CN105607167B - A kind of three-stage surface phasmon lens - Google Patents
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Abstract
一种三段式表面等离激元透镜,涉及表面等离激元。由三层刻蚀在金属表面的矩形凹槽组成,在线偏振光照明下,将形成突破衍射极限的越小尺寸表面等离激元焦点,凹槽宽度为λ/2,每层凹槽的中心位置均分布在三条线段上,对于第i层(i=1,2,3),每层凹槽的长度和中心位置按如下设计:第i层凹槽左右侧边中点到焦点的距离分别满足f+(i‑1)d+kλ/3和f+(i‑1)d+(k+1)λ/3,k称为凹槽的级次,使同一层相邻两个凹槽的k相差3,各凹槽对应于传统波带片中的菲尼尔带;当沿y方向偏振的平面波垂直金属表面照明结构时,表面等离激元将在各凹槽上被同相激发,且传播到焦点处时相长干涉形成焦点。
A three-stage surface plasmon lens relates to surface plasmons. It consists of three layers of rectangular grooves etched on the metal surface. Under the illumination of linear polarized light, it will form a smaller-sized surface plasmon focus that breaks through the diffraction limit. The width of the groove is λ/2. The center of each groove The positions are all distributed on three line segments. For the i-th layer (i=1, 2, 3), the length and center position of each layer of grooves are designed as follows: Satisfying f+(i‑1)d+kλ/3 and f+(i‑1)d+(k+1)λ/3, k is called the order of the groove, so that the k difference between two adjacent grooves on the same layer 3. Each groove corresponds to the Fresnel zone in the traditional zone plate; when the plane wave polarized along the y direction is perpendicular to the metal surface to illuminate the structure, the surface plasmons will be excited in the same phase on each groove and propagate to At the focal point constructive interference forms the focal point.
Description
技术领域technical field
本发明涉及表面等离激元,尤其是涉及可实现超小焦点的一种三段式表面等离激元透镜。The invention relates to surface plasmons, in particular to a three-stage surface plasmon lens capable of realizing ultra-small focus.
背景技术Background technique
表面等离激元(Surface Plasmon Polariton)是一种局域在金属/介质表面的电磁场表面模式,其特点是电磁场强度在垂直于金属表面的方向上指数衰减;并且以大于介质中同频率光子的波数沿金属表面传播。在一定条件下,光和表面等离激元之间可以实现能量转换。这使得人们可以利用表面等离激元在微米乃至纳米尺度的范围内对光进行操控。基于表面等离激元的各种功能器件的研究以及相关理论研究成为近年来的热点,吸引着众多科研人员的关注。Surface Plasmon Polariton (Surface Plasmon Polariton) is an electromagnetic field surface mode localized on the metal/medium surface, which is characterized by the exponential decay of the electromagnetic field strength in the direction perpendicular to the metal surface; Wavenumbers propagate along the metal surface. Under certain conditions, energy conversion between light and surface plasmons can be achieved. This allows people to use surface plasmons to manipulate light in the range of micrometer and nanoscale. Research on various functional devices based on surface plasmons and related theoretical research has become a hot spot in recent years, attracting the attention of many researchers.
在众多表面等离激元的平面光子学器件中,对表面等离激元的透镜件研究一直是表面等离激元器件研究的热点,这是因为实现聚焦直接关系到显微成像、探测、光存储、光镊等应用功能目前实现二维表面等离激元聚焦的结构主要有以下方案:(1)利用在金属表面构建突起结构对传播途径中的表面等离激元作波前调控实现聚焦;(2)利用纳米颗粒构成抛物线和圆弧聚焦表面等离激元;(3)在金属表面制备圆形光栅聚焦表面等离激元;(4)利用光栅段作为基本结构单元的表面等离激元透镜等。虽然这几种方案的核心思想都是利用表面等离激元的电磁场在焦点处的相位完全相干增强而聚焦,但在具体的实现上稍有不同。在方案(1)和(2)中表面等离激元的激发和相位调控是两个独立的过程:即先通过金属上的窄条突起或纳米洞点阵(作为天线)先实现远场光到表面等离激元的转换耦合;其次再利用金属表面微纳米结构对波前进行整形。而在方案(3)和(4)中,表面等离激元的相位在激发的同时就已经被设计确定,即表面等离激元的激发耦合和相位控制结构合二为一。在上述众多的表面等离激元透镜件中,最受广泛关注的是方案(3)中的圆型透镜,其结构是刻在金属膜上的单个或多个同心圆环槽构成。由于圆的几何对称性,相比于线偏振光照明,若采用径向偏振光(Radially Polarized Light)激发,将能明显提高聚焦效果,得到更强的焦点和更小的焦点半宽(G.M.Lerman,A.Yanai,and U.Levy,“Demonstration ofnanofocusing by the use of plasmonic lens illuminated with radially polarizedlight”,Nano Lett.9,2139(2009);W.Chen,D.C.Abeysinghe,R.L.Nelson,and Q.Zhan,“Plasmonic lens made of multiple concentric metallic rings under radiallypolarized illumination”,Nano Lett.9,4320(2009))。这是因为表面等离激元是横磁波,只有垂直于光栅结构的偏振分量才能有效激发。径向偏振照明时,光偏振方向处处垂直圆型光栅,各个位置都能同强度激发沿圆心传播的表面等离激元。而用线偏振光作为激发源时,实际上并未完全利用到整个圆型光栅结构,特别是在偏振方向平行圆弧切线的位置,表面等离激元的激发效率很低(A.V.Zayatsa,I.I.Smolyaninovb,and A.A.Maradudinc,“Nano-optics of surface plasmon polaritons”,Phys.Reports 408,131(2005))。但是采用径向偏振激发的方案存在两大问题:首先产生径向偏振光需预先将线偏振光作一定处理,这给实际应用带来不便;其次径向偏振照明存在光源和结构的对准问题,即需要保证激发光斑的中心处在圆型透镜的圆心上。考虑到透镜的尺寸(~直径几十微米),实现起来并不容易。Among the many planar photonic devices of surface plasmons, the research on the lens of surface plasmons has always been a hot spot in the research of surface plasmons, because the realization of focusing is directly related to microscopic imaging, detection, Optical storage, optical tweezers and other application functions currently realize two-dimensional surface plasmon focusing structures mainly include the following schemes: (1) Use the protrusion structure on the metal surface to control the wave front of the surface plasmon in the propagation path. Focusing; (2) Use nanoparticles to form parabola and arc focusing surface plasmons; (3) Prepare circular grating focusing surface plasmons on the metal surface; (4) Use grating segments as the surface of the basic structural unit, etc. excitonic lens, etc. Although the core idea of these schemes is to use the phase coherent enhancement of the electromagnetic field of surface plasmons at the focal point to focus, the specific implementations are slightly different. In schemes (1) and (2), the excitation and phase regulation of surface plasmons are two independent processes: first, the far-field light is first realized through the narrow strip protrusions or nanohole lattices on the metal (as antennas). The conversion coupling to the surface plasmon; secondly, the wavefront is shaped by the micro-nano structure of the metal surface. In schemes (3) and (4), the phase of the surface plasmons has been designed and determined at the same time as the excitation, that is, the excitation coupling and phase control structure of the surface plasmons are combined into one. Among the numerous surface plasmon lens elements mentioned above, the circular lens in solution (3) is the most widely concerned, and its structure is composed of single or multiple concentric annular grooves carved on the metal film. Due to the geometric symmetry of the circle, compared with linearly polarized light illumination, if radially polarized light (Radialy Polarized Light) is used for excitation, the focusing effect will be significantly improved, and a stronger focus and smaller focus half-width will be obtained (G.M.Lerman , A.Yanai, and U.Levy, "Demonstration of nanofocusing by the use of plasmonic lens illuminated with radially polarized light", Nano Lett.9, 2139 (2009); W.Chen, D.C.Abeysinghe, R.L.Nelson, and Q.Zhan, "Plasmonic lens made of multiple concentric metallic rings under radially polarized illumination", Nano Lett. 9, 4320 (2009)). This is because the surface plasmon is a transverse magnetic wave, and only the polarization component perpendicular to the grating structure can be effectively excited. In the case of radially polarized illumination, the light polarization direction is perpendicular to the circular grating everywhere, and each position can excite the surface plasmons propagating along the center of the circle with the same intensity. When linearly polarized light is used as the excitation source, the entire circular grating structure is not fully utilized, especially at the position where the polarization direction is parallel to the arc tangent, and the excitation efficiency of surface plasmons is very low (A.V.Zayatsa, I.I. Smolyaninovb, and A.A. Maradudinc, "Nano-optics of surface plasmon polaritons", Phys. Reports 408, 131 (2005)). However, there are two major problems in the scheme of radially polarized excitation: firstly, linearly polarized light needs to be processed in advance to generate radially polarized light, which brings inconvenience to practical applications; secondly, there is an alignment problem between the light source and the structure in radially polarized illumination , that is, it is necessary to ensure that the center of the excitation spot is on the center of the circular lens. Considering the size of the lens (~ tens of microns in diameter), it is not easy to realize.
发明内容Contents of the invention
本发明的目的在于提供可实现超小焦点的一种三段式表面等离激元透镜。The purpose of the present invention is to provide a three-segment surface plasmon lens capable of realizing an ultra-small focus.
本发明由三层刻蚀在金属表面的矩形凹槽组成,在垂直于金属表面入射的线偏振光照明下,将形成突破衍射极限的越小尺寸表面等离激元焦点,所述矩形凹槽的宽度W均为λ/2,其中λ是表面等离激元的波长,每层凹槽的中心位置均分布在三条线段上,对于第i层(i=1,2,3),其轨迹由以下分段函数给出:The invention consists of three layers of rectangular grooves etched on the metal surface. Under the illumination of linearly polarized light incident perpendicular to the metal surface, a smaller-sized surface plasmon focus that breaks through the diffraction limit will be formed. The rectangular grooves The width W of each is λ/2, where λ is the wavelength of the surface plasmon, and the center positions of the grooves in each layer are distributed on three line segments. For the i-th layer (i=1, 2, 3), the trajectory is given by the following piecewise function:
其中f是焦距,d=2λ/3是水平线段部分的层间距,α和β是两个需要优化的参数,式(1)中的“+”和“-”号分别对应x≥[f+(i-1)d]tanα和x≤-[f+(i-1)d]tanα;每层凹槽的长度和中心位置按照如下设计:第i层凹槽的左侧边和右侧边中点到焦点的距离分别满足f+(i-1)d+kλ/3和f+(i-1)d+(k+1)λ/3,其中整数k称为凹槽的级次,k按如下方式取值,使同一层相邻两个凹槽的k相差3,即:Wherein f is the focal length, d=2λ/3 is the layer spacing of the horizontal line segment, α and β are two parameters that need to be optimized, and the "+" and "-" signs in the formula (1) correspond to x≥[f+( i-1)d]tanα and x≤-[f+(i-1)d]tanα; the length and center position of each layer of grooves are designed as follows: the left and right midpoints of the i-th layer of grooves The distance to the focal point satisfies f+(i-1)d+kλ/3 and f+(i-1)d+(k+1)λ/3 respectively, where the integer k is called the order of the groove, and k is taken as follows value, so that the k difference between two adjacent grooves on the same layer is 3, namely:
各个凹槽对应于传统波带片中的菲尼尔带(fresnel zone)。当沿y方向偏振的平面波垂直金属表面照明结构时,表面等离激元将在各个凹槽上被同相激发,且传播到焦点处时相长干涉形成焦点。Each groove corresponds to a Fresnel zone in a conventional zone plate. When the plane wave polarized along the y direction illuminates the structure perpendicular to the metal surface, the surface plasmons will be excited in phase on each groove, and constructively interfere to form the focus when propagating to the focus.
本发明只需线偏振光激发就能达到和径向偏振照明圆型透镜相同的性能:焦点具有旋转对称性(rotational symmetry);焦点半宽相同。The present invention can achieve the same performance as that of the radially polarized illumination circular lens only by excitation of linearly polarized light: the focal point has rotational symmetry (rotational symmetry); and the half width of the focal point is the same.
本发明的结构可保证每一个凹槽的取向和偏振方向均能成一定角度,有效避免在线偏振照明圆形透镜时,在偏振方向平行圆弧切线的位置表面等离激元不被激发的缺点。本发明具有如下优点:The structure of the present invention can ensure that the orientation and polarization direction of each groove can form a certain angle, effectively avoiding the disadvantage that the surface plasmon is not excited at the position where the polarization direction is parallel to the tangent of the arc when the circular lens is illuminated by linear polarization. The present invention has the following advantages:
1、安排在倾斜线段部分凹槽能提供大角度汇聚的表面等离激元波,显著提高了透镜的数值孔径,因此能使实现超分辨率聚焦,即焦点光斑沿x方向的半高全宽非常小,这一点是传统波带片做不到的。1. The grooves arranged on the inclined line segment can provide surface plasmon waves converging at a large angle, which significantly improves the numerical aperture of the lens, so that super-resolution focusing can be realized, that is, the full width at half maximum of the focal spot along the x direction is very small , which cannot be achieved by traditional zone plates.
2、通过对各个凹槽“舍去”或者“保留”调整各角度汇聚波的权重,可以进一步优化焦点的尺寸。2. By "dropping" or "retaining" each groove and adjusting the weights of convergent waves at each angle, the size of the focal point can be further optimized.
3、若将两个同样的三段式表面等离激元透镜上下相对放置(参见图3),则只需要在线偏振光照明下,将生成超高分辨率且旋转对称的焦点,其在x和y两个方向上的半高全小至λ0/3,突破λ0/2的衍射极限,这里λ0是入射光的真空波长。这里两个焦点相距λ/2是考虑到从上下两个透镜激发的表面等离激元具有π的相位差。3. If two identical three-segment surface plasmon lenses are placed up and down (see Figure 3), only under linear polarized light illumination will generate a super-resolution and rotationally symmetric focal point, which is at x The full half-height values in the two directions of λ and y are as small as λ 0 /3, breaking through the diffraction limit of λ 0 /2, where λ 0 is the vacuum wavelength of the incident light. Here, the distance between the two focal points is λ/2 because the surface plasmons excited from the upper and lower lenses have a phase difference of π.
4、三段式表面等离激元透镜配合线偏振光束就能达到圆型透镜配合径向偏振光束照明是的聚焦效果,同时避免了后者存在的光束中心和结构中心的对准问题,由于只需同时线偏振光,降低了实施的成本。4. The three-stage surface plasmon lens combined with the linearly polarized beam can achieve the focusing effect of the circular lens combined with the radially polarized beam illumination, while avoiding the alignment problem of the beam center and the structure center in the latter, because Only the light needs to be linearly polarized at the same time, reducing the cost of implementation.
附图说明Description of drawings
图1为本发明的三段式表面等离激元透镜的结构示意图;FIG. 1 is a schematic structural view of a three-stage surface plasmon lens of the present invention;
图2为本发明的三段式表面等离激元透镜的设计原理图;2 is a schematic diagram of the design of the three-stage surface plasmon lens of the present invention;
图3为本发明的两个同样的三段式表面等离激元透镜相对放置示意图;Fig. 3 is a schematic diagram of relative placement of two identical three-segment surface plasmon lenses of the present invention;
图4为本发明实施例中的两种三段式表面等离激元透镜结构示意图;Fig. 4 is a schematic structural diagram of two kinds of three-segment surface plasmon lenses in an embodiment of the present invention;
图5为本发明实施例中的三段式表面等离激元透镜和圆型透镜(单层,半径=5μm)焦点强度分布对比图;Fig. 5 is a comparison diagram of focus intensity distribution between a three-stage plasmon lens and a circular lens (single layer, radius = 5 μm) in an embodiment of the present invention;
图6为本发明实施例中三段式表面等离激元透镜焦点的x和y方向一维强度分布度以及半高全宽。FIG. 6 shows the one-dimensional intensity distribution in the x and y directions and the full width at half maximum of the focal point of the three-segment surface plasmon lens in the embodiment of the present invention.
具体实施方式detailed description
以下实施例将结合附图对本发明作进一步说明。The following embodiments will further illustrate the present invention in conjunction with the accompanying drawings.
参见图1,本发明由三层刻蚀在金属表面4的矩形凹槽2组成,在垂直于金属表面4入射的线偏振光1照明下,将形成突破衍射极限的越小尺寸表面等离激元焦点3,所述矩形凹槽2的宽度W均为λ/2,其中λ是表面等离激元的波长(参见图2),每层凹槽的中心位置均分布在三条线段上,对于第i层(i=1,2,3),其轨迹由以下分段函数给出:Referring to Fig. 1, the present invention consists of three layers of rectangular grooves 2 etched on the metal surface 4. Under the illumination of the linearly polarized light 1 incident perpendicular to the metal surface 4, a smaller-sized surface plasmon excitation that breaks through the diffraction limit will be formed. Element focal point 3, the width W of described rectangular groove 2 is λ/2, and wherein λ is the wavelength of surface plasmon polaritons (referring to Fig. 2), and the central position of each groove is all distributed on three line segments, for The i-th layer (i=1,2,3), whose trajectory is given by the following piecewise function:
其中f是焦距,d=2λ/3是水平线段部分的层间距,α和β是两个需要优化的参数,其含义见图2。式(1)中的“+”和“-”号分别对应x≥[f+(i-1)d]tanα和x≤-[f+(i-1)d]tanα。每层凹槽的长度和中心位置按照如下设计:第i层凹槽的左侧边和右侧边中点到焦点的距离分别满足f+(i-1)d+kλ/3和f+(i-1)d+(k+1)λ/3,这里整数k称为凹槽的级次,k按如下方式取值,使同一层相邻两个凹槽的k相差3,即:Where f is the focal length, d=2λ/3 is the interlayer spacing of the horizontal line segment, α and β are two parameters that need to be optimized, and their meanings are shown in Figure 2. The signs "+" and "-" in formula (1) correspond to x≥[f+(i-1)d]tanα and x≤-[f+(i-1)d]tanα respectively. The length and center position of each layer of grooves are designed as follows: the distances from the midpoints of the left side and right side of the i-th layer of grooves to the focal point satisfy f+(i-1)d+kλ/3 and f+(i- 1) d+(k+1)λ/3, where the integer k is called the order of the groove, and k is valued as follows, so that the k of two adjacent grooves on the same layer differ by 3, namely:
这样设计的结构实际上是一个二维的表面等离激元波带片,各个凹槽对应于传统波带片中的菲尼尔带(fresnel zone)。当沿y方向偏振的平面波垂直金膜表面照明结构时,表面等离激元将在各个凹槽上被同相激发,且传播到焦点处时相长干涉形成焦点。The structure designed in this way is actually a two-dimensional surface plasmon zone plate, and each groove corresponds to the Fresnel zone in the traditional zone plate. When the plane wave polarized along the y direction illuminates the structure vertically to the surface of the gold film, the surface plasmons will be excited in the same phase on each groove, and constructively interfere to form the focus when propagating to the focus.
本发明的两个同样的三段式表面等离激元透镜相对放置示意图参见图3。Refer to FIG. 3 for a schematic diagram of relative placement of two identical three-segment surface plasmon lenses of the present invention.
考虑制备在50nm厚的金膜上的三段式透镜,凹槽的深度可以是20到40nm。对于λ0=830nm的入射光,表面等离激元波长λ=813.5nm,此时w=406.75nm,d=542.3nm,设计焦距f=5μm-d=4.46μm。α=80度和β=45度,各个凹槽的位置和长度由式(2)给出。为了使结构紧凑,分布在两边倾斜线段上的凹槽只保留到和焦点同高度的级次。在这些参数下,整个器件的横向长度约为72.6μm,宽度约为5μm,结构见图4(a)。焦点强度分布的获得可以通过麦克斯韦方程组加上边界条件或FDTD商用软件或基于表面等离激元点源模型的数值计算得到(C.Zhao,J.Zhang,“Plasmonic Demultiplexer and Guiding,”ACS Nano 4,6433(2010))。这里采用最后一种,即表面等离激元点源模型计算。通过计算发现,对于图4(a)的三段式透镜,焦点沿x和y方向的半高全宽分别是295和762nm,x方向的半高全宽已经<λ0/2,突破衍射极限,实现超高分辨率。利用本设计的优点(2),去掉k=-3,-2,-1,1,2,3这六个级次后,相应的结构见图4(b)。其焦点沿x和y方向的半高全宽分别是276和760nm,前者达到λ0/3。物理上,去掉这六个级次相当于提高了大角度汇聚的表面等离激元波的权重,增大了等效数值孔径,因此能获得更小的焦点。为了得到具有旋向对称的焦点,需要将y方向的半高全宽也压缩到1/3λ0左右,为此将两个图4(a)结构的按照图(3)方式相对放置。在线偏振光照明下的焦点强度分布图见图5(b)。作为对比,图5(a)是一个半径是5μm的圆形透镜在径向偏振光激发下焦点的分布图。由图可见,三段式透镜的焦点光斑具有和圆型透镜一样的旋向对称性。进一步的分析表明,圆型透镜的焦点x、y半高全宽都是289nm,我们的结构焦点x、y方向半高全宽在295nm左右,见图(6)。考虑到入射光是830nm,焦点的半宽接近1/3波长,突破了1/2波长的衍射极限。Considering a three-segment lens fabricated on a 50nm thick gold film, the depth of the grooves can be 20 to 40nm. For incident light of λ 0 =830nm, surface plasmon wavelength λ=813.5nm, at this time w=406.75nm, d=542.3nm, design focal length f=5μm-d=4.46μm. α=80 degrees and β=45 degrees, the position and length of each groove are given by formula (2). In order to make the structure compact, the grooves distributed on the inclined line segments on both sides are only reserved to the same height level as the focal point. Under these parameters, the lateral length of the entire device is about 72.6 μm, and the width is about 5 μm. The structure is shown in Figure 4(a). The focus intensity distribution can be obtained by Maxwell’s equations plus boundary conditions or FDTD commercial software or numerical calculation based on the surface plasmon point source model (C. Zhao, J. Zhang, “Plasmonic Demultiplexer and Guiding,” ACS Nano 4,6433 (2010)). Here, the last one, the surface plasmon point source model, is used for calculation. Through calculation, it is found that for the three-segment lens in Figure 4(a), the full width at half maximum of the focal point along the x and y directions are 295 and 762nm respectively, and the full width at half maximum in the x direction is already < λ 0 /2, breaking through the diffraction limit and achieving ultra-high resolution. Using advantage (2) of this design, after removing the six orders of k=-3,-2,-1,1,2,3, the corresponding structure is shown in Figure 4(b). The full width at half maximum of its focus along the x and y directions are 276 and 760nm respectively, and the former reaches λ 0 /3. Physically, removing these six orders is equivalent to increasing the weight of the surface plasmon waves converged at a large angle, increasing the equivalent numerical aperture, and thus obtaining a smaller focus. In order to obtain a focus with hand symmetry, it is necessary to compress the full width at half maximum in the y direction to about 1/3λ 0. For this reason, the two structures in Fig. 4(a) are placed opposite to each other according to Fig. (3). The focal intensity distribution map under linear polarized light illumination is shown in Fig. 5(b). For comparison, Fig. 5(a) is a distribution map of the focus of a circular lens with a radius of 5 μm excited by radially polarized light. It can be seen from the figure that the focal spot of the three-segment lens has the same rotational symmetry as that of the circular lens. Further analysis shows that the full width at half maximum of the focus x and y of the circular lens is 289nm, and the full width at half maximum of the focus x and y direction of our structure is about 295nm, see figure (6). Considering that the incident light is 830nm, the half-width of the focus is close to 1/3 wavelength, breaking through the diffraction limit of 1/2 wavelength.
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