CN105661666A - Mosquito-repellent anti-ultraviolet sock and making method thereof - Google Patents

Mosquito-repellent anti-ultraviolet sock and making method thereof Download PDF

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Publication number
CN105661666A
CN105661666A CN201610119440.8A CN201610119440A CN105661666A CN 105661666 A CN105661666 A CN 105661666A CN 201610119440 A CN201610119440 A CN 201610119440A CN 105661666 A CN105661666 A CN 105661666A
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CN
China
Prior art keywords
anophelifuge
resistance
socks
finishing agent
raw material
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Granted
Application number
CN201610119440.8A
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Chinese (zh)
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CN105661666B (en
Inventor
许孟葵
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Jiangsu Southwest Intelligent Textile Co Ltd
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Individual
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B11/00Hosiery; Panti-hose
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B17/00Selection of special materials for underwear
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • D06M13/175Unsaturated ethers, e.g. vinylethers

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a mosquito-repellent anti-ultraviolet sock and a making method thereof. The mosquito-repellent anti-ultraviolet sock is made by weaving, by weight, 60%-80% of cotton fibers and 20%-40% of spandex. The mosquito-repellent anti-ultraviolet sock is stable in technology, good in selected raw material and stable in quality through checking of all processes; in appearance, the mosquito-repellent anti-ultraviolet sock is uniform in woven fabric density, thick, solid, pure in color and luster and good in sizing and shaping and is an ideal choice for healthy home life.

Description

Anophelifuge UV resistance socks and preparation method thereof
Technical field
The present invention relates to a kind of socks, be specifically related to a kind of anophelifuge UV resistance socks and preparation method thereof.
Background technology
" socks " word sees " China notes at all times " the earliest, says: " three generations and week work angle, lie in ankle with band ". " three generations " refers to China's summer on the books the earliest, business, period in week, from the present existing 3000 or four thousand years history. " angle " should be the original socks made of animal skin, so writing " ". Later, along with the appearance of textile, socks again by beast cloth develop into cloth, fiber crops, silk make, " " also correspondingly changes into " socks ", be finally reduced to step by step today we described " socks ". The transmutation process of " socks " word, has contained the development process of Chinese civilization history in fact.
Ancient times, the shape system of socks about can divide three-chip type craft socks for having legging, frenulum socks, panty hose, point toe socks, shaven head socks and bottomless sock etc. six kinds. The stocking leg wherein having legging is different in size, some length to abdominal part, have only between ankle. Frenulum socks are in order that difficult drop-off when wearing. Dividing toe socks is separated with other four toes by big toe, and shape is bifurcation shape such as. Shaven head socks and bottomless sock are used for the women of foot-binding in ancient times, are commonly called as half socks.
Now, the kind of socks is a lot, divides by the length of the stocking leg, has stocking, Knee-socks and short legging and ship socks (invisible socks); Divide by stocking blank kind, have registered permanent residence socks, rib cuff socks and elastic top hosiery; By using object to divide, there are men's socks, female's socks and Children's Socks. Circular knit hosiery is by stocking blank, the stocking leg and stocking foot 3 portion of tissue. The specification of socks, represents with socks size, and socks number is to be of a size of standard with the physical length of the stocking sole, so just can choose, after knowing the foot length of oneself, the socks fitted. The raw material used due to socks is different, and it is also different in socks series.
Along with people are to improving constantly that healthy living is pursued, the performance of socks are not limited solely to warming, attractive in appearance etc., are also aided with various health cares and the safeguard functions such as more massage, demodicid mite antibacterial, anti-, moisture absorbing and sweat releasing, antistatic, uvioresistant.
The invention provides a kind of anophelifuge UV resistance socks, meet the people's multi-functional demand to socks.
Summary of the invention
For prior art above shortcomings, one of the technical problem to be solved is to provide a kind of anophelifuge UV resistance socks.
The preparation method that the two of the technical problem to be solved are to provide above-mentioned anophelifuge UV resistance socks.
The technical problem of the present invention, is achieved by following technical proposals:
A kind of anophelifuge UV resistance socks, are weaved by the raw material of following weight parts and form: 60-80wt% cotton fiber and 20-40wt% spandex.
Described anophelifuge UV resistance socks process step then through anophelifuge UV resistance and obtain.
It is impregnated in anophelifuge UV resistance finishing agent by described anophelifuge UV resistance socks that described anophelifuge UV resistance processes step, and described anophelifuge UV resistance finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part aloe essential oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.1-0.5 part Octabenzone, 0.1-0.5 part penetrating agent, 5-15 part ethanol, 0.1-0.5 part chelating agen, 95-105 part water.
Described penetrating agent is mixed by 40-60wt% aerosol OT and 40-60wt% tridecyl sodium sulfonate.
Preferably, described chelating agen is mixed by 40-60wt% ethylene diamine tetra methylene phosphonic acid five sodium-salt and 40-60wt% ATMP five sodium-salt.
The preparation method that present invention also offers above-mentioned anophelifuge UV resistance socks, it is characterised in that comprise the following steps:
(1) conventional method is adopted cotton fiber and spandex to be weaved, be processed into socks;
(2) above-mentioned socks are carried out anophelifuge UV resistance process.
Preferably, described step (2) is under 65-85 DEG C of condition, and socks impregnate 20-30min in anophelifuge UV resistance finishing agent, after dehydration, dries 5-10min under 70-90 DEG C of condition.
Described anophelifuge UV resistance finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part aloe essential oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.1-0.5 part Octabenzone, 0.1-0.5 part penetrating agent, 5-15 part ethanol, 0.1-0.5 part chelating agen, 95-105 part water.
Concrete, in the present invention:
Aloe essential oil, i.e. aloe, No. CAS: 100084-89-7.
Oil of Cymbopogon winterianus, No. CAS: 73049-78-2.
Octabenzone, No. CAS: 1843-05-6.
Aerosol OT, No. CAS: 577-11-7.
Tridecyl sodium sulfonate, No. CAS: 5802-89-1.
Ethylene diamine tetra methylene phosphonic acid five sodium-salt, No. CAS: 7651-99-2.
ATMP five sodium-salt, No. CAS: 2235-43-0.
Ethanol, No. CAS: 64-17-5.
The anophelifuge UV resistance socks of the present invention, process stabilizing, to select raw material good, by checking on of each procedure, steady quality, show in appearance, Density is uniform, abundant, pure color, forming of shaping, and is the ideal chose of healthy life staying idle at home.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, it is only to presently preferred embodiments of the present invention, the present invention not does the restriction of other forms, and any those skilled in the art are changed to the equal Equivalent embodiments changed possibly also with the technology contents of the disclosure above. Every without departing from the present invention program content, any simple modification following example done according to the technical spirit of the present invention or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Anophelifuge UV resistance socks raw material (percentage by weight): 70wt% cotton fiber (cotton fiber is long-staple cotton, and its length is 40mm, and fineness is 7200nm) and 30wt% spandex (adopting Du Pont's spandex thread, 70D).
Anophelifuge UV resistance finishing agent raw material (weight portion): 0.2 part of aloe essential oil, 0.2 part of oil of Cymbopogon winterianus, 0.3 part of Octabenzone, 0.3 part of penetrating agent, 10 parts of ethanol, 0.3 part of chelating agen, 100 parts of deionized waters.
Described penetrating agent is uniformly mixed is obtained by 50wt% aerosol OT and 50wt% tridecyl sodium sulfonate.
Described chelating agen is uniformly mixed is obtained by 50wt% ethylene diamine tetra methylene phosphonic acid five sodium-salt and 50wt% ATMP five sodium-salt.
The preparation method that present invention also offers above-mentioned anophelifuge UV resistance socks, comprises the following steps:
(1) adopt braider, according to a conventional method cotton fiber and spandex are woven into socks blank cloth (grammes per square metre is 160 grams/m), according to the technique and the requirement that make socks, after socks blank cloth cutting, be processed into socks;
(2) aloe essential oil, oil of Cymbopogon winterianus, Octabenzone, penetrating agent, ethanol, chelating agen are added deionized water for stirring mix homogeneously, obtain anophelifuge UV resistance finishing agent; Socks are placed in the anophelifuge UV resistance finishing agent that temperature is 75 DEG C and impregnate 25min, wherein socks are 1:10 (i.e. 1kg socks 10kg anophelifuge UV resistance finishing agent dipping) with the mass ratio of anophelifuge UV resistance finishing agent, after dehydration, under 80 DEG C of conditions, dry 8min; Obtain anophelifuge UV resistance socks.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described penetrating agent is only aerosol OT. Obtain the anophelifuge UV resistance socks of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described penetrating agent is only tridecyl sodium sulfonate. Obtain the anophelifuge UV resistance socks of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described chelating agen is only ethylene diamine tetra methylene phosphonic acid five sodium-salt. Obtain the anophelifuge UV resistance socks of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described chelating agen is only ATMP five sodium-salt. Obtain the anophelifuge UV resistance socks of embodiment 5.
Test case 1
The anophelifuge UV resistance socks of embodiment 1-5 are carried out anti-ultraviolet property test test, adopts the evaluation of GB/T18830-2009 ultraviolet resistance of fabric, test. UPF (be called for short: UPF) value, UVA transmission measurement data in Table 1.
Table 1: anti-ultraviolet property test chart
Comparing embodiment 1-3, embodiment 1 (aerosol OT, tridecyl sodium sulfonate are composite) uvioresistant effect, hence it is evident that be better than embodiment 2-3 (in aerosol OT, tridecyl sodium sulfonate single raw material); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt are composite) uvioresistant effect, hence it is evident that be better than embodiment 4-5 (in ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt single raw material).
Test case 2
The anophelifuge UV resistance socks of embodiment 1-5 are carried out anophelifuge test,
Test 18:00-20:00 between the lights to carry out, white mice is fixed on the three-ply board of one piece of 10cm × 15cm, Mus surface covers silk stocking, and fix in surrounding with elastic, then put it in the mosquito cage raising 1000 mosquitoes, timing 3 minutes, observe and record mosquito during this period and stop, on sample cloth cover, the number of times that falls, in triplicate, embodiment uses color identical with comparative example. Test data are in Table 2.
Table 2: synthesis test chart
Comparing embodiment 1-3, embodiment 1 (aerosol OT, tridecyl sodium sulfonate are composite) repelling effect, hence it is evident that be better than embodiment 2-3 (in aerosol OT, tridecyl sodium sulfonate single raw material); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt are composite) repelling effect, hence it is evident that be better than embodiment 4-5 (in ethylene diamine tetra methylene phosphonic acid five sodium-salt, ATMP five sodium-salt single raw material).
Test case 3
Embodiment 1 anophelifuge UV resistance finishing agent (anophelifuge UV resistance finishing agent raw material (weight portion): 0.2 part of aloe essential oil, 0.2 part of oil of Cymbopogon winterianus, 0.3 part of Octabenzone, 0.3 part of penetrating agent, 10 parts of ethanol, 0.3 part of chelating agen, 100 parts of deionized waters) toxicity test:
(1) anophelifuge UV resistance finishing agent per os acute toxicity; Taking the anophelifuge UV resistance finishing agent Kunming disposable per os gavage of kind standard white mice to 40 empty stomach 16h, anophelifuge UV resistance finishing agent dosage is up to 1000mg/kg. Observing animal and poisoning manifestations every day, within seven days, terminate experiment, each group laboratory animal is in whole experimentation, all normal without any poisoning manifestations, diet and motion, none animal dead.
(2) to skin irritation: 10 Japan's big ear tag quasi experiment spinal column diamond wools of rabbit are cut respectively, the gauze of anophelifuge UV resistance finishing agent will be impregnated, apply ointment or plaster on the skin that right side exposes. Observing application site skin after 24 hours, the irritation such as erythema and edema all do not occur, according to skin irritation strength grading standard, skin is belonged to non-stimulated material by this anophelifuge UV resistance finishing agent.
(3) to eye irritation: by anophelifuge UV resistance finishing agent, directly instill the big ear tag quasi experiment right eye of rabbit of Japan, left eye compares, passive Guan Bi 5 seconds, then clean with normal saline flushing, to observe after 24 hours, eyes are all without exception, according to eye irritation strength grading standard, eyes are belonged to non-stimulated material by this anophelifuge UV resistance finishing agent.

Claims (5)

1. anophelifuge UV resistance socks, it is characterised in that weaved by the raw material of following weight parts and form: 60-80wt% cotton fiber and 20-40wt% spandex.
Described anophelifuge UV resistance socks process step then through anophelifuge UV resistance and obtain.
It is impregnated in anophelifuge UV resistance finishing agent by described anophelifuge UV resistance socks that described anophelifuge UV resistance processes step, and described anophelifuge UV resistance finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part aloe essential oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.1-0.5 part Octabenzone, 0.1-0.5 part penetrating agent, 5-15 part ethanol, 0.1-0.5 part chelating agen, 95-105 part water.
Described penetrating agent is mixed by 40-60wt% aerosol OT and 40-60wt% tridecyl sodium sulfonate.
2. anophelifuge UV resistance socks as claimed in claim 1, it is characterised in that described chelating agen is mixed by 40-60wt% ethylene diamine tetra methylene phosphonic acid five sodium-salt and 40-60wt% ATMP five sodium-salt.
3. the preparation method of the anophelifuge UV resistance socks according to any one of claim 1-2, it is characterised in that comprise the following steps:
(1) conventional method is adopted cotton fiber and spandex to be weaved, be processed into socks;
(2) above-mentioned socks are carried out anophelifuge UV resistance process.
4. the preparation method of anophelifuge UV resistance socks according to claim 3, it is characterized in that, described step (2) is under 65-85 DEG C of condition, and socks impregnate 20-30min in anophelifuge UV resistance finishing agent, after dehydration, under 70-90 DEG C of condition, dry 5-10min.
5. the preparation method of anophelifuge UV resistance socks according to claim 4, it is characterized in that, described anophelifuge UV resistance finishing agent is made up of the raw material of following weight parts: 0.1-0.3 part aloe essential oil, 0.1-0.3 part oil of Cymbopogon winterianus, 0.1-0.5 part Octabenzone, 0.1-0.5 part penetrating agent, 5-15 part ethanol, 0.1-0.5 part chelating agen, 95-105 part water.
CN201610119440.8A 2016-03-03 2016-03-03 Mosquito repellent UV resistance socks and preparation method thereof Active CN105661666B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112281498A (en) * 2019-07-22 2021-01-29 新乡市护神特种织物有限公司 Ultraviolet-proof and mosquito-proof fabric and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102190591A (en) * 2010-03-12 2011-09-21 陈郁 Metal complex, preparation method and application thereof
CN104382242A (en) * 2014-12-10 2015-03-04 江南大学 Anti-flea knitted stocking
CN104499273A (en) * 2014-11-17 2015-04-08 浙江梦娜袜业股份有限公司 Mosquito-repelling and mite-resisting finishing agent for silk stockings and silk stocking production technology
CN105131174A (en) * 2015-08-20 2015-12-09 广东德美精细化工股份有限公司 Durable uvioresistant finishing agent applicable to both cotton and terylene and preparation method thereof
CN105200645A (en) * 2015-08-21 2015-12-30 沈汇明 Production process of woolen loose socks

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102190591A (en) * 2010-03-12 2011-09-21 陈郁 Metal complex, preparation method and application thereof
CN104499273A (en) * 2014-11-17 2015-04-08 浙江梦娜袜业股份有限公司 Mosquito-repelling and mite-resisting finishing agent for silk stockings and silk stocking production technology
CN104382242A (en) * 2014-12-10 2015-03-04 江南大学 Anti-flea knitted stocking
CN105131174A (en) * 2015-08-20 2015-12-09 广东德美精细化工股份有限公司 Durable uvioresistant finishing agent applicable to both cotton and terylene and preparation method thereof
CN105200645A (en) * 2015-08-21 2015-12-30 沈汇明 Production process of woolen loose socks

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112281498A (en) * 2019-07-22 2021-01-29 新乡市护神特种织物有限公司 Ultraviolet-proof and mosquito-proof fabric and preparation method thereof

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Effective date of registration: 20190710

Address after: 223600 Intelligent Knitting Industrial Park, Shuyang Economic and Technological Development Zone, Suqian City, Jiangsu Province (east of 205 National Road north of Youfu Road)

Patentee after: Jiangsu Southwest Intelligent Textile Co., Ltd.

Address before: 311825 Yuanxiang Government of Kengxi Village, Paitou Town, Zhuji City, Shaoxing City, Zhejiang Province

Patentee before: Xu Mengkui

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