CN105688840A - Stereoscopically-acting water clarifying agent - Google Patents

Stereoscopically-acting water clarifying agent Download PDF

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Publication number
CN105688840A
CN105688840A CN201610241954.0A CN201610241954A CN105688840A CN 105688840 A CN105688840 A CN 105688840A CN 201610241954 A CN201610241954 A CN 201610241954A CN 105688840 A CN105688840 A CN 105688840A
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CN
China
Prior art keywords
water
parts
fermentation
powder
minute
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Pending
Application number
CN201610241954.0A
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Chinese (zh)
Inventor
柯文斌
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Feidong Kewenbin Family Farm
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Feidong Kewenbin Family Farm
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Priority to CN201610241954.0A priority Critical patent/CN105688840A/en
Publication of CN105688840A publication Critical patent/CN105688840A/en
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28009—Magnetic properties
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46—Materials comprising a mixture of inorganic and organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
    • B01J2220/4825—Polysaccharides or cellulose materials, e.g. starch, chitin, sawdust, wood, straw, cotton
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds

Abstract

The invention discloses a stereoscopically-acting water clarifying agent. The stereoscopically-acting water clarifying agent is prepared from, by weight, 16-18 parts of rice chaff ash, 12-13 parts of sauce residue, 5-6 parts of tamarind polysaccharide gum, 4-5 parts of xylose powder, 3-4 parts of calcium bentonite, 1.1-1.2 parts of magnesium stearate, 65-68 parts of sunflower head, 2.3-2.5 parts of ferroferric oxide powder, 26-30 parts of 0.1 mol/L ferrous oxalate solution, an appropriate amount of acetic acid solution and an appropriate amount of water. The stereoscopically-acting water clarifying agent has the advantages that small bubbles in granules can be reduced by means of steam granulation, and uniformity of granule density is guaranteed while the density approximate to water is reached, so that the granules can suspend among water layers after entering the water and play a role in adsorption and clarification in the water layers, the problem of clarification effect lowering due to the fact that the granules are too large or too small in density is avoided, and stereoscopic clarification of the water is achieved finally.

Description

A kind of three-dimensional effect water body clarifier
Technical field
The present invention relates to water improvement technical field, particularly relate to a kind of three-dimensional effect water body clarifier。
Background technology
Raising along with people's quality of life, daily life uses substantial amounts of chemical article, a large amount of garbages of its generation are then drained in water body, meanwhile, in the breeding water bodies such as pond, reservoir, lake, because bait, a large amount of of fisheries drug put into and the excremental accumulation of Fish, water pollution, water turbidity, degree of viewing and admiring decline are resulted in。Because the pollutant of its generation are much larger than its purification ability of water body, partial contamination thing is gradually deposited at bed mud top layer, form anaerobic layer, and the long-term existence of anaerobic layer, cause that Sediments produces the poisonous and harmful substances such as hydrogen sulfide on the one hand, also can provide advantage for the flourish of pathogen on the other hand, eventually affect the health of aquatic animals and plants。
Although and existing water quality clarifier can improve water quality for the moment, but easily occurring repeatedly。Specifically the Chinese patent if application number is 201010615788.9 discloses a kind of water quality cleansing agent, and its component is: tourmaline 5-20 weight portion, montmorillonite 2 0-60 weight portion, zeolite 100-500 weight portion, molasses 5-30 weight portion, phosphate 0.5-5 weight portion, tryptophan 0.1-1 weight portion, microorganism formulation 10-50 weight portion。Wherein containing substantial amounts of inorganic mineral powder, these inorganic mineral powder are difficult to be decomposed and absorb in water body, can accumulate after repeatedly using in sediment of pond, consequently, it is possible to produce secondary pollution。
Pyrolytic carbon is due to flourishing internal pore structure and bigger specific surface area, organic contamination in water, heavy metal, suspended contaminant etc. had very strong adsorption cleaning ability, and ferrum is the component of multiple enzyme in microbial body, it it is a kind of requisite electron carrier in microbiological oxidation reduction reaction electron transport system, use Organic Iron is filled, the removal effect of chemical oxygen consumption (COC) in water body, total nitrogen and total phosphorus etc. can be significantly improved, the effect of enhanced water treatment, therefore Organic Iron and pyrolytic carbon are combined, have broad application prospects in water improvement clarification。
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of three-dimensional effect water body clarifier。
The present invention is achieved by the following technical solutions:
A kind of three-dimensional effect water body clarifier, is made up of the raw material of following weight portion: rice chaff ash 16-18, soy sauce residue 12-13, tamarind seed polysaccharide glue 5-6, xylose powder 4-5, calcium-base bentonite 3-4, magnesium stearate 1.1-1.2, Receptaculum Helianthi 65-68, ferroferric oxide powder 2.3-2.5,0.1mol/L Ferrox. solution 26-30, acetum is appropriate, water is appropriate。
Specifically comprising the following steps that of described solid effect water body clarifier preparation method
(1) Receptaculum Helianthi is placed in high temperature furnace, airtight heating 40-60 minute at 420-450 DEG C, it is placed in the acetum that volume fraction is 2.5-3.0% after taking-up, 20-24 hour is kept to carry out sufficient acid oxidase after being totally submerged, it is washed with water to neutrality afterwards, dry at 50-55 DEG C, add it in the Ferrox. solution of 0.1mol/L again, add tamarind seed polysaccharide glue, heating, to 40-45 DEG C, is stirred continuously lower reaction 100-120 minute, is washed with water to neutrality afterwards, dry at 70-80 DEG C, obtain the modified powdered carbon of Organic Iron standby；
(2) rice chaff ash, soy sauce residue mixing are put in fermentation vat, keep the skin wet to the 60-65% of fermentation heap maximum water holding capacity, take fermentation materials squeeze and filter after fermentation 3-4 week and obtain ferment slag and fermentation liquid is standby；
(3) modified for step 1 gained powdered carbon is joined in step 2 gained fermentation liquid, add xylose powder and ferroferric oxide powder, regulate PH to 5.5-6.0, ultrasonic mixing 60-65 minute under 530-550W power, after filtration with water rinse to neutral, dry magnetization modification powder is standby；
(4) it is placed under 125-140W high voltage mercury lamp by step 3 gained powder irradiation 15-20 minute; mix with step 2 gained fermentation residue, calcium-base bentonite, magnesium stearate and other leftover materials again; spray compound with steam and within 3-5 minute, be placed on adhesive aggregation pelletize in rotary drum granulator, obtain water body clarifier of the present invention。
The invention have the advantage that
By pyrolytic carbon as clarifier carrier, utilize modified surface roughness and the hydrophilic to increase product of Organic Iron, ultrasonication is coordinated to add the magnetic materials such as ferroso-ferric oxide, enhance the clarifier adsorptivity to Heavy Metals in Waters ion, organic pollution and suspending sundries greatly, and the irradiation of mercury lamp makes clarifier surface oxidation polarization group, further enhancing the biocompatibility of clarifier, make this clarifier can stable, long-term playing a role in water body, make it have extremely strong water body clarification, it is ensured that water quality limpid。The water body clarifier of the present invention adopts the mode of steam granulation can reduce the minute bubbles in granule simultaneously, reach with water similar density while ensure grain density well-balanced property, thus realizing the purpose that can keep suspending after granule enters water between each water layer, and the effect of adsorption clarification is played at each water layer, avoid settling the floating reduction causing clarifying effect because grain density is much or too small, finally realize the three-dimensional clarification of water body。
Detailed description of the invention
A kind of three-dimensional effect water body clarifier, is made up of the raw material of following weight portion (kg): rice chaff ash 16, soy sauce residue 12, tamarind seed polysaccharide glue 5, xylose powder 4, calcium-base bentonite 3, magnesium stearate 1.1, Receptaculum Helianthi 65, ferroferric oxide powder 2.3,0.1mol/L Ferrox. solution 26, acetum is appropriate, water is appropriate。
Specifically comprising the following steps that of described solid effect water body clarifier preparation method
(1) Receptaculum Helianthi is placed in high temperature furnace, airtight heating 40 minutes at 420 DEG C, it is placed in the acetum that volume fraction is 2.5% after taking-up, 20 hours are kept to carry out sufficient acid oxidase after being totally submerged, it is washed with water to neutrality afterwards, dry at 50 DEG C, add it in the Ferrox. solution of 0.1mol/L again, add tamarind seed polysaccharide glue, heating, to 40 DEG C, is stirred continuously lower reaction 100 minutes, is washed with water to neutrality afterwards, dry at 70 DEG C, obtain the modified powdered carbon of Organic Iron standby；
(2) rice chaff ash, soy sauce residue mixing are put in fermentation vat, keep the skin wet to the 60% of fermentation heap maximum water holding capacity, take fermentation materials squeeze and filter after fermenting 3 weeks and obtain ferment slag and fermentation liquid is standby；
(3) modified for step 1 gained powdered carbon is joined in step 2 gained fermentation liquid, add xylose powder and ferroferric oxide powder, regulate PH to 5.5, ultrasonic mixing 60 minutes under 530W power, after filtration with water rinse to neutral, dry magnetization modification powder is standby；
(4) it is placed under 125W high voltage mercury lamp by step 3 gained powder irradiation 15 minutes; mix with step 2 gained fermentation residue, calcium-base bentonite, magnesium stearate and other leftover materials again; spray compound with steam and within 3 minutes, be placed in rotary drum granulator adhesive aggregation pelletize, obtain water body clarifier of the present invention。
In order to further illustrate the using value of the present invention, inventor chooses two pieces of condition cultivation fish ponds that are identical and that do not clean in two years and tries object as confession, one of use clarifier of the present invention is as experimental group, another block uses commercially available common aquifer amendment as a control group, after using 2 months, experimental group fish pond relatively matched group visibility significantly improves, in water body, particle reduces, fish pond bed mud detection is taken after 6 months, wherein organic contamination and heavy-metal residual respectively relatively matched group reduce 47% and 72%, in the experimental group pool, fish and shrimp vigor is higher, visible water body clarifier of the present invention has good practical effect。

Claims (2)

1. a three-dimensional effect water body clarifier, it is characterized in that, be made up of the raw material of following weight portion: rice chaff ash 16-18, soy sauce residue 12-13, tamarind seed polysaccharide glue 5-6, xylose powder 4-5, calcium-base bentonite 3-4, magnesium stearate 1.1-1.2, Receptaculum Helianthi 65-68, ferroferric oxide powder 2.3-2.5,0.1mol/L Ferrox. solution 26-30, acetum is appropriate, water is appropriate。
2. the solid effect water body clarifier according to claims 1, it is characterised in that specifically comprising the following steps that of preparation method
(1) Receptaculum Helianthi is placed in high temperature furnace, airtight heating 40-60 minute at 420-450 DEG C, it is placed in the acetum that volume fraction is 2.5-3.0% after taking-up, 20-24 hour is kept to carry out sufficient acid oxidase after being totally submerged, it is washed with water to neutrality afterwards, dry at 50-55 DEG C, add it in the Ferrox. solution of 0.1mol/L again, add tamarind seed polysaccharide glue, heating, to 40-45 DEG C, is stirred continuously lower reaction 100-120 minute, is washed with water to neutrality afterwards, dry at 70-80 DEG C, obtain the modified powdered carbon of Organic Iron standby；
(2) rice chaff ash, soy sauce residue mixing are put in fermentation vat, keep the skin wet to the 60-65% of fermentation heap maximum water holding capacity, take fermentation materials squeeze and filter after fermentation 3-4 week and obtain ferment slag and fermentation liquid is standby；
(3) modified for step 1 gained powdered carbon is joined in step 2 gained fermentation liquid, add xylose powder and ferroferric oxide powder, regulate PH to 5.5-6.0, ultrasonic mixing 60-65 minute under 530-550W power, after filtration with water rinse to neutral, dry magnetization modification powder is standby；
(4) it is placed under 125-140W high voltage mercury lamp by step 3 gained powder irradiation 15-20 minute; mix with step 2 gained fermentation residue, calcium-base bentonite, magnesium stearate and other leftover materials again; spray compound with steam and within 3-5 minute, be placed on adhesive aggregation pelletize in rotary drum granulator, obtain water body clarifier of the present invention。
CN201610241954.0A 2016-04-19 2016-04-19 Stereoscopically-acting water clarifying agent Pending CN105688840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610241954.0A CN105688840A (en) 2016-04-19 2016-04-19 Stereoscopically-acting water clarifying agent

Publications (1)

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CN105688840A true CN105688840A (en) 2016-06-22

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009127887A2 (en) * 2008-04-15 2009-10-22 G.I.C. Ipari Szolgáltató Es Kereskedelmi Kft. Method and apparatus for sorbent production, primarily for removing arsenic from drinking water
CN102153208A (en) * 2010-12-31 2011-08-17 浙江大学 Aquaculture water purifying agent
CN104258823A (en) * 2014-10-27 2015-01-07 济南大学 Modified magnetic biochar adsorbing material and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009127887A2 (en) * 2008-04-15 2009-10-22 G.I.C. Ipari Szolgáltató Es Kereskedelmi Kft. Method and apparatus for sorbent production, primarily for removing arsenic from drinking water
CN102153208A (en) * 2010-12-31 2011-08-17 浙江大学 Aquaculture water purifying agent
CN104258823A (en) * 2014-10-27 2015-01-07 济南大学 Modified magnetic biochar adsorbing material and application thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《林业概论》编写组编: "《林业概论下册(森工部分)》", 30 September 1994, 中国林业出版社 *
姜祁: "碳纤维表面性能与好氧生物膜关联性研究", 《中国优秀硕士学位论文全文数据库(工程科技I辑)》 *
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Application publication date: 20160622