CN105650175A - Composite whisker-contained granule with high-temperature recession resistance function and preparation method thereof - Google Patents

Composite whisker-contained granule with high-temperature recession resistance function and preparation method thereof Download PDF

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Publication number
CN105650175A
CN105650175A CN201510720113.3A CN201510720113A CN105650175A CN 105650175 A CN105650175 A CN 105650175A CN 201510720113 A CN201510720113 A CN 201510720113A CN 105650175 A CN105650175 A CN 105650175A
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China
Prior art keywords
weight part
preparation
barium sulfate
high temperature
potassium titanate
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CN201510720113.3A
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Chinese (zh)
Inventor
郑辉
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HENGYANG ANPIN AUTOMOBILE FITTINGS CO Ltd
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HENGYANG ANPIN AUTOMOBILE FITTINGS CO Ltd
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Publication of CN105650175A publication Critical patent/CN105650175A/en
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Abstract

The invention discloses a whisker-contained granule with high-temperature recession resistance function and a preparation method thereof. A formula in the method comprises Nakaifu fibers, cryolite, magnetite powder, antimony sulfide, barium sulfate, F826 adhesive and potassium hexatitanate whiskers. The preparation method comprises the following steps: the raw materials are uniformly mixed by the formula, are fed in a double-roller rubber open mill for smelting, and are molten and plastified; and finally, the plastified materials are crushed to particles with particle sizes of 8-20 meshes to obtain the composite whisker-contained granule. The hardness and the compactness (density) of a friction piece can be effectively reduced to reduce the noise generated in braking; meanwhile, the friction coefficient of the friction piece at high temperature is increased; the performance is stable; the vehicle high-temperature braking stability is guaranteed; and such problems as film transfer, environmental protection, noise and ash falling are solved.

Description

A kind of have high temperature anti-ageing move back function must particulate material and its preparation method containing composite crystal
Technical field
The present invention relates to the material of friction plate in a kind of automobile brake sheet and its preparation method, particularly a kind of have high temperature anti-ageing move back function must particulate material and its preparation method containing composite crystal.
Background technology
Breaking system is one of security system the most important on automobile, and brake facing is the parts that to have suffered in breaking system important, it can directly have influence on the reliability of whole breaking system, breaking system defines friction pair by brake facing and brake flange phase mutual friction, produce braking moment, the kinetic energy of automobile is converted into heat energy, and temperature during braking can rise to 300��400 DEG C.
Conventional brake facing is divided into:
1, semi-metal type, main adopts coarse Steel Wool as the big mixture of reinforced fibers and important frictional coefficient, and major advantage is to adapt to normal operation at relatively high temperatures, but noise is too big, and the wear rate of brake flange is bigger;
2, without asbestos organic type, mainly with glass fibre, aromatic polyester fiber and other fibers as reinforcement material, its performance depends primarily on type and other mixture of fiber, and advantage is that shortcoming is that wear resistance and heat resistance are not strong without the ash fouling that falls, feature that noise is little.
The innovative point of application novel material is to utilize crystal whisker of hexa potassium titanate in friction process to the reflex action of energy and the generation of transfer film, thus ensure the stability of brake facing frictional coefficient, conventional asbestos friction material just there will be performance degradation phenomenon when 230 DEG C, and crystal whisker of hexa potassium titanate also there will not be performance degradation phenomenon when 350 DEG C, stable frictional behaviour still can be maintained. Noise is the most insoluble problem of all friction materials manufacturers always, crystal whisker of hexa potassium titanate makes it constantly form displacement membrane due to the molecular structure of its material uniqueness, the brake facing being made up of it is not only without high frequency noise, and substantially solve the problem of low frequency noise, potassium hexatitanate stable chemical performance, nontoxic, human security can not be injured, do not pollute the environment.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, and provide a kind of have high temperature anti-ageing move back function must particulate material containing composite crystal. Improve the heat fading performance of existing friction plate, and provide a kind of composite crystal must using method in formula.
The technical scheme realizing above-mentioned purpose of the present invention is: a kind of have high temperature anti-ageing move back function containing composite crystal must particulate material, it is adopted and is prepared from the following method:
Formula includes: Na Kaifu fiber 20��30 weight part, sodium aluminum fluoride 10��15 weight part, magnetite powder 25��30 weight part, antimony sulfide 3��6 weight part, barium sulfate 10��15 weight part, F826 sizing agent 8��15 weight part, crystal whisker of hexa potassium titanate 20��25 weight part.
Step of preparation process is as follows:
The first step: the group part and the respective weight part number that contain by material are prepared burden;
2nd step: mixed by raw material, drops into two rod rubber mixing mill and carries out melting, make raw materials melt and plastify, and its roller surface temperature is 50��60 DEG C; Smelting time is 20��30min;
3rd step: become particle diameter to be 8��20 object particles the material disintegrating after plasticizing.
The further technical scheme of the present invention is:
Formula includes: Na Kaifu fiber 20 weight part, sodium aluminum fluoride 10 weight part, magnetite powder 25 weight part, antimony sulfide 3 weight part, barium sulfate 10 weight part, F826 sizing agent 8 weight part, crystal whisker of hexa potassium titanate 20 weight part.
The present invention further technical scheme be:
Formula includes: Na Kaifu fiber 30 weight part, sodium aluminum fluoride 15 weight part, magnetite powder 30 weight part, antimony sulfide 6 weight part, barium sulfate 15 weight part, F826 sizing agent 15 weight part, crystal whisker of hexa potassium titanate 25 weight part.
The two of the object of the present invention are the above-mentioned deficiencies overcoming prior art, and provide a kind of and have the anti-ageing preparation method containing composite crystal palpus particulate material moving back function of high temperature.
The technical scheme realizing above-mentioned purpose of the present invention is: a kind of have the anti-ageing preparation method containing composite crystal palpus particulate material moving back function of high temperature,
Formula includes: Na Kaifu fiber 20��30 weight part, sodium aluminum fluoride 10��15 weight part, magnetite powder 25��30 weight part, antimony sulfide 3��6 weight part, barium sulfate 10��15 weight part, F826 sizing agent 8��15 weight part, crystal whisker of hexa potassium titanate 20��25 weight part;
Step of preparation process is as follows:
The first step: the group part and the respective weight part number that contain by material are prepared burden;
2nd step: mixed by raw material, drops into two rod rubber mixing mill and carries out melting, make raw materials melt and plastify, and its roller surface temperature is 50��60 DEG C; Smelting time is 20��30min;
3rd step: become particle diameter to be 8��20 object particles the material disintegrating after plasticizing.
The further technical scheme of the present invention is:
Formula includes: Na Kaifu fiber 20 weight part, sodium aluminum fluoride 10 weight part, magnetite powder 25 weight part, antimony sulfide 3 weight part, barium sulfate 10 weight part, F826 sizing agent 8 weight part, crystal whisker of hexa potassium titanate 20 weight part.
The present invention further technical scheme be:
Formula includes: Na Kaifu fiber 30 weight part, sodium aluminum fluoride 15 weight part, magnetite powder 30 weight part, antimony sulfide 6 weight part, barium sulfate 15 weight part, F826 sizing agent 15 weight part, crystal whisker of hexa potassium titanate 25 weight part.
The present invention is compared with prior art, there is following feature: the present invention can effectively reduce hardness and the degree of compactness (density) of friction plate, friction plate is made operationally to absorb the noise produced when contacting with brake flange, thus the noise produced when reducing braking, meanwhile, the frictional coefficient of friction plate when high temperature is increased, stable performance, ensure that the stability of automobile high-temperature brake, and solve transfer film problem and environmental protection, noise, fall ash etc. problem.
Below in conjunction with embodiment, content of the present invention is further described.
Embodiment
Embodiment 1
Have high temperature anti-ageing move back function containing composite crystal must a particulate material, it is adopted and is prepared from the following method:
Formula comprises: Na Kaifu fiber 20 weight part, sodium aluminum fluoride 10 weight part, magnetite powder 25 weight part, antimony sulfide 3 weight part, barium sulfate 10 weight part, F826 sizing agent 8 weight part, crystal whisker of hexa potassium titanate 20 weight part;
Its step of preparation process is as follows:
The first step: the group part and the respective weight part number that contain by material are prepared burden;
2nd step: mixed by raw material, drops into two rod rubber mixing mill and carries out melting, make raw materials melt and plastify, and its roller surface temperature is 50��60 DEG C; Smelting time is 20��30min;
3rd step: become particle diameter to be 8��20 object particles the material disintegrating after plasticizing.
Embodiment 2
Have high temperature anti-ageing move back function containing composite crystal must a particulate material, it is adopted and is prepared from the following method:
Formula comprises: Na Kaifu fiber 30 weight part, sodium aluminum fluoride 15 weight part, magnetite powder 30 weight part, antimony sulfide 6 weight part, barium sulfate 15 weight part, F826 sizing agent 15 weight part, crystal whisker of hexa potassium titanate 25 weight part;
Its preparation technology is identical with embodiment 1.
Embodiment 3
A kind of have the anti-ageing preparation method containing composite crystal palpus particulate material moving back function of high temperature, its formula comprises: Na Kaifu fiber 20 weight part, sodium aluminum fluoride 10 weight part, magnetite powder 25 weight part, antimony sulfide 3 weight part, barium sulfate 10 weight part, F826 sizing agent 8 weight part, crystal whisker of hexa potassium titanate 20 weight part;
Its step of preparation process is as follows:
The first step: the group part and the respective weight part number that contain by material are prepared burden;
2nd step: mixed by raw material, drops into two rod rubber mixing mill and carries out melting, make raw materials melt and plastify, and its roller surface temperature is 50��60 DEG C; Smelting time is 20��30min;
3rd step: become particle diameter to be 8��20 object particles the material disintegrating after plasticizing.
Embodiment 4
A kind of have the anti-ageing preparation method containing composite crystal palpus particulate material moving back function of high temperature, its formula comprises: Na Kaifu fiber 30 weight part, sodium aluminum fluoride 15 weight part, magnetite powder 30 weight part, antimony sulfide 6 weight part, barium sulfate 15 weight part, F826 sizing agent 15 weight part, crystal whisker of hexa potassium titanate 25 weight part;
Its preparation technology is identical with embodiment 3.
The above embodiment is only the better embodiment enumerated for absolutely proving the present invention, and protection scope of the present invention is not limited to this. The equivalent replacement that those skilled in the art do on basis of the present invention or conversion, all within protection scope of the present invention.

Claims (6)

1. have high temperature anti-ageing move back function containing composite crystal must a particulate material, it is characterized in that adopting and be prepared from the following method:
Formula includes: Na Kaifu fiber 20��30 weight part, sodium aluminum fluoride 10��15 weight part, magnetite powder 25��30 weight part, antimony sulfide 3��6 weight part, barium sulfate 10��15 weight part, F826 sizing agent 8��15 weight part, crystal whisker of hexa potassium titanate 20��25 weight part;
Step of preparation process is as follows:
The first step: the group part and the respective weight part number that contain by material are prepared burden;
2nd step: mixed by raw material, drops into two rod rubber mixing mill and carries out melting, make raw materials melt and plastify, and its roller surface temperature is 50��60 DEG C; Smelting time is 20��30min;
3rd step: become particle diameter to be 8��20 object particles the material disintegrating after plasticizing.
2. according to claim 1 a kind of have high temperature anti-ageing move back function must particulate material containing composite crystal, it is characterized in that formula includes: Na Kaifu fiber 20 weight part, sodium aluminum fluoride 10 weight part, magnetite powder 25 weight part, antimony sulfide 3 weight part, barium sulfate 10 weight part, F826 sizing agent 8 weight part, crystal whisker of hexa potassium titanate 20 weight part.
3. according to claim 1 a kind of have high temperature anti-ageing move back function must particulate material containing composite crystal, it is characterized in that formula includes: Na Kaifu fiber 30 weight part, sodium aluminum fluoride 15 weight part, magnetite powder 30 weight part, antimony sulfide 6 weight part, barium sulfate 15 weight part, F826 sizing agent 15 weight part, crystal whisker of hexa potassium titanate 25 weight part.
4. one kind has the anti-ageing preparation method containing composite crystal palpus particulate material moving back function of high temperature, it is characterized in that formula includes: Na Kaifu fiber 20��30 weight part, sodium aluminum fluoride 10��15 weight part, magnetite powder 25��30 weight part, antimony sulfide 3��6 weight part, barium sulfate 10��15 weight part, F826 sizing agent 8��15 weight part, crystal whisker of hexa potassium titanate 20��25 weight part;
Step of preparation process is as follows:
The first step: the group part and the respective weight part number that contain by material are prepared burden;
2nd step: mixed by raw material, drops into two rod rubber mixing mill and carries out melting, make raw materials melt and plastify, and its roller surface temperature is 50��60 DEG C; Smelting time is 20��30min;
3rd step: become particle diameter to be 8��20 object particles the material disintegrating after plasticizing.
5. according to claim 4 a kind of have high temperature anti-ageing move back function must the preparation method of particulate material containing composite crystal, it is characterized in that formula includes: Na Kaifu fiber 20 weight part, sodium aluminum fluoride 10 weight part, magnetite powder 25 weight part, antimony sulfide 3 weight part, barium sulfate 10 weight part, F826 sizing agent 8 weight part, crystal whisker of hexa potassium titanate 20 weight part.
6. according to claim 4 a kind of have high temperature anti-ageing move back function must the preparation method of particulate material containing composite crystal, it is characterized in that formula includes: Na Kaifu fiber 30 weight part, sodium aluminum fluoride 15 weight part, magnetite powder 30 weight part, antimony sulfide 6 weight part, barium sulfate 15 weight part, F826 sizing agent 15 weight part, crystal whisker of hexa potassium titanate 25 weight part.
CN201510720113.3A 2014-11-30 2015-10-30 Composite whisker-contained granule with high-temperature recession resistance function and preparation method thereof Withdrawn CN105650175A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410704030 2014-11-30
CN2014107040300 2014-11-30

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CN105650175A true CN105650175A (en) 2016-06-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114341308A (en) * 2019-08-23 2022-04-12 株式会社爱德克斯 Friction material and friction material composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114341308A (en) * 2019-08-23 2022-04-12 株式会社爱德克斯 Friction material and friction material composition
CN114341308B (en) * 2019-08-23 2023-10-13 株式会社爱德克斯 Friction material and friction material composition

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Application publication date: 20160608