CN105661266A - Method for simultaneously reducing production of acrylamide and 5-hydroxymethylfurfural in high-temperature processed foods - Google Patents

Method for simultaneously reducing production of acrylamide and 5-hydroxymethylfurfural in high-temperature processed foods Download PDF

Info

Publication number
CN105661266A
CN105661266A CN201610054084.6A CN201610054084A CN105661266A CN 105661266 A CN105661266 A CN 105661266A CN 201610054084 A CN201610054084 A CN 201610054084A CN 105661266 A CN105661266 A CN 105661266A
Authority
CN
China
Prior art keywords
acrylamide
odorant
temperature processed
microcapsule
hydroxymethyl furfural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610054084.6A
Other languages
Chinese (zh)
Other versions
CN105661266B (en
Inventor
石星波
温超
王紫梦
邓放明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Agricultural University
Original Assignee
Hunan Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Agricultural University filed Critical Hunan Agricultural University
Priority to CN201610054084.6A priority Critical patent/CN105661266B/en
Publication of CN105661266A publication Critical patent/CN105661266A/en
Application granted granted Critical
Publication of CN105661266B publication Critical patent/CN105661266B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Landscapes

  • General Preparation And Processing Of Foods (AREA)
  • Cosmetics (AREA)
  • Manufacturing Of Micro-Capsules (AREA)

Abstract

The invention relates to a method for simultaneously reducing production of acrylamide and 5-hydroxymethylfurfural in high-temperature processed foods. According to the method, flavor enhancer microcapsules in the shape of oval granules are prepared with a flavor enhancer used as a core material, a coating agent used as a wall material and ester used as an emulsifier, the granule size is 20-100 mu m, and the content of the accumulatively released flavor enhancer within 40 min is lower than 50%; under the high-temperature condition, the flavor enhancer microcapsules are added to a food system together with raw materials, the content of acrylamide and 5-hydroxymethylfurfural in the foods is monitored, and inhibition ratios are 20%-40% and 65%-90% respectively. With the adoption of the method, the flavor of the foods can be enhanced, the content of acrylamide and 5-hydroxymethylfurfural in the food system can be effectively and simultaneously reduced, and the method can be widely applied to multiple heat processed foods and has certain marketing value.

Description

A kind of method simultaneously reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food
Technical field
The present invention relates to a kind of food processing field, it is specifically related to a kind of method simultaneously reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food.
Background technology
Since Swedish National Food management board in 2002 proposes after acrylamide is extensively present in heated foods first, the security of heated foods causes the great attention of researcher within the scope of the world, and the thermal treatment of food is one manufacturing procedure indispensable in modern food technique. Food usually with the generation of Maillard reaction, and then generates the material of the such as poisonous and harmful such as acrylamide, 5 hydroxymethyl furfural in hot procedure.
In food hot procedure, strengthen the flavor characteristic of food often through odorants such as adding Sodium Glutamate, and then improve the local flavor of food. But, the odorants such as Sodium Glutamate, because of containing sodium ion, although the formation of acrylamide can be suppressed, can increase the content of 5 hydroxymethyl furfural in food significantly, and human body health is caused serious impact equally. Therefore studying food flavor enhancer to the impact of acrylamide and 5 hydroxymethyl furfural formation is a very valuable problem.
Microcapsulary is that one is embedded in biologically active substance in little capsule, control the technology of material core release rate within a certain period of time, have and improve that material is apparent and the ability of character, can reducing volatilization and the degraded of volatile active, it is widely used in foodstuffs industry and pharmaceutical industry. In food processing process, some biologically active substance, such as antioxidant, microorganism, VITAMIN etc. are added in food after being often made into microcapsule, to avoid it oxidized, rotten. The release function factor (such as, metal ion, antioxidant) that microcapsule energy is controlled, is expected to slow down Maillard reaction to the speed generating acrylamide and 5 hydroxymethyl furfural direction, plays the generation suppressing acrylamide and 5 hydroxymethyl furfural. Research finds, utilize microcapsulary parcel sodium-chlor can suppress the generation of 5 hydroxymethyl furfural to a certain extent, but this kind of method sodium-chlor addition is big, and then affect the quality of food, and people cannot be met to the pursuit of the fresh taste of food, therefore cannot commercially promote.
Summary of the invention
It is an object of the invention to provide a kind of method simultaneously reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food.
For reaching above-mentioned purpose, the technical solution adopted in the present invention is: a kind of method simultaneously reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food, the method is in the course of processing of high-temperature processed food, adding odorant microcapsule in raw material, the addition of these odorant microcapsule is the 0.001%-5% of raw material weight; Wherein, above-mentioned odorant microcapsule are take odorant as core, fruit glaze agent is wall material, ester class is made for emulsifying agent; By weight, the amount of each raw material is odorant 1-3 part, fruit glaze agent 1-6 part, emulsifying agent 1-3 part.
Above-mentioned odorant is one or more in Sodium Glutamate, 5'-GMP2Na, IMP or disodium succinate.
Above-mentioned fruit glaze agent is one or more in carnauba wax, beeswax, fruit wax, lac or chitosan.
Mentioned emulsifier is one or more in glyceryl monostearate, Polyglycerine monostearate, propylene glycolmonostearate, citric acid glyceryl monostearate or single lactic acid diglyceride.
Raw material is added with when described odorant microcapsule make the ultrapure water of 100-300 part weight. The concrete making processes of these odorant microcapsule is: gets odorant, fruit glaze agent and emulsifying agent by weight and stirs even, dissolve with the heating temperatures lower than 60 DEG C after adding ultrapure water again, the water-bath of 60 DEG C adopt high-speed shearing emulsion machine with the rotating speed emulsification 30min of 19000rpm/min, mixing solutions is made to become uniform milk sap, again with spraying dry or freeze-drying, obtain odorant microcapsule.
Above-mentioned obtained odorant microcapsule are oval particle, and its particle diameter is 20-100 μm, and in this odorant microcapsule 40min, the content of cumulative release odorant is less than 50%.
Hot conditions in the above-mentioned high-temperature processed food mentioned is that processing temperature is higher than 80 DEG C. This high-temperature processed food is the food being rich in carbohydrate, comprise taking face, ground rice as process raw material processed food, such as biscuit, bread, deep-fried twisted dough sticks etc.
The odorant microcapsule of the present invention add together with food raw material in high-temperature processed food, after interpolation, can the content of toxic substance acrylamide and 5 hydroxymethyl furfural in reduction system simultaneously effectively, its inhibiting rate is respectively 20-40% and 65-90%, show, these odorant microcapsule can be widely used in multiple heated foods, has certain market popularization value.
Tool of the present invention has the following advantages: the present invention adds odorant microcapsule in high-temperature processed food, can not only effectively suppress the generation of acrylamide and 5 hydroxymethyl furfural simultaneously, moreover it is possible to strengthen the look of food, perfume (or spice), taste well, especially fresh taste; Can be widely used in the food-processings such as biscuit, potato chips, bread, deep-fried twisted dough sticks.
Accompanying drawing explanation
Figure 1A and Figure 1B is the aspect graph of Sodium Glutamate microcapsule.
Fig. 2 is the typical curve utilizing conductometric titration to measure concentration of sodium glutamate.
Fig. 3 is the dissolving situations of Sodium Glutamate microcapsule in ultrapure water, i.e. sustained release performance.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described in further detail.
Following examples only for illustration of the present invention, but not in order to limit the scope of the invention. If not indicating especially, the conventional means that technique means used in embodiment is well known to those skilled in the art, raw materials used is commercial goods.
Embodiment 1
Take Sodium Glutamate as core, palm wax be wall material, glyceryl monostearate be emulsifying agent, make Sodium Glutamate microcapsule; Taking the homogeneity of Sodium Glutamate microcapsule granularity and slow release effect as the quality of benchmark measurement microcapsule, under the high temperature conditions, Sodium Glutamate microcapsule replace Sodium Glutamate be added in biscuit making.
Specific operation process is as follows:
1, Sodium Glutamate microcapsule are made: take 2 parts of Sodium Glutamates, 4 parts of palm waxs, 1 part of glyceryl monostearate by weight, add 200 parts of ultrapure water post-heating to dissolve, with high-speed shearing emulsion machine with the rotating speed emulsification 30min of 19000rpm/min in the water-bath of 60 DEG C, mixing solutions is made to become uniform milk sap, inlet temperature be 180 DEG C, temperature out is 35 DEG C and carries out spraying dry, obtained Sodium Glutamate microcapsule when input speed is 60mL/h.
2, the detection of microencapsulated forms and particle diameter: detecting microencapsulated forms and particle diameter by scanning electronic microscope, see Figure 1A and Figure 1B, result shows: microcapsule are oval particle, and its size distribution is at 20-100 μm.
3, the mensuration of sustained release performance:
With conductivity meter detect 0.5000 respectively, 1.0000,1.5000,2.0000,2.5000mmol/L, and be X-coordinate taking concentration of sodium glutamate, corresponding specific conductivity is ordinate zou production standard curve, sees Fig. 2.
The battery lead rod of conductivity meter is immersed in 10.8mL ultrapure water, 0.0030g Sodium Glutamate and 0.0105g Sodium Glutamate microcapsule (containing 0.0030g Sodium Glutamate) are added respectively to being equipped with in the beaker of ultrapure water, it is made to dissolve 40min with the rotating speed of 400rpm/min under constant temperature 14-16 DEG C of condition, timing adding from sample, count a specific conductivity at regular intervals, and the concentration of Sodium Glutamate in calculating solution at this very moment. As shown in Figure 3, when slow-release time continues to 40min, concentration of sodium glutamate is only 0.723mmol/L to result, and its cumulative release amount is only 49.66%.
4, the impact that acrylamide and 5 hydroxymethyl furfural in biscuit generate content and formed is investigated:
Build biscuit simulated system: take materials of wheat powder 1-5 part, mealy potato 1-2 part, edible oil 1-2 part, water 2-4 part, glucose 0.5-2 part and Sodium Glutamate microcapsule 0.05-0.25 part by weight, mixed even, rub and become dough in 3-6 minute; After the first one-step forming of dough base, proof 10-15 minute, compression molding; Utilize 180 DEG C of baking boxs baking 5-12min, biscuit.
The Instrument measuring such as high performance liquid chromatography or LC-MS is utilized to add the growing amount of acrylamide and 5 hydroxymethyl furfural in biscuit. Result shows, after Maillard reaction simulated system adds the Sodium Glutamate microcapsule of different concns, different Sodium Glutamate microcapsule addition inhibitions is different, but can produce to suppress to acrylamide and 5 hydroxymethyl furfural, and inhibiting rate is respectively 20-40% and 65-90%.
Embodiment 2
Take 1 part of 5'-GMP2Na, 1 part of chitosan and 1 part of single lactic acid diglyceride by weight, add 100 parts of ultrapure waters, by the obtained odorant microcapsule of the method in embodiment 1, but during last shaping, adopt freeze-drying. Being added to by the addition for raw material weight 0.5% by obtained microcapsule in the processing and fabricating of potato chips, detected by the finished product being processed into, result shows, and the inhibiting rate of acrylamide and 5 hydroxymethyl furfural is respectively 32.4% and 86.1%.
Embodiment 3
Take 3 parts of disodium succinates, 6 parts of beeswaxs and 3 parts of Polyglycerine monostearates by weight, add 300 parts of ultrapure waters, by the obtained odorant microcapsule of the method in embodiment 1.Being added to by the addition for raw material weight 0.8% by obtained microcapsule in the processing and fabricating of bread, detected by the finished product being processed into, result shows, and the inhibiting rate of acrylamide and 5 hydroxymethyl furfural is respectively 36.7% and 87.5%.
Embodiment 4
Take 2 parts of IMPs, 5 portions of lacs and 2 parts of citric acid glyceryl monostearates by weight, add 250 parts of ultrapure waters, by the obtained odorant microcapsule of the method in embodiment 1. Being added to by the addition for raw material weight 0.3% by obtained microcapsule in the processing and fabricating of deep-fried twisted dough sticks, detected by the finished product being processed into, result shows, and the inhibiting rate of acrylamide and 5 hydroxymethyl furfural is respectively 27.3% and 75.7%.

Claims (9)

1. one kind is reduced the method that in high-temperature processed food, acrylamide and 5 hydroxymethyl furfural generate simultaneously, it is characterized in that: the method is in the course of processing of high-temperature processed food, adding odorant microcapsule in raw material, the addition of these odorant microcapsule is the 0.001%-5% of raw material weight;
Wherein, above-mentioned odorant microcapsule are take odorant as core, fruit glaze agent is wall material, ester class is made for emulsifying agent; By weight, the amount of each raw material is odorant 1-3 part, fruit glaze agent 1-6 part, emulsifying agent 1-3 part.
2. a kind of as claimed in claim 1 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterised in that, raw material is added with when described odorant microcapsule make the ultrapure water of 100-300 part weight.
3. a kind of as claimed in claim 1 or 2 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterized in that, described odorant is one or more in Sodium Glutamate, 5'-GMP2Na, IMP or disodium succinate.
4. a kind of as claimed in claim 1 or 2 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterised in that, described fruit glaze agent is one or more in carnauba wax, beeswax, fruit wax, lac or chitosan.
5. a kind of as claimed in claim 1 or 2 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterized in that, described emulsifying agent is one or more in glyceryl monostearate, Polyglycerine monostearate, propylene glycolmonostearate, citric acid glyceryl monostearate or single lactic acid diglyceride.
6. a kind of as claimed in claim 1 or 2 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterised in that, described odorant microcapsule are oval particle, and its particle diameter is 20-100 μm.
7. a kind of as claimed in claim 1 or 2 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterised in that, in described odorant microcapsule 40min, the content of cumulative release odorant is less than 50%.
8. a kind of as claimed in claim 1 or 2 reduce the method that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed food simultaneously, it is characterised in that, the hot conditions in described high-temperature processed food is that temperature is higher than 80 DEG C.
9. as claim 1 or 2 state a kind of reduce the methods that acrylamide and 5 hydroxymethyl furfural generate in high-temperature processed foods simultaneously, it is characterised in that, described food is the food being rich in carbohydrate.
CN201610054084.6A 2016-01-27 2016-01-27 Method that is a kind of while reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food Expired - Fee Related CN105661266B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610054084.6A CN105661266B (en) 2016-01-27 2016-01-27 Method that is a kind of while reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610054084.6A CN105661266B (en) 2016-01-27 2016-01-27 Method that is a kind of while reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food

Publications (2)

Publication Number Publication Date
CN105661266A true CN105661266A (en) 2016-06-15
CN105661266B CN105661266B (en) 2019-07-09

Family

ID=56303160

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610054084.6A Expired - Fee Related CN105661266B (en) 2016-01-27 2016-01-27 Method that is a kind of while reducing acrylamide and 5 hydroxymethyl furfural generation in high-temperature processed food

Country Status (1)

Country Link
CN (1) CN105661266B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108013407A (en) * 2017-11-30 2018-05-11 江南大学 A kind of method of acrylamide and 5 hydroxymethyl furfural content in reduction potato chips
CN109691627A (en) * 2018-11-13 2019-04-30 浙江工业大学 A method of reducing frying process Acrylamide in Foods and fat content
CN111557324A (en) * 2020-05-20 2020-08-21 南昌大学 Butter crisp biscuit and preparation method thereof
CN114041554A (en) * 2021-10-28 2022-02-15 南昌大学 Production method for reducing 5-hydroxymethylfurfural in fried potato chips
CN114931202A (en) * 2022-04-21 2022-08-23 东莞思朗食品有限公司 Method for reducing glyoxal and formaldehyde in food, adduct generated by method and detection method
CN115568488A (en) * 2022-09-07 2023-01-06 南昌大学 Method for simultaneously reducing acrylamide and 5-hydroxymethyl furfural content in baked biscuits

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1927050A (en) * 2006-09-18 2007-03-14 汕头市润科生物工程有限公司 DHA microcapsule food additives, DHA soft capsule health product and uses thereof
CN100998587A (en) * 2006-01-11 2007-07-18 中国医学科学院药物研究所 Application of 5-hydroxy furfurol for preparing medicine

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100998587A (en) * 2006-01-11 2007-07-18 中国医学科学院药物研究所 Application of 5-hydroxy furfurol for preparing medicine
CN1927050A (en) * 2006-09-18 2007-03-14 汕头市润科生物工程有限公司 DHA microcapsule food additives, DHA soft capsule health product and uses thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ALBERTO FIORE等: "Controlling the Maillard Reaction by Reactant Encapsulation: Sodium Chloride in Cookies", 《JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY》 *
刘钟栋等主编: "《食品添加剂》", 30 April 2015, 郑州大学出版社 *
蔡芸: "几种添加剂和豆粉对Maillard体系中丙烯酰胺和羟甲基糠醛形成的影响", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108013407A (en) * 2017-11-30 2018-05-11 江南大学 A kind of method of acrylamide and 5 hydroxymethyl furfural content in reduction potato chips
CN109691627A (en) * 2018-11-13 2019-04-30 浙江工业大学 A method of reducing frying process Acrylamide in Foods and fat content
CN111557324A (en) * 2020-05-20 2020-08-21 南昌大学 Butter crisp biscuit and preparation method thereof
CN114041554A (en) * 2021-10-28 2022-02-15 南昌大学 Production method for reducing 5-hydroxymethylfurfural in fried potato chips
CN114931202A (en) * 2022-04-21 2022-08-23 东莞思朗食品有限公司 Method for reducing glyoxal and formaldehyde in food, adduct generated by method and detection method
CN115568488A (en) * 2022-09-07 2023-01-06 南昌大学 Method for simultaneously reducing acrylamide and 5-hydroxymethyl furfural content in baked biscuits
CN115568488B (en) * 2022-09-07 2024-02-09 南昌大学 Method for simultaneously reducing acrylamide and 5-hydroxymethylfurfural content in baked biscuits

Also Published As

Publication number Publication date
CN105661266B (en) 2019-07-09

Similar Documents

Publication Publication Date Title
CN105661266A (en) Method for simultaneously reducing production of acrylamide and 5-hydroxymethylfurfural in high-temperature processed foods
Kurozawa et al. Effect of carrier agents on the physicochemical properties of a spray dried chicken meat protein hydrolysate
CN102625715B (en) Seamless alginate capsules
Bag et al. Optimization of process parameters for foaming of bael (Aegle marmelos L.) fruit pulp
Rayo et al. Production of instant green banana flour (Musa cavendischii, var. Nanicão) by a pulsed-fluidized bed agglomeration
Rocha et al. Drying of tropical fruit pulps: Spouted bed process optimization as a function of pulp composition
CN104054849A (en) High-content medium chain triglyceride powdered oil and preparation method thereof
CN101410175B (en) Method for preparing microcapsules by coacervation
CN104206561A (en) Preparation process of peony seed oil micro-capsule powder
Tan et al. Alginate/starch composites as wall material to achieve microencapsulation with high oil loading
Yousefi et al. Developing spray-dried powders containing anthocyanins of black raspberry juice encapsulated based on fenugreek gum
Shavakhi et al. Effects of enzymatic liquefaction, maltodextrin concentration, and spray-dryer air inlet temperature on pumpkin powder characteristics
CN105285559A (en) Processing method of instant Chinese yam rhizome powder
JP4733040B2 (en) Edible products containing flavored microcapsules
Cai et al. Controlling sodium release using maltodextrin and octenyl‐succinic‐anhydride‐modified starch with two types of spray‐dryer nozzles
US11478004B2 (en) Process for making a bouillon tablet or bouillon cube
CN106577935A (en) Making method of cookie with rich macadamia nuts
CN105394746B (en) A kind of preparation process of spicy golden mushroom
CN104397213A (en) Pine nut oil microcapsule and preparation method thereof
CN105533011A (en) Ginkgo fruit tea production process
JP5956285B2 (en) Granule soy sauce manufacturing method and granule soy sauce
CN105533428B (en) Freshwater mussel vermicelli and preparation method thereof
JPH03131338A (en) Preparation of spherical particle
CN101971989A (en) Preparation method for microencapsulating coixenolid
CN106732220B (en) A method of improving liposome high ionic strength stability inferior

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20190709

Termination date: 20220127