CN105645939B - 一种低温耐热陶瓷 - Google Patents

一种低温耐热陶瓷 Download PDF

Info

Publication number
CN105645939B
CN105645939B CN201511014149.6A CN201511014149A CN105645939B CN 105645939 B CN105645939 B CN 105645939B CN 201511014149 A CN201511014149 A CN 201511014149A CN 105645939 B CN105645939 B CN 105645939B
Authority
CN
China
Prior art keywords
glaze
raw material
low temperature
temperature thermal
production technology
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201511014149.6A
Other languages
English (en)
Other versions
CN105645939A (zh
Inventor
危连进
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUJIAN DEHUA WILL CERAMIC Co Ltd
Original Assignee
FUJIAN DEHUA WILL CERAMIC Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUJIAN DEHUA WILL CERAMIC Co Ltd filed Critical FUJIAN DEHUA WILL CERAMIC Co Ltd
Priority to CN201511014149.6A priority Critical patent/CN105645939B/zh
Priority claimed from CN201410538158.4A external-priority patent/CN104310956B/zh
Publication of CN105645939A publication Critical patent/CN105645939A/zh
Application granted granted Critical
Publication of CN105645939B publication Critical patent/CN105645939B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/19Alkali metal aluminosilicates, e.g. spodumene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/66Specific sintering techniques, e.g. centrifugal sintering
    • C04B2235/661Multi-step sintering

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Glass Compositions (AREA)

Abstract

本发明公开了一种低温耐热陶瓷及其生产工艺,由质量百分比为锂云母36%~42%、氧化铝24%~30%、龙岩高岭土30%~32%、膨润土2%~4%的原料制成,将原料进行预粉碎后,并用球磨机进行湿法球磨,筛选后磁选除去铁杂质,进行成型,修坯素烧,然后彩画施喷亮光釉进行釉烧,包装及入库,即得产品。本发明生产工艺使用光亮釉,生产出的产品质量好,色泽光亮,性能稳定;且烧制温度低,节约大量热量,因此能耗可降低30%,不仅降低了燃料消耗及燃料成本,而且对于节能减排具有重大作用。

Description

一种低温耐热陶瓷
技术领域
本发明涉及陶瓷产品技术领域,具体是一种低温耐热陶瓷及其生产工艺。
背景技术
本发明是对申请号2014105381584的中国发明专利申请的分案申请。
耐高温陶瓷是特种陶瓷的重要组成部分,有时也作为高温耐火材料的组成部分。可作为高温结构材料,用于宇航、原子能、电子技术、机械、化工、冶金等许多领域,是现代科学和技术不可缺少的高温工程材料,品种繁多,用途极为广泛。
由于传统耐高温陶瓷材料成分单一,在性质上存在着明显的不足,而且耐高温陶瓷材料存在加工困难,抗热震性差,不易进行粘结等缺点,因此业界开始研究新型耐高温陶瓷材料以及低温耐热材料。此低温耐热材料是在较低的高温下制得,但是却以其特有的结构及性能,有着耐高温的性能,因此低温耐热材料具有很大的市场前景,对于新材料领域也有着很重要的意义。
发明内容
本发明的目的在于提供一种制备温度低且性能优越的低温耐热陶瓷及其生产工艺,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:
一种低温耐热陶瓷,由以下质量百分比的原料制成:锂云母36%~42%、氧化铝24%~30%、龙岩高岭土30%~32%、膨润土2%~4%。
一种低温耐热陶瓷的生产工艺,具体步骤如下:(1)将龙岩高岭土和膨润土分别粉碎至直径小于6mm的颗粒状;(2)按照质量百分比称取原料锂云母、氧化铝、龙岩高岭土和膨润土颗粒;(3)原料放入球磨机中加入清水并研磨25~30h,并通过220~300目筛进行筛选;(4)进行磁选,以除去泥浆原料中所含的铁杂质;(5)将泥浆原料进行压滤脱水,后进行真空练泥成泥条,含水率小于22%;(6)将泥条进行成型,修坯,并烧800℃,4h左右;(8)冷却后,可进行釉下彩,施喷亮光釉,在1150~1200℃的温度下继续釉烧8~10h;(9)也可将釉烧后的产品进行贴花烤制、包装及入库。
与现有技术相比,本发明的有益效果是:本发明生产工艺使用光亮釉,生产出的产品质量好,色泽光亮,性能稳定;且烧制温度低,节约大量热能,因此能耗可降低30%,不仅降低了燃料消耗及燃料成本,而且对于节能减排具有重大作用。
具体实施方式
下面将结合本发明实施例,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1
一种低温耐热陶瓷,由以下质量百分比的原料制成:锂云母36%、氧化铝30%、龙岩高岭土30%、膨润土4%。
实施例2
一种低温耐热陶瓷,由以下质量百分比的原料制成:锂云母39%、氧化铝27%、龙岩高岭土31%、膨润土3%。
实施例3
一种低温耐热陶瓷,由以下质量百分比的原料制成:锂云母42%、氧化铝24%、龙岩高岭土32%、膨润土2%。
上述实施例1、实施例2和实施例3所述的低温耐热陶瓷的生产工艺,具体步骤如下:(1)将龙岩高岭土和膨润土分别粉碎至直径小于6mm的颗粒状;(2)按照质量百分比称取原料锂云母、氧化铝、龙岩高岭土和膨润土颗粒;(3)原料放入球磨机中加入清水并研磨25~30h,并通过220~300目筛进行筛选;(4)进行磁选,以除去泥浆原料中所含的铁杂质;(5)将泥浆原料进行压滤脱水成泥饼进行真空练泥成泥条,使得泥条的含水率小于22%;(6)将泥条进行成型,修坯,并烧800℃,4h左右后可进行釉下彩;(8)冷却后,施喷亮光釉,在1150℃-1200℃的温度下继续釉烧8-10h;(9)也可将釉烧后的产品进行贴花烤制、包装及入库。
本发明生产工艺使用光亮釉,生产出的产品质量好,色泽光亮;且烧制温度低,节约大量能量,因此能耗可降低30%,不仅降低了燃料消耗及燃料成本,而且对于节能减排具有重大作用;在操作过程中出现的废料废渣可回收利用,降低了生产的总成本,提高了经济效益。
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。

Claims (1)

1.一种低温耐热陶瓷,其特征在于,由以下质量百分比的原料制成:锂云母39%、氧化铝27%、龙岩高岭土31%、膨润土3%。
CN201511014149.6A 2014-10-14 2014-10-14 一种低温耐热陶瓷 Active CN105645939B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511014149.6A CN105645939B (zh) 2014-10-14 2014-10-14 一种低温耐热陶瓷

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410538158.4A CN104310956B (zh) 2014-10-14 2014-10-14 一种低温耐热陶瓷及其生产工艺
CN201511014149.6A CN105645939B (zh) 2014-10-14 2014-10-14 一种低温耐热陶瓷

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201410538158.4A Division CN104310956B (zh) 2014-10-14 2014-10-14 一种低温耐热陶瓷及其生产工艺

Publications (2)

Publication Number Publication Date
CN105645939A CN105645939A (zh) 2016-06-08
CN105645939B true CN105645939B (zh) 2018-03-20

Family

ID=56478468

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201511014149.6A Active CN105645939B (zh) 2014-10-14 2014-10-14 一种低温耐热陶瓷

Country Status (1)

Country Link
CN (1) CN105645939B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020528B (zh) * 2018-09-17 2019-12-31 福建省德化县晖龙陶瓷有限公司 一种低温高耐热全瓷及其制备方法
CN109574645A (zh) * 2019-01-16 2019-04-05 福建省威尔陶瓷股份有限公司 一种中温耐热陶瓷制品及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1907908A (zh) * 2006-08-17 2007-02-07 钟旭东 一种采用低温烧结生产抛光砖的方法
CN102040374A (zh) * 2009-10-19 2011-05-04 泉州坤达礼品有限公司 一种低温烧制的锂镁瓷及其制造方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101314741B1 (ko) * 2011-10-13 2013-10-08 이동희 산화마그네슘과 이의 경화제를 이용한 상온 무기발포 성형체의 제조방법

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1907908A (zh) * 2006-08-17 2007-02-07 钟旭东 一种采用低温烧结生产抛光砖的方法
CN102040374A (zh) * 2009-10-19 2011-05-04 泉州坤达礼品有限公司 一种低温烧制的锂镁瓷及其制造方法

Also Published As

Publication number Publication date
CN105645939A (zh) 2016-06-08

Similar Documents

Publication Publication Date Title
CN104310956B (zh) 一种低温耐热陶瓷及其生产工艺
CN102276276B (zh) 一种氧化铝空心球隔热制品
CN108840710A (zh) 利用锂尾矿及钢渣尾矿生产发泡陶瓷建筑保温材料的方法
CN101935203B (zh) 一种制备日用陶瓷的方法
CN103435336A (zh) 自成釉白玉瓷泥料及瓷泥料制品的制造方法
CN105837174A (zh) 一种耐火型日用陶瓷制品
CN102531649B (zh) 水泥窑烧成带用方镁石复合尖晶石砖的制备方法
CN106380176A (zh) 高可塑性日用耐热陶瓷及其制备方法
CN103319156A (zh) 一种瓷质砖生产中废瓷再利用的方法
CN103351154A (zh) 一种减薄陶瓷砖及其制造方法
CN102910892A (zh) 一种利用天然矿物及提钒尾渣制备的黑色陶板及其制备方法
CN107857562A (zh) 陶瓷素坯及其制备方法
CN105645939B (zh) 一种低温耐热陶瓷
CN106630962A (zh) 一种耐腐蚀填料的生产工艺
CN101121612A (zh) 利用赤泥和红砂岩制备自释釉陶瓷材料的方法
CN105669170B (zh) 一种含烧失造孔剂的重轻复合耐火砖
CN104326734A (zh) 一种超薄再生陶瓷砖及其制作方法
CN103964812B (zh) 以褐煤提锗尾渣为主要原料的烧结砖及其制备方法
CN103739302A (zh) 一种耐高温陶瓷的生产工艺
CN103819174B (zh) 以褐煤提锗尾渣为主要原料的烧结陶粒及其制备方法
CN105541351A (zh) 玻璃熔窑蓄热室顶部专用复合尖晶石锆砖及其制造方法
CN103864306A (zh) 一种全固废高强度玻璃陶瓷及其制备方法与应用
CN103159458A (zh) 一种以硫铁尾矿为主要原料制备彩色陶板的方法
CN103496948A (zh) 一种家装陶瓷装饰材料及其制备方法
CN103880400A (zh) 一种超白耐磨瓷砖及其生产工艺

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant