CN105638677A - A pesticide composition containing copper(succinate+glutarate+adipate) and triazole - Google Patents
A pesticide composition containing copper(succinate+glutarate+adipate) and triazole Download PDFInfo
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- CN105638677A CN105638677A CN201410649709.4A CN201410649709A CN105638677A CN 105638677 A CN105638677 A CN 105638677A CN 201410649709 A CN201410649709 A CN 201410649709A CN 105638677 A CN105638677 A CN 105638677A
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Abstract
The invention discloses a pesticide composition containing copper(succinate+glutarate+adipate) and triazole, particularly a sterilization composition effective components of which comprise an active component A and an active component B, wherein the active component A is the copper(succinate+glutarate+adipate), the active component B is one compound selected from epoxiconazole and penconazole, and the weight ratio of the active component A to the active component B is 1:80-80:1. The composition has synergistic effects for a plurality of diseases endangering agriculture production, reduces the using amount of pesticides, reduces the residual amount of pesticides on crops, reduces environment pollution, and is safe to human and livestock and good in environment compatibility. Drug resistance for diseases is not liable to generate.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of agriculture containing tiger glue adipic acid copper and triazole typeThe application of drug composition on corps diseases.
Background technology
Tiger glue adipic acid copper (Copper (succinate+glutarate+adipate)), cures mainly plantBacterial disease, copper ion and the lip-deep cation exchange of cause of disease mycoderm, make pathogen thinProtein coagulating on after birth, simultaneously part copper iontophoretic injection enters in pathogen cell and certainA little enzyme combinations, affect its activity. Can be used for preventing and treating cucumber bacterial angular leaf spot, and to plantGrowth has spread effect.
Epoxiconazole, penconazole all belong to common fungicide, are widely used in the disease of crops.
But, in the real process of agricultural production, prevent and treat the problem that disease the most easily producesIt is the generation of disease drug resistance. Different cultivars composition carries out composite, is to prevent and treat resistance disease veryCommon method. Heterogeneity is carried out composite, according to practical application effect, judges certainComposite be synergy, add and or antagonism. In most cases, the composite effect of sterilizationFruit is all additive effect, really has the composite little of synergistic effect, and especially synergistic effect is non-Chang Mingxian, synergy ratio very high composite just still less. Through inventor's research, finding willAfter tiger glue adipic acid copper and epoxiconazole, penconazole are composite, can produce good synergistic effect, and closeNot yet open in the relevant report that tiger glue adipic acid copper and epoxiconazole, penconazole are composite.
Summary of the invention
The object of the invention is to propose one and have that synergistic function, use cost are low, preventive effectThe good composition pesticide containing tiger glue adipic acid copper and triazole type.
What the present invention proposed contain activity containing tiger glue adipic acid copper and the composition pesticide of triazole type becomesDivide A and active component B, activity is divided into A and active component B weight ratio is 1 ︰ 80～80 ︰1, described active components A is tiger glue adipic acid copper, and active component B is selected from epoxiconazole, penta bacteriumOne in azoles, active components A and the preferred weight ratio of active component B are 1 ︰ 60～60 ︰1; More preferably the weight ratio of tiger glue adipic acid copper and epoxiconazole is 30:1～1:20, tiger glue adipic acid copperWith the weight ratio of penconazole be 40:1～1:10; Most preferably be the weight of tiger glue adipic acid copper and epoxiconazoleAmount is than being 19:1～1:9, and the weight ratio of tiger glue adipic acid copper and penconazole is 29:1～1:1.
The composition pesticide containing tiger glue adipic acid copper and triazole type that the present invention proposes is used for preventing and treating agricultureThe purposes of disease on crop, described crops comprise cereal crops, legume crop, fiber workThing, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, rootStem class crop, oil crops, flowers crop, medicinal crop, raw material crop, green manure herbage doThing; Described disease is angular leaf spot, downy mildew, anthracnose, droop, canker, vertical witheredDisease, virosis, soft rot, clubroot, black rot, black spot, balck shank, circle line disease,Shot hole, macula disease, downright bad disease, fruit rot, sour rot, spot disease, leaf spot, whiteStar disease, black points, epidemic disease, powdery mildew, bacterial wilt, verticillium wilt, scab, false smut,White rot or rust.
The weight ratio of active components A, active component B is 1 ︰ 80～80 ︰ 1. Conventionally compositionThe weight percentage of middle active component is 0.5%～90% of gross weight, be preferably 5%～80%. According to different preparation types, active component content scope is different. Conventionally liquid,Body preparation contains 1%～70% active material by weight, is preferably 5%～50%; GuBody preparation contains 5%～80% active material by weight, is preferably 10%～80%.
In bactericidal composition of the present invention, at least contain a kind of surfactant, while being beneficial to useThe dispersion of active component in water. Surface-active contents is 5%～30% of total formulation weight amount,Surplus is solid or liquid diluent.
Bactericidal composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method known in those skilled in the art, is about to activeAfter material mixes with liquid flux or solid carrier, then add surfactant as dispersant, steadyDetermine one or more in agent, wetting agent, binding agent, defoamer, disintegrant, antifreeze etc.
Bactericidal composition of the present invention, can be processed in any sterilization acceptable dose on demandType, wherein more preferably formulation be wettable powder, water dispersible granules, suspending agent, suspension emulsion,Aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent, can also granulationAgent, seed coat agent, suspension seed-coating agent, ultra low volume liquids.
When making wettable powder, composition comprises following constituent content: active components A 0.1%～80%, active component B0.1%～80%, dispersant 2%～10%, wetting agent 2%～10%, fill outMaterial surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 0.1%～80%, active component B0.1%～80%, dispersant 3%～12%, wetting agent 1%～8%, collapseSeparate agent 1%～10%, binding agent 0～8%, filler surplus.
When making suspending agent, composition comprises following constituent content: active components A 0.1%～50%,Active component B0.1%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer0.01%～2%, thickener 0～2%, antifreeze 0～8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent1%～15%, thickener 0～2%, emulsifying agent 2%～12%, antifreeze 0～8%, deionized waterAdd to 100%.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, solvent 1%～30%, emulsifying agent 1%～15%, antifreeze 0～8%,Thickener 0～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
When making microemulsion, composition comprises following constituent content: active components A 0.5%～50%,Active component B0.5%～50%, solvent 1%～30%, emulsifying agent 3%～25%, antifreeze 0～8%,Defoamer 0.01%～2%, deionized water are supplied surplus.
When making microcapsule suspending agent, composition comprises following constituent content: active components A0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersionAgent 1%～10%, organic solvent 1%～10%, emulsifying agent 1%～7%, defoamer 0.01%～2%,PH adjusting agent 0.01%～5%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following constituent content: active components A0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersionAgent 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifying agent 1%～6%,Defoamer 0.01%～2%, thickener 0～2%, pH adjusting agent 0.01%～5%, deionized waterAdd to 100%;
Wettable powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) tiger glue adipic acid copper and epoxiconazole, penconazole composite after, there is obvious synergy and holding effectEffect; (2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop,Fruits crop, dry fruit crop, hobby crop, root crop, oil crops, flowersDisease on crop, medicinal crop, raw material crop, green manure pasture crop all has greater activity;(3) reduce agricultural chemicals dosage, reduced the residual quantity of agricultural chemicals on crop, alleviated ringEnvironment pollution; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance toRain drop erosion.
Detailed description of the invention
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment isPercentage by weight, but the present invention is not limited thereto.
Application Example one
Embodiment 1～8 wettable powder
By tiger glue adipic acid copper, active component B, dispersant, wetting agent, filler in mixed cylinderMix, after airslide disintegrating mill is pulverized, mix again, can make of the present inventionWettable powder product, specifically in table 1.
The each component of table 1 embodiment 1～8 and weight portion
Embodiment 9～16 water dispersible granules
By tiger glue adipic acid copper, active component B, dispersant, wetting agent, disintegrant, filler etc.Obtain through air-flow crushing the particle diameter needing together, then add binding agent (can add and can not add) etc. itsIts auxiliary agent, obtains the materials of granulating. Item is quantitatively sent in fluidized bed granulation drying machine through systemGrain and dry after, can make water dispersible granules product of the present invention, specifically in table 2.
The each component of table 2 embodiment 9～16 and weight portion
Embodiment 17～24 suspending agents
By dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (canAdd and can not add), mix through high speed shear, add tiger glue adipic acid copper, active component B,Ball milling 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, and surplus spendsIonized water is supplied, and can make suspending agent product of the present invention, specifically in table 3.
The each component of table 3 embodiment 17～24 and weight portion
Embodiment 25～28 suspension emulsions
By dispersant, defoamer, thickener (can add and can not add), (can add can for antifreezeDo not add) mix through high speed shear, add tiger glue adipic acid copper, ball milling in ball mill2～3 hours, make diameter of particle all below 5 μ m, make the suspending agent of tiger glue adipic acid copper,Then by directly breast of high speed agitator for active component B, solvent, emulsifying agent and various auxiliary agentChange in suspending agent, surplus is supplied by deionized water, makes suspension emulsion of the present invention and producesProduct, specifically in table 4.
The each component of table 4 embodiment 25～28 and weight portion
Embodiment 29～32 aqueous emulsions
Tiger glue adipic acid copper, active component B, solvent, emulsifying agent are added together, make to be dissolved intoEvenly oil phase; By deionized water, antifreeze (can add and can not add), (can add can be or not thickenerAdd), defoamer mixes, and becomes homogeneous water. Under high-speed stirred, water is addedOil phase, surplus is supplied by deionized water; Can make aqueous emulsion product of the present invention, toolBody is in table 5.
The each component of table 5 embodiment 29～32 and weight portion
Epoxiconazole in 1-5, penconazole exchange will be shown, novel formulation can be made.
Embodiment 33～35 microemulsions
By tiger glue adipic acid copper, active component B, solvent, emulsifying agent, antifreeze, (can add can be notAdd), defoamer is fully mixed into the oil phase of homogeneous transparent, under agitation slowly adds deionizationWater, forms WO emulsion, then through agitating heating, makes it rapid phase inversion and become oil-in-water type,Be chilled to room temperature and make it to reach balance, after filtration, surplus is supplied by deionized water; Can make thisThe microemulsion product that invention is described, specifically in table 6.
The each component of table 6 embodiment 33～35 and weight portion
Embodiment 36,37 microcapsule suspending agents
By tiger glue adipic acid copper, active component B, macromolecule cyst material, solvent, make moltenSolution becomes even oil phase, under shearing condition, oil phase is joined and contains emulsifying agent, pH adjustingIn the aqueous phase solution of agent, dispersant, surplus is supplied by deionized water, and bi-material is at profit circleFace reacts, and forms macromolecule cyst wall, makes the finely disseminated micro-capsule of the present composition outstandingFloating agent product. Specifically in table 7.
Table 7 embodiment 36,37 each component and weight portions
Embodiment 38,39 microcapsule suspensions-suspending agent
By epoxiconazole, macromolecule cyst material, solvent, make to be dissolved into even oil phase, willOil phase joins in the aqueous phase solution that contains emulsifying agent, pH adjusting agent under shearing condition, systemBecome finely disseminated microcapsule suspending agent. By dispersant, wetting agent, defoamer, thickener (canAdd and can not add) mix through high speed shear, add tiger glue adipic acid copper, ball in ball millGrind 2～3 hours, make diameter of particle all below 5 μ m, make suspending agent, then will hangFloating agent joins in the aqueous phase solution of micro-capsule suspension, and deionized water is supplied surplus, makes thisFinely disseminated microcapsule suspension-the suspending agent of invention composition product, specifically in table 8.
Table 8 embodiment 38,39 each component and weight portions
The embodiment of the present invention is the method that adopts Toxicity Determination and field test to combine. FirstBy Toxicity Determination, the synergy ratio after clear and definite two kinds of medicaments are composite by a certain percentage(SR), SR < 0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 isSynergistic effect, on this basis, then carries out field test.
Test method: after the effective inhibition concentration scope of each medicament is determined in prerun, medicament is by effectiveComponent content is established respectively 5 dosage processing, establishes clear water contrast. With reference to " the indoor biometric of agricultural chemicalsDetermine test rule bactericide " carry out, adopt mycelial growth rate method to measure medicament to crop germVirulence. After 72h, measure colony diameter by right-angled intersection method, calculate each processing net growth,Mycelial growth inhibition rate. Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) conversionBecome logarithm value (x), try to achieve virulence regression equation (y=a+bx) with least square method, and thusCalculate the EC of every kind of medicament50Value. Calculate the different proportionings of two medicaments according to Wadley method simultaneouslySynergy ratio (SR), SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action,SR > 1.5 is synergistic effect. Computing formula is as follows:
Wherein: a, b are respectively active components A and active component B shared ratio in combination;
A is tiger glue adipic acid copper;
B is selected from the one in epoxiconazole, penconazole.
Application Example two:
For trying disease: sigatoka; Test medicine provides by applicant.
Experimental design: determine tiger glue adipic acid copper and epoxiconazole raw drug and the two not through pilot studyWith effective inhibition concentration scope of proportioning mixture.
Toxicity test result
The composite toxicity test analysis of results table to sigatoka of table 9 tiger glue adipic acid copper and epoxiconazole
As shown in Table 9, tiger glue adipic acid copper and epoxiconazole proportioning in the time of 80 ︰ 1～1 ︰ 80 to bananaThe synergy ratio SR of leaf spot is all greater than 1.5, illustrates that both are in 80 ︰ 1～1 ︰ 80 scopesMixture all shows synergistic effect, when the proportioning of tiger glue adipic acid copper and epoxiconazole is at 30:1～1:20Time, synergistic effect is more outstanding, and synergy ratio is all more than 2.25; When tiger glue adipic acid copper withThe proportioning of epoxiconazole is in the time of 19:1～1:9, and synergistic effect is more outstanding, and synergy ratio is all 2.40Above, especially synergy ratio maximum in the time that tiger glue adipic acid copper and epoxiconazole weight ratio are 4:1,Synergistic effect is the most obvious.
Application Example three:
For trying disease: angular leaf spot of cucumber; Test medicine provides by applicant.
Experimental design: determine tiger glue adipic acid copper and the former medicine of penconazole and the two not through pilot studyWith effective inhibition concentration scope of proportioning mixture.
Toxicity test result
The composite toxicity test analysis of results table to angular leaf spot of cucumber of table 10 tiger glue adipic acid copper and penconazole
As shown in Table 10, tiger glue adipic acid copper and penconazole proportioning in the time of 80 ︰ 1～1 ︰ 80 to HuangThe synergy ratio SR of melon angular leaf spot is all greater than 1.5, illustrates that both are in 80 ︰ 1～1 ︰ 80 scopesInterior mixture all shows synergistic effect, when the proportioning of tiger glue adipic acid copper and penconazole existsWhen 40:1～1:10, synergistic effect is more outstanding, and synergy ratio is all more than 2.20; Work as amberThe proportioning of glue adipic acid copper and penconazole is in the time of 29:1～1:1, and synergistic effect is more outstanding, synergyRatio is all more than 2.30, and especially working as tiger glue adipic acid copper and penconazole weight ratio is 14:1Shi Zengxiao ratio maximum, synergistic effect is the most obvious.
Test and find that the optimum ratio of tiger glue adipic acid copper and epoxiconazole is 30 ︰ 1,29 through applicant︰1、28︰1、27︰1、26︰1、25︰1、24︰1、23︰1、22︰1、21︰1、20︰1、19︰1、18︰1、17︰1、16︰1、15︰1、14︰1、13︰1、12︰1、11︰1、10︰1、9︰1、8︰1、7︰1、6︰1、5︰1、4︰1、3︰1、2︰1、1︰1、1︰2、1︰3、1︰4、1︰5、1︰6、1︰7、1︰8、1︰9、1︰10、1︰11、1︰12、1︰13、1︰14、1︰15、1︰16、1︰17、1︰18, when 1 ︰ 19,1 ︰ 20; The optimum ratio of tiger glue adipic acid copper and penconazole is 40 ︰ 1,39︰1、38︰1、37︰1、36︰1、35︰1、34︰1、33︰1、32︰1、31︰1、30︰1、29︰1、28︰1、27︰1、26︰1、25︰1、24︰1、23︰1、22︰1、21︰1、20︰1、19︰1、18︰1、17︰1、16︰1、15︰1、14︰1、13︰1、12︰1、11︰1、10︰1、9︰1、8︰1、7︰1、6︰1、5︰1、4︰1、3︰1、2︰1、1︰1、1︰2、1︰3、1︰4、1︰5、1︰6、1︰7、1When ︰ 8,1 ︰ 9,1 ︰ 10; Synergistic effect is comparatively obvious.
Find through test simultaneously: after tiger glue adipic acid copper and active component B are composite to various cropOn angular leaf spot, downy mildew, anthracnose, droop, canker, damping-off, virosis,Soft rot, clubroot, black rot, black spot, balck shank, circle line disease, shot hole, maculaSick, downright bad disease, fruit rot, sour rot, spot disease, leaf spot, white star, black points,Epidemic disease, powdery mildew, bacterial wilt, verticillium wilt, scab, false smut, white rot or rustControl has obvious synergistic effect, and synergy ratio SR is all greater than 1.5.
Effect experiment part: test medicine is researched and developed, provided by applicant, contrast medicament 30% amber glueAdipic acid copper wettable powder (commercial), 12.5% epoxiconazole suspension concentrate (commercial), 10% penta bacteriumAzoles missible oil (autogamy).
Application Example four tiger glue adipic acid coppers and active component B and the composite angular leaf spot of cucumber of preventing and treating thereofThe test of pesticide effectiveness.
This test arrangement, at Xian District, Shanxi Province suburban area, is investigated angular leaf spot of cucumber disease index before medicine,In the dispenser of disease early period of origination, also meter of 3 days, 10 days, 20 days investigation disease indexes after dispenserCalculate preventive effect. Result of the test is as follows:
Table 11 tiger glue adipic acid copper and active component B and the composite angular leaf spot of cucumber test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 11, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeAngular leaf spot of cucumber, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat powdery mildew of cucumber, downy mildew, prevention effect, all higher than 97%, is better than single dosePreventive effect, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example five tiger glue adipic acid coppers and active component B and composite control tomato virus disease thereofThe test of pesticide effectiveness.
This test arrangement, at Xian District, Shanxi Province suburban area, is investigated tomato virus disease disease index before medicine,In the dispenser of disease early period of origination, also meter of 3 days, 10 days, 20 days investigation disease indexes after dispenserCalculate preventive effect. Result of the test is as follows:
Table 12 tiger glue adipic acid copper and active component B and the composite control tomato virus disease test of pesticide effectiveness thereof
As can be seen from Table 12, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeTomato virus disease, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat tomato blight, soft rot, circle line disease, shot hole, macula disease, canker,Downright bad disease, fruit rot, sour rot, spot disease, bacterial wilt or verticillium wilt, prevention effect is all highIn 97%, be better than the preventive effect of single dose, and the preventive effect phase is long. In test scope of medication, target is doneThing has no adverse effects.
Application Example six tiger glue adipic acid coppers and active component B and composite control pepper anthracnose thereofThe test of pesticide effectiveness.
This test arrangement, at Xian District, Shanxi Province suburban area, is investigated pepper anthracnose disease index before medicine,In the dispenser of disease early period of origination, also meter of 3 days, 10 days, 20 days investigation disease indexes after dispenserCalculate preventive effect. Result of the test is as follows:
Table 13 tiger glue adipic acid copper and active component B and the composite control pepper anthracnose test of pesticide effectiveness thereof
As can be seen from Table 13, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositePepper anthracnose, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat capsicum leaf spot, soft rot, white star, black points, black spot, white powderDisease, shot hole, droop, verticillium wilt, prevention effect, all higher than 97%, is better than the anti-of single doseEffect, and the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example seven tiger glue adipic acid coppers and active component B and composite control rice green smut thereofThe test of pesticide effectiveness.
This test arrangement, at Shaanxi Province's Hanzhong City, is investigated rice green smut disease index before medicine,The dispenser of disease early period of origination, after dispenser, 3 days, 10 days, 20 days investigation disease indexes also calculatePreventive effect. Result of the test is as follows:
Table 14 tiger glue adipic acid copper and active component B and the composite control rice green smut test of pesticide effectiveness thereof
As can be seen from Table 14, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeRice green smut, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat rice seedling blight, prevention effect, all higher than 97%, is better than the preventive effect of single dose,And the preventive effect phase is long. In test scope of medication, target crop is had no adverse effects.
Application Example eight tiger glue adipic acid coppers and active component B and composite control uncinula necator thereofThe test of pesticide effectiveness.
This test arrangement is in Weinan City Dali County, Shaanxi Province, and before medicine, investigation uncinula necator disease refers toNumber, in the dispenser of disease early period of origination, 3 days, 10 days, 20 days investigation disease indexes after dispenserAnd calculate preventive effect. Result of the test is as follows:
Table 15 tiger glue adipic acid copper and active component B and the composite control uncinula necator test of pesticide effectiveness thereof
As can be seen from Table 15, tiger glue adipic acid copper and active component B can effectively prevent and treat after compositeUncinula necator, through applicant test find tiger glue adipic acid copper and active component B composite after alsoCan effectively prevent and treat fruit white rot of grape, anthracnose, downy mildew, prevention effect is all higher than 97%,Be better than the preventive effect of single dose, and the preventive effect phase is long. Test scope of medication in to target crop without badImpact.
After draw through different local throughout the country tests, tiger glue adipic acid copper and active componentB composite rear to the angular leaf spot in various crop, downy mildew, anthracnose, droop, canker,Damping-off, virosis, soft rot, clubroot, black rot, black spot, balck shank, circle lineDisease, shot hole, macula disease, downright bad disease, fruit rot, sour rot, spot disease, leaf spot,White star, black points, epidemic disease, powdery mildew, bacterial wilt, verticillium wilt, scab, false smut,The preventive effect of the Common Diseases such as white rot or rust all, more than 97%, is better than single dose preventive effect, synergyEffect obviously.
Claims (6)
1. containing a composition pesticide for tiger glue adipic acid copper and triazole type, it is characterized in that: haveEffect active component is active components A and active component B, active components A and active component BWeight ratio is 1 ︰ 80～80 ︰ 1, and described active components A is tiger glue adipic acid copper, active componentB is selected from the one in epoxiconazole, penconazole.
2. the composition pesticide containing tiger glue adipic acid copper and triazole type according to claim 1,It is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 60～60 ︰ 1.
3. the composition pesticide containing tiger glue adipic acid copper and triazole type according to claim 2,It is characterized in that:
The weight ratio of tiger glue adipic acid copper and epoxiconazole is 30:1～1:20;
The weight ratio of tiger glue adipic acid copper and penconazole is 40:1～1:10.
According to described in any one in claims 1 to 3 containing tiger glue adipic acid copper and triazole typeComposition pesticide, it is characterized in that: composition make wettable powder, water dispersible granules,Suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent.
5. the composition pesticide containing tiger glue adipic acid copper and triazole type according to claim 4For preventing and treating the purposes of disease on crops.
6. purposes according to claim 5, is characterized in that: described disease is anglePinta, downy mildew, anthracnose, droop, canker, damping-off, virosis, soft rot,Clubroot, black rot, black spot, balck shank, circle line disease, shot hole, macula disease, necrosisDisease, fruit rot, sour rot, spot disease, leaf spot, white star, black points, epidemic disease,Powdery mildew, bacterial wilt, verticillium wilt, scab, false smut, white rot or rust.
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