CN105674751A - Treatment system for industrial waste gases - Google Patents

Treatment system for industrial waste gases Download PDF

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Publication number
CN105674751A
CN105674751A CN201610154868.6A CN201610154868A CN105674751A CN 105674751 A CN105674751 A CN 105674751A CN 201610154868 A CN201610154868 A CN 201610154868A CN 105674751 A CN105674751 A CN 105674751A
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CN
China
Prior art keywords
tower
water
cooling
flushing cinder
flushing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610154868.6A
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Chinese (zh)
Other versions
CN105674751B (en
Inventor
赵海浩
管振泳
缪胜东
张成权
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Jiangsu Kenle Environmental Protection Technology Co Ltd
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Jiangsu Kenle Environmental Protection Technology Co Ltd
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Priority to CN201610154868.6A priority Critical patent/CN105674751B/en
Publication of CN105674751A publication Critical patent/CN105674751A/en
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Publication of CN105674751B publication Critical patent/CN105674751B/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/15Tapping equipment; Equipment for removing or retaining slag
    • F27D3/1545Equipment for removing or retaining slag
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/60Combinations of devices covered by groups B01D46/00 and B01D47/00
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/02Preparation of phosphorus
    • C01B25/027Preparation of phosphorus of yellow phosphorus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a treatment system for industrial waste gases. A slag flushing tower is established between an electric furnace and a settling tank; phosphorus slags are directly discharged into the tower; a tower inlet is sprayed and cooled by a large amount of flushing water; water flushing slags and generated water vapor enter into the slag flushing tower; a tower outlet is immersed into water; and water and the slags in the tower are discharged into the settling tank. The water vapor in the tower cannot enter into the settling tank due to liquid seal; the water vapor is sprayed by using cooling water at the upper part of the slag flushing tower; the temperature of flue gases is primarily cooled; then the cooled flue gases enter into a spraying tower from the top of the spraying tower for secondarily cooling; a downstream spray pattern is adopted in the spraying tower; and the secondarily-cooled flue gases pass through a wire mesh demister from the bottom of the spraying tower to remove the water vapor, subsequently enter into a fan for boosting, further enter into a packed tower for cooling for the third time, and finally are directly discharged into the atmosphere from a chimney at the top of the packed tower.

Description

Industry Waste gas processing system
Technical field
The present invention relates to a kind of Industry Waste gas processing system, particularly relate to the exhaust treatment system in a kind of phosphorus production process. Belong to chemical technology field.
Background technology
Current yellow phosphorus furnace slag processing method adopts slag bath water quenching. Ensureing certain water level by slag bath, molten slag flows directly into slag bath by slag runner and carries out shrend, and the good later phosphorus slag of shrend grabs slag storehouse with driving again. This method produces a large amount of steam when water quenching phosphorus slag, and steam contains a large amount of noxious substance such as fluorine-containing, directly causing severe contamination in discharge air, additionally driving causes site environment severe when capturing phosphorus slag, sewage and the unordered discharge of steam, it is impossible to effectively manage. Such as, river phosphorus has 8 set Yellow phosphorus furnaces, and once, each 20 minutes, each 55t, phosphorus slag temperature was about 1350 DEG C to every 3.5 hours deslagginves of every electric furnace. After flush slag, steam is very big, and substantial amounts of steam wafts and brims with aloft, and working environment is quite severe, and national requirements for environmental protection is more and more higher, is badly in need of changing present situation.
Summary of the invention
The technical problem to be solved is to provide a kind of Industry Waste gas processing system for above-mentioned prior art, yellow phosphoric tail gas can be realized solid-liquid separation, eliminate the steam of 100%, meet relevant emission standards, and eliminate the harmful substance in steam, safety and environmental protection.
This invention address that the technical scheme that the problems referred to above adopt is: a kind of Industry Waste gas processing system, it includes flushing cinder tower, spray column, packed tower, sedimentation tank, water cooling pond and hot-tub, the bottom of described flushing cinder tower is connected with electric furnace, the outlet of flushing cinder tower is immersed in the water of sedimentation tank, cold water in described water cooling pond is connected to the entry position of flushing cinder tower through flushing pump, the outlet of described sedimentation tank is connected with hot-tub, hot water is driven into cooling tower cooling by cooling down pump by hot-tub, the outlet of cooling tower is connected with water cooling pond, one group of one-level chilling spray head it is provided with on the top of described flushing cinder tower, described water cooling pond is connected with the chilling spray head in flushing cinder tower by spray pump, the described top of flushing cinder tower connects with the top of spray column, on the top setting of described spray column also has two groups, two grades of chilling spray heads of lower layout, described two grades of chilling spray heads are connected with water cooling pond by the first cooling pump, outlet at bottom at described spray column is connected with packed tower by centrifugal blower, three grades of chilling spray heads it are provided with on the top of described packed tower, described three grades of chilling spray heads are connected with water cooling pond by the second cooling pump.
Preferably, separating and have run-off in described sedimentation tank, described hot-tub is connected with run-off.
Preferably, the one-level chilling spray head in described flushing cinder tower is provided above demister.
Preferably, the outlet at bottom position of described spray column is provided with wire mesh demister.
Compared with prior art, it is an advantage of the current invention that:
1, slag is directly entered in flushing cinder tower, and all collects steam by the mode of fluid-tight, and steam collects 100%.
2, the mode cooled flue gas of gradient cooling, effect becomes apparent from, and water outlet stripping temperature is close to atmospheric temperature, without obvious steam.
3, adopting wire mesh demister to collect steam, outlet is without obvious steam.
Accompanying drawing explanation
Fig. 1 is the system construction drawing of a kind of Industry Waste gas processing system of the present invention.
Wherein:
Flushing cinder tower 1, spray column 2, packed tower 3, sedimentation tank 4, water cooling pond 5, hot-tub 6, electric furnace 7, flushing pump 8, cooling pump 9, cooling tower 10, spray pump 11, first cool down pump 12, centrifugal blower 13, second cools down pump 14, one-level chilling spray head 1.1,1.2, two grades of chilling spray heads 2.1 of demister, wire mesh demister 2.2, three grades of chilling spray heads 3.1, run-offs 4.1.
Detailed description of the invention
Below in conjunction with accompanying drawing embodiment, the present invention is described in further detail.
The present invention relates to a kind of Industry Waste gas processing system, mainly include flushing cinder tower 1, spray column 2, packed tower 3, sedimentation tank 4, water cooling pond 5 and hot-tub 6, the bottom of described flushing cinder tower 1 is connected with electric furnace 7, the outlet of flushing cinder tower 1 is immersed in the water of sedimentation tank 4, cold water in described water cooling pond 5 is connected to the entry position of flushing cinder tower 1 through flushing pump 8, the tail gas that electric furnace 7 is produced is rinsed, the outlet of described sedimentation tank 4 is connected with hot-tub 6, hot water is driven into cooling tower 10 by cooling pump 9 and cools down by hot-tub 6, the outlet of cooling tower 10 is connected with water cooling pond 5, hot water in hot-tub is evacuated to cooling tower cooling through supercooling pump, the water cooled down enters water cooling pond, the water of water cooling pond is used as to rinse, spray, cooling. separating in described sedimentation tank 4 and have run-off 4.1, described hot-tub 6 is connected with run-off 4.1.
One group of one-level chilling spray head 1.1 it is provided with on the top of described flushing cinder tower 1, described water cooling pond 5 is connected with the chilling spray head 1.1 in flushing cinder tower 1 by spray pump 11, chilling spray head 1.1 is mainly used to cool down the flue-gas temperature in flushing cinder tower 1, the top of described flushing cinder tower 1 connects with the top of spray column 2, and the flue gas after once cooling enters in spray column 2 after demister 1.2.
The top of described spray column 2 arranges the two grades of chilling spray heads 2.1 also having two groups of upper and lower layouts, described two grades of chilling spray heads 2.1 are connected with water cooling pond 5 by the first cooling pump 12, spray column adopts along spray mode, the outlet at bottom position of described spray column 2 is provided with wire mesh demister 2.2, and the outlet of spray column 2 is connected with packed tower 3 by centrifugal blower 13, be provided with three grades of chilling spray heads 3.1 on the top of described packed tower 3, described three grades of chilling spray heads 3.1 are connected with water cooling pond 5 by the second cooling pump 14.
Concrete technology flow process is as follows:
Building a flushing cinder tower between electric furnace and sedimentation tank, phosphorus slag is directly discharged in tower, and tower entrance is with a large amount of flushing water spraying coolings, and the steam of flush slag and generation enters flushing cinder tower, and in tower outlet immersion water, the water in tower is discharged in sedimentation tank with slag. Steam in tower is because of the reason of fluid-tight, it is impossible to enter in sedimentation tank, in flushing cinder tower top cool water shower, a cooled flue gas temperature, enters spray column cooling twice after flue gas cooling from spray column top, and what adopt in spray column is the mode of suitable spray.Flue gas after cooling twice bottom spray column through wire mesh demister vapor-removing, subsequently enter blower fan supercharging and enter packed tower three times cooling, finally from the chimney discharging directly into atmosphere of packed tower top.
Sedimentation tank is entered after flushing water and cool water shower, water in sedimentation tank overflows to run-off (being separated by sedimentation tank), water in run-off flows automatically in hot-tub by trench, and the hot water in hot-tub is evacuated to cooling tower cooling through supercooling pump, and the water cooled down enters water cooling pond. The water of water cooling pond is used as flushing, spray, cooling.
The flushing cinder top of tower flue gas of 5#, 6# causes spray column, and two electric furnace deslagging times, separately interval was not less than 0.5h.
Expected Results: near former flushing cinder pond, steam is less, and pool inner water temperature is 50-60 DEG C, and chimney breast steam is not as obvious, closely just can see steam when summer, relative humidity was not high.
In addition to the implementation, present invention additionally comprises the technical scheme that other embodiments, all employing equivalents or equivalence substitute mode are formed, all should fall within the protection domain of the claims in the present invention.

Claims (4)

1. an Industry Waste gas processing system, it is characterized in that: it includes flushing cinder tower (1), spray column (2), packed tower (3), sedimentation tank (4), water cooling pond (5) and hot-tub (6), the bottom of described flushing cinder tower (1) is connected with electric furnace (7), the outlet of flushing cinder tower (1) is immersed in the water of sedimentation tank (4), cold water in described water cooling pond (5) is connected to the entry position of flushing cinder tower (1) through flushing pump (8), the outlet of described sedimentation tank (4) is connected with hot-tub (6), hot water is driven into cooling tower (10) cooling by cooling down pump (9) by hot-tub (6), the outlet of cooling tower (10) is connected with water cooling pond (5), the top of described flushing cinder tower (1) is provided with one group of one-level chilling spray head (1.1), described water cooling pond (5) is connected with the chilling spray head (1.1) in flushing cinder tower (1) by spray pump (11), the top of described flushing cinder tower (1) connects with the top of spray column (2), on the top setting of described spray column (2) also has two groups, two grades of chilling spray heads (2.1) of lower layout, described two grades of chilling spray heads (2.1) cool down pump (12) by first and are connected with water cooling pond (5), outlet at bottom at described spray column (2) is connected with packed tower (3) by centrifugal blower (13), three grades of chilling spray heads (3.1) it are provided with on the top of described packed tower (3), described three grades of chilling spray heads (3.1) cool down pump (14) by second and are connected with water cooling pond (5).
2. a kind of Industry Waste gas processing system according to claim 1, it is characterised in that: separating in described sedimentation tank (4) and have run-off (4.1), described hot-tub (6) is connected with run-off (4.1).
3. a kind of Industry Waste gas processing system according to claim 1, it is characterised in that: one-level chilling spray head (1.1) in described flushing cinder tower (1) is provided above demister (1.2).
4. a kind of Industry Waste gas processing system according to claim 1, it is characterised in that: the outlet at bottom position of described spray column (2) is provided with wire mesh demister (2.2).
CN201610154868.6A 2016-03-18 2016-03-18 Industrial waste gas processing system Active CN105674751B (en)

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Application Number Priority Date Filing Date Title
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CN105674751B CN105674751B (en) 2018-06-26

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112524962A (en) * 2020-08-20 2021-03-19 云南江磷集团股份有限公司 Yellow phosphorus electric furnace tail gas recovery and purification process
CN113521929A (en) * 2021-08-20 2021-10-22 骏化生态工程有限公司 Method for washing particles in tail gas of compound fertilizer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2628877Y (en) * 2003-08-08 2004-07-28 商涛 Fluid-bed boiler slagging and refrigerating apparatus
CN102534073A (en) * 2010-12-14 2012-07-04 保尔伍斯股份有限公司 Steam condensation tower for a granulation installation
CN203281180U (en) * 2013-04-28 2013-11-13 苏州天皓环保科技有限公司 Activated charcoal, microwave and water-spraying combined purification tower
CN204752617U (en) * 2015-06-08 2015-11-11 邢台旭阳煤化工有限公司 Wet quenching system
CN205537144U (en) * 2016-03-18 2016-08-31 江苏垦乐环保科技有限公司 Industrial waste gas treatment system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2628877Y (en) * 2003-08-08 2004-07-28 商涛 Fluid-bed boiler slagging and refrigerating apparatus
CN102534073A (en) * 2010-12-14 2012-07-04 保尔伍斯股份有限公司 Steam condensation tower for a granulation installation
CN203281180U (en) * 2013-04-28 2013-11-13 苏州天皓环保科技有限公司 Activated charcoal, microwave and water-spraying combined purification tower
CN204752617U (en) * 2015-06-08 2015-11-11 邢台旭阳煤化工有限公司 Wet quenching system
CN205537144U (en) * 2016-03-18 2016-08-31 江苏垦乐环保科技有限公司 Industrial waste gas treatment system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112524962A (en) * 2020-08-20 2021-03-19 云南江磷集团股份有限公司 Yellow phosphorus electric furnace tail gas recovery and purification process
CN113521929A (en) * 2021-08-20 2021-10-22 骏化生态工程有限公司 Method for washing particles in tail gas of compound fertilizer

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Address after: 214434 Jiangsu city of Wuxi province Jiangyin City Road 201, Powerise Industrial Park wisdom Fang B Room 405

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