gas vents connect low pressure gas cylinder and gas cylinder, are then passed to filling machine to the user for needing hydrogen fuel, substitutionization The stone energy for various Industrial Boilers, hotel, organ, school lunch service catering industry.
The beneficial effects of the invention are as follows：
1st, catalyst is derived from plant extracts, abundant raw material, and extraction process is simple.
2nd, alcohol water preparation Hydrogen Energy is gradually replaced into gasoline, tapped a new source of energy, be a weight of current each countries and regions Wanting for task, gasoline, natural gas failure arrive before promote the technology by be the mankind exploitation the energy direction.
3rd, with ethyl alcohol（Methanol）For catalytic material cracking hydrogen production, there is Hydrogen Energy (alcohol hydrogen fuel, hydrogen-rich gas) production technology Advantage（With production with adding, can be used with vehicle hydrogen manufacturing, with vehicle）, solve Hydrogen Energy and prepare the problems such as difficult, storage transport difficult.
4th, according to non-grain-production ethyl alcohol, such as the biomass ferments such as sugar grass, cornstalk, rice hulls, sugarcane, molasses Produce ethyl alcohol, the discharged CO of burning2Consumed CO is grown with the biological source as raw material2, quantitatively remain basically stable, This is to reducing atmosphere pollution and inhibiting greenhouse effects significant.
5th, the present invention can utilize the temperature that solar panel provides, and more than 180 DEG C thermal energy make alcohol decompose generator Cerebroysin alcohol instantaneously generates hydrogen-rich gas, can be pressed into hydrogen bottle, as hydrogen energy source, substitution fossil energy for various Industrial Boilers, Hotel, organ, school lunch service catering industry.
Description of the drawings
Fig. 1 is car-mounted device structure diagram of the present invention.
Fig. 2 is rotor machine structure diagram.
Fig. 3 is hydrogen-rich gas station apparatus structure schematic diagram.
The component names that serial number represents in figure as：
1st, feeder, 2, hydrogen-rich bottle, 3, alcohol decompose generator, 4, pressure gauge, 5, pressure reducing valve, 6, controller, 7, nozzle, 8, Engine, 11, engine A, 12, hydrogen-rich air inlet pipe, 13, the exhaust pipe of engine, 14, feeder B, 15, alcohol decompose generator B, 16th, hydrogen-rich bottle B, 17, engine shaft；18th, generator, 19, storage battery；21st, solar panels, 22, alcohol decompose generator C, 23 plus Glassware, 24, low pressure gas cylinder, 25. gas cylinders, 26, filling machine.
As shown in Figure 1, the car-mounted device is that an alcohol is disposed to decompose generator A2 on automobile, alcohol decomposes generator Feeder 1 is equipped with before A2,（Cerebroysin alcohol）Alcohol-water solution and bioactivity catalyst inject alcohol by feeder 1 and decompose generator In A2, the alcohol decomposes generator A2 and is equipped with blender and heating device, alcohol-water solution catalysis reaction generation hydrogen, titanium dioxide Carbon and a small amount of carbon monoxide and methane；Alcohol decomposes generator A2 gas vents and meets hydrogen-rich bottle A 3, passes through pressure reducing valve 5 and control Hydrogen-rich gas is sprayed into the acting of 11 combusted cylinders of engine A by device 6 from nozzle 7；Pressure gauge 4 is mounted on what hydrogen-rich bottle A 3 was exported On pipeline；Lack of gas after the burnings of engine A 11 connect the heat exchanger in feeder A1, to alcohol-water solution and catalyzer temperature-elevating.
As shown in Fig. 2, the rotor machine is the one feeder B14 of placement exported in engine 11, with alcohol point Solution generator B 15 is connected,（Cerebroysin alcohol）It injects alcohol by feeder B 14 after alcohol-water solution and catalyst heating and decomposes and occur In device B 15, the alcohol decomposes generator B 15 and is equipped with blender and heating device, alcohol-water solution catalysis reaction generation hydrogen, Carbon dioxide and a small amount of carbon monoxide and methane；Alcohol decomposes 15 gas vent of generator B and connects hydrogen-rich bottle, by pressure reducing valve and Hydrogen-rich gas is sprayed into engine cylinder work by combustion by controller from nozzle；Engine output shaft 17 and 18 axis connection of generator. Alcohol-water solution can be catalytically conveted to hydrogen-rich gas by the engine exhaust heat of the present apparatus, provided the energy for engine, be converted into electricity Can, small-sized power station is can be developed into, cost of electricity-generating is less than conventional fuel oil generator.
As shown in figure 3, the hydrogen-rich aerating station arrangement can be by the use of solar energy as heating source；Solar panels 21 export Heat or electricity generator C's 22 is decomposed to alcohol（Cerebroysin alcohol）Alcohol-water solution and bioactivity catalyst carry out heat resolve, institute The alcohol stated decomposes generator C 22 and is equipped with blender and heating device, alcohol-water solution catalysis reaction generation hydrogen, carbon dioxide and few The carbon monoxide and methane of amount；Alcohol decomposes 22 gas vents of generator C and connects low pressure gas cylinder 24 and gas cylinder 25, is then passed to Filling machine 26 gives the user for needing hydrogen fuel.
Specific embodiment
It is the preparation embodiment of bioactivity catalyst below：
Embodiment 1：
（1）The preparation of mulberry branch extract, apricot branch extract and rush extract：
Mulberry branch is shredded, the boiling for adding in branch 5 times of weight of weight is boiled 2 hours, and filtering, filter residue adds 2 times of weight Boiling boil 1 hour, merge filtrate twice, it is 1.1 to be concentrated into the relative density that 6O DEG C of heat is surveyed, and obtains mulberry branch extract.
Apricot branch water extract is the chopping of apricot branch, and the boiling for adding in branch 5 times of weight of weight is boiled 2 hours, filtering, The boiling that filter residue adds 2 times of weight is boiled 1 hour, merges filtrate twice, and it is 1.1 to be concentrated into the relative density that 6O DEG C of heat is surveyed, and is obtained To apricot branch extract.
Rush water extract is rush chopping, and the boiling for adding in branch 5 times of weight of weight is boiled 2 hours, filtering, filter residue The boiling for adding 2 times of weight is boiled 1 hour, merges filtrate twice, and it is 1.1 to be concentrated into the relative density that 6O DEG C of heat is surveyed, and obtains lamp Core swath extract.
（2）The application method of bioactivity catalyst
1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain biology Active catalyst；
2）By 55% ethyl alcohol of weight content（Water content 45%）Is stated with 5% waterborne（1）The bioactivity catalyst mixing of step It stirs evenly, obtains cerebroysin alcohol；
3）By cerebroysin alcohol adding apparatus 1（Car-mounted device）In, automobile can be made to be run on highway with using gasoline.
4）By cerebroysin alcohol adding apparatus 2（Rotor machine）In, it can produce electricl energy.
5）By cerebroysin alcohol adding apparatus 3（Hydrogen-rich aerating station arrangement）In, hydrogen-rich gas can be generated.
Embodiment 2：
（1）The preparation of mulberry branch extract, apricot branch extract and rush extract：
Mulberry branch is shredded, the boiling for adding in branch 10 times of weight of weight is boiled 3 hours, and filtering, filter residue adds 3 times of weight Boiling boil 2 hours, merge filtrate twice, it is 1.1 to be concentrated into the relative density that 6O DEG C of heat is surveyed, and obtains mulberry branch extract.
Apricot branch water extract is the chopping of apricot branch, and the boiling for adding in branch 10 times of weight of weight is boiled 4 hours, mistake Filter, the boiling that filter residue adds 2 times of weight are boiled 2 hours, merge filtrate twice, and it is 1.1 to be concentrated into the relative density that 6O DEG C of heat is surveyed, Obtain apricot branch extract.
Rush water extract is rush chopping, and the boiling for adding in branch 10 times of weight of weight is boiled 2 hours, is filtered, filter The boiling that slag adds 2 times of weight is boiled 1 hour, merges filtrate twice, and it is 1.1 to be concentrated into the relative density that 6O DEG C of heat is surveyed, and is obtained Rush extract.
（2）The application method of bioactivity catalyst
1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain biology Active catalyst；
2）By 80% ethyl alcohol of weight content（Water content 20%）With 2% above-mentioned（1）The bioactivity catalyst mixing of step is stirred It mixes uniformly, obtains cerebroysin alcohol；
3）By cerebroysin alcohol adding apparatus 1（Car-mounted device）In,（180-400 DEG C of decomposition temperature）It can make automobile with using gasoline Equally run on highway.
4）By cerebroysin alcohol adding apparatus 2（Rotor machine）In,（180-400 DEG C of decomposition temperature）It can produce electricl energy.
5）By cerebroysin alcohol adding apparatus 3（Hydrogen-rich aerating station arrangement）In,（180-400 DEG C of decomposition temperature）Hydrogen rich gas can be generated Body.
Embodiment 3：
（1）The preparation of mulberry branch extract, apricot branch extract and rush extract：
Mulberry branch is shredded, is first extracted 1.5 hours with the ethyl alcohol of more than 70% weight content, takes out liquid and ramulus mori respectively Slag, mulberry branch slag add 3 times of boiling to boil 1.5 hours, merge organic solvent extracting solution and Aqueous extracts, obtain mulberry branch extraction Object.
The second extract of apricot branch organic solvent is to shred apricot branch, first with the second of more than 70% weight content Alcohol extracting 2 hours, takes out liquid and apricot branch slag respectively, and apricot branch slag adds 3 times of boiling to boil 1.5 hours, merges organic Solvent extraction liquid and Aqueous extracts obtain apricot branch extract
Rush is shredded, is first extracted 2 hours with the ethyl alcohol of more than 70% weight content, takes out liquid and rush respectively Slag, rush slag add 3 times of boiling to boil 1.5 hours, merge organic solvent extracting solution and Aqueous extracts.
（2）The application method of bioactivity catalyst
1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain biology Active catalyst；
2）By 55% methanol of weight content（Water content 45%）With 5% above-mentioned（1）The bioactivity catalyst compounds of step It is uniformly mixed, obtains cerebroysin alcohol；
3）Cerebroysin alcohol is added in car-mounted device,（180-400 DEG C of decomposition temperature）Can make automobile with using gasoline It is run on highway.
4）Cerebroysin alcohol is added in rotor machine,（180-400 DEG C of decomposition temperature）It can produce electricl energy.
5）Cerebroysin alcohol is added in hydrogen-rich aerating station arrangement,（180-400 DEG C of decomposition temperature）Hydrogen-rich gas can be generated.
Embodiment 4,
（1）The preparation of mulberry branch extract, apricot branch extract and rush extract：
Mulberry branch is shredded, first with the extracted by ether of more than 70% weight content 1 hour, takes out liquid and mulberry branch respectively Slag, mulberry branch slag add 3 times of boiling to boil 1 hour, merge organic solvent extracting solution and Aqueous extracts, recycle ether, obtain mulberry branch Extract.
The second extract of apricot branch organic solvent is to shred apricot branch, first with the second of more than 70% weight content Ether extracts 1 hour, takes out liquid and apricot branch slag respectively, and apricot branch slag adds 3 times of boiling to boil 1 hour, merges organic molten Agent extracting solution and Aqueous extracts recycle ether, obtain apricot branch extract.
Rush is shredded, first with the extracted by ether of more than 70% weight content 1 hour, takes out liquid and rush respectively Slag, rush slag add 3 times of boiling to boil 1 hour, merge organic solvent extracting solution and Aqueous extracts, recycle ether, obtain rush Extract.
（2）The application method of bioactivity catalyst
1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain biology Active catalyst；
2）By 80% methanol of weight content（Water content 20%）With 2% above-mentioned（1）The bioactivity catalyst mixing of step is stirred It mixes uniformly, obtains cerebroysin alcohol；
3）Cerebroysin alcohol is added in car-mounted device, automobile can be made to be run on highway with using gasoline.
4）Cerebroysin alcohol is added in rotor machine, can be produced electricl energy.
5）Cerebroysin alcohol is added in hydrogen-rich aerating station arrangement, hydrogen-rich gas can be generated.
Embodiment 5：
（1）The preparation of mulberry branch extract, apricot branch extract and rush extract：
Mulberry branch is shredded, is first extracted 2 hours with the ethyl acetate of more than 70% weight content, takes out liquid and mulberry respectively Branch slag, liquids recovery ethyl acetate are spare；Mulberry branch slag add 4 times boiling boil 1 hour, merge organic solvent extracting solution and Aqueous extracts obtain mulberry branch extract.
The second extract of apricot branch organic solvent is to shred apricot branch, first with the second of more than 70% weight content Acetoacetic ester extracts 2 hours, takes out liquid respectively and apricot branch slag, liquids recovery ethyl acetate are spare；Apricot branch slag adds 4 Boiling again is boiled 1 hour, is merged organic solvent extracting solution and Aqueous extracts, is obtained apricot branch extract.
Rush is shredded, is first extracted 2 hours with the ethyl acetate of more than 70% weight content, takes out liquid and lamp respectively Core grass slag, liquids recovery ethyl acetate are spare；Rush slag add 3 times boiling boil 1 hour, merge organic solvent extracting solution and Aqueous extracts.
（2）The application method of bioactivity catalyst
1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain biology Active catalyst；
2）By the ethyl alcohol of weight content 70%（Water content 30%）With 4% and above-mentioned（1）The bioactivity catalyst of step Compound stirs evenly, and obtains cerebroysin alcohol；
3）Cerebroysin alcohol is added in car-mounted device,（180-400 DEG C of decomposition temperature）Can make automobile with using gasoline It is run on highway.
4）Cerebroysin alcohol is added in rotor machine,（180-400 DEG C of decomposition temperature）It can produce electricl energy.
5）Cerebroysin alcohol is added in hydrogen-rich aerating station arrangement,（180-400 DEG C of decomposition temperature）Hydrogen-rich gas can be generated.
In above-described embodiment, organic solvent extracting solution can also use benzene, toluene or chloroform and dichloroethanes, process with Alcohol, ethyl acetate are similar.
Alcohol water system reformation hydrogen production hydrogen-rich gas theory forms（Volume %）H2：75%,CO2:25%, the present invention（Embodiment 2 Cerebroysin alcohol）Calculated value such as following table：
Experimental data shows：Reaction temperature reaches 200 DEG C, alcohol water system hydrogen manufacturing reforming reaction cmpletely, the present invention The hydrogen-rich gas of generation does not contain intermediate product（CO、CH4）, the use of this catalyst can make alcohol water system hydrogen manufacturing reforming reaction completeer Entirely, more fully, product hydrogen-rich gas composition illustrates that the bioactivity catalyst using the present invention can make alcohol water system close to theoretical value Catalytic pyrolysis becomes hydrogen-rich gas to system at low temperature, and hydrogen purity improves, and closer to theoretical value, alcohol consumption also significantly drops It is low.
Cerebroysin alcohol methanol fuel is applied to car-mounted device by the present inventor, is started in October, 2014 in Jining of Shandong Province, Zhejiang Jiang Wenzhou, Zhejiang Hangzhou carry out small-scale taxi commerial vehicle experiment, and power performance is no different with gasoline, and traffic-operating period is good Good, taxi driver is very satisfied.
In August, 2015, a car is transformed in we, and cerebroysin alcohol alcohol fuel on probation is run, and achieving automobile should Data through detection department of the cerebroysin alcohol sample presentation to profession is examined, meet car use, every technical parameter is better than mesh Preceding 93# gasoline, what is emitted is steam, and environment is not polluted.Fuel cost is only the 50%--60% of gasoline, completely 93# gasoline can be replaced for automobile.Car uses cerebroysin alcohol to compare mileage travelled as fuel：4582 kilometers, in city Road driving mileage：1367 kilometers, 45 kilometers of average speed per hour；In highway driving mileage：3215 kilometers, average speed per hour 107 Kilometer, climbing power foot.

Claims (4)

1. a kind of bioactivity catalyst for making alcohol water system reformation hydrogen production, is made of the raw material of following parts by weight：
30-40 parts of mulberry branch extract；20-30 parts of apricot branch extract；10-25 parts of rush extract；
Mulberry branch extract, apricot branch extract and the rush extract is mulberry branch, apricot branch and rush Water extract or the second extract of water and organic solvent；
The water extract of the mulberry branch is to shred mulberry branch, and 2- is boiled in the boiling that 5-10 times of weight is added in by mulberry branch weight 4 hours, filtering, the boiling that filter residue adds 2-3 times of weight was boiled 1-2 hours, merges filtrate twice, was concentrated into the phase that 6O DEG C of heat is surveyed It is 1.1 to density, obtains mulberry branch extract；
The apricot branch water extract is the chopping of apricot branch, and the boiling that 5-10 times of weight is added in by apricot branch weight is boiled 2-4 hours, filtering, the boiling that filter residue adds 2-3 times of weight was boiled 1-2 hours, merges filtrate twice, was concentrated into what 6O DEG C of heat was surveyed Relative density is 1.1, obtains apricot branch extract；
The rush water extract is rush chopping, and the boiling boiling 2-4 that 5-10 times of weight is added in by rush weight is small When, filtering, the boiling that filter residue adds 2-3 times of weight is boiled 1-2 hour, merges filtrate twice, is concentrated into the opposite of 6O DEG C of heat survey Density is 1.1, obtains rush extract；
The mulberry branch water and the second extract of organic solvent are to shred mulberry branch, first small with organic solvent extraction 1-2 When, take out liquid and mulberry branch slag respectively, mulberry branch slag adds 3-5 times of boiling to boil 1-2 hour, merging organic solvent extracting solution with Aqueous extracts obtain second extract after recycling organic solvent；
The second extract of apricot branch organic solvent is to shred apricot branch, is first extracted 1-2 hours with organic solvent, respectively Liquid and apricot branch slag are taken out, apricot branch slag adds 3-5 times of boiling to boil 1-2 hours, merges organic solvent extracting solution and water Extract obtains second extract after recycling organic solvent；
The second extract of rush organic solvent is to shred rush, is first extracted 1-2 hours with organic solvent, taken out respectively Liquid and rush slag, rush slag add 3-5 times of boiling to boil 1-2 hours, merge organic solvent extracting solution and Aqueous extracts, recycling Second extract is obtained after organic solvent；
The organic solvent is methanol, ethyl alcohol, ether, petroleum ether, benzene, toluene, chloroform, ethyl acetate and dichloroethanes；Or The mixture of person's methanol and ethyl alcohol；Or the mixture of benzene and toluene.
2. the bioactivity catalyst described in claim 1 for making alcohol water system reformation hydrogen production, it is characterised in that：Its application method It is as follows：
（1）Mulberry branch extract, apricot branch extract and rush extract are mixed in parts by weight, obtain bioactivity Catalyst；
（2）By the ethyl alcohol of weight content 55-80% or the bioactivity of any mixture and 2-5% of methanol or ethyl alcohol and methanol Catalyst, which is uniformly mixed, obtains cerebroysin alcohol；
（3）The alcohol that cerebroysin alcohol is passed through to car-mounted device, rotor machine or hydrogen-rich aerating station arrangement is decomposed in generator, treats temperature 180 DEG C or more are increased to, the hydrogen-rich gas that reforming reaction generates high-purity occurs for moment.
3. the bioactivity catalyst according to claim 2 for making alcohol water system reformation hydrogen production, it is characterised in that：Described Car-mounted device is that alcohol is disposed to decompose generator A on automobile, and alcohol, which decomposes, is equipped with feeder before generator A, alcohol-water solution and Bioactivity catalyst injects alcohol by feeder and decomposes in generator A, and the alcohol decomposes generator A and is equipped with blender and liter Warm device, alcohol-water solution catalysis reaction generation hydrogen, carbon dioxide and a small amount of carbon monoxide and methane；Alcohol decomposes generator A gas Body outlet meets hydrogen-rich bottle A, and by pressure reducing valve and controller, hydrogen-rich gas is sprayed into the acting of engine A combusted cylinders from nozzle；
Lack of gas after engine A burnings connect the heat exchanger in feeder A, to alcohol-water solution and catalyzer temperature-elevating.
4. the bioactivity catalyst according to claim 2 for making alcohol water system reformation hydrogen production, it is characterised in that：Described Rotor machine is one feeder B of placement in engine export, and decomposing generator B with alcohol connect, alcohol-water solution and catalysis Alcohol being injected after agent heating by feeder B to decompose in generator B, the alcohol decomposes generator B and is equipped with blender and heating device, Alcohol-water solution catalysis reaction generation hydrogen, carbon dioxide and a small amount of carbon monoxide and methane；Alcohol decomposes generator B gases and goes out Mouth connects hydrogen-rich bottle, and by pressure reducing valve and controller, hydrogen-rich gas is sprayed into engine cylinder work by combustion from nozzle；Engine is defeated Shaft is connect with generator shaft；Alcohol-water solution can be catalytically conveted to hydrogen-rich gas by engine exhaust heat, and energy is provided for engine Source is converted into electric energy, can be developed into small-sized power station, and cost of electricity-generating is less than conventional fuel oil generator.
CN201610026449.4A 2016-01-16 2016-01-16 A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production Active CN105688982B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610026449.4A CN105688982B (en) 2016-01-16 2016-01-16 A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610026449.4A CN105688982B (en) 2016-01-16 2016-01-16 A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production

Publications (2)

Publication Number Publication Date
CN105688982A CN105688982A (en) 2016-06-22
CN105688982B true CN105688982B (en) 2018-07-10

Family

ID=56226495

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610026449.4A Active CN105688982B (en) 2016-01-16 2016-01-16 A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production

Country Status (1)

Country Link
CN (1) CN105688982B (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1829821A1 (en) * 2006-03-01 2007-09-05 Enea-Ente Per Le Nuove Tecnologie, L'Energia e L'Ambiente Membrane process for hydrogen production from reforming of organic products, such as hydrocarbons or alcohols
CN104229734A (en) * 2014-09-03 2014-12-24 深圳北纯能源科技有限公司 Reforming hydrogen production reactor and hydrogen production method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1829821A1 (en) * 2006-03-01 2007-09-05 Enea-Ente Per Le Nuove Tecnologie, L'Energia e L'Ambiente Membrane process for hydrogen production from reforming of organic products, such as hydrocarbons or alcohols
CN104229734A (en) * 2014-09-03 2014-12-24 深圳北纯能源科技有限公司 Reforming hydrogen production reactor and hydrogen production method

Also Published As

Publication number Publication date
CN105688982A (en) 2016-06-22

Similar Documents

Publication Publication Date Title
CN103142669B (en) Enzyme method for extracting ginsenoside and obtained ginsenoside extractive
CN101619107B (en) Astragalus polysaccharide extraction method
CN101570716B (en) Method for extracting natural Chinese medicinal herb fragrance component and application of extract thereof
CN102241786B (en) Preparation method and application of selenium enriched puerarin polysaccharide
CN102504038B (en) Plant polysaccharide and preparation method thereof as well as application of plant polysaccharide in cigarette
CN102715650B (en) Application of Dendrobium officinale polysaccharide to cigarette
Xu et al. Natural variation of lignocellulosic components in miscanthus biomass in china
CN103319564A (en) Method for producing diosgenin, yellow pigment and acidic starch by using yellow ginger
Basumatary et al. Yellow oleander (Thevetia peruviana) seed as a potential bioresource for industrial applications
CN105175563A (en) Extraction method and application of Grateloupia turuturu Yamada polysaccharide
CN102499463A (en) Plant essential oil, preparation method of plant essential oil, and application of plant essential oil to cigarettes
CN105688982B (en) A kind of bioactivity catalyst for making alcohol water system reformation hydrogen production
CN106916860A (en) A kind of preparation method and applications of edible and medical fungi tunning
CN104193794A (en) Method for extracting and preparing ginsenoside Rg3 from ginseng
WO2013056269A2 (en) Industrial hemp/cannabis sativa
CN108410531A (en) A kind of preparation method and applications of modification biological fuel
CN104147071A (en) Method for extracting effective components from saussurea involucrata
CN101191135B (en) Method for producing fuel ethanol by kudzu root synchronization saccharification fermentation
CN100434434C (en) Method for extracting high purity stachyose from radix rehmanniae recen and producing prepared rehmannia root
CN108264965A (en) A kind of preparation method of mud wormwood artemisia enzymatic hydrolyzed extract and its application in cigarette
CN108102735A (en) A kind of alcohol fuel and preparation method thereof
CN101429475A (en) Fig honey wine and method of preparing the same
CN101402876B (en) Method for producing biological diesel oil with seed oil of Chinese pine
TWI579381B (en) A method for preparing bio-ethanol
CN102268381A (en) Method for producing starter of fresh Shanlan yellow wine

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20200421

Address after: 410019 Guishui building 1903, No. 469, Section 1, Wanjiali Middle Road, Yuhua District, Changsha City, Hunan Province

Patentee after: Sanjou International New Energy Technology Co., Ltd

Address before: 530299 the Guangxi Zhuang Autonomous Region Nanning Qingxiu District No. 16 Xianhu Avenue West Peak delicacy square A Holy City Hotel 12 floor

Patentee before: GUANGXI SANJIU NEW ENERGY TECHNOLOGY Co.,Ltd.

TR01 Transfer of patent right