CN105603831A - High-strength waterproof plant fiberboard and production process thereof - Google Patents

High-strength waterproof plant fiberboard and production process thereof Download PDF

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Publication number
CN105603831A
CN105603831A CN201511000804.2A CN201511000804A CN105603831A CN 105603831 A CN105603831 A CN 105603831A CN 201511000804 A CN201511000804 A CN 201511000804A CN 105603831 A CN105603831 A CN 105603831A
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fibre board
strength
vegetable fibre
strength waterproof
latex
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CN105603831B (en
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曾伟新
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Walkkind Technology IncOf Guangdong
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Walkkind Technology IncOf Guangdong
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21JFIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
    • D21J1/00Fibreboard
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • D21H21/20Wet strength agents

Abstract

The invention relates to the field of fiberboard production, in particular to a high-strength waterproof plant fiberboard and a production process thereof. The high-strength waterproof plant fiberboard comprises 70-85% of plant fiber, 10-25% of latex mixed liquid, 0.5-2% of wet strength agent mixed liquid, 0.8-2.5% of water-resistant agent and 3-13% of water. The process comprises the following steps: a) preparing the latex mixed liquid; b) preparing the wet strength agent mixed liquid; c) disintegrating and grinding plant fiber into slurry; d) preparing mixed slurry; e) forming a wet board through the mixed slurry; and f) performing drying treatment on the wet board to obtain the high-strength waterproof plant fiberboard. The high-strength waterproof plant fiberboard is simple in raw material component, extensive in source, low in cost, non-toxic and harmless, and the product is easy to degrade and conforms to the requirements on environmental protection and practicality; the equipment investment is small, the production process is simple and easy to operate, and the production cost is low; and the produced product is small in specific gravity, waterproof, resistant to fire and abrasion, high in strength and very good in formability, machinability and electrical characteristics.

Description

A kind of high-strength waterproof vegetable fibre board and production technology thereof
Technical field
The present invention relates to Fibreboard Production field, relate in particular to and utilize string and regeneration secondary string as raw material, be aided with multiple macromolecular material, produce there is very strong toughness, waterproof vegetable fibre board and the production technology thereof of deflection and higher water resistance.
Background technology
High-strength waterproof fiberboard is a kind of thicker than general fibre plate, the vegetable fibre board that intensity is higher, it has the features such as proportion is little, waterproof, antidetonation, sound insulation, difficult combustion, wear-resisting wiping, can be used as the substitute of timber, plastics, canvas, vulcan fibre, metallic plate and wood-based plate etc., be widely used in the industries such as automobile, shoemaking, industrial container, leather, electrical equipment, packaging and case and bag, wherein with automobile making and shoemaking industry consumption maximum. The multiple parts such as instrument board on automobile, top control panel, boot liner can be manufactured, car body weight can be alleviated significantly. At the bottom of also can be used for manufacturing the thorax of mold pressing leather shoes, heel etc., alleviate footwear weight, reduce production costs.
At present the production technology of traditional vegetable fibre board is continued to use for many years, and it is mainly how to make string or aftergrowth fiber wire-dividing broom purification as best one can, and makes full use of interfibrous autonomous combination improve the quality of products (interlayer adhesion); For trying to achieve the stiff degree of product, the tightness of medium and high-grade goods is done larger and larger simultaneously, and the tightness of medium and high-grade goods is most of at 1.28~1.30g/cm on the market at present3, and continue to higher tightness development. Will produce like this problem: for ensureing adhesion between gas producing formation, defibrination beating degree is more and more higher, cause fiber wet weight to reduce, fiber fines increases; Product tightness is increasing simultaneously, more and more pursues hardness, therefore can inevitably produce product and occur not only hard but also crisp problem. And the increasing of beating degree, therefore and not to be suitable for this thickness thicker, the production of the vegetable fibre board that intensity is higher the increase of tightness, also can make manufacturing cost increase.
Summary of the invention
The object of the invention is to propose that a kind of proportion is little, waterproof, difficult combustion, wear-resisting wiping, high-strength waterproof vegetable fibre board and production technology thereof.
For reaching this object, the present invention by the following technical solutions:
A production technology for high-strength waterproof vegetable fibre board, comprises the following steps:
Raw material: by gross mass umber 100%, comprising: string 70%~85%, latex mixed liquor 10%~25%, wet strength agent mixed liquor 0.5%~2%, water repellent agent 0.8%~2.5%, water 3~13%;
1), the preparation of material solution:
A) preparation of latex mixed liquor: two kinds of different types of polymer emulsions are added in reactor, mix, then add water and regulate the concentration of final latex mixed liquor, make it between 15%~30%, for subsequent use;
B) preparation of wet strength agent mixed liquor: by anti-blushing agent and wet strength agent taking the ratio of solid content as (6~8): (2~4) join in reactor, then add water and make the concentration of mixed liquor between 20%~30%, for subsequent use;
C) preparation of paper pulp: string and water are put into pulper pulping, the better slurry of size degradation is delivered in pulp storage tank, and utilize fiberizer to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, added colorant, then add successively latex mixed liquor, wet strength agent mixed liquor and water repellent agent in pond with slurry, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, the pulp layer that moulding obtains is delivered to moulding cylinder and is wound around, when being wound around thickness, it reaches after technological requirement thickness, going out knife system by moulding cylinder cuts off, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then make wet plate through piling, setting-out;
F) processing of wet plate drying obtains high-strength waterproof vegetable fibre board.
More excellent, described step a) in: two kinds of different types of emulsions are latex A and emulsion B; Described latex A is polyacrylate dispersion or Polystyrene-acrylate latex; Described emulsion B is styrene-butadiene emulsion or carboxylic styrene butadiene latex; Described latex A and emulsion B are taking the ratio of solid content as (6~8): (2~4) add in reactor.
Further illustrate, described string is the mixture of bleaching needle-leaved wood fibre and secondary stock, and by gross mass mark 100%, the bleaching needle-leaved wood fibre by 80% and 20% secondary stock mix.
Further illustrate, described pulper is hydrabrusher; Described fiberizer adopts sticky shape mode defibrination.
More excellent, described step order a), b) and c) is in no particular order.
More excellent, described step is also provided with step g after f)): described high-strength waterproof vegetable fibre board is processed into finished product successively after hot pressing, press polish, trimming and cutting process.
Illustrate further, described wet strength agent is polyamine epichlorohydrin resin, and described anti-blushing agent is the melamine aqueous solution, the modified cyanurotriamide aqueous solution or the pollopas aqueous solution.
Illustrate further, the mode of described dry processing be in shady dry canopy shade do, dry in canopy, dry or drying machine in dry.
Illustrate further, described water repellent agent is paraffin wax emulsions, Organic fluoride emulsion or modified polyacrylic acid emulsion.
Advantage of the present invention has: 1, raw material components of the present invention is simple, and primary raw material string wide material sources are cheap, nontoxic, and goods are easy to degraded and meet environmental protection real requirement. 2, production technology of the present invention, has equipment investment few, and technique is simple, easily grasps, and easy to operate, energy consumption is low, and water power consumption is few, and production cost is low, and can realize the feature of cleaner production. 3, of the present invention manufacturing a product, proportion is little, waterproof, antidetonation, sound insulation, difficult combustion, wear-resisting wiping, intensity are high, and good springiness, weatherability are excellent, and mouldability, machining property and electrical characteristic are all fine, and surface can be covered with paint, lacquer, colour wash, etc. shades of colour, be extruded various decoration lines.
Detailed description of the invention
Further illustrate technical scheme of the present invention below in conjunction with detailed description of the invention.
The product standard of table 1 waterproof string plate material
Example one
A production technology for high-strength waterproof vegetable fibre board, comprises the following steps:
1), the preparation of material solution:
A) preparation of latex mixed liquor: polyacrylate dispersion and styrene-butadiene emulsion, taking the ratio of solid content as 6:2 adds in reactor, are mixed, then add water and regulate the concentration of latex mixed liquor to be 15%, for subsequent use;
B) preparation of wet strength agent mixed liquor: the melamine aqueous solution and polyamine epichlorohydrin resin are joined in reactor taking the ratio of solid content as 6:2, then add water and make the concentration of mixed liquor be 20%, for subsequent use;
C) preparation of paper pulp: the string (72.5%) that will be mixed by bleaching needle-leaved wood fibre (80%) and secondary stock (20%), put into hydrabrusher pulping with water, again the good slurry of size degradation is delivered in pulp storage tank, and utilize fiberizer to adopt sticky shape mode to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, add colorant (0.1%), in pond with slurry, add successively latex mixed liquor (24.2%), wet strength agent mixed liquor (1%) and paraffin wax emulsions (2.2%) again, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, the pulp layer that moulding obtains is delivered to moulding cylinder and is wound around, when being wound around thickness, it reaches after technological requirement thickness, going out knife system by moulding cylinder cuts off, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then make wet plate through piling, setting-out;
F) processing of wet plate drying obtains high-strength waterproof vegetable fibre board;
G) the high-strength waterproof vegetable fibre board obtaining is processed into finished product successively after hot pressing, press polish, trimming and cutting process.
The actual detection of this example product data are as table 2:
Table 2 example one product detects data
Example two
A production technology for high-strength waterproof vegetable fibre board, comprises the following steps:
1), the preparation of material solution:
A) preparation of latex mixed liquor: polyacrylate dispersion and carboxylic styrene butadiene latex, taking the ratio of solid content as 8:4 adds in reactor, are mixed, then add water and regulate the concentration of final latex mixed liquor to be 30%, for subsequent use;
B) preparation of wet strength agent mixed liquor: the melamine aqueous solution and polyamine epichlorohydrin resin are joined in reactor taking the ratio of solid content as 6:4, then add water and make the concentration of mixed liquor be 20%, for subsequent use;
C) preparation of paper pulp: the string (78.7%) that will be mixed by bleaching needle-leaved wood fibre (80%) and secondary stock (20%), put into hydrabrusher pulping with water, again the good slurry of size degradation is delivered in pulp storage tank, and utilize fiberizer to adopt sticky shape mode to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, add colorant (0.1%), in pond with slurry, add successively latex mixed liquor (18.4%), wet strength agent mixed liquor (0.5%) and modified polyacrylic acid emulsion (0.8%) again, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, the pulp layer that moulding obtains is delivered to moulding cylinder and is wound around, when being wound around thickness, it reaches after technological requirement thickness, going out knife system by moulding cylinder cuts off, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then make wet plate through piling, setting-out;
F) processing of wet plate drying obtains high-strength waterproof vegetable fibre board;
G) the high-strength waterproof vegetable fibre board obtaining is processed into finished product successively after hot pressing, press polish, trimming and cutting process.
The actual detection of this example product data are as table 3:
Table 3 example two products detect data
Example three
A production technology for high-strength waterproof vegetable fibre board, comprises the following steps:
1), the preparation of material solution:
A) preparation of latex mixed liquor: polyacrylate dispersion and styrene-butadiene emulsion, taking the ratio of solid content as 7:2 adds in reactor, are mixed, then add water and regulate the concentration of final latex mixed liquor to be 20%, for subsequent use;
B) preparation of wet strength agent mixed liquor: the pollopas aqueous solution and polyamine epichlorohydrin resin are joined in reactor taking the ratio of solid content as 8:3, then add water and make the concentration of mixed liquor be 30%, for subsequent use;
C) preparation of paper pulp: the string (83.5%) that will be mixed by bleaching needle-leaved wood fibre (80%) and secondary stock (20%), put into hydrabrusher pulping with appropriate water, again the good slurry of size degradation is delivered in pulp storage tank, and utilize fiberizer to adopt sticky shape mode to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, add colorant (0.1%), in pond with slurry, add successively latex mixed liquor (14.8%), wet strength agent mixed liquor (0.8%) and modified polyacrylic acid emulsion (0.8%) again, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, the pulp layer that moulding obtains is delivered to moulding cylinder and is wound around, when being wound around thickness, it reaches after technological requirement thickness, going out knife system by moulding cylinder cuts off, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then make wet plate through piling, setting-out;
F) processing of wet plate drying obtains high-strength waterproof vegetable fibre board;
G) the high-strength waterproof vegetable fibre board obtaining is processed into finished product successively after hot pressing, press polish, trimming and cutting process.
The actual detection of this example product data are as table 4:
Table 4 example three products detect data
Example four
A production technology for high-strength waterproof vegetable fibre board, comprises the following steps:
1), the preparation of material solution:
A) preparation of latex mixed liquor: Polystyrene-acrylate latex and carboxylic styrene butadiene latex, taking the ratio of solid content as 7:3 adds in reactor, are mixed, then add water and regulate the concentration of final latex mixed liquor to be 30%, for subsequent use;
B) preparation of wet strength agent mixed liquor: the modified cyanurotriamide aqueous solution and polyamine epichlorohydrin resin are joined in reactor taking the ratio of solid content as 7:3, then add water and make the concentration of mixed liquor be 25%, for subsequent use;
C) preparation of paper pulp: the string (70%) that will be mixed by bleaching needle-leaved wood fibre (80%) and secondary stock (20%), put into hydrabrusher pulping with water, again the good slurry of size degradation is delivered in pulp storage tank, and utilize fiberizer to adopt sticky shape mode to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, add colorant (0.1%), in pond with slurry, add successively latex mixed liquor (25%), wet strength agent mixed liquor (1%) and Organic fluoride emulsion (2.5%) again, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, the pulp layer that moulding obtains is delivered to moulding cylinder and is wound around, when being wound around thickness, it reaches after technological requirement thickness, going out knife system by moulding cylinder cuts off, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then make wet plate through piling, setting-out;
F) processing of wet plate drying obtains high-strength waterproof vegetable fibre board;
G) the high-strength waterproof vegetable fibre board obtaining is processed into finished product successively after hot pressing, press polish, trimming and cutting process.
The actual detection of this example product data are as table 2:
Table 5 example one product detects data
Example five
A production technology for high-strength waterproof vegetable fibre board, comprises the following steps:
1), the preparation of material solution:
A) preparation of latex mixed liquor: Polystyrene-acrylate latex and styrene-butadiene emulsion, taking the ratio of solid content as 8:4 adds in reactor, are mixed, then add water and regulate the concentration of final latex mixed liquor to be 30%, for subsequent use;
B) preparation of wet strength agent mixed liquor: the melamine aqueous solution and polyamine epichlorohydrin resin are joined in reactor taking the ratio of solid content as 6:2, then add water and make the concentration of mixed liquor be 30%, for subsequent use;
C) preparation of paper pulp: the string (85%) that will be mixed by bleaching needle-leaved wood fibre (80%) secondary stock (20%), put into hydrabrusher pulping with water, again the good slurry of size degradation is delivered in pulp storage tank, and utilize fiberizer to adopt sticky shape mode to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, add colorant (0.2%), in pond with slurry, add successively latex mixed liquor (10%), wet strength agent mixed liquor (0.5%) and paraffin wax emulsions (2.5%) again, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, the pulp layer that moulding obtains is delivered to moulding cylinder and is wound around, when being wound around thickness, it reaches after technological requirement thickness, going out knife system by moulding cylinder cuts off, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then make wet plate through piling, setting-out;
F) wet plate successively drying processing obtain high-strength waterproof vegetable fibre board;
G) the high-strength waterproof vegetable fibre board obtaining is processed into finished product successively after hot pressing, press polish, trimming and cutting process.
Table 6 example one product detects data
Comparative example
The present embodiment just raw material of use is existing on market and at the waterproof fibre plate of selling, and this product overwhelming majority adopts traditional production technology to produce; According to the said goods criteria table, it is carried out to coherent detection, obtains the actual detection of this example product data as table 7:
The detection data of table 7 comparative example product
The present invention relates to a kind of fibre board material and production technology thereof with high strength and high water resistance, be specifically related to utilize string and regeneration secondary string as raw material, be aided with multiple macromolecular material, the product density producing is not high, but waterproof board and the production technology thereof with very strong toughness and higher water resistance, can be applicable to numerous aspects such as automobile making and the production of footwear industry. Raw material components is simple simultaneously, and primary raw material string wide material sources are cheap, nontoxic, and goods are easy to degraded and meet environmental requirement
Know-why of the present invention has below been described in conjunction with specific embodiments. These are described is in order to explain principle of the present invention, and can not be interpreted as by any way limiting the scope of the invention. Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other detailed description of the invention of the present invention, within these modes all will fall into protection scope of the present invention.

Claims (10)

1. a production technology for high-strength waterproof vegetable fibre board, is characterized in that, comprises the following steps:Raw material: by gross mass umber 100%, comprising: string 70%~85%, latex mixed liquor 10%~25%,Wet strength agent mixed liquor 0.5%~2%, water repellent agent 0.8%~2.5%, water 3~13%;
1), the preparation of material solution:
A) preparation of latex mixed liquor: two kinds of different types of polymer emulsions are added in reactor, mixEvenly, then add water and regulate the concentration of latex mixed liquor, make it between 15%~30%, for subsequent use;
B) preparation of wet strength agent mixed liquor: by anti-blushing agent and wet strength agent taking the ratio of solid content as (6~8): (2~4)Join in reactor, then add water and make the concentration of mixed liquor between 20%~30%, for subsequent use;
C) preparation of paper pulp: string and appropriate water are put into pulper pulping, then size degradation is goodSlurry is delivered in pulp storage tank, and utilizes fiberizer to carry out defibrination processing to obtain paper pulp;
2), mix the preparation of slurry and the moulding of high-strength waterproof vegetable fibre board production:
D) paper pulp of milled is delivered in pond with slurry, added colorant, then add successively latex mixed in pond with slurryClose liquid, wet strength agent mixed liquor and water repellent agent, after mixing, obtain mixing slurry;
E) mixing slurry is delivered to machine chest, mixed slurry is delivered to wet plate former moulding, and moulding obtainsPulp layer is delivered to moulding cylinder and is wound around, and reaches after technological requirement thickness when it is wound around thickness, goes out cutter dress by moulding cylinderPut cut-out, and cut through the transmission of wet plate conveying device and according to the size of technological requirement, then through piling, setting-outMake wet plate;
F) processing of wet plate drying obtains high-strength waterproof vegetable fibre board.
2. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, described step a) in: two kinds of different types of emulsions are latex A and emulsion B; Described latex A isPolyacrylate dispersion or Polystyrene-acrylate latex; Described emulsion B is styrene-butadiene emulsion or CarboxyLatex; Described latex A and emulsion B are taking the ratio of solid content as (6~8): (2~4) add in reactor.
3. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, described string is the mixture of bleaching needle-leaved wood fibre and secondary stock, by gross mass mark100%, the bleaching needle-leaved wood fibre by 80% and 20% secondary stock mix.
4. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, described step c) in, described pulper is hydrabrusher; Described fiberizer adopts sticky shape mode to grindSlurry.
5. according to the production of a kind of high-strength waterproof vegetable fibre board described in claim 1 or 2 or 3 or 4Technique, is characterized in that, described step order a), b) and c) in no particular order.
6. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, described step is also provided with step g after f)): described high-strength waterproof vegetable fibre board is successively through overheatedAfter pressure, press polish, trimming and cutting process, be processed into finished product.
7. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, described wet strength agent is polyamine epichlorohydrin resin, described anti-blushing agent be the melamine aqueous solution,The modified cyanurotriamide aqueous solution or the pollopas aqueous solution.
8. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, the mode of described dry processing be in shady dry canopy shade do, dry in canopy, dry or drying machine in dry.
9. the production technology of a kind of high-strength waterproof vegetable fibre board according to claim 1, its featureBe, described water repellent agent is paraffin wax emulsions, Organic fluoride emulsion or modified polyacrylic acid emulsion.
10. one kind according to the production of the high-strength waterproof vegetable fibre board described in any one in claim 1-9The high-strength waterproof vegetable fibre board that technique prepares.
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Publication number Priority date Publication date Assignee Title
CN106589140A (en) * 2016-12-13 2017-04-26 厦门壳氏新材料科技有限公司 Modified vegetable fiber molded product and manufacturing method thereof
CN106894282A (en) * 2017-04-18 2017-06-27 邱雪平 A kind of leaching membrane paper water-repellent paint
CN108310755A (en) * 2017-01-16 2018-07-24 济南凯莱丝克实业有限公司 A kind of changeable intention drawing board and preparation method thereof
CN108755278A (en) * 2017-07-15 2018-11-06 芜湖乾凯材料科技有限公司 A kind of environment protection pressed-fibre board and its processing method of modified liquid paraffin
CN110820428A (en) * 2019-11-14 2020-02-21 广东华凯科技股份有限公司 Preparation method of high-flexibility waterproof fiberboard and finished product thereof
CN115464740A (en) * 2022-10-27 2022-12-13 湖南航天康达新材料有限公司 Waterproof high-density fiberboard and preparation method thereof

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CN103266530A (en) * 2013-04-15 2013-08-28 广东华凯特种纤维板科技有限公司 Brim material made from plant fiberboard and preparation method thereof
CN104928993A (en) * 2015-05-25 2015-09-23 东莞市绿保电子科技有限公司 Production method of waterproof and mildewproof plant multifilament modified boards

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US5342875A (en) * 1990-04-30 1994-08-30 The Procter & Gamble Company Polycationic latex wet strength agent
CN103266530A (en) * 2013-04-15 2013-08-28 广东华凯特种纤维板科技有限公司 Brim material made from plant fiberboard and preparation method thereof
CN104928993A (en) * 2015-05-25 2015-09-23 东莞市绿保电子科技有限公司 Production method of waterproof and mildewproof plant multifilament modified boards

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589140A (en) * 2016-12-13 2017-04-26 厦门壳氏新材料科技有限公司 Modified vegetable fiber molded product and manufacturing method thereof
CN106589140B (en) * 2016-12-13 2019-03-08 厦门壳氏新材料科技有限公司 A kind of modified plant fibers molded article and its manufacturing method
CN108310755A (en) * 2017-01-16 2018-07-24 济南凯莱丝克实业有限公司 A kind of changeable intention drawing board and preparation method thereof
CN106894282A (en) * 2017-04-18 2017-06-27 邱雪平 A kind of leaching membrane paper water-repellent paint
CN108755278A (en) * 2017-07-15 2018-11-06 芜湖乾凯材料科技有限公司 A kind of environment protection pressed-fibre board and its processing method of modified liquid paraffin
CN110820428A (en) * 2019-11-14 2020-02-21 广东华凯科技股份有限公司 Preparation method of high-flexibility waterproof fiberboard and finished product thereof
CN110820428B (en) * 2019-11-14 2021-12-10 广东华凯科技股份有限公司 Preparation method of high-flexibility waterproof fiberboard and finished product thereof
CN115464740A (en) * 2022-10-27 2022-12-13 湖南航天康达新材料有限公司 Waterproof high-density fiberboard and preparation method thereof

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