CN105623489B - Anti scuffing polyurethane matte paint - Google Patents

Anti scuffing polyurethane matte paint Download PDF

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Publication number
CN105623489B
CN105623489B CN201610154009.7A CN201610154009A CN105623489B CN 105623489 B CN105623489 B CN 105623489B CN 201610154009 A CN201610154009 A CN 201610154009A CN 105623489 B CN105623489 B CN 105623489B
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China
Prior art keywords
parts
anti scuffing
matte paint
polyurethane
polyurethane matte
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Active
Application number
CN201610154009.7A
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Chinese (zh)
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CN105623489A (en
Inventor
朱意明
李钊
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LIUZHOU KAIBAI CHEMICAL Co Ltd
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LIUZHOU KAIBAI CHEMICAL Co Ltd
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Application filed by LIUZHOU KAIBAI CHEMICAL Co Ltd filed Critical LIUZHOU KAIBAI CHEMICAL Co Ltd
Priority to CN201610154009.7A priority Critical patent/CN105623489B/en
Publication of CN105623489A publication Critical patent/CN105623489A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention discloses a kind of anti scuffing polyurethane matte paint, counts, is mainly made up of following raw material in parts by weight:20 30 parts of polyurethane resin, 10 16 parts of polycarbonate elastomer body resin, 26 33 parts of propandiol butyl ether, 35 parts of dispersant, 12 15 parts of propylene glycol monomethyl ether, 15 parts of methylisobutylketone, 6 10 parts of flatting silica, 12 parts of anti scuffing auxiliary agent, 14 20 parts of UV absorbers.The anti scuffing polyurethane matte paint of the present invention can further enrich the coating material solidified selections in the application of the plastic casing such as automobile or mobile phone of PU, not only wear-resisting scratch-resisting, chemical proofing, durability of such product etc. are all had a distinct increment, also to its feel, anti-pollution can greatly improve, meet the requirement of high-grade automobile or electronic product casing, good economic benefit can be produced.

Description

Anti scuffing polyurethane matte paint
Technical field
The invention belongs to paint field, and in particular to a kind of anti scuffing polyurethane matte paint.
Background technology
Urethane cures coating is tradition and uses most, the most wide coating system of purposes, except with high-performance at present Chemical resistance, or both economical type, low baking, the efficient saving energy, coating performance is good after solidification, and being adapted to should The advantages that for high-speed automated production, so the coating material solidified yield of PU is constantly in stable uptrend in recent years, Plastic cement products, such as automobile, mobile phone, the application utilization rate of computer swift electron consumer goods shell and dosage also greatly improve.But With the development of society and the requirement more and more higher of consumer, the performance and appearance requirement of coating also improve therewith.Pursue first Comfortable feel, secondly anti scuffing effect is good, is not easy to damage, and convenient not trace is arranged in cleaning, durable in use, increases substantially product Class, so being applied to the new high anti scuffing high-performance PU matte varnish in automobile or consumer electronicses field It is imperative.
The content of the invention
The technical problem to be solved in the present invention is to overcome the defects of existing, there is provided a kind of anti scuffing polyurethane matte paint.
In order to solve the above-mentioned technical problem, the invention provides following technical scheme:
Anti scuffing polyurethane matte paint, is counted in parts by weight, is mainly made up of following raw material:
Polyurethane resin 20-30 parts,
Polycarbonate elastomer body resin 10-16 parts,
Propandiol butyl ether 26-33 parts,
Dispersant 3-5 parts,
Propylene glycol monomethyl ether 12-15 parts,
Methylisobutylketone 1-5 parts,
Flatting silica 6-10 parts,
Anti scuffing auxiliary agent 1-2 parts,
UV absorbers 14-20 parts.
Further, the anti scuffing auxiliary agent is aralkyl modified methylalkylpolysiloxanes.
Further, the raw material of the anti scuffing polyurethane matte paint also includes the stain resistance auxiliary agent of 1-2 parts by weight.
Further, the stain resistance auxiliary agent is silicone-modified polyacrylate.
Further, the raw material of the anti scuffing polyurethane matte paint also includes the drier of 6-14 parts by weight.
Further, the drier is lutidines.
Propylene glycol monomethyl ether is used in mixed way with propandiol butyl ether to be helped to prevent the erosion to priming paint.
It is coating material solidified in the modeling such as automobile or mobile phone that the anti scuffing polyurethane matte paint of the present invention can further enrich PU Expect the selection in the application of shell, not only have to wear-resisting scratch-resisting, chemical proofing, durability of such product etc. larger Lifting, can also greatly improve to its feel, anti-pollution, meet the requirement of high-grade automobile or electronic product casing, can be with Produce good economic benefit.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, and a part for constitution instruction, the reality with the present invention Apply example to be used to explain the present invention together, be not construed as limiting the invention.In the accompanying drawings:
Fig. 1 is the anti scuffing performance test of the present invention.
Embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that described herein preferred real Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
The formula of anti scuffing polyurethane matte paint of the present invention is as follows:
First add 1-6 items to add in stirred tank, after stirring, be slow added into the 7th, stir.Redisperse 10-15 min, to fineness 3.5H, 8-11 items are then added successively, are stirred, be eventually adding the 12nd and adjust and glue.
Polyurethane resin needs color inhibition, and ultraviolet lamp burn-in test, 1200kJ paint films aberration is less than 0.03, to acrylic acid Priming paint has strong adhesive force;Polycarbonate elastomer resin need to have it is not counter stick, constant temperature and humidity occurs without viscous hand, touches flexible Feel.
The key technical indexes of product of the present invention:
1st, remarkable scratch resistance energy(Anti- more than 2N mechanical performance stroke wound), nail scratch leave no trace.
2nd, grease, cosmetics and it is other it is dirty be stained with after, it is easy to be rubbed off.
3rd, possesses very smooth hand sense of touch.
3rd, solvent resistant, chemicals-resistant and salt spray test, show unchanged.
4th, UV is exposed to the sun E less than 0.7, and adhesive force is intact.
5th, adhesive force test is more than 4B.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic. Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's Within protection domain.

Claims (4)

1. anti scuffing polyurethane matte paint, is counted in parts by weight, mainly it is made up of following raw material:
Polyurethane resin 20-30 parts,
Polycarbonate elastomer body resin 10-16 parts,
Propandiol butyl ether 26-33 parts,
Dispersant 3-5 parts,
Propylene glycol monomethyl ether 12-15 parts,
Methylisobutylketone 1-5 parts,
Flatting silica 6-10 parts,
Anti scuffing auxiliary agent 1-2 parts,
UV absorbers 14-20 parts,
Stain resistance auxiliary agent 1-2 parts by weight, the stain resistance auxiliary agent are silicone-modified polyacrylate.
2. anti scuffing polyurethane matte paint according to claim 1, it is characterised in that the anti scuffing auxiliary agent is aralkyl Modified methyl alkyl polysiloxane.
3. anti scuffing polyurethane matte paint according to claim 1, it is characterised in that the raw material also includes 6-14 weight The drier of part.
4. anti scuffing polyurethane matte paint according to claim 3, it is characterised in that the drier is dimethyl pyrazole Pyridine.
CN201610154009.7A 2016-03-17 2016-03-17 Anti scuffing polyurethane matte paint Active CN105623489B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610154009.7A CN105623489B (en) 2016-03-17 2016-03-17 Anti scuffing polyurethane matte paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610154009.7A CN105623489B (en) 2016-03-17 2016-03-17 Anti scuffing polyurethane matte paint

Publications (2)

Publication Number Publication Date
CN105623489A CN105623489A (en) 2016-06-01
CN105623489B true CN105623489B (en) 2017-12-29

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108330732A (en) * 2018-01-31 2018-07-27 上海宏盾防伪材料有限公司 One kind having the function of the mute adjustable aqueous polyurethane coating of degree of scratch resistant
CN108977019A (en) * 2018-05-18 2018-12-11 刘凡领 A kind of preparation method of high viscosity high-leveling dumb light paint
CN112590446B (en) * 2020-12-30 2022-05-24 佛山市长盛兴隆装饰材料有限公司 Antique copper wire drawing PET transfer film, preparation method thereof and printing stock
CN112852273B (en) * 2020-12-31 2022-05-03 惠州飞凯新材料有限公司 Water-based matte scratch-resistant paint and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381581A (en) * 2008-10-27 2009-03-11 深圳市广田环保涂料有限公司 Polyurethane transparent matt topcoat, preparation method and use method thereof
CN101717603A (en) * 2009-11-03 2010-06-02 深圳市广田环保涂料有限公司 Aqueous dull finishing coat, preparation method and use method thereof
CN104725622A (en) * 2013-12-23 2015-06-24 常州华科聚合物股份有限公司 Elastic resin, method for preparing elastic resin and elastic hand feeling paint

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101435968B1 (en) * 2012-12-20 2014-08-29 (주)노루페인트 Anti-scratch clear paint composition and method of manufacturing paint film using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101381581A (en) * 2008-10-27 2009-03-11 深圳市广田环保涂料有限公司 Polyurethane transparent matt topcoat, preparation method and use method thereof
CN101717603A (en) * 2009-11-03 2010-06-02 深圳市广田环保涂料有限公司 Aqueous dull finishing coat, preparation method and use method thereof
CN104725622A (en) * 2013-12-23 2015-06-24 常州华科聚合物股份有限公司 Elastic resin, method for preparing elastic resin and elastic hand feeling paint

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