CN105649828B - Application method on alcohols hydrogen production from catalytic pyrolysis device and its liquid fuel within automobile - Google Patents

Application method on alcohols hydrogen production from catalytic pyrolysis device and its liquid fuel within automobile Download PDF

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CN105649828B
CN105649828B CN201610183258.9A CN201610183258A CN105649828B CN 105649828 B CN105649828 B CN 105649828B CN 201610183258 A CN201610183258 A CN 201610183258A CN 105649828 B CN105649828 B CN 105649828B
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alcohols
catalyst
hydrogen
engine
reaction chamber
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CN105649828A (en
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张树
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/10Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone
    • F02M25/12Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone the apparatus having means for generating such gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N5/00Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy
    • F01N5/02Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy the devices using heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/02Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Abstract

A kind of application method on alcohols hydrogen production from catalytic pyrolysis device and its liquid fuel within automobile, inlet manifold interface in the device is positioned close on the side wall of outer shell of economizer bank, outlet manifold interface is positioned close on the side wall of outer shell of reaction chamber, at least one the first exhaust gas channel separated with catalyst seal is provided in catalyst between inlet manifold interface and outlet manifold interface, reaction chamber bottom is equipped with alcohols injector, the hydrogen and carbon monoxide decomposited successively passes through check valve, enter at each cylinder inlet manifold inlet valve of engine after air accumulator and multiple solenoid valves.The present invention can increase the contact area of tail gas and catalyst; improve tail gas heat quantity utilization rate; it preferably utilizes, guard catalyst; extend catalyst service life; improve combustion position of the engine in starting heating, idle running; so that the amount of the hydrogen entered at each cylinder inlet manifold inlet valve of engine is changed with the variation of engine operating condition, realizes the optimum proportioning of hydrogen and fuel.

Description

Application method on alcohols hydrogen production from catalytic pyrolysis device and its liquid fuel within automobile
Technical field:
The present invention relates to Technology for Production Hydrogen from Methanol fields, are especially a kind of small-sized automatically controlled double heat source alcohols hydrogen production from catalytic pyrolysis Application method on device and its liquid fuel within automobile.
Background technique:
Hydrogen is current most light molecule, it exists in a manner of compound in nature.It can be discharged when hydrogen is with oxygen chemical combination Big energy out.Hydrogen is easy to uniformly mix with air, and inflammability limit is 4.1~75%, and maximum flame propagation velocity is 291cm/s, maximum flame propagation velocity are 7.72 times of gasoline.Use hydrogen and gasoline, diesel oil, natural gas mixed, meeting band Carry out the improvement that economy, dynamic property and engine distribute performance, the burning velocity of reason hydrogen is fast, and crude fuel mixes certain proportion Hydrogen after, the rapid combustion period of fuel can be greatly shortened, increase efficiency of combustion.After hydrogen is added especially in diesel engine, by Very wide (4.1~75%) in the inflammability limit of hydrogen, internal cylinder temperature once reaches its ignition temperature, hydrogen just ignition. Since the flame propagation velocity of hydrogen is more faster than diesel oil, one combust of diesel oil is pushed, improves cylinder endogenous fire flame propagation velocity, Fuel faster burns, and shortens diesel engine rapid combustion period.In this period, due to increased flame speeds, the fuel of consumption is also than original It is next more, decline the combustion mixture concentration of ormal combustion period, reduce the quantity of diesel oil under anoxia condition, reduce gas oil pyrolysis, produces The factor of raw free carbon.Ormal combustion period shortens, and destroys the condition of soot (PM2.5) formation, can significantly reduce diesel oil hair The particulate emission of motivation.Suitable incorporation hydrogen, the characteristic that diesel engine can be kept original may also reach up no particulate matter Discharge.Currently, the hydrogen production process majority of the prior art uses alcohols cracking hydrogen production method, such as methanol or ethyl alcohol, they be carbon, The compound of hydrogen, oxygen can resolve into hydrogen (H in the case where heating, decompression, catalysis2) and carbon monoxide (CO).
The Authorization Notice No. that the applicant has applied is that the patent of invention of CN1111647C discloses a kind of reduction diesel oil hair The method and its smoke purification equipment of motivation soot are mainly characterized by the confession using Vehicular exhaust and low-voltage electric heating Heat makes alcohols catalytic pyrolysis obtain hydrogen (H2) and carbon monoxide (CO), so as to economy, diesel oil is easily greatly lowered Engine soot generation reaches low-carbon cigarette, or even without soot emissions, and reduces NO simultaneouslyxDischarge.
However pass through constantly practice for many years, it has been found that there are two defects for the smoke purification equipment: 1, entering alcohol The contact area of the catalyst in motor exhaust and reaction chamber in class cracking reaction room is fewer, i.e. the heat-absorbent surface of catalyst Product is smaller, to reduce the utilization rate of engine tail gas heat quantity;2, the methanol for carrying out catalytic pyrolysis is needed in original device is Work by methanol pump in methanol tank from being quantitatively pumped into methanol decomposition reaction chamber, since quantity of methyl alcohol is not to supply as needed Give, therefore the ability of catalyst is not fully utilized, can not preferably guard catalyst, eventually lead to shortening catalyst Service life.
At the same time, it has been found that original reduce engine soot generation method there is also following two defects: 1, it is known that Combustion position of the engine in starting heating, idle running is very poor, and discharge amount is big, and original method only passes through a pressure balance Tank and a solenoid valve are by the hydrogen of former smoke purification equipment and carbon monoxide exhaust outlet and motor intake manifold manifold entrance Place's connection, the volume very little of pressure balancing tank only serve the effect that pressure is balanced when air inlet, do not store hydrogen substantially, therefore should Method is unable to improve combustion position of the engine in starting heating, idle running;2, original method by hydrogen and carbon monoxide only It is introduced at motor intake manifold manifold entrance, therefore enters the hydrogen and an oxygen at each cylinder inlet manifold inlet valve of engine Changing carbon sendout, there are biggish differences.
Summary of the invention:
The technical problem to be solved by the present invention is to provide and a kind of be not only able to effectively increase motor exhaust and catalyst Contact area improves the utilization rate of engine tail gas heat quantity, and can preferably utilize the ability of catalyst, preferably protects Catalyst extends the alcohols hydrogen production from catalytic pyrolysis device of the service life of catalyst.
The invention solves another technical problem be to provide a kind of alcohols hydrogen production from catalytic pyrolysis device liquid fuel within Application method on automobile, this method not only can preferably improve burning shape of the engine in starting heating, idle running Condition, and can also make to enter the amount of the hydrogen and carbon monoxide at each cylinder inlet manifold inlet valve of engine convenient for quantitative control It can change with the variation of engine operating condition, to realize the optimum proportioning of hydrogen and fuel.
The technical solution of the invention is as follows, provides a kind of alcohols hydrogen production from catalytic pyrolysis device having following structure, it Including inlet manifold interface, outlet manifold interface, the shell with insulating layer, the reaction chamber filled with catalyst, it is placed in shell The interior and economizer bank being connected to reaction chamber bottom and the electric heater and temperature sensor that are placed in catalyst, cover top portion are set There is the alcohols entrance for connecting and communicating with economizer bank, the cover top portion above reaction chamber is equipped with ring flange and lid connected to it Plate, cover board are equipped with exhaust outlet, the wiring outlet of electric heater and the outlet of temperature sensor, wherein inlet manifold interface is set It sets on the side wall of outer shell close to economizer bank, outlet manifold interface is positioned close on the side wall of outer shell of reaction chamber, inlet manifold At least one the first exhaust gas channels are provided between interface and outlet manifold interface in catalyst, the first exhaust gas channel is and catalysis What sealing separated, reaction chamber bottom is equipped with one and connect the alcohols injector communicated with economizer bank.
Preferably, alcohols hydrogen production from catalytic pyrolysis device of the present invention, wherein the quantity of exhaust gas channel can be two~six Item.
After using the above structure, compared with prior art, alcohols hydrogen production from catalytic pyrolysis device of the present invention is had the advantage that
1, since inlet manifold interface is positioned close on the side wall of outer shell of economizer bank, outlet manifold interface is positioned close to It on the side wall of outer shell of reaction chamber, therefore just by the tail gas that engine is discharged is heated to economizer bank first, tail gas at this time has Enough heats, therefore the present invention can reduce the quantity of economizer bank, in other words, in the lesser situation of economizer bank heating surface area Under economizer bank can also be heated well.
2, in the case that the present invention has the second exhaust gas channel originally between catalyst and shell, in inlet manifold interface At least one the first exhaust gas channels are provided in catalyst between outlet manifold interface again, this to enter alcohols cracking The contact area of the catalyst in motor exhaust and reaction chamber in reaction chamber greatly increases, i.e. the endotherm area of catalyst is big It is big to increase, to effectively increase the utilization rate of engine tail gas heat quantity.
3, reaction chamber bottom setting connect the alcohols injector that communicates with economizer bank not only through the spray of its multiple spout It penetrates, so that alcohol-based liquid is more convenient for being atomized, evaporated, and, according to engine operating condition, can press under the control of vehicle control system According to actual demand, alcohols is injected to catalyst, to make full use of the ability of catalyst, preferably guard catalyst, is extended The service life of catalyst.
Another technical solution of the invention is to provide a kind of alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile On application method, method includes the following steps:
1. methanol or ethyl alcohol in alcohol-based liquid case are pumped into economizer bank by the work by the pump connecting with ignition switch;
2. the tail gas of engine discharge is introduced cracking hydrogen production dress by the inlet manifold interface close to economizer bank side In the shell set, to heat first to alcohol-based liquid in economizer bank, alcohol vapor is made, then again by least Three or more exhaust gas channels heat the catalyst in reaction chamber;
3. step 2. in, vehicle control system issue instruction, control alcohols injector according to actual demand will heat after Economizer bank in alcohol vapor be injected in reaction chamber, and it is heated after catalyst effect decomposite hydrogen and one oxidation Carbon;
4. the hydrogen decomposited and carbon monoxide are discharged from exhaust outlet, and successively by air accumulator and multiple and vehicle control The solenoid valve of system connection processed, built in gas tank set the pressure sensor connecting with vehicle control system, multiple solenoid valves It connect and communicates with each cylinder inlet manifold inlet valve of engine respectively, the effect of air accumulator is cooling, decompression and storage hydrogen and one Carbonoxide, vehicle control system issue instruction according to the operating condition of engine, open each solenoid valve, and hydrogen and carbon monoxide spray into At each cylinder inlet manifold inlet valve of engine and fresh air enters combustion chamber together, and burning is participated in after compression.
By using above step, the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile is in addition to upper It states except three advantages, also has the advantages that
1, not only volume is big for the air accumulator in the present invention, and pressure balance effect increases, and can store certain amount Hydrogen and carbon monoxide, the hydrogen and carbon monoxide of storage when engine start heating, idle running for using, thus effectively The discharge amount of this period of time engine is reduced, burning shape of the engine in starting heating, idle running is preferably improved Condition.
2 only introduce hydrogen and carbon monoxide from original method different at motor intake manifold manifold entrance, the present invention Described in alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile on application method, air accumulator and each cylinder of engine into Multiple solenoid valves are provided at gas gas manifold inlet door, the quantity of solenoid valve is determined according to the quantity of each cylinder inlet manifold, and sentence is changed It talks about, by the control of vehicle control system, the hydrogen at each cylinder inlet manifold inlet valve of engine is discharged by each solenoid valve The amount of gas and carbon monoxide can determine according to the operating condition of engine, to realize the optimum proportioning of hydrogen and fuel.
Preferably, the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile of the present invention, In, step 2. in it is further comprising the steps of: vehicle control system controlled according to the temperature signal that temperature sensor is fed back electricity plus The on-off of hot device, when the tail gas of engine discharge cannot be guaranteed the temperature that alcohols cracking needs, vehicle control system control electricity Heater fever, when the tail gas of engine discharge supplies the temperature that alcohols cracking needs enough, vehicle control system control electricity Heater power-off.
Preferably, the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile of the present invention, In, the hydrogen and carbon monoxide that alcohols decomposites after exhaust outlet discharge are entered back into air accumulator after check valve.Setting The purpose of check valve is that hydrogen and carbon monoxide are flow backwards in order to prevent.
Detailed description of the invention:
Fig. 1 is the structural schematic diagram of alcohols hydrogen production from catalytic pyrolysis device in the present invention;
Fig. 2 is the schematic cross-sectional view of " A-A " line along Fig. 1;
Application principle schematic diagram when Fig. 3 is by alcohols hydrogen production from catalytic pyrolysis device application liquid fuel within automobile.
Specific embodiment:
With reference to the accompanying drawings and detailed description to alcohols hydrogen production from catalytic pyrolysis device of the present invention and its liquid fuel within Application method on automobile is described further:
As depicted in figs. 1 and 2, alcohols hydrogen production from catalytic pyrolysis device of the present invention includes inlet manifold interface 13, outlet manifold It interface 14, electric heater 5, temperature sensor 6, the shell 1 with insulating layer, the reaction chamber 3 filled with catalyst 2 and is placed in The economizer bank 4 being connected in shell 1 and with 3 bottom of reaction chamber.It is equipped at the top of shell 1 and connect the alcohols entrance communicated with economizer bank 4 7, ring flange 8 and cover board connected to it 9 are equipped at the top of the shell 1 of the top of reaction chamber 3, and cover board 9 is equipped with exhaust outlet 10, electricity The wiring outlet 11 of heater 5 and the outlet 12 of temperature sensor 6.Inlet manifold interface 13 is positioned close to the outer of economizer bank 4 On 1 side wall of shell, outlet manifold interface 14 is positioned close on 1 side wall of shell of reaction chamber 3,3 bottom of reaction chamber be equipped with one with Economizer bank 4 connects the alcohols injector 16 communicated.Catalyst 2 in reaction chamber 3 is sealed set, in other words, catalyst 2 It is located in a sealing unit 30, catalyst 2 is divided into upper, middle and lower by separating element (not shown) along the vertical direction Three layers, catalyst 2 between layers passes through the cavity being arranged on separating element and is connected to.Between catalyst 2 and shell 1 There are while the second exhaust gas channel 28, the present invention is provided with the first exhaust gas channel 15 of two axial directions also in catalyst 2, and two The first exhaust gas channel of item 15 is connected to inlet manifold interface 13 and outlet manifold interface 14 simultaneously, two the first exhaust gas channels 15 be with The sealing of catalyst 2 separates, and in other words, the present invention will guarantee the tail gas in the first exhaust gas channel 15 and the second exhaust gas channel 28 It cannot directly be contacted with the catalyst 2 in reaction chamber, but the heat of tail gas institute band can pass to catalysis by sealing unit 30 Agent 2.Increased two the first exhaust gas channels 15 of the present invention, considerably increase the heating surface area of catalyst 2, start to improve The utilization rate of tail gas heat.Electric heater 5 and temperature sensor 6 in the present invention are respectively positioned in catalyst 2, quantity difference For 6 and 3.
As shown in figure 3, the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile is as follows:
1. 17 both ends of ignition switch are separately connected power supply 26 (battery, generator) and pump 18, after ignition switch 17 is opened, Pump 18 start to work, by alcohol-based liquid case 22 methanol or ethyl alcohol be pumped into economizer bank 4;
2. the tail gas that engine 19 is discharged, which is passed through the inlet manifold interface 13 close to 4 side of economizer bank, is introduced into cracking system In the shell 1 of hydrogen production device 21, to heat first to alcohol-based liquid in economizer bank 4, alcohol vapor is made, then again The catalyst 2 in reaction chamber 3 is heated by the four rules above exhaust gas channel 15;
3. after economizer bank 4 heats, vehicle control system 20 issues instruction, control alcohols injector 16 will according to actual demand The alcohol vapor in economizer bank 4 after heating is injected in reaction chamber 3 by four spouts thereon, and it is heated after catalysis The effect of agent 2 decomposites hydrogen and carbon monoxide;
4. the hydrogen decomposited and carbon monoxide are discharged from exhaust outlet 10, and successively pass through check valve 29, air accumulator 23 And multiple solenoid valves 24 connecting with vehicle control system 20, the interior setting one of air accumulator 23 are connect with vehicle control system 20 Pressure sensor 25, multiple solenoid valves 24 connect with each cylinder inlet manifold inlet valve of engine communicate respectively, the work of air accumulator 23 With being cooling, decompression and storage hydrogen and carbon monoxide, vehicle control system 20 issues instruction according to the operating condition of engine, opens Each solenoid valve 24, hydrogen and carbon monoxide spray at each cylinder inlet manifold inlet valve of engine to be entered together with fresh air Combustion chamber participates in burning after compression.
Above-mentioned steps 2. in, vehicle control system 20 controlled according to the temperature signal that temperature sensor 6 is fed back electricity plus The on-off of hot device 5, when the tail gas that engine 19 is discharged cannot be guaranteed the temperature that alcohols cracking needs, vehicle control system 20 is controlled Electric heater 5 processed generates heat, when the tail gas that engine 19 is discharged supplies the temperature that alcohols cracking needs enough, vehicle control system 20 control electric heaters 5 power off.It says in more detail, temperature signal is transferred to vehicle control system 20, vehicle by temperature sensor 6 Control system 20 adjusts the supply of alcohol-based liquid by the open and close of the temperature control electromagnetic switch 27 in schizolysis hydrogen production plant 21 The on-off of amount and electric heater 5.When the tail gas of engine discharge cannot be guaranteed the temperature that alcohols cracking needs, vehicle control system System 20 issues instruction, and electric heater 5 generates heat, and guarantees the normal temperature of alcohols cracking, makes to crack lasting progress.Work as motor exhaust When heat needed for supplying schizolysis hydrogen production plant 21 enough, temperature sensor 6 outputs signal to vehicle control system 20, vehicle control System 20 processed issues instruction, and electric heater 5 is disconnected, by motor exhaust independent heat supply.In engine start, motor exhaust Temperature is extremely low, and vehicle control system 20 issues instruction, and electric heater 5 is connected, and is mainly supplied by power supply 26 (battery, generator) Electricity guarantees the normal lytic temperature of schizolysis hydrogen production plant 21, is normally carried out cracking reaction.Crack the low pressure hydrogen (H generated2) Enter stainless steel gas storage tank 23 with carbon monoxide (CO), the low pressure hydrogen (H in air accumulator 232) and carbon monoxide (CO) press The instruction unpack solenoid valve 24 of vehicle control system 20 is supplied actually required low pressure hydrogen (H by engine operating condition2) and an oxygen Change carbon (CO) and air (combustion mixture) and enters cylinder participation burning together.Vehicle control system 20 is additionally provided with one and shows Show device 27, consequently facilitating some relevant parameters and state of display schizolysis hydrogen production plant 21.
Other structures and method in the present invention are same as the prior art, and therefore, not repeat them here.
Embodiments described above is only that preferred embodiments of the present invention will be described, not to of the invention Range is defined, and without departing from the spirit of the design of the present invention, those of ordinary skill in the art are to technology of the invention The various changes and improvements that scheme is made should all be fallen into the protection scope that claims of the present invention determines.

Claims (4)

1. the application method on a kind of alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile, it includes inlet manifold interface (13), outlet manifold interface (14), the shell (1) with insulating layer, filled with catalyst (2) reaction chamber (3), be placed in shell (1) in and the economizer bank (4) being connected to reaction chamber (3) bottom and the electric heater (5) and temperature that are placed in catalyst (2) pass Sensor (6), shell (1) top, which is equipped with, connect the alcohols entrance (7) communicated with economizer bank (4), above the reaction chamber (3) Shell (1) at the top of be equipped with ring flange (8) and cover board connected to it (9), the cover board (9) be equipped with exhaust outlet (10), The wiring outlet (11) of electric heater (5) and the outlet (12) of temperature sensor (6), it is characterised in that: the inlet manifold connects Mouth (13) is positioned close on shell (1) side wall of economizer bank (4), and the outlet manifold interface (14) is positioned close to reaction chamber (3) it on shell (1) side wall, is set in the catalyst (2) between the inlet manifold interface (13) and outlet manifold interface (14) At least one the first exhaust gas channels (15) are equipped with, first exhaust gas channel (15) is separated with catalyst (2) sealing, described Reaction chamber (3) bottom is equipped with one and connect the alcohols injector (16) communicated with economizer bank (4), which includes following step It is rapid:
1. methanol or ethyl alcohol in alcohol-based liquid case (22) are pumped into pre- by the work for the pump (18) being connect with ignition switch (17) In heat pipe (4);
2. the inlet manifold interface (13) that the tail gas of engine (19) discharge passes through close to economizer bank (4) side is introduced into cracking In the shell (1) of device for producing hydrogen (21), to heat first to alcohol-based liquid in economizer bank (4), alcohols steaming is made Then vapour passes through in catalyst (2) at least one or more the first exhaust gas channel (15) and catalyst (2) and shell (1) again Between the second exhaust gas channel (28) catalyst (2) in reaction chamber (3) is heated;
3. step 2. in, vehicle control system (20) issue instruction, control alcohols injector (16) according to actual demand will plus The alcohol vapor in economizer bank (4) after heat is injected in reaction chamber (3), and it is heated after catalyst (2) effect decompose Hydrogen and carbon monoxide out;
4. the hydrogen decomposited and carbon monoxide are discharged from exhaust outlet (10), and successively pass through air accumulator (23) and multiple and vehicle A pressure connecting with vehicle control system (20) is arranged in air accumulator (23) in the solenoid valve (24) of control system (20) connection Force snesor (25), multiple solenoid valves (24) connect with each cylinder inlet manifold inlet valve of engine communicate respectively, air accumulator (23) Effect be cooling, decompression and storage hydrogen and carbon monoxide, vehicle control system (20) refers to according to the operating condition sending of engine It enables, opens each solenoid valve (24), hydrogen and carbon monoxide spray at each cylinder inlet manifold inlet valve of engine and fresh air Enter combustion chamber together, burning is participated in after compression.
2. the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile according to claim 1, special Sign is: the quantity of the exhaust gas channel (15) is two~six.
3. the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile according to claim 1, special Sign is: step 2. in it is further comprising the steps of: the temperature signal that vehicle control system (20) is fed back according to temperature sensor (6) The on-off of electric heater (5) is controlled, when the tail gas of engine (19) discharge cannot be guaranteed the temperature that alcohols cracking needs, vehicle Control system (20) control electric heater (5) fever, when the tail gas of engine (19) discharge supply alcohols cracking needs enough Temperature when, vehicle control system (20) control electric heater (5) power-off.
4. the application method on alcohols hydrogen production from catalytic pyrolysis device liquid fuel within automobile according to claim 1, special Sign is: the hydrogen and carbon monoxide that alcohols decomposites are to enter back into storage after check valve (29) after exhaust outlet (10) discharge In gas tank (23).
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4858582A (en) * 1988-07-11 1989-08-22 Brown Paul M Carburetor fuel preconditioner
CN2228980Y (en) * 1995-09-06 1996-06-12 上海华联机电技术研究所 Catalytic cracking reactor for fuel-saving dirt-reducing device for car
CN2237727Y (en) * 1995-05-31 1996-10-16 上海华联机电技术研究所 Oil-saving pollution-reducing device for automobile
CN1316586A (en) * 2000-04-03 2001-10-10 张树 Method for producing carbon smoke of diesel engine and smoke reducing purifier
CN1356257A (en) * 2000-11-30 2002-07-03 中国科学院成都有机化学研究所 Two-segment process for preparing CO and hydrogen by cracking methanol
CN202023613U (en) * 2011-03-08 2011-11-02 苗林卿 Methanol cracking gas making device utilizing waste heat of tail gas emitted by internal combustion engine
CN104555923A (en) * 2015-02-03 2015-04-29 武汉理工大学 Vehicle-mounted hydrous ethanol low-temperature reforming hydrogen production method and device and application system
CN205477990U (en) * 2016-03-28 2016-08-17 张树 Alcohols catalytic cracking hydrogen plant

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2435530Y (en) * 2000-07-27 2001-06-20 梁洪铭 Coil alcohol cracker

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4858582A (en) * 1988-07-11 1989-08-22 Brown Paul M Carburetor fuel preconditioner
CN2237727Y (en) * 1995-05-31 1996-10-16 上海华联机电技术研究所 Oil-saving pollution-reducing device for automobile
CN2228980Y (en) * 1995-09-06 1996-06-12 上海华联机电技术研究所 Catalytic cracking reactor for fuel-saving dirt-reducing device for car
CN1316586A (en) * 2000-04-03 2001-10-10 张树 Method for producing carbon smoke of diesel engine and smoke reducing purifier
CN1356257A (en) * 2000-11-30 2002-07-03 中国科学院成都有机化学研究所 Two-segment process for preparing CO and hydrogen by cracking methanol
CN202023613U (en) * 2011-03-08 2011-11-02 苗林卿 Methanol cracking gas making device utilizing waste heat of tail gas emitted by internal combustion engine
CN104555923A (en) * 2015-02-03 2015-04-29 武汉理工大学 Vehicle-mounted hydrous ethanol low-temperature reforming hydrogen production method and device and application system
CN205477990U (en) * 2016-03-28 2016-08-17 张树 Alcohols catalytic cracking hydrogen plant

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