CN105614652A - Heavy metal remover and method for removing heavy metal in fishy products by same - Google Patents

Heavy metal remover and method for removing heavy metal in fishy products by same Download PDF

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Publication number
CN105614652A
CN105614652A CN201610073166.5A CN201610073166A CN105614652A CN 105614652 A CN105614652 A CN 105614652A CN 201610073166 A CN201610073166 A CN 201610073166A CN 105614652 A CN105614652 A CN 105614652A
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China
Prior art keywords
heavy metal
removing agent
sodium
fish products
parts
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Pending
Application number
CN201610073166.5A
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Chinese (zh)
Inventor
周劲松
钱植龙
杨忠明
万梅梅
马培元
杨桓
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HUNAN HUAWEN FOOD Co Ltd
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HUNAN HUAWEN FOOD Co Ltd
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Priority to CN201610073166.5A priority Critical patent/CN105614652A/en
Publication of CN105614652A publication Critical patent/CN105614652A/en
Pending legal-status Critical Current

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Abstract

The invention provides a heavy metal remover which comprises, by mass, 25-30 parts of sodium gluconate, 25-30 parts of sodium acetate, 25-30 parts of sodium citrate and 5-10 parts of sodium carbonate. The invention further provides a method for removing heavy metal in fishy products by the heavy metal remover. The ingredients of the heavy metal remover, namely sodium gluconate, sodium acetate, sodium citrate and sodium carbonate, are all natural and safe food additives harmless to human beings. The method includes making soak solution by the heavy metal remover and soaking fishy products in the soak solution. By the method, more than 50% of heavy metal in fishes can be removed. Accordingly, the method is simple and effective.

Description

Heavy metal removing agent and utilize the method for heavy metal in its elimination fish products
Technical field
The present invention relates to fish products, particularly relate to heavy metal removing agent and utilize the method for heavy metal in its elimination fish products.
Background technology
Along with the modern development of industrial or agricultural, the discharge of municipal domestic waste and Industrial " three Waste " is increasing, industrial wastewater containing various chemical toxicants enters rivers,lakes and seas in a large number, heavy metal contaminants is constantly accumulated and is enriched with in fish body, human body is entered finally by food chain, human body is worked the mischief, and therefore, how removing the heavy metal in fish products becomes countries in the world all questions of common concern.
In traditional elimination fish products, the method for heavy metal has: adopt non-food stuff additive that fish products is processed, but treatment effect is bad, and bringing secondary pollution to fish products, these non-food stuff additives enter human body and can human body be worked the mischief equally.
Summary of the invention
Based on this, it is necessary to for Problems existing in background technology, it is provided that a kind of efficient, safe, harmless heavy metal removing agent.
Additionally, the present invention also provides for a kind of utilizing the method for heavy metal in above-mentioned heavy metal removing agent elimination fish products.
A kind of heavy metal removing agent, in mass fraction, composed of the following components:
Sodium gluconate 25 ~ 30 parts;
Sodium acetate 25 ~ 30 parts;
Sodium citrate 25 ~ 30 parts;
Sodium carbonate 5 ~ 10 parts.
A kind of utilize the method for heavy metal in above-mentioned heavy metal removing agent elimination fish products, comprise the following steps:
The sodium gluconate of 25 ~ 30 mass parts, the sodium acetate of 25 ~ 30 mass parts, the sodium citrate of 25 ~ 30 mass parts and the sodium carbonate of 5 ~ 10 mass parts are mixed, obtains heavy metal removing agent;
By soluble in water for described heavy metal removing agent, obtain soak;
Fish products being put in described soak and soak 12 ~ 14 hours, taking-up drains away the water, the fish products after being processed.
Wherein in an embodiment, in described soak, heavy metal removing agent is 1 ~ 1.5:100 ~ 120 with the mass ratio of water;
Wherein in an embodiment, described fish products is 1 ~ 1.2:5 ~ 8 with the mass ratio of water in described soak.
Wherein in an embodiment, described heavy metal is one or more in cadmium, lead, arsenic, hydrargyrum.
Above-mentioned heavy metal removing agent is made up of sodium gluconate, sodium acetate, sodium citrate and sodium carbonate, is all food additive natural safely, harmless.
Additionally, heavy metal removing agent is made soak, fish products is put into and wherein soaks, just can by the heavy metal removing of more than 50% on fish body, simple, efficiently, and without influence on the voluptuousness of fish body and mouthfeel.
Detailed description of the invention
Understandable for enabling the above-mentioned purpose of the present invention, feature and advantage to become apparent from, below the specific embodiment of the present invention is described in detail. Elaborate a lot of detail in the following description so that fully understanding the present invention. But the present invention can implement being much different from alternate manner described here, and those skilled in the art can do similar improvement when without prejudice to intension of the present invention, therefore the present invention is by the following public restriction being embodied as.
A kind of heavy metal removing agent, is made up of the sodium gluconate of 25 ~ 30 mass parts, the sodium acetate of 25 ~ 30 mass parts, the sodium citrate of 25 ~ 30 mass parts and the sodium carbonate of 5 ~ 10 mass parts.
In this heavy metal removing agent, sodium gluconate, sodium acetate, sodium citrate, sodium carbonate are the food additive that safety is natural, harmless.
A kind of utilize the method for heavy metal in above-mentioned heavy metal removing agent elimination fish products, comprise the following steps:
S110, by the sodium carbonate mixing of the sodium gluconate of 25 ~ 30 mass parts, the sodium acetate of 25 ~ 30 mass parts, the sodium citrate of 25 ~ 30 mass parts and 5 ~ 10 mass parts, obtain heavy metal removing agent.
S120, by soluble in water for above-mentioned heavy metal removing agent, obtain soak.
Wherein, in soak, the mass ratio of heavy metal removing agent and water is 1 ~ 1.5:100 ~ 120.
Preferably, in soak, the mass ratio of heavy metal removing agent and water is 1:100.
It is appreciated that, in in immersion, the height of heavy metal removing agent concentration can be allocated according to the content of heavy metal on fish body, the important indicator that in soak, the height of heavy metal removing agent concentration will be elimination heavy metal, the heavy metal that can remove when concentration height is also more many, and the heavy metal removed when the concentration is low is more few.
S130, fish products is put in above-mentioned soak soak 12 ~ 14 hours, taking-up drains away the water, the fish products after being processed.
Wherein, fish products is 1 ~ 1.2:5 ~ 8 with the mass ratio of water in soak.
Preferably, fish products is 1:5 with the mass ratio of water in soak.
It should be noted that above-mentioned immersion is to be completely submerged in soak by fish products, fish products is more little with the more big then removal effect of mass ratio of water in soak, and the more little then removal effect of mass ratio is more big.
Adopting atomic absorption instrument, detect by GB heavy metal detection method, in the fish products after adopting heavy metal removing agent to process, on fish body, the heavy metal of more than 50% obtains elimination.
In the present embodiment, heavy metal is one or more in cadmium, lead, arsenic, hydrargyrum.
Above-mentioned utilize the method for heavy metal in heavy metal removing agent elimination fish products, adopt the scientific matching of these simple ion chelating agents in heavy metal removing agent, the mode exchanged by ion makes the heavy metal ions removal in fish body out, reduce the content of heavy metal, simply, efficiently, the heavy metal of more than 50% on fish body can be removed.
It it is below specific embodiment.
Embodiment 1
30g sodium gluconate, 30g sodium acetate, 30g sodium citrate and 10g sodium carbonate are mixed, obtains heavy metal removing agent.
1g heavy metal removing agent is dissolved in 100g water, makes soak.
20g fish products is put in above-mentioned soak and soak 12 hours, take out, drain away the water, the fish products after being processed.
Adopting atomic absorption instrument by GB heavy metal detection method, the fish products adopting heavy metal removing agent to process front and back to be detected, its result is in Table 1.
Table 1 fish products processes the content of front and back heavy metal
As can be seen from Table 1, no matter being ocean fishes or fresh-water fishes, the fish products after adopting heavy metal removing agent to process, on fish body, the heavy metal of more than 50% is obtained for elimination, and the content of beary metal of the fish products after process meets the requirements.
Embodiment described above only have expressed the several embodiments of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention. It should be pointed out that, for the person of ordinary skill of the art, without departing from the inventive concept of the premise, it is also possible to making some deformation and improvement, these broadly fall into protection scope of the present invention. Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (5)

1. a heavy metal removing agent, it is characterised in that in mass fraction, composed of the following components:
Sodium gluconate 25 ~ 30 parts;
Sodium acetate 25 ~ 30 parts;
Sodium citrate 25 ~ 30 parts;
Sodium carbonate 5 ~ 10 parts.
2. the method for heavy metal in the heavy metal removing agent elimination fish products that a kind utilizes described in claim 1, it is characterised in that comprise the following steps:
The sodium gluconate of 25 ~ 30 mass parts, the sodium acetate of 25 ~ 30 mass parts, the sodium citrate of 25 ~ 30 mass parts and the sodium carbonate of 5 ~ 10 mass parts are mixed, obtains heavy metal removing agent;
By soluble in water for described heavy metal removing agent, obtain soak;
Fish products being put in described soak and soak 12 ~ 14 hours, taking-up drains away the water, the fish products after being processed.
3. according to claim 2 utilize the method for heavy metal in heavy metal removing agent elimination fish products, it is characterised in that in described soak, heavy metal removing agent is 1 ~ 1.5:100 ~ 120 with the mass ratio of water.
4. according to claim 3 utilize the method for heavy metal in heavy metal removing agent elimination fish products, it is characterised in that described fish products is 1 ~ 1.2:5 ~ 8 with the mass ratio of water in described soak.
5. according to claim 2 utilize the method for heavy metal in heavy metal removing fish products, it is characterised in that described heavy metal is one or more in cadmium, lead, arsenic, hydrargyrum.
CN201610073166.5A 2016-02-03 2016-02-03 Heavy metal remover and method for removing heavy metal in fishy products by same Pending CN105614652A (en)

Priority Applications (1)

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CN201610073166.5A CN105614652A (en) 2016-02-03 2016-02-03 Heavy metal remover and method for removing heavy metal in fishy products by same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610073166.5A CN105614652A (en) 2016-02-03 2016-02-03 Heavy metal remover and method for removing heavy metal in fishy products by same

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107647326A (en) * 2017-09-11 2018-02-02 浙江海洋大学 A kind for the treatment of agent formula of instant shelled shrimp and the processing method of instant shelled shrimp
CN107712819A (en) * 2017-09-21 2018-02-23 浙江海洋大学 A kind of de- cadmium inkfish juice sauce processing method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103693789A (en) * 2013-12-09 2014-04-02 华南师范大学 Resource recycling method of heavy metals in heavy metal wastewater

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103693789A (en) * 2013-12-09 2014-04-02 华南师范大学 Resource recycling method of heavy metals in heavy metal wastewater

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张光华: "《水处理化学品制备与应用指南》", 31 October 2003, 中国石化出版社 *
黄民生 等: "曲霉对水中重金属的吸附去除", 《化工装备技术》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107647326A (en) * 2017-09-11 2018-02-02 浙江海洋大学 A kind for the treatment of agent formula of instant shelled shrimp and the processing method of instant shelled shrimp
CN107712819A (en) * 2017-09-21 2018-02-23 浙江海洋大学 A kind of de- cadmium inkfish juice sauce processing method

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Application publication date: 20160601