CN105623800A - Strippable and easily-recoverable hard-film rust preventive oil and preparation method thereof - Google Patents
Strippable and easily-recoverable hard-film rust preventive oil and preparation method thereof Download PDFInfo
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- CN105623800A CN105623800A CN201511031841.XA CN201511031841A CN105623800A CN 105623800 A CN105623800 A CN 105623800A CN 201511031841 A CN201511031841 A CN 201511031841A CN 105623800 A CN105623800 A CN 105623800A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/20—Condensation polymers of aldehydes or ketones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/40—Polysaccharides, e.g. cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/02—Natural products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/24—Epoxidised acids; Ester derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/285—Esters of aromatic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/48—Slushing oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
Abstract
The invention relates to strippable and easily-recoverable hard-film rust preventive oil. The hard-film rust preventive oil contains a main film forming agent, an auxiliary film forming agent, a rust preventer, a plasticizer, an antioxidant, other additives and a solvent and is uniform transparent liquid which is prepared through proportionally mixing all the ingredients. According to the hard-film rust preventive oil, the main film forming agent is selected from natural products such as cellulose, agarose and chitosan, and derivatives thereof, and other ingredients, i.e., alkali metal or alkaline-earth metal petroleum sulfonate with relatively good rust resistance, amides with better film forming or supplementary film forming property, carboxylic acids with relatively high polarity and relatively high adsorptivity, esters which give attention to product rust prevention and product stability improvement, and naphthenates which give attention to rust prevention and drying assisting performance are selected, so that the product is relatively good in film forming property and toughness and is applicable to operation of different oil impregnation processes such as dip-coating, brush-coating and spray-coating; during removal, the common solvent cleaning process can be changed into a manual stripping process, and the product obtained through stripping can be recovered and then be recycled as a new raw material, so that the pollution discharge of downstream enterprises is lowered.
Description
Technical field
The invention belongs to rust-proof oil technical field of improvement, especially a kind of peelable easy recovery hard film rust preventive oil and preparation method thereof.
Background technology
Metal is in storage, in transport and use procedure, easily by the impact of external environment, there is corrosion, thus causing that the outward appearance of metal changes, the reduction of performance, even functional forfeiture, in order to avoid or reduce corrosion of metal harmful effect that society is brought, various antirust technologies should need and give birth to, this technology mainly includes surface preparation, plating, thermal spraying, hot-dip, surface modification, diffusion into the surface is penetrated into, corrosion inhibiter, antirust oil, passivating solution etc., wherein antirust oil can form one layer of protective film in metal surface, can effectively prevent external substance corroding metal, there is practical simplicity, easily remove, outward appearance does not affect follow-up assembling advantage after beautifying and removing during as temporary transient antirust means, the application of all kinds of rust prevention during manufactures occupies leading position. hard film rust preventive oil in antirust oil due to its dry tack free, be easily portable, the advantage such as antirust cycle length, get most of the attention in antirust oil. but general hard film rust preventive oil have can not stack, clean difficulty, subsequent treatment produces the problem such as pollution, not only increases the use cost of product, product cleans the problems such as the environmental protection that produces and also limit the extensive use of hard film rust preventive oil.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that different process easy to use, applicable, moulding property and good toughness, the peelable easy recovery hard film rust preventive oil of free of contamination one.
The present invention adopts the technical scheme that:
A kind of peelable easy recovery hard film rust preventive oil, it is characterised in that: include the following components mixed by weight percentage:
And, described main film former is any one or two kinds in methylcellulose, ethyl cellulose, carboxymethyl cellulose, Triafol T, hydroxypropyl methylcellulose, maleation chitosan, phthaloyl chitosan, ether amine chitosan, synthetic wax, cellulose xanthate, cellulose acetate butyrate, palm wax.
And, described auxiliary film former is any one or two kinds in rosin resin, phenolic resin, Petropols, alkyd varnish, terpene resin, butadiene-styrene rubber, EP rubbers.
And, described antirust agent be in calcium mahogany sulfonate, the new decyl amide of N-octadecyl, petroleum sodium sulfonate, this Pan 80, dodecenylsuccinic acid, oleic acid, N-octadecyl oleamide, N-cetyl stearmide, castor oil acid, cyclohexyl cinnamate, zinc naphthenate, oxidized petrolatum, dinonylnaphthalene sulfonic acid calcium, stearic acid, DC11, N-octadecyl isooctyl acid amine any one, two kinds, three kinds or four kinds.
And, described plasticizer is any one in dibutyl phthalate, epoxy soybean oil, dioctyl adipate, diisooctyl phthalate, phthalic acid ester.
And, described antioxidant is any one in 2,6 ditertiary butyl p cresol, antioxidant 330, antioxidant MEB.
And, other additives described be in defoamer (B-458, N-10), auxiliary rheological agents (RC-750, EW-180), dyestuff (fat lemon yellow, oil-soluble blue), leveling auxiliary agent (DP-231, Z6030), thinner (CA093) any one, two or three.
And, described solvent is any one or two kinds in dehydrated alcohol, 120# solvent naphtha, banana oil, anhydrous isopropyl alcohol, petroleum ether, 200# solvent naphtha, dichloromethane.
The preparation method that it is a further object to provide a kind of peelable easy recovery hard film rust preventive oil, it is characterized in that: comprise the following steps: solvent is put into reactor, then main film former and secondary film formers are added, stand or after stirring immersion 16h, start stirring, to be filmed dose be completely dissolved after, it is warming up to 45��55 DEG C, puts into antioxidant, antirust agent in order successively, plasticizer and other additives, namely stirring obtains product to system transparent and homogeneous.
Advantages of the present invention and having the benefit effect that
In the present invention, including main film former, auxiliary film former, antirust agent, plasticizer, antioxidant, other additives and solvent, after each component is mixed in proportion, after forming transparent and homogeneous liquid, it is product. main film former is selected from cellulose, agarose, the natural products such as chitosan and derivant thereof, other compositional selecting petroleum sulfonate of rustless property preferably alkali metal or alkaline-earth metal, film forming or the better amide-type of supplementary film property, polarity is bigger, the carboxylic acids that adsorptivity is stronger, take into account product antirust and increase the esters of product stability, take into account antirust with drying ability in the Naphthenates of one, product film property and toughness are all better, not easily season cracking, thin film has isotropism and inter-molecular binding force is strong, using method is simply extensive, color is transparent and adjustable, good stability, viscosity is adjustable within the specific limits, to adapt to dip-coating, brush, the different immersion oil technique such as spraying is operated, can change conventional solvent washing process during removal is peel manually separating process, process is simple and convenient, safety and environmental protection, and significantly reduce the use cost of product, peel off the product that obtains recyclable after re-use as new raw material, reduce the disposal of pollutants of down-stream enterprise.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described, and following embodiment is illustrative, is not determinate, it is impossible to limits protection scope of the present invention with following embodiment.
A kind of peelable easy recovery hard film rust preventive oil, the innovation of the present invention is in that: include the following components mixed by weight percentage:
Wherein, described main film former is any one or two kinds in methylcellulose, ethyl cellulose, carboxymethyl cellulose, Triafol T, hydroxypropyl methylcellulose, maleation chitosan, phthaloyl chitosan, ether amine chitosan, synthetic wax, cellulose xanthate, cellulose acetate butyrate, palm wax.
Described auxiliary film former is any one or two kinds in rosin resin, phenolic resin, Petropols, alkyd varnish, terpene resin, butadiene-styrene rubber, EP rubbers.
Described antirust agent be in calcium mahogany sulfonate, the new decyl amide of N-octadecyl, petroleum sodium sulfonate, this Pan 80, dodecenylsuccinic acid, oleic acid, N-octadecyl oleamide, N-cetyl stearmide, castor oil acid, cyclohexyl cinnamate, zinc naphthenate, oxidized petrolatum, dinonylnaphthalene sulfonic acid calcium, stearic acid, DC11, N-octadecyl isooctyl acid amine any one, two kinds, three kinds or four kinds.
Described plasticizer is any one in dibutyl phthalate, epoxy soybean oil, dioctyl adipate, diisooctyl phthalate, phthalic acid ester.
Described antioxidant is any one in DBPC 2,6 ditertiary butyl p cresol, antioxidant 330, antioxidant MEB.
Other additives described be in defoamer (B-458, N-10), auxiliary rheological agents (RC-750, EW-180), dyestuff (fat lemon yellow, oil-soluble blue), leveling auxiliary agent (DP-231, Z6030), thinner (CA093) any one, two or three.
Described solvent is any one or two kinds in dehydrated alcohol, 120# solvent naphtha, banana oil, anhydrous isopropyl alcohol, petroleum ether, 200# solvent naphtha, dichloromethane.
The preparation method of above-mentioned peelable easy recovery hard film rust preventive oil is: solvent is put into reactor, then main film former and secondary film formers are added, stand or after stirring immersion 16h, starting stirring, to be filmed dose is completely dissolved rear (about 8h), is warming up to 45��55 DEG C, put into antioxidant in order successively, antirust agent, plasticizer and other additives, stir to system transparent and homogeneous (about 8h) and namely obtain product.
Embodiment 1:
Embodiment 2:
Embodiment 3:
Embodiment 4:
Embodiment 5:
Embodiment 6:
Embodiment 7:
Embodiment 8:
Embodiment 9:
Embodiment 10:
Embodiment 11:
Embodiment 12:
Embodiment 13:
Embodiment 14:
Embodiment 15:
Product should away from kindling material, thermal source, and absolutely no smoking in working space, uses ventilating system and the equipment of explosion-proof type, it is prevented that vapour leakage is in workplace air, it is to avoid with oxidising agent. Want with light packs during carrying gently to unload, prevent packaging and container damage, it is stored in the storehouse of cool place, ventilation, Ku Wen is no more than 30 DEG C, prevent from exposing to the weather and drenching with rain, never mixed storage, adopt explosion-proof type illumination, ventilation equipment, prohibitting the use of the plant equipment and instrument that are easily generated spark, storage area should have leakage emergency processing equipment and suitable collecting material.
Product stock solution uses, it is adaptable to the Rustproof process on common metal surface. To ferrous metal antirust cycle of indoor preservation more than 2 years.
When the present invention uses:
First being cleaned up by pending metal works, remove surface and oil contaminant and hand perspiration finish-drying, the workpiece of painting antirust oil is not allow for hand perspiration or Korrosionsmedium remains in metal surface.
Room temperature uses, and according to technological requirement, adopts the oiling modes such as dip-coating, brushing, spraying.
After being completely dried film forming, when can adopt PE-PP composite waterproofing membrane, packaging and storage, the mutual collision between workpiece should be avoided, in order to avoid damage oil film is complete as far as possible.
During part unpacking, thin film directly can be taken off from metal surface and return manufacturer and recycle further after de-dirt processes.
With tradition antirust oil comparison in Table 1:
Table 1: with tradition antirust oil comparison result
In the present invention, including main film former, auxiliary film former, antirust agent, plasticizer, antioxidant, other additives and solvent, after each component is mixed in proportion, after forming transparent and homogeneous liquid, it is product. main film former is selected from cellulose, agarose, the natural products such as chitosan and derivant thereof, other compositional selecting petroleum sulfonate of rustless property preferably alkali metal or alkaline-earth metal, film forming or the better amide-type of supplementary film property, polarity is bigger, the carboxylic acids that adsorptivity is stronger, take into account product antirust and increase the esters of product stability, take into account antirust with drying ability in the Naphthenates of one, product film property and toughness are all better, not easily season cracking, thin film has isotropism and inter-molecular binding force is strong, using method is simply extensive, color is transparent and adjustable, good stability, viscosity is adjustable within the specific limits, to adapt to dip-coating, brush, the different immersion oil technique such as spraying is operated, can change conventional solvent washing process during removal is peel manually separating process, process is simple and convenient, safety and environmental protection, and significantly reduce the use cost of product, peel off the product that obtains recyclable after re-use as new raw material, reduce the disposal of pollutants of down-stream enterprise.
Claims (9)
1. a peelable easy recovery hard film rust preventive oil, it is characterised in that: include the following components mixed by weight percentage:
2. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: described main film former is any one or two kinds in methylcellulose, ethyl cellulose, carboxymethyl cellulose, Triafol T, hydroxypropyl methylcellulose, maleation chitosan, phthaloyl chitosan, ether amine chitosan, synthetic wax, cellulose xanthate, cellulose acetate butyrate, palm wax.
3. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: described auxiliary film former is any one or two kinds in rosin resin, phenolic resin, Petropols, alkyd varnish, terpene resin, butadiene-styrene rubber, EP rubbers.
4. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: described antirust agent be in calcium mahogany sulfonate, the new decyl amide of N-octadecyl, petroleum sodium sulfonate, this Pan 80, dodecenylsuccinic acid, oleic acid, N-octadecyl oleamide, N-cetyl stearmide, castor oil acid, cyclohexyl cinnamate, zinc naphthenate, oxidized petrolatum, dinonylnaphthalene sulfonic acid calcium, stearic acid, DC11, N-octadecyl isooctyl acid amine any one, two kinds, three kinds or four kinds.
5. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: described plasticizer is any one in dibutyl phthalate, epoxy soybean oil, dioctyl adipate, diisooctyl phthalate, phthalic acid ester.
6. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: described antioxidant is any one in 2,6 ditertiary butyl p cresol, antioxidant 330, antioxidant MEB.
7. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: other additives described be in defoamer, auxiliary rheological agents, dyestuff, leveling auxiliary agent, thinner any one, two or three.
8. the peelable easy recovery hard film rust preventive oil of one according to claim 1, it is characterised in that: described solvent is any one or two kinds in dehydrated alcohol, 120# solvent naphtha, banana oil, anhydrous isopropyl alcohol, petroleum ether, 200# solvent naphtha, dichloromethane.
9. the preparation method of a kind of peelable easy recovery hard film rust preventive oil according to claim 1, it is characterised in that: comprise the following steps:
Solvent is put into reactor, then main film former and secondary film formers are added, stand or after stirring immersion 16h, start stirring, to be filmed dose be completely dissolved after, be warming up to 45��55 DEG C, put into antioxidant in order successively, antirust agent, plasticizer and other additives, namely stirring obtains product to system transparent and homogeneous.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511031841.XA CN105623800A (en) | 2015-12-30 | 2015-12-30 | Strippable and easily-recoverable hard-film rust preventive oil and preparation method thereof |
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| CN201511031841.XA CN105623800A (en) | 2015-12-30 | 2015-12-30 | Strippable and easily-recoverable hard-film rust preventive oil and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833844A (en) * | 2017-01-21 | 2017-06-13 | 上海新平精细化学品有限公司 | A kind of peelable plastic sheeting antirust agent of solvent-borne type and preparation method thereof |
| CN107177400A (en) * | 2017-04-25 | 2017-09-19 | 安徽索立德铸业有限公司 | A kind of hot investment casting part antirust oil and preparation method thereof |
| CN107653045A (en) * | 2017-11-01 | 2018-02-02 | 上海有道新能源技术有限公司 | Antirust oil and preparation method thereof |
| CN108707497A (en) * | 2018-07-11 | 2018-10-26 | 佛山市陵谐环保科技有限公司 | A kind of corrosion-resistant hard film rust preventive oil |
| CN110643230A (en) * | 2019-09-05 | 2020-01-03 | 中海油常州涂料化工研究院有限公司 | Hot-melt super-hydrophobic corrosion-inhibition coating anticorrosive material and preparation method thereof |
| CN113845809A (en) * | 2021-10-10 | 2021-12-28 | 山立欣业新材料(广东)有限公司 | Cleaning-free antirust material capable of being stripped or cleaned by heating as well as preparation and application thereof |
| CN114921147A (en) * | 2022-05-13 | 2022-08-19 | 杭州金固环保设备科技有限公司 | Recyclable antirust agent, preparation method thereof and recycling method thereof |
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| CN103540393A (en) * | 2013-10-28 | 2014-01-29 | 李荣福 | Brown high-build quick-drying antirust oil applicable to diesel engines of ships and warships and preparation method thereof |
| CN104194902A (en) * | 2014-09-28 | 2014-12-10 | 无锡康柏斯机械科技有限公司 | Preparation method of hard film anti-rust oil with high hardness |
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| CN1218076A (en) * | 1997-11-24 | 1999-06-02 | 中国石油化工总公司 | Wax composition for durably dustproofing metal products |
| CN101892116A (en) * | 2010-07-21 | 2010-11-24 | 广西大学 | Environmentally friendly car parts antirust oil |
| CN103540393A (en) * | 2013-10-28 | 2014-01-29 | 李荣福 | Brown high-build quick-drying antirust oil applicable to diesel engines of ships and warships and preparation method thereof |
| CN104194902A (en) * | 2014-09-28 | 2014-12-10 | 无锡康柏斯机械科技有限公司 | Preparation method of hard film anti-rust oil with high hardness |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833844A (en) * | 2017-01-21 | 2017-06-13 | 上海新平精细化学品有限公司 | A kind of peelable plastic sheeting antirust agent of solvent-borne type and preparation method thereof |
| CN106833844B (en) * | 2017-01-21 | 2019-06-04 | 上海新平精细化学品有限公司 | A kind of peelable plastic film antirust agent of solvent type and preparation method thereof |
| CN107177400A (en) * | 2017-04-25 | 2017-09-19 | 安徽索立德铸业有限公司 | A kind of hot investment casting part antirust oil and preparation method thereof |
| CN107653045A (en) * | 2017-11-01 | 2018-02-02 | 上海有道新能源技术有限公司 | Antirust oil and preparation method thereof |
| CN108707497A (en) * | 2018-07-11 | 2018-10-26 | 佛山市陵谐环保科技有限公司 | A kind of corrosion-resistant hard film rust preventive oil |
| CN110643230A (en) * | 2019-09-05 | 2020-01-03 | 中海油常州涂料化工研究院有限公司 | Hot-melt super-hydrophobic corrosion-inhibition coating anticorrosive material and preparation method thereof |
| CN110643230B (en) * | 2019-09-05 | 2021-07-13 | 中海油常州涂料化工研究院有限公司 | Hot-melt super-hydrophobic corrosion-inhibition coating anticorrosive material and preparation method thereof |
| CN113845809A (en) * | 2021-10-10 | 2021-12-28 | 山立欣业新材料(广东)有限公司 | Cleaning-free antirust material capable of being stripped or cleaned by heating as well as preparation and application thereof |
| CN114921147A (en) * | 2022-05-13 | 2022-08-19 | 杭州金固环保设备科技有限公司 | Recyclable antirust agent, preparation method thereof and recycling method thereof |
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