CN105623326B - 一种纳米贝壳粉生态功能弹涂涂料 - Google Patents
一种纳米贝壳粉生态功能弹涂涂料 Download PDFInfo
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- CN105623326B CN105623326B CN201610211964.XA CN201610211964A CN105623326B CN 105623326 B CN105623326 B CN 105623326B CN 201610211964 A CN201610211964 A CN 201610211964A CN 105623326 B CN105623326 B CN 105623326B
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- C—CHEMISTRY; METALLURGY
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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Abstract
本发明涉及一种环保涂料，即一种纳米贝壳粉生态功能弹涂涂料。它由贝壳粉、灰钙、高岭土、重钙、水合硅酸镁、钛白粉、醋酸乙烯酯、羟乙基纤维素、聚乙烯醇、聚二甲基硅氧烷、减水剂、消泡剂、石英粉、分解酶成分制成。解决了“甲醛、苯、氨、氡、有机化合物TVOC、APEO”污染问题。解决了传统室内壁材发黄、发霉、鼓包、变色、裂缝、使用时间短、返潮后滋生大量细菌的问题。解决了室内温度、湿度，空气清新度问题。
Description
技术领域
本发明涉及一种环保涂料，即一种纳米贝壳粉生态功能弹涂涂料。
背景技术
在现有技术中，随着人们对健康意识的需求不断提高，传统墙面材料因释放有害物质和不会“呼吸”所导致的“塑料大棚效应”，对居住舒适性以及健康产生重大影响。壁材传统产品存在的环境，甲醛、苯、氨、氡、有机化合物、TVOC、重金属污染的问题。
贝壳粉涂料应需而生，满足了人们对现代壁材健康，环保，美观等所有消费需求，从此，墙面壁材进入了一个崭新的时代――“贝壳粉时代”。
发明内容
本发明的目的是针对上述不足而提供一种纳米贝壳粉生态功能弹涂涂料。解决了“甲醛、苯、氨、氡、有机化合物TVOC、APEO”污染问题。解决了传统室内壁材发黄、发霉、鼓包、变色、裂缝、使用时间短、返潮后滋生大量细菌的问题。解决了室内温度、湿度，空气清新度问题。
本发明的技术解决方案是：一种纳米贝壳粉生态功能弹涂涂料，其特征在于由以下重量份数的原料制成：贝壳粉（锻烧）240－300，粒度24.72um－18.54um，灰钙100－125，粒度24.72um，高岭土70－90，重钙190－230，粒度18.54um，水合硅酸镁85－105，粒度18.54um，钛白粉14－18，醋酸乙烯酯30－40，羟乙基纤维素5－7，聚乙烯醇8－12，粒度98.9um，聚二甲基硅氧烷2.5－3.5，减水剂0.5－1.5，消泡剂2.5－3.5，分解酶0.5－1.5，石英粉135－165，粒度123.6um。
优选纳米贝壳粉生态功能弹涂涂料，其特征在于由以下重量份数的原料制成：贝壳粉（锻烧）275，粒度24.72um－18.54um，灰钙115，粒度24.72um，高岭土80，重钙210，粒度18.54um，水合硅酸镁95，粒度18.54um，钛白粉16，醋酸乙烯酯35，羟乙基纤维素6，聚乙烯醇10，粒度98.9um，聚二甲基硅氧烷3，减水剂1，消泡剂3，分解酶1，石英粉150，粒度123.6um。
贝壳粉（锻烧）制备方法：将贝壳经酸浸泡0.5-1h，经二次水洗机清水洗涤0.2h，经滚筒脱水筛脱水，送入烘干机干燥，在烘干后设置旋风除尘器除尘，再送入锻烧烘干机，在900℃-1200℃煅烧催化，送入冷却机冷却，锤破，提升到超细微粉磨超细研磨，制得纳米贝壳粉。
用途：直接用于内墙涂料。
弹涂配料方法其施工工艺解决了墙面装饰平（滚）涂简单的工艺方法，而使墙面装修呈立体感，美感。本配方配料可实现丰富多彩的手工工艺制作肌理。图案如：如松、滚花、压花、稻香、土伦、拟丝、布艺、陶纹、水纹、细流、抹花、喷涂、连波、波纹、松方、扇贝、砖艺、梦幻、树皮、双陶纹麻面、思绪、蝶舞、羽艺、风韵、艺术佛印、祥云、如涛、冰湖、平湖、金木、欧式、典雅等，并可实现单花、对角花、碎花、壁纸花、剪影、书画、树、网印、镂印、辊花、卡通、走廊、中国花、祥云、沙发、花开富贵、畅想、新简欧、灯池二十一大系列工艺制作肌理。
工艺上采用自动化变频，煅烧工艺自动温控：500℃、600℃、800℃、850℃、900℃、1000℃、1050℃、1100℃、1150℃、1200℃可调控。超细微磨粉，脉冲除尘工艺，其主要回转体、扬料板、传动装置和密封体，结构合理，产品高能耗低。采用天然气热源，脉冲除尘采用国内外最先进的在线脉冲，喷吹技术，清灰彻底，运行阻力低，除尘高效，完全自动控制，运转效率高。超细微粉磨机产品细度一次性可达到d97≤5um.它由磨粉机，送粉机，集粉器、除尘器、风机、消声器，隔音室。给料机一体结构，环保型，脉冲除尘器和消声器的使用可以减轻粉尘污染，降低噪音，达到国家的环保标准，对周围的环境无污染。选用国内先进的自动化生产设备，最先进的自动煅烧、变频、研磨、脉冲除尘、自动混配料、自动调频、自动罐装，自动打包生产线，以保证产品质量，满足产品十五大生态功能特性要求。
制备原料含量说明：
1、贝壳粉：主要成份是碳酸钙，贝壳粉碳酸钙经煅烧后为多孔纤维状双螺旋体结构，可有效去除空气中的游离甲醛，氨及由吸烟产生的异味，净化室内空气。另外，贝壳粉碳酸钙的多孔结构有利于制成具有光触媒特性的生态壁材。
贝壳粉碳酸钙具有抑菌，杀菌能力，可通过在贝壳粉碳酸钙微孔中负载活性纳米二氧化钛和纳米电气石粉实现。纳米级的二氧化钛和纳米级的电气石粉负载到贝壳粉碳酸钙的微孔之中后，与贝壳粉碳酸钙是一种紧密且牢固的结合，不会因擦洗而脱落，可以长久的释放出负氧离子对室内空气进行净化和杀菌处理。
2、灰钙：灰钙别名氢氧化钙。是一种气硬性胶凝材料，应用于建筑涂料中能够提高涂料的耐水性、耐洗刷性、流平性好。灰钙粉的主要成分是Ca(OH)2、CaO和少量CaCO3的混合物，是石灰的精加工产品。灰钙粉是由以CaCO3为主要成分的天然优质石灰石，经高温煅烧后成为生石灰（CaO）后，再经精选，部分消化，然后再通过高速风选锤式粉碎机粉碎而成的，其表观洁白细腻。近年来，由于粉体加工技术的进步，市场上已经具有细度在600目以上的或更高细度的灰钙粉商品。
灰钙粉加入涂料中，随着涂料的涂装成膜，氢氧化钙（氧化钙遇水后也变成氢氧化钙）会与空气中的CO2反应生成碳酸钙晶体而产生强度，进而在涂膜中能够为涂料组分提供一定的粘结性，并赋予涂料显著的耐水性。以灰钙粉为主要活性填料生产的各种建筑涂料具有成本低，耐水性好等特点。
3、高岭土：质纯的高岭土具有白度高、质软、易分散悬浮于水中、良好的可塑性和高的粘粘性、优良的电绝缘性能；具有良好的抗酸溶性、很低的阳离子交换量、较好的耐火性等理化性质。
4、重钙：通常用作填料，起到增加产品的体积，降低生产成本。涂料用重质碳酸钙（重钙粉）800目或1000目，白度：95%，碳酸钙：96%，)能使涂料不沉降，易分散，光泽好等特性。
5、水合硅酸镁（滑石粉）：滑石主要成分是滑石含水的硅酸镁，分子式为Mg3［Si4O10］(OH)2。水合硅酸镁：化工级滑石粉 ，用于强化改质填充剂。特点：增加产品行状的稳定，增加张力强度，剪切强度，绕曲强度，压力强度，降低变形，伸张率，热膨胀系数，白度高、粒度均匀分散性强等特点。
滑石具有润滑性、抗黏、助流、耐火性、抗酸性、绝缘性、熔点高、化学性不活泼、遮盖力良好、柔软、光泽好、吸附力强等优良的物理、化学特性。
6、钛白粉：钛白粉的主要成分是TiO2，他兼有锌白的持久性和铅白的遮盖性，是高档白色颜料，与其他白色颜料比较有优越的白度、着色力、遮盖力、耐候性、耐热性、和化学稳定性，特别是没有毒性。
涂料行业是钛白粉的最大用户，特别是金红石型钛白粉，大部分被涂料工业所消耗。用钛白粉制造的涂料，色彩鲜艳，遮盖力高，着色力强，用量省，品种多，对介质的稳定性可起到保护作用，并能增强漆膜的机械强度和附着力，防止裂纹，防止紫外线和水分透过，延长漆膜寿命。
7、醋酸乙烯酯：乙酸乙烯酯为无色液体，具有甜的醚味；微溶于水，溶于醇、丙酮、苯、氯仿。用于作黏结剂等。
8、羟乙基纤维素：羟乙基纤维素作为一种非离子型的表面活性剂，除具有增稠、悬浮、粘合、浮化、成膜、分散、保水及提供保护胶体作用。即用作作表面活性剂，胶体保护剂，氯乙烯、醋酸乙烯等乳液取合用的乳化稳定剂，以及乳胶的增粘剂、分散剂、分散稳定剂等。广泛应用于涂料。
9、聚乙烯醇：简称PVA。外观为白色粉末，是一种用途相当广泛的水溶性高分子聚合物，性能介于塑料和橡胶之间，具有独特的强力粘接性、皮膜柔韧性、平滑性、耐油性、耐溶剂性、保护胶体性、气体阻绝性、耐磨性以及经特殊处理具有的耐水性，被大量用作粘合剂。
10、聚二甲基硅氧烷：聚二甲基硅氧烷(PDMS)是一种高分子有机硅化合物，通常被称为有机硅。具有光学透明，具有耐热性、耐寒性、防水性、导热性，黏度随温度变化小、表面张力小。
11、减水剂：减水剂主要能提高砂浆的强度。具有减水和增强作用。
12、消泡剂：消泡剂（又名：抗泡剂），产品特点：易分散、消泡速度快、抑泡持久，不会造成水的二次污染。消泡剂抑泡性强，不影响体系的各种技术参数。用量少，效率高。
13、石英粉：是制造涂料的填加料，具备如下机能：（1）精良的光学性子：方石英的折射率从石英的1.55降低到1.48，更靠近PE、PP及一些树脂的折射率。夹杂后的树脂呈通明状，不粉饰颜料自己的色采，而用别的填料添补则会使颜料的色采变浅、失真。（2）反射率：方石英的详细布局有助光反射，可代替玻璃微珠作反光油漆，既可加强防滑性，又可进步油漆的反光性。（3）白度，低密度、光彩亮光：方石英的白度达95%以上，在涂料、油漆中使用，可代替部门钛白粉，低落配方本钱。（4）抗腐化、耐刻画、耐擦洗、耐磨机能好。（5）不含有机物净化,金属含量极低:可加强涂料的抗紫内线本领,并具备精良的绝缘性、精良的电磁辐射性和低的介电常数。（6）精良的抗热震性，方石英受热220m240℃左右时，产生必定水平的热收缩，恰好抵偿环氧树脂、石膏等在此温度下固化反响时的紧缩，使浇注体不变形。
14、分解酶：分解吸收室内装修叠加效应产生的甲醛等有害物质。
本发明的优点是：
1.净化空气，清除甲醛：新房子装修后的地板，大芯板、沙发、家具等散发的游离甲醛、苯、氨、氡、TVOC等有毒重金属有害物质被贝壳粉张开的数以万计的小孔吸收、分解、消除。贝壳粉张网以待室内每天不断散发的有害物质，释放多少、分解多少。
2.呼吸调湿：呼吸调湿是贝壳粉的基本功能，当室内潮湿超过70%时，贝壳粉的微孔将空气中的水分吸进去储备起来，当空气湿度低于40%时，将水分释放出来，所以人们把贝壳粉称为“会呼吸的墙壁”不用加湿器，不用人为操纵，保持室内达到人体最舒适的湿度，另外，贝壳粉也保证被子、衣物不会潮湿。墙体也不含有发霉现象发生。
3.减弱噪音：无数微孔可以吸收、阻隔噪音。他的效果相当于同等厚度的水泥砂浆和石板的2倍以上，同时还吸收50%的余音。
4.消除异味：能去除生活污染产生的各种异味。例如：养鱼的鱼腥味，宠物的体臭味。厨房、卫生间、吸烟带来的异味，可吸附并通过空气对流释放，时刻保持室内的空气清新。
5.防火阻燃：贝壳粉壁材耐高温1400摄氏度，只有熔点没有燃点，遇明火不燃烧，不产生任何有毒烟雾。
6.抗菌、抑菌、杀菌消毒：不滋生任何菌类，永不霉变，能够有效杀死空气中的各种流感和传染病病菌。
7.使用寿命长：作为装修材料的贝壳粉使用寿命长达25年以上，永不退色，不翘边，不脱落、耐氧化，始终如新。
8.易修补：局部损坏，极易修补，修补后的墙面与原体一致，局部污染用橡皮既可擦掉。
9.防静电：贝壳粉是天然的矿物质，主要成分是钙，自身不含重金属，不产生静电，所以不吸尘、永保室内墙壁清洁。
10.防止光污染：吸光性强，反射光线柔和不刺眼，眼不疲劳，降低儿童近视几率。
11.色彩柔和：因为贝壳粉是由海洋贝壳粉煅烧、研磨成粉末制成的，富含各种皮肤再生需要的氨基酸和微量元素，钙、磷、锰、锌、铜、铁、钾、镁等，有保持滋润，复活再生的效果，可以改变皮肤暗沉，能预测皮肤老化，适合各种肤质。所以贝壳粉也是一种时尚的化妆品。
12.隔热节能：形态结构决定了贝壳粉的热传导率很低，保温隔热性能非常好，比水泥和砂浆高6倍以上，大大节约耗电和采暖费用。
13.释放负氧离子和远红外线：贝壳粉每平方厘米释放1800多个负氧离子，负氧离子在空气中四处浮游，人如同生活在大自然中，远红外线有利于调节人体微循环，提高人们的睡眠质量。
14.艺术效果：各种图案、纹理，丝绸效果综合应用，应有尽有，豪华而文雅，色彩持续稳定，不褪色，不脱落。
15.采用纳米技术及材料生产：具有“分子筛”结构特点，螺旋体多孔性能强，孔隙率高。
16.本产品经吉林省长春市产品质量监督检验院检测，所有污染源全部是“0”。具体是: 苯、甲醛、乙苯、二甲苯总和未检出（标准mg/kg＜50），合格。游离甲醛未检出（标准mg/kg＜5），合格。可溶性重金属未检出（标准mg/kg＜10），合格。甲醛净化效率大于79％（标准mg/kg大于75％），合格。挥发性有机化合物含量未检出（标准g/kg＜1），合格。
下面将结合实施例对本发明的实施方式作进一步详细描述。
具体实施方式
实施例1
纳米贝壳粉生态功能弹涂涂料，其特征在于由以下重量份数的原料制成：贝壳粉（锻烧）275，粒度24.72um－18.54um，灰钙115，粒度24.72um，高岭土80，重钙210，粒度18.54um，水合硅酸镁95，粒度18.54um，钛白粉16，醋酸乙烯酯35，羟乙基纤维素6，聚乙烯醇10，粒度98.9um，聚二甲基硅氧烷3，减水剂1，消泡剂3，分解酶1，石英粉150，粒度123.6um。
本发明这一具有划时代意义的生态功能涂料， 是全球最先进的，性能最好的第五代新型功能涂料产品，解决了室内装饰装潢。本发明具有抗霉菌，净化空气，防霉变，螺旋式孔结构，涂层厚度3.0mm-3.5mm，光泽度高，无明显色差，耐冲击，耐磨，耐水，耐高低温，耐候老化，使产品使用寿命长达25年以上等特点。
实施例2
工艺流程：经螺旋式洗料机二次水洗使贝壳壳体表面更洁净，无残留物质存在→滚筒式脱水筛脱水，含水量低于10%→进入烘干机煅烧（煅烧温度900-1200℃，煅烧时间3.7t/h），煅烧过程采用天然气热源，经脉冲除尘器进行除尘处理→煅烧后经冷却机对物料进行冷却→锤破破碎→经风送提升机将物料送入超细微粉磨，叶轮碾压方法自动化变频，磨粉达到24.72um-18.54um之间后经风送至储料罐→将半成品料用螺旋提升机送至U型螺带混合机混拌→经单嘴阀口包装机及敞口式包装机定量计量包装。
Claims (2)
1.一种贝壳粉生态功能弹涂涂料，其特征在于由以下重量份数的原料制成：贝壳粉240－300，粒度24.72μm－18.54μm；灰钙100－125，粒度24.72μm；高岭土70－90；重钙190－230，粒度18.54μm；水合硅酸镁85－105，粒度18.54μm；钛白粉14－18；醋酸乙烯酯30－40；羟乙基纤维素5－7；聚乙烯醇8－12，粒度98.9μm；聚二甲基硅氧烷2.5－3.5；减水剂0.5－1.5；消泡剂2.5－3.5；分解酶0.5－1.5；石英粉135－165，粒度123.6μm；所述的贝壳粉是将贝壳经酸浸泡0.5-1h，经二次水洗机清水洗涤0.2h，经滚筒脱水筛脱水，送入烘干机干燥，在烘干后设置旋风除尘器除尘处理，再送入锻烧烘干机，在900℃-1200℃煅烧催化，送入冷却机冷却，锤破，提升到超细微粉磨超细研磨，制得贝壳粉。
2.按照权利要求1所述的贝壳粉生态功能弹涂涂料，其特征在于由以下重量份数的原料制成：贝壳粉275，粒度24.72μm－18.54μm；灰钙115，粒度24.72μm；高岭土80；重钙210，粒度18.54μm；水合硅酸镁95，粒度18.54μm；钛白粉16；醋酸乙烯酯35；羟乙基纤维素6；聚乙烯醇10，粒度98.9μm；聚二甲基硅氧烷3；减水剂1；消泡剂3；分解酶1；石英粉150，粒度123.6μm。
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