CN105672005A - Environment-friendly acidic fabric color fixing agent and preparation method thereof - Google Patents
Environment-friendly acidic fabric color fixing agent and preparation method thereof Download PDFInfo
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- CN105672005A CN105672005A CN201610198555.0A CN201610198555A CN105672005A CN 105672005 A CN105672005 A CN 105672005A CN 201610198555 A CN201610198555 A CN 201610198555A CN 105672005 A CN105672005 A CN 105672005A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses an environment-friendly acidic fabric color fixing agent. The environment-friendly acidic fabric color fixing agent is prepared from the following components in percentage by weight: 4-10 parts of 4-hydroxyphenoxy propylamine hydrochloride, 2-8 parts of dimethylamine, 3-12 parts of 1,1-cyclohexyl dicapric acid monoamide, 10-15 parts of aliphatic polygylcol ester, 13-19 parts of diglycol monoethyl ether acetate, 6-12 parts of 2,2'-dyhydroxydiethylamine, 9-15 parts of 6-acetyl caproic acid, 1-5 parts of potassium persulfate, 11-17 parts of cis-3-hexenyl isobutyrate, 15-22 parts of propylene glycol monomethyl ether acetate and 80-130 parts of water. The color fixing agent prepared by the invention is environmentally friendly, does not release harmful substances including formaldehyde and the like in a utilization process, and has a good color fixing effect on a fabric.
Description
Technical field
The invention belongs to color fixing agent field, particularly to a kind of environment-friendly type acidity fabric color fixing agent and preparation method thereof.
Background technology
Color fixing agent is the important auxiliary agent of class in textile industry, and it can improve dyestuff color moisture resistant fastness on fabric and light fastness. Along with increasing substantially of people's environmental consciousness in recent years and living standard, textile is proposed comfortable, safe and environment-friendly requirement. Because would be likely to occur the harmful substances such as formaldehyde in current existing color fixing agent, human body is easily caused damage by life-time service process, and production procedure and technique are wayward, thus colour fixation is inconspicuous, just easily fading after washing and simple detergent are cleaned, extreme influence people normally use and live.
Summary of the invention
For the above technical problem existed in prior art, the invention provides a kind of environment-friendly type acidity fabric color fixing agent and preparation method thereof, achieve the environmental protection of color fixing agent preparation technology and color fixing agent itself, pollution-free, use procedure is formaldehydeless waits harmful substance release, and the colour fixation of fabric is good.
Technical scheme: a kind of environment-friendly type acidity fabric color fixing agent; each component including following percentage by weight: 4-hydroxyphenoxy propylamin hydrochloride 4-10 part; dimethylamine 2-8 part; 1; 1-cyclohexyl two capric acid monoamides 3-12 part; aliphatic poly glycol ester 10-15 part; TC acetate 13-19 part; 2,2'-dihydroxy diethylamine 6-12 parts, 6-acetyl group caproic acid 9-15 part; potassium peroxydisulfate 1-5 part; isopropylformic acid. folic alcohol ester 11-17 part, propylene glycol methyl ether acetate 15-22 part, water 80-130 part.
Preferably, described 4-hydroxyphenoxy propylamin hydrochloride 6-8 part, dimethylamine 3-6 part; 1,1-cyclohexyl two capric acid monoamides 5-10 part, aliphatic poly glycol ester 12-14 part; TC acetate 15-18 part; 2,2'-dihydroxy diethylamine 8-10 parts, 6-acetyl group caproic acid 11-13 part; potassium peroxydisulfate 2-5 part; isopropylformic acid. folic alcohol ester 12-15 part, propylene glycol methyl ether acetate 17-20 part, water 100-120 part.
Preferably, described 4-hydroxyphenoxy propylamin hydrochloride 7 parts, dimethylamine 4 parts; 1,1-cyclohexyl two capric acid monoamides 8 parts, aliphatic poly glycol ester 13 parts; TC acetate 16 parts; 2,2'-dihydroxy diethylamine 9 parts, 6-acetyl group caproic acid 13 parts; potassium peroxydisulfate 4 parts; isopropylformic acid. folic alcohol ester 14 parts, propylene glycol methyl ether acetate 18 parts, 115 parts of water.
The preparation method of a kind of environment-friendly type acidity fabric color fixing agent, comprises the steps:
S1: by 1,1-cyclohexyl two capric acid monoamides 3-12 part, TC acetate 13-19 part, potassium peroxydisulfate 1-5 part, propylene glycol methyl ether acetate 15-22 part and water 80-130 part stirring mixing, and sonicated after, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 4-10 part, dimethylamine 2-8 part, aliphatic poly glycol ester 10-15 part and isopropylformic acid. folic alcohol ester 11-17 part are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 30-40 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, temperature 40-50 DEG C of insulation reaction after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 6-12 parts and 6-acetyl group caproic acid 9-15 part in reactor in step S2, raises temperature to 70-80 DEG C, is stirred continuously lower reaction 1-5h; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
Preferably, power ultrasonic described in step S1 is 600-800W, and ultrasonic time is 5-10min.
Preferably, temperature of reactor described in step S2 is 36 DEG C, and the temperature of described insulation reaction is 48 DEG C, insulation reaction 1-2.5h.
Preferably, temperature described in step S3 is 75 DEG C, and the speed of described stirring is 400-500r/min, reacts 3-3.5h.
Beneficial effect:
The preparation method of environment-friendly type acidity fabric color fixing agent of the present invention, by 4-hydroxyphenoxy propylamin hydrochloride, 1,1-cyclohexyl two capric acid monoamides 3-12 part, 6-acetyl group caproic acid 9-15 part, propylene glycol methyl ether acetate 15-22 part and other raw materials are prepared color fixing agent by techniques such as ultrasonic, stirring, dropping mixing, nitrogen protections; Preparation process is easy, pollution-free; Obtained color fixing agent environmental protection, in use unharmful substance release, does not affect health, and colour fixation is good.
Detailed description of the invention
Embodiment 1
S1: by the stirring mixing of 1,1-cyclohexyl two capric acid monoamides 3 parts, TC acetate 13 parts, potassium peroxydisulfate 1 part, propylene glycol methyl ether acetate 15 parts and 80 parts of water, and under power 600W after supersound process 5min, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 4 parts, dimethylamine 2 parts, aliphatic poly glycol ester 10 parts and isopropylformic acid. folic alcohol ester 11 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 30 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 30min, at 40 DEG C of insulation reaction 1h of temperature after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 6 parts and 6-acetyl group caproic acid 9 parts in reactor in step S2, raises temperature to 70 DEG C, is stirred continuously lower reaction 1h at rotating speed 400r/min; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
Embodiment 2
S1: by the stirring mixing of 1,1-cyclohexyl two capric acid monoamides 12 parts, TC acetate 19 parts, potassium peroxydisulfate 5 parts, propylene glycol methyl ether acetate 22 parts and 130 parts of water, and under power 800W after supersound process 10min, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 10 parts, dimethylamine 8 parts, aliphatic poly glycol ester 15 parts and isopropylformic acid. folic alcohol ester 17 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 40 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 60min, at temperature 50 C insulation reaction 2.5h after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 12 parts and 6-acetyl group caproic acid 15 parts in reactor in step S2, raises temperature to 80 DEG C, is stirred continuously lower reaction 5h at rotating speed 500r/min; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
Embodiment 3
S1: by the stirring mixing of 1,1-cyclohexyl two capric acid monoamides 5 parts, TC acetate 15 parts, potassium peroxydisulfate 2 parts, propylene glycol methyl ether acetate 17 parts and 100 parts of water, and under power 600W after supersound process 5min, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 6 parts, dimethylamine 3 parts, aliphatic poly glycol ester 12 parts and isopropylformic acid. folic alcohol ester 12 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 30 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 40min, at 40 DEG C of insulation reaction 1.5h of temperature after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 8 parts and 6-acetyl group caproic acid 11 parts in reactor in step S2, raises temperature to 70 DEG C, is stirred continuously lower reaction 3h at rotating speed 400r/min; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
Embodiment 4
S1: by the stirring mixing of 1,1-cyclohexyl two capric acid monoamides 10 parts, TC acetate 18 parts, potassium peroxydisulfate 5 parts, propylene glycol methyl ether acetate 20 parts and 120 parts of water, and under power 800W after supersound process 10min, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 8 parts, dimethylamine 6 parts, aliphatic poly glycol ester 14 parts and isopropylformic acid. folic alcohol ester 15 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 40 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 50min, at temperature 50 C insulation reaction 2h after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 10 parts and 6-acetyl group caproic acid 13 parts in reactor in step S2, raises temperature to 80 DEG C, is stirred continuously lower reaction 2h at rotating speed 500r/min; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
Embodiment 5
S1: by the stirring mixing of 1,1-cyclohexyl two capric acid monoamides 8 parts, TC acetate 16 parts, potassium peroxydisulfate 4 parts, propylene glycol methyl ether acetate 18 parts and 115 parts of water, and under power 700W after supersound process 8min, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 7 parts, dimethylamine 4 parts, aliphatic poly glycol ester 13 parts and isopropylformic acid. folic alcohol ester 14 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 36 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 40min, at 48 DEG C of insulation reaction 2h of temperature after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 9 parts and 6-acetyl group caproic acid 13 parts in reactor in step S2, raises temperature to 75 DEG C, is stirred continuously lower reaction 3.5h at rotating speed 450r/min; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
Comparative example 1
S1: by the stirring mixing of TC acetate 13 parts, potassium peroxydisulfate 1 part and 80 parts of water, and under power 600W after supersound process 5min, obtain mixed liquor A;
S2: dimethylamine 2 parts, aliphatic poly glycol ester 10 parts and isopropylformic acid. folic alcohol ester 11 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 30 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 30min, at 40 DEG C of insulation reaction 1h of temperature after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 6 parts in reactor in step S2, raises temperature to 70 DEG C, is stirred continuously lower reaction 1h at rotating speed 400r/min; Question response can obtain color fixing agent after terminating cooling.
Comparative example 2
S1: by the stirring mixing of TC acetate 19 parts, potassium peroxydisulfate 5 parts and 130 parts of water, and under power 800W after supersound process 10min, obtain mixed liquor A;
S2: dimethylamine 8 parts, aliphatic poly glycol ester 15 parts and isopropylformic acid. folic alcohol ester 17 parts are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 40 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, time for adding is 60min, at temperature 50 C insulation reaction 2.5h after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 12 parts in reactor in step S2, raises temperature to 80 DEG C, is stirred continuously lower reaction 5h at rotating speed 500r/min; Question response can obtain color fixing agent after terminating cooling. Color fixing agent in each embodiment and comparative example is investigated its colour fixation, result such as following table (1-5 level, 5 grades is best):
| Experiment | Dry fastness | Fastness to wet rubbing | Washing fastness | Fastness to perspiration |
| Embodiment 1 | 4 grades | 3 grades | 3 grades | 3 grades |
| Comparative example 1 | 2 grades | 1 grade | 2 grades | 1 grade |
| Embodiment 2 | 4 grades | 3 grades | 3 grades | 4 grades |
| Comparative example 2 | 2 grades | 1 grade | 1 grade | 2 grades |
| Embodiment 3 | 4 grades | 3 grades | 3 grades | 3 grades |
| Embodiment 4 | 5 grades | 4 grades | 4 grades | 4 grades |
| Embodiment 5 | 5 grades | 4 grades | 4 grades | 5 grades |
Claims (7)
1. an environment-friendly type acidity fabric color fixing agent; it is characterized in that; each component including following percentage by weight: 4-hydroxyphenoxy propylamin hydrochloride 4-10 part; dimethylamine 2-8 part; 1; 1-cyclohexyl two capric acid monoamides 3-12 part; aliphatic poly glycol ester 10-15 part, TC acetate 13-19 part, 2; 2'-dihydroxy diethylamine 6-12 part; 6-acetyl group caproic acid 9-15 part, potassium peroxydisulfate 1-5 part, isopropylformic acid. folic alcohol ester 11-17 part; propylene glycol methyl ether acetate 15-22 part, water 80-130 part.
2. a kind of environment-friendly type acidity fabric color fixing agent according to claim 1, it is characterised in that described 4-hydroxyphenoxy propylamin hydrochloride 6-8 part; dimethylamine 3-6 part, 1,1-cyclohexyl two capric acid monoamides 5-10 part; aliphatic poly glycol ester 12-14 part, TC acetate 15-18 part, 2; 2'-dihydroxy diethylamine 8-10 part; 6-acetyl group caproic acid 11-13 part, potassium peroxydisulfate 2-5 part, isopropylformic acid. folic alcohol ester 12-15 part; propylene glycol methyl ether acetate 17-20 part, water 100-120 part.
3. a kind of environment-friendly type acidity fabric color fixing agent according to claim 2, it is characterised in that described 4-hydroxyphenoxy propylamin hydrochloride 7 parts; dimethylamine 4 parts, 1,1-cyclohexyl two capric acid monoamides 8 parts; aliphatic poly glycol ester 13 parts, TC acetate 16 parts, 2; 2'-dihydroxy diethylamine 9 parts; 6-acetyl group caproic acid 13 parts, potassium peroxydisulfate 4 parts, isopropylformic acid. folic alcohol ester 14 parts; propylene glycol methyl ether acetate 18 parts, 115 parts of water.
4. the preparation method of an environment-friendly type acidity fabric color fixing agent, it is characterised in that comprise the steps:
S1: by 1,1-cyclohexyl two capric acid monoamides 3-12 part, TC acetate 13-19 part, potassium peroxydisulfate 1-5 part, propylene glycol methyl ether acetate 15-22 part and water 80-130 part stirring mixing, and sonicated after, obtain mixed liquor A;
S2: 4-hydroxyphenoxy propylamin hydrochloride 4-10 part, dimethylamine 2-8 part, aliphatic poly glycol ester 10-15 part and isopropylformic acid. folic alcohol ester 11-17 part are added in reactor, pass into nitrogen protection simultaneously, temperature of reactor is risen to 30-40 DEG C, subsequently the described mixed liquor A in step S1 is added dropwise in reactor, temperature 40-50 DEG C of insulation reaction after dropwising;
S3: continue to add 2,2'-dihydroxy diethylamine 6-12 parts and 6-acetyl group caproic acid 9-15 part in reactor in step S2, raises temperature to 70-80 DEG C, is stirred continuously lower reaction 1-5h; Question response can obtain described environment-friendly type acidity fabric color fixing agent after terminating cooling.
5. the preparation method of a kind of environment-friendly type acidity fabric color fixing agent according to claim 4, it is characterised in that power ultrasonic described in step S1 is 600-800W, and ultrasonic time is 5-10min.
6. the preparation method of a kind of environment-friendly type acidity fabric color fixing agent according to claim 4, it is characterised in that temperature of reactor described in step S2 is 36 DEG C, and the temperature of described insulation reaction is 48 DEG C, insulation reaction 1-2.5h.
7. the preparation method of a kind of environment-friendly type acidity fabric color fixing agent according to claim 4, it is characterised in that temperature described in step S3 is 75 DEG C, and the speed of described stirring is 400-500r/min, reacts 3-3.5h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610198555.0A CN105672005A (en) | 2016-04-01 | 2016-04-01 | Environment-friendly acidic fabric color fixing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610198555.0A CN105672005A (en) | 2016-04-01 | 2016-04-01 | Environment-friendly acidic fabric color fixing agent and preparation method thereof |
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| CN105672005A true CN105672005A (en) | 2016-06-15 |
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| CN201610198555.0A Pending CN105672005A (en) | 2016-04-01 | 2016-04-01 | Environment-friendly acidic fabric color fixing agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109763363A (en) * | 2019-01-18 | 2019-05-17 | 江西德盛精细化学品有限公司 | A kind of high-efficiency environment protection acidic color fixing agent and preparation method thereof |
| CN113491682A (en) * | 2020-04-01 | 2021-10-12 | 宁海德宝立新材料有限公司 | Gallstone dissolving agent |
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| CN103147327A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Dye fixing agent and preparation method thereof |
| CN103497286A (en) * | 2013-09-03 | 2014-01-08 | 苏州经贸职业技术学院 | Preparation method of environment-friendly acidic dye fixing agent |
| CN103603217A (en) * | 2013-11-20 | 2014-02-26 | 上海德桑精细化工有限公司 | Color fixing agent and preparation method thereof |
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2016
- 2016-04-01 CN CN201610198555.0A patent/CN105672005A/en active Pending
Patent Citations (3)
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| CN103147327A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Dye fixing agent and preparation method thereof |
| CN103497286A (en) * | 2013-09-03 | 2014-01-08 | 苏州经贸职业技术学院 | Preparation method of environment-friendly acidic dye fixing agent |
| CN103603217A (en) * | 2013-11-20 | 2014-02-26 | 上海德桑精细化工有限公司 | Color fixing agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109763363A (en) * | 2019-01-18 | 2019-05-17 | 江西德盛精细化学品有限公司 | A kind of high-efficiency environment protection acidic color fixing agent and preparation method thereof |
| CN113491682A (en) * | 2020-04-01 | 2021-10-12 | 宁海德宝立新材料有限公司 | Gallstone dissolving agent |
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