CN105647377B - A kind of ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable - Google Patents
A kind of ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable Download PDFInfo
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- CN105647377B CN105647377B CN201610224361.3A CN201610224361A CN105647377B CN 105647377 B CN105647377 B CN 105647377B CN 201610224361 A CN201610224361 A CN 201610224361A CN 105647377 B CN105647377 B CN 105647377B
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- ultraviolet
- vacuum coating
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses ultraviolet-curing vacuum coating metal finish paint of a kind of electrostatically sprayable and preparation method thereof, the ultraviolet-curing vacuum coating metal covering enamel-cover of the electrostatically sprayable includes the following component calculated by weight：10~20 parts of urethane acrylates, 5~10 parts of pure acrylates, 5~10 parts of polyester acrylates, 5~10 parts of single functionality reactive diluents, 10~20 parts of tripropylene glycol diacrylates, 30~40 parts of trimethylolpropane trimethacrylates, 5~10 parts of dipentaerythritol acrylates；2 ~ 5 parts of light triggers, 0.01 ~ 0.2 part of levelling agent, 0.05 ~ 0.3 part of adhesion promoter, 0 ~ 4 part of dyestuff；0.01 ~ 0.5 part of conductive agent, 3 ~ 5 parts of electrostatic diluents.Prepared finish paint can carry out electrostatic spraying, have the advantages that hardness is high, adhesive force is good, salt fog resistance is strong, production efficiency is high, utilization efficiency of coatings is high, with wide market prospects.
Description
Technical field
The invention belongs to ultraviolet-curing paint technical field, in particular it relates to a kind of purple of electrostatically sprayable
Outer photocuring vacuum coating metal finish paint.
Background technology
Vacuum coating technology is the new technology that last decade grows up, and can show to plate the thin metal of last layer in plating piece
Layer, assigns substrate metal gloss.After vacuum coating, an aspect paint is also coated again on coating, it can improve plated film
Wearability, corrosion resistance and weatherability of layer etc., can also colour film plating layer, plating piece is reflected prismy metal light
Pool.
Current ultraviolet-curing vacuum coating coating can not carry out electrostatic spraying, and reason is, coating is difficult to meet simultaneously
Vacuum coating and the requirement of electrostatic spraying, main now using the construction of the methods such as aerial spraying, coating crosses spray phenomenon seriously, paint
Consumption is big, and utilization efficiency of coatings is low, and working environment is severe, seriously polluted, while product edges coating quality is poor, causes enterprise to give birth to
Production efficiency is low, yields is low, cost increase, and profit reduction hinders the development of ultraviolet-curing vacuum coating coating industry.
In addition, with the increasingly raising of environmental requirement, the limitation to VOC in coating (VOC) is also more next
It is stricter.Therefore, a kind of VOC content need to be sought low, cheap, the excellent purple for carrying out electrostatic spraying of comprehensive mechanical property
Outer photocuring vacuum coating metal finish paint.
The content of the invention
It is contemplated that overcoming the defect of above-mentioned prior art to solidify Vacuum Deposition there is provided a kind of ultraviolet light of electrostatically sprayable
Film metal finish paint, gained finish paint hardness is high, and salt fog resistance, water boiling resistance are good, and adhesive force is strong, and hardness is high and VOC content is low.
Another object of the present invention is to provide the ultraviolet-curing vacuum coating metal finish paint of the electrostatically sprayable
Preparation method.
The goal of the invention of the present invention is achieved by the following technical programs：
A kind of ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable, including the following group calculated by weight
Point：
10~20 parts of urethane acrylate；
5~10 parts of pure acrylate；
5~10 parts of polyester acrylate；
5~10 parts of single functionality reactive diluent；
10~20 parts of tripropylene glycol diacrylate；
30~40 parts of trimethylolpropane trimethacrylate；
5~10 parts of dipentaerythritol acrylate；
2~5 parts of light trigger；
0.01~0.2 part of levelling agent；
0.05~0.3 part of adhesion promoter；
0~4 part of dyestuff；
0.01~0.5 part of conductive agent；
3~5 parts of electrostatic diluent；
The viscosity that the ultraviolet-curing vacuum coating metal finish paint applies No. 4 cups is 10~30s, and resistivity is 5~50M
Ω·cm。
The present invention is lived using urethane acrylate, pure acrylate, polyester acrylate as matrix resin with single functionality
Property diluting monomer, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, dipentaerythritol acrylate compounding
As reactive diluent, suitable ultraviolet-curing vacuum coating metal finish paint has been made.Wherein urethane acrylate is to institute
Metal cladding adhesive force is excellent, and hardness is high；Pure acrylate and polyester acrylate pliability is good and viscosity is low, it is possible to decrease system
Viscosity, realizes without organic solvent to be adjustable to required viscosity；Compared to other reactive diluents, trimethylolpropane tris third
Olefin(e) acid ester curing rate is fast, and viscosity is low, and can assign film higher hardness, single functionality activity diluting monomer and 3 the third two
Alcohol diacrylate can then significantly reduce system viscosity and shrinkage, and it is very high that dipentaerythritol acrylate can assign paint film
Hardness.Seldom, in spraying process, a small amount of electrostatic diluent can volatilize the electrostatic amount of diluent that the present invention need to be used, body
The VOC content of system is low, very environmentally friendly.Gained finish paint hardness height, good adhesive force, salt fog resistance, water boiling resistance are good.
Preferably, the urethane acrylate be polyester-type aliphatic urethane acrylate, it is acrylate modified poly-
One or both of urethane acrylate.
Preferably, the electrostatic diluent is the one or more in DAA, low-carbon alcohols, ketone.
Preferably, the single functionality activity diluting monomer is hydroxyethyl methacrylate, hydroxy propyl methacrylate, first
One or more in base isobornyl acrylate.
Preferably, the light trigger be 2,2- dimethoxy -2- phenyl acetophenones, 1- hydroxycyclohexyl phenyl ketones,
One or more in 2- hydroxy-2-methyl -1- phenyl -1- acetone, 2,4,6- trimethyl benzoyl diphenyl base phosphorous oxides.
Preferably, the levelling agent is organic silicon modified by polyether oxygen alkane solution, alkyl-modified organosiloxane solution, propylene
One or more in acid ester copolymer solution, silicone ethylene glycol copolymerization liquid solution.
Preferably, the adhesion promoter is one in phosphate polyester polymers, phosphoester acrylic ester polymer
Plant or two kinds.
Preferably, the conductive agent is one or both of quarternary ammonium salt compound solution, organic amine salt compound solution.
Preferably, the dyestuff is premetallized dye.
The preparation method of the ultraviolet-curing vacuum coating metal finish paint of the electrostatically sprayable, comprises the following steps：
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added in stirred tank and mixed by proportioning
2~4 hours, it is uniformly dispersed；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1~2 hour, obtaining can
The ultraviolet-curing vacuum coating metal finish paint of electrostatic spraying.
Compared with prior art, the present invention has the advantages that：The present invention solves ultraviolet-curing vacuum coating
The problem of metallic paint is unable to electrostatic spraying, realizes the electrostatic spraying of ultraviolet-curing vacuum coating metal finish paint；It is prepared
Ultraviolet-curing vacuum coating metallic paint have that hardness is high, adhesive force is good, levelability is good, salt fog resistance is strong, production efficiency
The advantages of with utilization efficiency of coatings height, energy-conserving and environment-protective.
Embodiment
The present invention is further described with reference to specific embodiment, but embodiment does not do any shape to the present invention
The restriction of formula, as long as the technical scheme obtained using the form of equivalent substitution or equivalent transformation, all should be included in power of the present invention
Within the protection domain that profit is required.
Unless otherwise indicated, the source chemicals that the embodiment of the present invention is used is conventional source chemicals purchased in market.
Embodiment 1
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 3 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Embodiment 2
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 2 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 2 hours, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Embodiment 3
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 4 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Embodiment 4
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 3 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Embodiment 5
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 3 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Embodiment 6
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 3 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Comparative example 1
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 2
Stir 3 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Comparative example 2
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 2
Stir 2 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 2 hours, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Comparative example 3
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 2
Stir 4 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Comparative example 4
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added successively by proportioning shown in table 1
Stir 3 hours, be uniformly dispersed in stirred tank；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
Combination property detection is carried out to the finish paint prepared by embodiment, its testing result is shown in Table 3.
Combination property detection is carried out to the finish paint prepared by comparative example, its testing result is shown in Table 4.
The Example formulations of table 1
The comparative example formula of table 2
The embodiment testing result of table 3
The comparative example testing result of table 4
It can be seen from the test result of embodiment, the ultraviolet-curing vacuum coating face of electrostatically sprayable of the present invention
Paint has good adhesive force, salt fog resistance, water boiling resistance good, the advantages of hardness is high.Can according to the contrast of comparative example 1 and embodiment 1
Know, can just make finish paint that there is higher hardness using the dipentaerythritol acrylate of certain content；According to comparative example 2 and in fact
The contrast for applying example 2 is understood, using urethane acrylate finish paint can be made to have good adhesive force to aluminium coated, while ensureing face
Paint has higher hardness；It can be seen from the contrast of comparative example 3 and embodiment 3, trimethylolpropane trimethacrylate energy is used
Enough ensure dispensing viscosity it is relatively low, trimethylolpropane trimethacrylate price is relatively low, can also be reduced using this raw material finish paint into
This；It can be seen from the contrast of comparative example 4 and embodiment 4, dipentaerythritol acrylate can improve the hardness of finish paint, still
The content of dipentaerythritol acrylate is unsuitable too high, and otherwise system viscosity is excessive, it is difficult to carry out electrostatic spraying (electrostatic spraying
The general viscosity for requiring coating is 10~30s).
Claims (11)
1. a kind of ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable, it is characterised in that including it is following by weight
The component of calculating：
10~20 parts of urethane acrylate；
5~10 parts of pure acrylate；
5~10 parts of polyester acrylate；
5~10 parts of single functionality reactive diluent；
10~20 parts of tripropylene glycol diacrylate；
30~40 parts of trimethylolpropane trimethacrylate；
Dipentaerythritol acrylate 5~10；
2 ~ 5 parts of light trigger；
0.01 ~ 0.2 part of levelling agent；
0.05 ~ 0.3 part of adhesion promoter；
0 ~ 4 part of dyestuff；
0.01 ~ 0.5 part of conductive agent；
3 ~ 5 parts of electrostatic diluent；
The viscosity that the ultraviolet-curing vacuum coating metal finish paint applies No. 4 cups is 10~30 s, and resistivity is 5~50M Ω
cm。
2. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Urethane acrylate is one kind in polyester-type aliphatic urethane acrylate, polymerization of acrylic modified polyurethane acrylate
Or two kinds.
3. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Electrostatic diluent is the one or more in low-carbon alcohols, ketone.
4. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Electrostatic diluent is DAA.
5. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Single functionality reactive diluent is in hydroxyethyl methacrylate, hydroxy propyl methacrylate, isobornyl methacrylate
It is one or more.
6. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Light trigger is 2,2- dimethoxy -2- phenyl acetophenones, 1- hydroxycyclohexyl phenyl ketones, 2- hydroxy-2-methyl -1- benzene
One or more in base -1- acetone, 2,4,6- trimethyl benzoyl diphenyl base phosphine oxides.
7. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Levelling agent is organic silicon modified by polyether oxygen alkane solution, alkyl-modified organosiloxane solution, acrylate copolymer solution, silicone
One or more in ethylene glycol copolymerization liquid solution.
8. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Adhesion promoter is one or both of phosphate polyester polymers, phosphoester acrylic ester polymer.
9. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that described
Conductive agent is one or both of quarternary ammonium salt compound solution, organic amine salt compound solution.
10. the ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable according to claim 1, it is characterised in that institute
Dyestuff is stated for premetallized dye.
11. the ultraviolet-curing vacuum coating metal of electrostatically sprayable as described in claim 1 to 10 any one claim
The preparation method of finish paint, it is characterised in that comprise the following steps：
S1. ultraviolet-curing vacuum coating resin, reactive diluent, light trigger are added in stirred tank by proportioning and mix 2~
4 hours, it is uniformly dispersed；
S2. levelling agent, adhesion promoter, dyestuff, conductive agent, electrostatic diluent are added, is stirred 1~2 hour, obtaining can be quiet
The ultraviolet-curing vacuum coating metal finish paint of electrospray.
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| Application Number | Priority Date | Filing Date | Title |
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| CN105647377B true CN105647377B (en) | 2017-10-13 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111944415A (en) * | 2020-07-09 | 2020-11-17 | 湖南松井新材料股份有限公司 | Ultraviolet curing coating and preparation method and application thereof |
| CN111849283A (en) * | 2020-07-28 | 2020-10-30 | 上海蓝宝涂料有限公司 | Vacuum plating UV (ultraviolet) photocuring finish paint and preparation method thereof |
| CN114276739B (en) * | 2021-12-15 | 2023-01-10 | 上海立邦长润发涂料有限公司 | Vacuum spraying UV (ultraviolet) color-correction finishing paint and preparation method thereof |
| CN115558401B (en) * | 2021-12-29 | 2023-08-04 | 江苏兴业联合装备技术有限公司 | High-strength SPC floor UV (ultraviolet) curing coating and preparation method thereof |
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| CN101280154A (en) * | 2007-04-06 | 2008-10-08 | 上海海优威电子技术有限公司 | Ultraviolet curing vacuum metallizing coating |
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| EP2447299A1 (en) * | 2009-06-26 | 2012-05-02 | Idemitsu Kosan Co., Ltd. | Polycarbonate copolymer, coating liquid using same, and electrophotographic photosensitive body |
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