CN105674751B - Industrial waste gas processing system - Google Patents

Industrial waste gas processing system Download PDF

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Publication number
CN105674751B
CN105674751B CN201610154868.6A CN201610154868A CN105674751B CN 105674751 B CN105674751 B CN 105674751B CN 201610154868 A CN201610154868 A CN 201610154868A CN 105674751 B CN105674751 B CN 105674751B
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China
Prior art keywords
tower
water
flushing cinder
cooling
spray
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Application number
CN201610154868.6A
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Chinese (zh)
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CN105674751A (en
Inventor
赵海浩
管振泳
缪胜东
张成权
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Ken Le Energy-Saving Environmental Protection Science And Technology Ltd Co
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Jiangsu Ken Le Energy-Saving Environmental Protection Science And Technology Ltd Co
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Priority to CN201610154868.6A priority Critical patent/CN105674751B/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/15Tapping equipment; Equipment for removing or retaining slag
    • F27D3/1545Equipment for removing or retaining slag
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/60Combinations of devices covered by groups B01D46/00 and B01D47/00
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/02Preparation of phosphorus
    • C01B25/027Preparation of phosphorus of yellow phosphorus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of industrial waste gas processing systems, and a flushing cinder tower is built between electric furnace and sedimentation basin, and phosphorus slag is directly discharged into tower, the a large amount of flushing water spraying coolings of tower entrance, flush slag and the steam of generation enter flushing cinder tower, and tower is exported in immersion water, and the water in tower is discharged to slag in sedimentation basin.Steam in tower is because the reason of fluid-tight, it is impossible to which into sedimentation basin, in flushing cinder tower top cool water shower, a cooled flue gas temperature enters spray column secondary cooling at the top of spray column after flue gas cooling, using the mode along spray in spray column.Flue gas removes steam after secondary cooling from spray tower bottom by wire mesh demister, subsequently enters wind turbine supercharging and is cooled down three times into packed tower, finally from chimney discharging directly into atmosphere at the top of packed tower.

Description

Industrial waste gas processing system
Technical field
The present invention relates to the vent gas treatment systems during a kind of industrial waste gas processing system more particularly to a kind of phosphorus production System.Belong to chemical technology field.
Background technology
Yellow phosphorus furnace slag processing method uses slag bath water quenching at present.Slag bath is ensured to certain water level, molten slag leads to It crosses slag runner and flows directly into slag bath progress water quenching, the good later phosphorus slag of water quenching grabs slag storehouse with driving again.This method is in water quenching phosphorus A large amount of vapor are generated during slag, and vapor contains the largely noxious materials such as fluorine-containing, and serious dirt is caused in direct emission air In addition dye causes site environment severe, sewage and the unordered discharge of steam, it is impossible to effectively management during driving crawl phosphorus slag.For example, river Phosphorus shares 8 sets of Yellow phosphorus furnaces, and the every 3.5 hours deslagginves of every electric furnace are primary, and 20 minutes every time, each 55t, phosphorus slag temperature was about 1350 ℃.Steam is very big after flush slag, and a large amount of steam wafts and brims in the air, and working environment is quite severe, and national requirements for environmental protection is got over Carry out higher, the present situation of urgent need change.
Invention content
The technical problems to be solved by the invention are to provide a kind of industrial waste gas processing system, energy for the above-mentioned prior art It is enough that separation of solid and liquid is realized to yellow phosphoric tail gas, 100% steam is eliminated, meets relevant emission standards, and eliminate having in steam Evil substance, safety and environmental protection.
Technical solution is used by the present invention solves the above problems:A kind of industrial waste gas processing system, it includes flushing cinder Tower, spray column, packed tower, sedimentation basin, water cooling pond and hot-tub, the bottom of the flushing cinder tower are connected with electric furnace, flushing cinder tower Outlet is immersed in the water of sedimentation basin, and the cold water in the water cooling pond is connected to the entry position of flushing cinder tower, institute by flushing pump The outlet for stating sedimentation basin is connected with hot-tub, and hot water is driven into cooling tower cooler by hot-tub by cooling pump, cooling tower Outlet is connected with water cooling pond, one group of level-one chilling spray head is provided on the top of the flushing cinder tower, the water cooling pond passes through Spray pump is connected with the chilling spray head in flushing cinder tower, and the top of the flushing cinder tower is connected with the top of spray column, the spray The top setting of tower also has two groups of two level chilling spray heads arranged above and below, and the two level chilling spray head passes through the first cooling Pump is connected with water cooling pond, is connected in the outlet at bottom of the spray column by centrifugal blower with packed tower, in the packed tower Top is provided with three-level chilling spray head, and the three-level chilling spray head is connected by the second cooling pump with water cooling pond.
Preferably, separating in the sedimentation basin has run-off, and the hot-tub is connected with run-off.
Preferably, it is provided with demister above the level-one chilling spray head in the flushing cinder tower.
Preferably, the outlet at bottom position of the spray column is provided with wire mesh demister.
Compared with prior art, the advantage of the invention is that:
1st, slag is directly entered in flushing cinder tower, and all collects steam with the mode of fluid-tight, and steam collects 100%.
2nd, the mode cooled flue gas of classification cooling, effect become apparent from, and outlet steam temperature is close to atmospheric temperature, without apparent water Vapour.
3rd, steam is collected using wire mesh demister, exported without apparent steam.
Description of the drawings
Fig. 1 is a kind of system construction drawing of industrial waste gas processing system of the present invention.
Wherein:
Flushing cinder tower 1, spray column 2, packed tower 3, sedimentation basin 4, water cooling pond 5, hot-tub 6, electric furnace 7, flushing pump 8, cooling pump 9th, cooling tower 10, spray pump 11, the first cooling pump 12, centrifugal blower 13, the second cooling pump 14, level-one chilling spray head 1.1, remove Foam device 1.2, two level chilling spray head 2.1, wire mesh demister 2.2, three-level chilling spray head 3.1, run-off 4.1.
Specific embodiment
The present invention is described in further detail below in conjunction with attached drawing embodiment.
The present invention relates to a kind of industrial waste gas processing systems, mainly include flushing cinder tower 1, spray column 2, packed tower 3, sedimentation basin 4th, water cooling pond 5 and hot-tub 6, the bottom of the flushing cinder tower 1 are connected with electric furnace 7, and the outlet of flushing cinder tower 1 is immersed in sedimentation basin 4 Water in, cold water in the water cooling pond 5 is connected to the entry position of flushing cinder tower 1 by flushing pump 8, the tail generated to electric furnace 7 Gas is rinsed, and the outlet of the sedimentation basin 4 is connected with hot-tub 6, and hot water is driven into cold by hot-tub 6 by cooling pump 9 But tower 10 cools down, and the outlet of cooling tower 10 is connected with water cooling pond 5, and it is cold that the hot water in hot-tub by cooling pump is evacuated to cooling tower But, the water to cool down enters water cooling pond, and the water of water cooling pond is used as rinsing, spray, cool down.Separating in the sedimentation basin 4 has Run-off 4.1, the hot-tub 6 are connected with run-off 4.1.
One group of level-one chilling spray head 1.1 is provided on the top of the flushing cinder tower 1, the water cooling pond 5 passes through spray pump 11 are connected with the chilling spray head 1.1 in flushing cinder tower 1, and chilling spray head 1.1 is mainly used to cool down the flue gas temperature in flushing cinder tower 1 Degree, the top of the flushing cinder tower 1 are connected with the top of spray column 2, laggard by demister 1.2 by primary flue gas after cooling Enter into spray column 2.
The top setting of the spray column 2 also has two groups of two level chilling spray heads 2.1 arranged above and below, and the two level is cold But spray head 2.1 is connected by the first cooling pump 12 with water cooling pond 5, is used in spray column along spray mode, in the spray column 2 Outlet at bottom position is provided with wire mesh demister 2.2, and the outlet of spray column 2 is connected by centrifugal blower 13 with packed tower 3, The top of the packed tower 3 is provided with three-level chilling spray head 3.1, and the three-level chilling spray head 3.1 passes through the second cooling pump 14 are connected with water cooling pond 5.
Concrete technology flow process is as follows:
A flushing cinder tower is built between electric furnace and sedimentation basin, phosphorus slag is directly discharged into tower, and tower entrance is sprayed with a large amount of flushing waters The steam of leaching cooling, flush slag and generation enters flushing cinder tower, and tower is exported in immersion water, and the water in tower is discharged to slag in sedimentation basin. Steam in tower is because the reason of fluid-tight, it is impossible into sedimentation basin, in flushing cinder tower top cool water shower, once cool down cigarette Temperature degree, enters spray column secondary cooling at the top of the spray column after flue gas cooling, using the mode along spray in spray column.Cigarette Gas removes steam after secondary cooling from spray tower bottom by wire mesh demister, subsequently enters wind turbine supercharging and enters packed tower three Secondary cooling, finally from chimney discharging directly into atmosphere at the top of packed tower.
Enter sedimentation basin after flushing water and cool water shower, the water in sedimentation basin overflows to run-off(Separated by sedimentation basin It opens), the water in run-off flowed automatically to by trench in hot-tub, and it is cold that the hot water in hot-tub by cooling pump is evacuated to cooling tower But, the water to cool down enters water cooling pond.The water of water cooling pond is used as rinsing, spray, cool down.
The flushing cinder top of tower flue gas of 5#, 6# lead to spray column, and two electric furnace deslagging times separate, and interval is not less than 0.5h.
Desired effect:Nearby steam is smaller in former flushing cinder pond, and pool inner water temperature is 50-60 DEG C, and chimney breast steam is not very bright It is aobvious, it closely can just see steam in the case where summer relative humidity is not high.
In addition to the implementation, it is all to use equivalent transformation or equivalent replacement the invention also includes there is an other embodiment The technical solution that mode is formed should all be fallen within the scope of the hereto appended claims.

Claims (4)

1. a kind of industrial waste gas processing system, it is characterised in that:It includes flushing cinder tower(1), spray column(2), packed tower(3), it is heavy Shallow lake pond(4), water cooling pond(5)And hot-tub(6), the flushing cinder tower(1)Bottom and electric furnace(7)It is connected, flushing cinder tower(1)Go out Mouth is immersed in sedimentation basin(4)Water in, the water cooling pond(5)In cold water pass through flushing pump(8)It is connected to flushing cinder tower(1)Enter Mouth position, the sedimentation basin(4)Outlet and hot-tub(6)It is connected, hot-tub(6)Pass through cooling pump(9)Hot water is squeezed into To cooling tower(10)Cooling, cooling tower(10)Outlet and water cooling pond(5)It is connected, in the flushing cinder tower(1)Top setting There is one group of level-one chilling spray head(1.1), the water cooling pond(5)Pass through spray pump(11)With flushing cinder tower(1)Interior chilling spray Head(1.1)It is connected, the flushing cinder tower(1)Top and spray column(2)Top connection, the spray column(2)Top setting The also two groups two level chilling spray heads arranged above and below(2.1), the two level chilling spray head(2.1)Pass through the first cooling pump (12)With water cooling pond(5)It is connected, in the spray column(2)Outlet at bottom pass through centrifugal blower(13)With packed tower(3)It is connected, In the packed tower(3)Top be provided with three-level chilling spray head(3.1), the three-level chilling spray head(3.1)Pass through Two cooling pumps(14)With water cooling pond(5)It is connected.
2. a kind of industrial waste gas processing system according to claim 1, it is characterised in that:In the sedimentation basin(4)In point It is separated with run-off(4.1), the hot-tub(6)With run-off(4.1)It is connected.
3. a kind of industrial waste gas processing system according to claim 1, it is characterised in that:In the flushing cinder tower(1)Interior Level-one chilling spray head(1.1)Top is provided with demister(1.2).
4. a kind of industrial waste gas processing system according to claim 1, it is characterised in that:In the spray column(2)Bottom Portion outlet port is provided with wire mesh demister(2.2).
CN201610154868.6A 2016-03-18 2016-03-18 Industrial waste gas processing system Active CN105674751B (en)

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CN105674751B true CN105674751B (en) 2018-06-26

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Publication number Priority date Publication date Assignee Title
CN112524962B (en) * 2020-08-20 2022-08-02 云南江磷集团股份有限公司 Yellow phosphorus electric furnace tail gas recovery and purification process
CN113521929A (en) * 2021-08-20 2021-10-22 骏化生态工程有限公司 Method for washing particles in tail gas of compound fertilizer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205537144U (en) * 2016-03-18 2016-08-31 江苏垦乐环保科技有限公司 Industrial waste gas treatment system

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CN2628877Y (en) * 2003-08-08 2004-07-28 商涛 Fluid-bed boiler slagging and refrigerating apparatus
LU91765B1 (en) * 2010-12-14 2012-06-15 Wurth Paul Sa Steam condensation tower for a granulation installation
CN203281180U (en) * 2013-04-28 2013-11-13 苏州天皓环保科技有限公司 Activated charcoal, microwave and water-spraying combined purification tower
CN204752617U (en) * 2015-06-08 2015-11-11 邢台旭阳煤化工有限公司 Wet quenching system

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205537144U (en) * 2016-03-18 2016-08-31 江苏垦乐环保科技有限公司 Industrial waste gas treatment system

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Address after: 214434 Jiangsu city of Wuxi province Jiangyin City Road 201, Powerise Industrial Park wisdom Fang B Room 405

Applicant after: Jiangsu Ken Le energy-saving environmental protection science and technology limited company

Address before: 214434 Jiangsu city of Wuxi province Jiangyin City Road 201, Powerise Industrial Park wisdom Fang B Room 405

Applicant before: JIANGSU KENLE ENVIRONMENTAL PROTECTION TECHNOLOGY CO., LTD.

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