CN105670086A - Polyethylene gas pipe material - Google Patents
Polyethylene gas pipe material Download PDFInfo
- Publication number
- CN105670086A CN105670086A CN201610224181.5A CN201610224181A CN105670086A CN 105670086 A CN105670086 A CN 105670086A CN 201610224181 A CN201610224181 A CN 201610224181A CN 105670086 A CN105670086 A CN 105670086A
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- Prior art keywords
- parts
- polyethylene
- alkyloxydimethicone
- hdpe
- phosphite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Abstract
The invention discloses a polyethylene gas pipe material which is prepared from, by weight, 100-110 parts of high-density polyethylene, 18-24 parts of nitrile rubber, 5-12 parts of tris(nonyl phenyl) phosphate, 3-5 parts of oleamide, 2-4 parts of alkylphenol ethoxylate, 2-6 parts of silicon dioxide, 2-6 parts of octyl diphenyl ester, 3-5 parts of polyethylene wax, 5-9 parts of acrylate copolymer, 3-5 parts of sodium lauryl sulfate and 6-8 parts of alkoxyl solydimethyl siloxane.The polyethylene gas pipe material has good flame retardancy, pressure resistance, flexibility, low temperature and high temperature resistance, quick in crack growth and high in fracture toughness.
Description
Technical field
The present invention is specifically related to a kind of fuel gas polyethylene tube material.
Technical background
Plastic pipe is the chemical building material that high-tech is composited, and chemical building material is after steel, timber, cement, the 4th big class New Building Materials that the present age is emerging. Chemical building material achieves rapid progress fast development in China, especially the widely using of novel environment friendly plastics tubing, and has started the revolution that a sound substitutes traditional construction material. Plastic pipe, because having the advantages such as current loss little, energy-conservation, material-saving, protecting ecology, completion is convenient, is widely used in the fields such as building water supply and drainage, cities and towns plumbing and gas line, becoming the main force of new millennium urban construction pipe network.
Plastic pipe is compared with the pipelines such as traditional cast iron pipe, galvanized steel pipe, cement pipe, there is energy-saving material-saving, environmental protection, high-strength light, corrosion-resistant, inner wall smooth non-scaling, construction and the advantage such as maintenance simplicity, long service life, it is widely used in construction industry, municipal administration, industry and the agriculture fields such as building water supply and drainage, town and country plumbing, gas, electric power and optical cable sheath, industrial fluids conveying, agricultural irrigation.
Plastics are different with traditional material, technical progress paces faster, the new technology that constantly occurs, novel material, novel process make plastics tubing more and more outstanding relative to the advantage of traditional material. Plastic pipe is compared with cement pipe with traditional metal tube, there is weight light, the 1/6-1/10 being generally only metal tube, has good erosion resistance, shock resistance and tensile strength, plastics tubing internal surface more smooth than cast iron pipe many, frictional coefficient is little, fluid resistance is little, can reduce water delivery energy consumption more than 5%, synthesis energy saving is good, manufactures the right reduction by 75% of energy consumption, convenient transportation, install simple, it may also be useful to the life-span reaches 30-50. Plastic pipe is very fast in countries in the world development, and developed country has accounted for absolute advantage plastic pipe and has not only been used in a large number replacing traditional steel pipe, cast iron pipe etc. in feedwater field and gas burning field application, and reason is just technological innovation. Material has great progress on the one hand; On the other hand utilisation technology has new development, makes traditional piping material not have competitive capacity being applicable to the occasion adopted in this way at all. Also have a lot of novel material, new technology to study, or found out on probation examine to, it is possible to certainly, the technical progress of 10 years plastics tubings from now on will impel plastics tubing to develop more rapidly, more extensively.
China's plastic conduit development is very fast, and quality is improving constantly. At present, begun to take shape with the plastics tubing industry of polyvinyl chloride (PVC-U) pipe, polyethylene (PE) pipe and polypropylene (PP-R) Guan Weizhu.Wherein polyethylene (PE) pipe is widely used in building water supply, construction drainage, buried drain pipe, building and heating, gas transmission and distribution, pneumatic tube, electrician and telecommunication protective casing, industrial pipe, agricultural pipe etc. due to the advantage of himself uniqueness. It is mainly used in Urban water supply, city gas supply and field irrigation. PE is polyethylene (english abbreviation of Polyethyleneofraisedtemperatureresistance), and the range of application of general PE tubing feedwater piping is the temperature lower than 40 DEG C, cannot be used for delivery pipeline. PE tubing is a kind of degree of crystallinity height, nonpolar thermoplastic resin. The milky appearance of former state HDPE, translucent in a certain degree in meagre cross section. PE has excellent resistance to great majority life and the characteristic of industrial chemical.
The production technology of China's type material falls behind, and most equipment all needs import, adds the impact of external enterprise so that manufacturing enterprise of China faces severe market test. But along with various novel material, new installation and novel process are constantly emerged in large numbers, towards diversification of varieties, customizations by impelling the plastic pipe of China and possess multi-functional plastic pipe direction and develop. Along with the further expansion of urban construction, polyethylene gas pipe also will be applied in more severe environment by further, the low temperature that such as continues, in acid or alkali environment, so needing the performance of further lifting PE gas line. Therefore carry out modification on its basis, exploitation high-performance, and meet the product of international standard, its use field can be expanded to a great extent.
Summary of the invention
In order to realize above-mentioned purpose, the present invention provides a kind of fuel gas polyethylene tube material.
It is an object of the invention to be achieved through the following technical solutions:
A kind of fuel gas polyethylene tube material, it is made up of the component mix and blend of following weight part number: high density polyethylene(HDPE) 100-110 part, paracril 18-24 part, trisnonylphenyl phosphite 5-12 part, oleylamide 3-5 part, alkylphenol polyoxyethylene 2-4 part, silicon-dioxide 2-6 part, octyl diphenyl phosphite 2-6 part, polyethylene wax 3-5 part, acrylic acid esters co-polymer 5-9 part, sodium laurylsulfate 3-5 part and alkyloxydimethicone 6-8 part.
One of preferred version: it obtains by the component of following weight part number: polyvinyl resin 74 parts, 22 parts, ethylene-propylene rubber(EPR), trisnonylphenyl phosphite 8 parts, antioxidant 264 4 parts, alkylphenol polyoxyethylene 3 parts, 3 parts, aluminum oxide, phosphorous acid benzene di-isooctyl 8 parts, carbon nanotube 4 parts, benzoyl peroxide 8 parts, 3 parts, octyl mercaptan tin and alkyloxydimethicone 7 parts.
The two of preferred version: it obtains by the component of following weight part number: high density polyethylene(HDPE) 110 parts, paracril 24 parts, trisnonylphenyl phosphite 12 parts, oleylamide 5 parts, alkylphenol polyoxyethylene 4 parts, silicon-dioxide 6 parts, octyl diphenyl phosphite 6 parts, polyethylene wax 5 parts, acrylic acid esters co-polymer 9 parts, sodium laurylsulfate 5 parts and alkyloxydimethicone 8 parts.
The three of preferred version: it obtains by the component of following weight part number: high density polyethylene(HDPE) 102 parts, paracril 19 parts, trisnonylphenyl phosphite 6 parts, oleylamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon-dioxide 3 parts, octyl diphenyl phosphite 3 parts, polyethylene wax 4 parts, acrylic acid esters co-polymer 6 parts, sodium laurylsulfate 4 parts and alkyloxydimethicone 7 parts.
The four of preferred version: it obtains by the component of following weight part number: high density polyethylene(HDPE) 108 parts, paracril 22 parts, trisnonylphenyl phosphite 11 parts, oleylamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon-dioxide 5 parts, octyl diphenyl phosphite 5 parts, polyethylene wax 4 parts, acrylic acid esters co-polymer 8 parts, sodium laurylsulfate 4 parts and alkyloxydimethicone 7 parts.
The method of tubing prepared by this material: carry out after being mixed in proportion by each raw material stirring 10-12 minute in low-speed mixer, then the batch mixing feeding single screw extrusion machine that will prepare, processing temperature controls at 160-210 DEG C, and screw speed controls at 60-90rpm, extruding pipe material.
The present invention has following useful effect: polyethylene gas pipe tubing provided by the invention has good flame retardant resistance, resistance to compression, snappiness, resistance to low temperature, high temperature resistant, and quick crack growth fracture toughness property is strong.
Embodiment
The following stated is only the preferred embodiments of the present invention, it is not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, technical scheme described in foregoing embodiments still can be modified by it, or wherein part technology feature carries out equivalent replacement. Within the spirit and principles in the present invention all, any amendment of doing, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Embodiment 1
A kind of fuel gas polyethylene tube material, it is made up of the component mix and blend of following weight part number: high density polyethylene(HDPE) 100 parts, paracril 18 parts, trisnonylphenyl phosphite 5 parts, oleylamide 3 parts, alkylphenol polyoxyethylene 2 parts, silicon-dioxide 2 parts, octyl diphenyl phosphite 2 parts, polyethylene wax 3 parts, acrylic acid esters co-polymer 5 parts, sodium laurylsulfate 3 parts and alkyloxydimethicone 6 parts.
Embodiment 2
A kind of fuel gas polyethylene tube material, it is made up of the component mix and blend of following weight part number: high density polyethylene(HDPE) 110 parts, paracril 24 parts, trisnonylphenyl phosphite 12 parts, oleylamide 5 parts, alkylphenol polyoxyethylene 4 parts, silicon-dioxide 6 parts, octyl diphenyl phosphite 6 parts, polyethylene wax 5 parts, acrylic acid esters co-polymer 9 parts, sodium laurylsulfate 5 parts and alkyloxydimethicone 8 parts.
Embodiment 3
A kind of fuel gas polyethylene tube material, it is made up of the component mix and blend of following weight part number: high density polyethylene(HDPE) 102 parts, paracril 19 parts, trisnonylphenyl phosphite 6 parts, oleylamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon-dioxide 3 parts, octyl diphenyl phosphite 3 parts, polyethylene wax 4 parts, acrylic acid esters co-polymer 6 parts, sodium laurylsulfate 4 parts and alkyloxydimethicone 7 parts.
Embodiment 4
A kind of fuel gas polyethylene tube material, it is made up of the component mix and blend of following weight part number: high density polyethylene(HDPE) 108 parts, paracril 22 parts, trisnonylphenyl phosphite 11 parts, oleylamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon-dioxide 5 parts, octyl diphenyl phosphite 5 parts, polyethylene wax 4 parts, acrylic acid esters co-polymer 8 parts, sodium laurylsulfate 4 parts and alkyloxydimethicone 7 parts.
Claims (5)
1. a fuel gas polyethylene tube material, it is characterised in that it obtains by the component of following weight part number: high density polyethylene(HDPE) 100-110 part, paracril 18-24 part, trisnonylphenyl phosphite 5-12 part, oleylamide 3-5 part, alkylphenol polyoxyethylene 2-4 part, silicon-dioxide 2-6 part, octyl diphenyl phosphite 2-6 part, polyethylene wax 3-5 part, acrylic acid esters co-polymer 5-9 part, sodium laurylsulfate 3-5 part and alkyloxydimethicone 6-8 part.
2. a kind of fuel gas polyethylene tube material according to claim 1, it is characterised in that it obtains by the component of following weight part number: high density polyethylene(HDPE) 100 parts, paracril 18 parts, trisnonylphenyl phosphite 5 parts, oleylamide 3 parts, alkylphenol polyoxyethylene 2 parts, silicon-dioxide 2 parts, octyl diphenyl phosphite 2 parts, polyethylene wax 3 parts, acrylic acid esters co-polymer 5 parts, sodium laurylsulfate 3 parts and alkyloxydimethicone 6 parts.
3. a kind of fuel gas polyethylene tube material according to claim 1, it is characterised in that it obtains by the component of following weight part number: high density polyethylene(HDPE) 110 parts, paracril 24 parts, trisnonylphenyl phosphite 12 parts, oleylamide 5 parts, alkylphenol polyoxyethylene 4 parts, silicon-dioxide 6 parts, octyl diphenyl phosphite 6 parts, polyethylene wax 5 parts, acrylic acid esters co-polymer 9 parts, sodium laurylsulfate 5 parts and alkyloxydimethicone 8 parts.
4. a kind of fuel gas polyethylene tube material according to claim 1, it is characterised in that it obtains by the component of following weight part number: high density polyethylene(HDPE) 102 parts, paracril 19 parts, trisnonylphenyl phosphite 6 parts, oleylamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon-dioxide 3 parts, octyl diphenyl phosphite 3 parts, polyethylene wax 4 parts, acrylic acid esters co-polymer 6 parts, sodium laurylsulfate 4 parts and alkyloxydimethicone 7 parts.
5. a kind of fuel gas polyethylene tube material according to claim 1, it is characterised in that it obtains by the component of following weight part number: high density polyethylene(HDPE) 108 parts, paracril 22 parts, trisnonylphenyl phosphite 11 parts, oleylamide 4 parts, alkylphenol polyoxyethylene 3 parts, silicon-dioxide 5 parts, octyl diphenyl phosphite 5 parts, polyethylene wax 4 parts, acrylic acid esters co-polymer 8 parts, sodium laurylsulfate 4 parts and alkyloxydimethicone 7 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610224181.5A CN105670086A (en) | 2016-04-11 | 2016-04-11 | Polyethylene gas pipe material |
Applications Claiming Priority (1)
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CN201610224181.5A CN105670086A (en) | 2016-04-11 | 2016-04-11 | Polyethylene gas pipe material |
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CN105670086A true CN105670086A (en) | 2016-06-15 |
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CN201610224181.5A Withdrawn CN105670086A (en) | 2016-04-11 | 2016-04-11 | Polyethylene gas pipe material |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106810749A (en) * | 2017-02-20 | 2017-06-09 | 广西金盛科技发展有限公司 | The production technology of high density polyethylene (HDPE) plastic-steel spirally-wound pipe |
CN106832525A (en) * | 2017-02-20 | 2017-06-13 | 广西金盛科技发展有限公司 | The processing technology of high density polyethylene (HDPE) bilayer feed pipe |
CN110305381A (en) * | 2019-06-17 | 2019-10-08 | 河南联塑实业有限公司 | A kind of preparation method of fuel gas polyethylene tubing material |
CN116041832A (en) * | 2023-02-28 | 2023-05-02 | 江苏惠升管业集团有限公司 | POE grafted GMA and application method thereof in polyethylene gas pipe |
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CN1322773A (en) * | 2001-05-24 | 2001-11-21 | 宁波信高塑化有限公司 | Inorganic nanometer particle modified optical cable protecting casing material and its prepn |
CN1322774A (en) * | 2001-06-06 | 2001-11-21 | 宁波信高塑化有限公司 | Material specially for communication optical cable protecting casing and its prepn |
CN1657562A (en) * | 2004-12-07 | 2005-08-24 | 青岛科技大学 | Special material for large-diameter plastic draining pipe |
CN1657561A (en) * | 2004-12-07 | 2005-08-24 | 青岛科技大学 | Special material for antistatic impact fire resistant polyethylene pipe |
CN1958656A (en) * | 2006-10-24 | 2007-05-09 | 辽宁艾海滑石有限公司 | Rigidity enhanced, modified dedicated material of plastic pipe material |
CN102850629A (en) * | 2012-09-18 | 2013-01-02 | 浙江新大塑料管件有限公司 | Mine polyethylene tube |
CN103709485A (en) * | 2013-12-27 | 2014-04-09 | 湖北金科环保科技有限公司 | Special material for modification and regeneration of polyethylene anticorrosive pipeline and preparation method thereof |
-
2016
- 2016-04-11 CN CN201610224181.5A patent/CN105670086A/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1322773A (en) * | 2001-05-24 | 2001-11-21 | 宁波信高塑化有限公司 | Inorganic nanometer particle modified optical cable protecting casing material and its prepn |
CN1322774A (en) * | 2001-06-06 | 2001-11-21 | 宁波信高塑化有限公司 | Material specially for communication optical cable protecting casing and its prepn |
CN1657562A (en) * | 2004-12-07 | 2005-08-24 | 青岛科技大学 | Special material for large-diameter plastic draining pipe |
CN1657561A (en) * | 2004-12-07 | 2005-08-24 | 青岛科技大学 | Special material for antistatic impact fire resistant polyethylene pipe |
CN1958656A (en) * | 2006-10-24 | 2007-05-09 | 辽宁艾海滑石有限公司 | Rigidity enhanced, modified dedicated material of plastic pipe material |
CN102850629A (en) * | 2012-09-18 | 2013-01-02 | 浙江新大塑料管件有限公司 | Mine polyethylene tube |
CN103709485A (en) * | 2013-12-27 | 2014-04-09 | 湖北金科环保科技有限公司 | Special material for modification and regeneration of polyethylene anticorrosive pipeline and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106810749A (en) * | 2017-02-20 | 2017-06-09 | 广西金盛科技发展有限公司 | The production technology of high density polyethylene (HDPE) plastic-steel spirally-wound pipe |
CN106832525A (en) * | 2017-02-20 | 2017-06-13 | 广西金盛科技发展有限公司 | The processing technology of high density polyethylene (HDPE) bilayer feed pipe |
CN110305381A (en) * | 2019-06-17 | 2019-10-08 | 河南联塑实业有限公司 | A kind of preparation method of fuel gas polyethylene tubing material |
CN116041832A (en) * | 2023-02-28 | 2023-05-02 | 江苏惠升管业集团有限公司 | POE grafted GMA and application method thereof in polyethylene gas pipe |
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