CN105860187A - Polyethylene water feed pipe formula - Google Patents

Polyethylene water feed pipe formula Download PDF

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Publication number
CN105860187A
CN105860187A CN201610223582.9A CN201610223582A CN105860187A CN 105860187 A CN105860187 A CN 105860187A CN 201610223582 A CN201610223582 A CN 201610223582A CN 105860187 A CN105860187 A CN 105860187A
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China
Prior art keywords
parts
formula
polyethylene
feed pipe
monoglyceride
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Application number
CN201610223582.9A
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Chinese (zh)
Inventor
叶青
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Individual
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Individual
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Priority to CN201610223582.9A priority Critical patent/CN105860187A/en
Publication of CN105860187A publication Critical patent/CN105860187A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/12Rigid pipes of plastics with or without reinforcement
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

The invention discloses a polyethylene water feed pipe formula. The formula comprises, by weight, 50-65 parts of high density polyethylene, 8-14 parts of cis-polybutadiene rubber, 5-10 parts of an ethylene-vinyl acetate copolymer, 3-6 parts of UV-9, 2-4 parts of nonylphenol polyoxyethylene ether, 5-9 parts of silica, 5-9 parts of diisooctyl phenyl phosphite, 1-3 parts of monoglyceride, 5-12 parts of a methyl methacrylate-butadiene-styrene copolymer and 3-6 parts of acetyl tributyl citrate. Polyethylene pipes made through the formula have high bearing ability, can resist heat and wear, are simple and easy to manufacture, can well adapt to harsh working environment, and have long service life.

Description

A kind of polyethylene feed pipe formula
Technical field
Present invention relates particularly to a kind of polyethylene feed pipe formula.
Technical background
Plastic pipe is the chemical building material that high-tech is composited, and chemical building material be continue steel, After timber, cement, the fourth-largest class New Building Materials that the present age is emerging.Chemical building material is at me State achieves being widely used of rapid progress fast development, especially novel environment friendly plastics tubing, Start a sound and substitute the revolution of traditional construction material.Plastic pipe because of have current loss little, energy-conservation, The advantage such as material-saving, protecting ecology, completion are convenient, be widely used in building water supply and drainage, cities and towns to The field such as draining and Gas Pipe, becomes the main force of new century urban construction pipe network.
Plastic pipe, compared with the pipelines such as traditional cast iron pipe, coating steel pipe, pipe of cement, has Energy-saving material-saving, environmental protection, high-strength light, corrosion-resistant, inner wall smooth non-scaling, construct and keep in repair The advantages such as simplicity, length in service life, are widely used in building water supply and drainage, town and country plumbing, city The building industry such as city's combustion gas, electric power and cable jacket, industrial fluids conveying, agricultural irrigation, municipal administration, Industry and agriculture field.
Plastics are different with traditional material, technological progress paces faster, constantly occur is new Technology, new material, new technology make the advantage of the relatively conventional material of plastic tube more and more prominent.Mould Material tubing, compared with traditional metal tube and pipe of cement, has lightweight, is typically only metal tube 1/6-1/10, have preferable corrosion resistance, shock resistance and tensile strength, plastic tube inner surface Than cast iron pipe smooth many, coefficient of friction is little, fluid resistance is little, can reduce water delivery energy consumption 5% Above, synthesis energy saving is good, manufactures the right reduction of energy consumption 75%, convenient transportation, installs simple, makes With the life-span up to 30-50.Plastic pipe develops quickly in countries in the world, and developed country is giving It is not only a large amount of for replacing that water field and gas burning field application have accounted for absolute advantage plastic pipe Traditional steel pipe, cast iron pipe etc., reason is that technological innovation.On the one hand material has great Progressive;On the other hand application technology has new development, makes traditional piping material this side of applicable employing The occasion of method does not has competitiveness at all.A lot of new materials, new technique is also had to study, or Found out on probation examine to, can affirm, the technology of 10 years plastic tubes is entered from now on Step will promote plastic tube more quickly to develop, more extensively.
China's plastic conduit develops quickly, and quality is improving constantly.At present, preliminarily formed with Polrvinyl chloride (PVC-U) pipe, polyethylene (PE) pipe and polypropylene (PP-R) Guan Weizhu's Plastic tube industry.Wherein polyethylene (PE) pipe due to himself uniqueness advantage by widely should For building water supply, construction drainage, buried drain pipe, building and heating, gas transmission and distribution, gas transmission Pipe, electrician and telecommunication protection sleeve pipe, industrial pipe, agricultural pipe etc..It is mainly used in city City's water supply, city gas supply and field irrigation.PE, is polyethylene (Polyethylene of The english abbreviation of raised temperature resistance), general PE tubing feed pipe The range of application in road is the temperature less than 40 DEG C, it is impossible to for delivery pipeline.PE tubing It it is a kind of degree of crystallinity thermoplastic resin high, nonpolar.The milky appearance of ortho states HDPE, It is a certain degree of translucent in meagre cross section.PE have excellent resistance to great majority life and The characteristic of chemicals for industrial use.
The production technology of China's new material falls behind, and most equipment all needs import, adds external The impact of enterprise so that manufacturing enterprise of China faces the market test of sternness.But it is as various New material, new equipment and new technology are constantly emerged in large numbers, and the plastic pipe of China will be promoted towards product Kind of variation, customizations and possess multi-functional plastic pipe direction and develop.Therefore, poly-second Alkene (PE) pipe application is the most constantly expanding, but common PE material make to Water pipe thermostability, is modified the most on its basis, develops high-fire resistance, and meets the world The product of standard, can largely expand its use field.
Summary of the invention
To achieve these goals, the invention provides a kind of polyethylene feed pipe formula.
It is an object of the invention to be achieved through the following technical solutions:
A kind of polyethylene feed pipe formula, this formula each raw material weight component is: high-density polyethylene Alkene 50-65 part, butadiene rubber 8-14 part, ethylene-vinyl acetate copolymer 5-10 part, UV-9 3-6 part, NPE 2-4 part, silicon dioxide 5-9 part, phosphorous acid benzene two are different Monooctyl ester 5-9 part, monoglyceride 1-3 part, MBS 5-12 part and tributyl 2-acetylcitrate 3-6 part.
One of preferred version: this formula each raw material weight component is: high density polyethylene (HDPE) 50 parts, Butadiene rubber 8 parts, ethylene-vinyl acetate copolymer 5 parts, UV-9 3 parts, nonyl phenol are poly- Oxygen vinyl Ether 2 parts, silicon dioxide 5 parts, phosphorous acid benzene di-isooctyl 5 parts, monoglyceride 1 part, MBS 5 parts and tributyl 2-acetylcitrate 3 Part.
The two of preferred version: this formula each raw material weight component is: high density polyethylene (HDPE) 65 parts, Butadiene rubber 14 parts, ethylene-vinyl acetate copolymer 10 parts, UV-9 6 parts, nonyl phenol Polyoxyethylene ether 4 parts, silicon dioxide 9 parts, phosphorous acid benzene di-isooctyl 9 parts, monoglyceride 3 Part, MBS 12 parts and acetyl tributyl citrate three fourth Ester 6 parts.
The three of preferred version: this formula each raw material weight component is: high density polyethylene (HDPE) 53 parts, Butadiene rubber 9 parts, ethylene-vinyl acetate copolymer 7 parts, UV-9 4 parts, nonyl phenol are poly- Oxygen vinyl Ether 3 parts, silicon dioxide 6 parts, phosphorous acid benzene di-isooctyl 6 parts, monoglyceride 2 parts, MBS 7 parts and tributyl 2-acetylcitrate 4 Part.
The four of preferred version: this formula each raw material weight component is: high density polyethylene (HDPE) 62 parts, Butadiene rubber 11 parts, ethylene-vinyl acetate copolymer 8 parts, UV-9 5 parts, nonyl phenol are poly- Oxygen vinyl Ether 3 parts, silicon dioxide 8 parts, phosphorous acid benzene di-isooctyl 8 parts, monoglyceride 2 parts, MBS 11 parts and tributyl 2-acetylcitrate 5 Part.
This formula prepares the method for tubing: at low-speed mixer after being mixed in proportion by each raw material In be stirred 10-12 minute, the batch mixing feeding single screw extrusion machine that then will prepare, add Work temperature controls at 160-210 DEG C, and screw speed controls at 60-90rpm, extruding pipe material.
The method have the advantages that the polyethylene that the formula provided by the present invention is prepared Tubing bearing capacity is high, and heat-resisting, wear-resistant, preparation process is simple, can preferably fit Working environment that should be severe, service life is long.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
A kind of polyethylene feed pipe formula, this formula each raw material weight component is: high-density polyethylene 50 parts of alkene, butadiene rubber 8 parts, ethylene-vinyl acetate copolymer 5 parts, UV-9 3 parts, NPE 2 parts, silicon dioxide 5 parts, phosphorous acid benzene di-isooctyl 5 parts, list Sweet ester 1 part, MBS 5 parts and acetyl tributyl citrate Tributyl 3 parts.
Embodiment 2
A kind of polyethylene feed pipe formula, this formula each raw material weight component is: high-density polyethylene 65 parts of alkene, butadiene rubber 14 parts, ethylene-vinyl acetate copolymer 10 parts, UV-9 6 parts, NPE 4 parts, silicon dioxide 9 parts, phosphorous acid benzene di-isooctyl 9 parts, list Sweet ester 3 parts, MBS 12 parts and acetyl Fructus Citri Limoniae Acid tributyl 6 parts.
Embodiment 3
A kind of polyethylene feed pipe formula, this formula each raw material weight component is: high-density polyethylene 53 parts of alkene, butadiene rubber 9 parts, ethylene-vinyl acetate copolymer 7 parts, UV-9 4 parts, NPE 3 parts, silicon dioxide 6 parts, phosphorous acid benzene di-isooctyl 6 parts, list Sweet ester 2 parts, MBS 7 parts and acetyl tributyl citrate Tributyl 4 parts.
Embodiment 4
A kind of polyethylene feed pipe formula, this formula each raw material weight component is: high-density polyethylene 62 parts of alkene, butadiene rubber 11 parts, ethylene-vinyl acetate copolymer 8 parts, UV-9 5 parts, NPE 3 parts, silicon dioxide 8 parts, phosphorous acid benzene di-isooctyl 8 parts, list Sweet ester 2 parts, MBS 11 parts and acetyl Fructus Citri Limoniae Acid tributyl 5 parts.

Claims (5)

1. a polyethylene feed pipe formula, it is characterised in that this formula each raw material weight component For: high density polyethylene (HDPE) 50-65 part, butadiene rubber 8-14 part, ethene-vinyl acetate copolymerization Thing 5-10 part, UV-9 3-6 part, NPE 2-4 part, silicon dioxide 5-9 Part, phosphorous acid benzene di-isooctyl 5-9 part, monoglyceride 1-3 part, methyl methacrylate-fourth Diene-styrene copolymer 5-12 part and tributyl 2-acetylcitrate 3-6 part.
A kind of polyethylene feed pipe formula the most according to claim 1, it is characterised in that This formula each raw material weight component is: high density polyethylene (HDPE) 50 parts, butadiene rubber 8 parts, second Alkene-acetate ethylene copolymer 5 parts, UV-9 3 parts, NPE 2 parts, two Silicon oxide 5 parts, phosphorous acid benzene di-isooctyl 5 parts, monoglyceride 1 part, methyl methacrylate -BS 5 parts and tributyl 2-acetylcitrate 3 parts.
A kind of polyethylene feed pipe formula the most according to claim 1, it is characterised in that This formula each raw material weight component is: high density polyethylene (HDPE) 65 parts, butadiene rubber 14 parts, second Alkene-acetate ethylene copolymer 10 parts, UV-9 6 parts, NPE 4 parts, two Silicon oxide 9 parts, phosphorous acid benzene di-isooctyl 9 parts, monoglyceride 3 parts, methyl methacrylate -BS 12 parts and tributyl 2-acetylcitrate 6 parts.
A kind of polyethylene feed pipe formula the most according to claim 1, it is characterised in that This formula each raw material weight component is: high density polyethylene (HDPE) 53 parts, butadiene rubber 9 parts, second Alkene-acetate ethylene copolymer 7 parts, UV-9 4 parts, NPE 3 parts, two Silicon oxide 6 parts, phosphorous acid benzene di-isooctyl 6 parts, monoglyceride 2 parts, methyl methacrylate -BS 7 parts and tributyl 2-acetylcitrate 4 parts.
A kind of polyethylene feed pipe formula the most according to claim 1, it is characterised in that This formula each raw material weight component is: high density polyethylene (HDPE) 62 parts, butadiene rubber 11 parts, second Alkene-acetate ethylene copolymer 8 parts, UV-9 5 parts, NPE 3 parts, two Silicon oxide 8 parts, phosphorous acid benzene di-isooctyl 8 parts, monoglyceride 2 parts, methyl methacrylate -BS 11 parts and tributyl 2-acetylcitrate 5 parts.
CN201610223582.9A 2016-04-11 2016-04-11 Polyethylene water feed pipe formula Withdrawn CN105860187A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610223582.9A CN105860187A (en) 2016-04-11 2016-04-11 Polyethylene water feed pipe formula

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Application Number Priority Date Filing Date Title
CN201610223582.9A CN105860187A (en) 2016-04-11 2016-04-11 Polyethylene water feed pipe formula

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867098A (en) * 2017-04-02 2017-06-20 枣庄玉龙农业科技有限公司 A kind of high-strength abrasion-proof Agricultural hose and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1322774A (en) * 2001-06-06 2001-11-21 宁波信高塑化有限公司 Material specially for communication optical cable protecting casing and its prepn
CN1322773A (en) * 2001-05-24 2001-11-21 宁波信高塑化有限公司 Inorganic nanometer particle modified optical cable protecting casing material and its prepn
CN1657561A (en) * 2004-12-07 2005-08-24 青岛科技大学 Special material for antistatic impact fire resistant polyethylene pipe
CN1657562A (en) * 2004-12-07 2005-08-24 青岛科技大学 Special material for large-diameter plastic draining pipe
CN1958656A (en) * 2006-10-24 2007-05-09 辽宁艾海滑石有限公司 Rigidity enhanced, modified dedicated material of plastic pipe material
CN102850629A (en) * 2012-09-18 2013-01-02 浙江新大塑料管件有限公司 Mine polyethylene tube
CN103709485A (en) * 2013-12-27 2014-04-09 湖北金科环保科技有限公司 Special material for modification and regeneration of polyethylene anticorrosive pipeline and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1322773A (en) * 2001-05-24 2001-11-21 宁波信高塑化有限公司 Inorganic nanometer particle modified optical cable protecting casing material and its prepn
CN1322774A (en) * 2001-06-06 2001-11-21 宁波信高塑化有限公司 Material specially for communication optical cable protecting casing and its prepn
CN1657561A (en) * 2004-12-07 2005-08-24 青岛科技大学 Special material for antistatic impact fire resistant polyethylene pipe
CN1657562A (en) * 2004-12-07 2005-08-24 青岛科技大学 Special material for large-diameter plastic draining pipe
CN1958656A (en) * 2006-10-24 2007-05-09 辽宁艾海滑石有限公司 Rigidity enhanced, modified dedicated material of plastic pipe material
CN102850629A (en) * 2012-09-18 2013-01-02 浙江新大塑料管件有限公司 Mine polyethylene tube
CN103709485A (en) * 2013-12-27 2014-04-09 湖北金科环保科技有限公司 Special material for modification and regeneration of polyethylene anticorrosive pipeline and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867098A (en) * 2017-04-02 2017-06-20 枣庄玉龙农业科技有限公司 A kind of high-strength abrasion-proof Agricultural hose and preparation method thereof

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Application publication date: 20160817

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