CN105603735A - Anti-crease finishing agent for textiles and preparation method thereof - Google Patents
Anti-crease finishing agent for textiles and preparation method thereof Download PDFInfo
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- CN105603735A CN105603735A CN201610111207.5A CN201610111207A CN105603735A CN 105603735 A CN105603735 A CN 105603735A CN 201610111207 A CN201610111207 A CN 201610111207A CN 105603735 A CN105603735 A CN 105603735A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/376—Oximes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/137—Acetals, e.g. formals, or ketals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an anti-crease finishing agent for textiles. The anti-crease finishing agent is prepared from, by weight, 8-15 parts of salicylhydroxamic acid, 15-20 parts of methylnaphthalene sodium sulfonate formaldehyde resin, 7-12 parts of ammonium persulfate, 3-9 parts of erucic amide, 2-6 parts of trisodium citrate, 9-15 parts of maleic anhydride, 3-8 parts of aluminum tartrate, 1-5 parts of diethylene glycol, 13-18 parts of glyoxal and 35-45 parts of deionized water. By applying the anti-crease finishing agent, the elasticity, crease recovery performance and dimensional stability of cotton fabrics can be remarkably improved.
Description
Technical field
The invention belongs to finishing agent field, be specifically related to a kind of fabric crease preventing finishing agent and preparation method thereof.
Background technology
Soft comfortable cotton fiber is for welcomed by the people, but it exists the problem of easy wrinkle also to become a difficult problem for industry.The easy generation of its wrinkle is mainly because the hydrogen bond in the amorphous regions of cotton fiber deforms in the time standing external force, works as external forceGreatly, when long, system variant can not recover just to have occurred permanent deformation the time. The object of wrinkle resistant type finishing agent exploitation is just, logicalCross fabric is used to crease proofing agent, make exactly fabric have easy-care properties, fabric is after washing, even if do not press or press a littleScald also very flat enduring, dimensionally stable.
Summary of the invention
For the above technical problem existing in prior art, the invention provides a kind of fabric crease preventing finishing agent and system thereofPreparation Method, can improve elasticity, crease recovery and the dimensional stability of cotton goods by anti-crease finishing.
Technical scheme: a kind of fabric crease preventing finishing agent, comprises the composition of following parts by weight: Using Salicyl Hydroximic Acid 8-15Part, methyl naphthalene sulfonic acid sodium formaldehyde resin 15-20 part, ammonium persulfate 7-12 part, erucyl amide 3-9 part, trisodium citrate 2-6 part,Maleic anhydride 9-15 part, tartaric acid aluminium 3-8 part, diethylene glycol (DEG) 1-5 part, glyoxal 13-18 part, deionized water 35-45 part.
Preferably, described Using Salicyl Hydroximic Acid 10-13 part, methyl naphthalene sulfonic acid sodium formaldehyde resin 17-19 part, ammonium persulfate 9-11Part, erucyl amide 5-8 part, trisodium citrate 3-5 part, maleic anhydride 11-14 part, tartaric acid aluminium 5-7 part, diethylene glycol (DEG) 2-4Part, glyoxal 14-17 part, deionized water 38-42 part.
Preferably, 12 parts of described Using Salicyl Hydroximic Acids, 18 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 10 parts of ammonium persulfates, erucic acid6 parts of acid amides, 4 parts of trisodium citrates, 13 parts of maleic anhydrides, 6 parts, tartaric acid aluminium, 3 parts of diethylene glycol (DEG)s, 16 parts of glyoxals, go from40 parts, sub-water.
A preparation method for fabric crease preventing finishing agent, comprises the steps:
(1) by Using Salicyl Hydroximic Acid 8-15 part, erucyl amide 3-9 part, glyoxal 13-18 part and maleic anhydride 9-15 partAdd in reactor, rising temperature, to 40-50 DEG C, is reacted 20-30min;
(2) by methyl naphthalene sulfonic acid sodium formaldehyde resin 15-20 part, trisodium citrate 2-6 part, diethylene glycol (DEG) 1-5 part and deionizationWater 35-45 part is stirred to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently ammonium persulfate 7-12 parts and tartaric acid aluminium 3-8 part, pass into nitrogen, reacts 1-4h, question response with speed 300-500r/min at temperature 60-80 DEG CAfter end, can obtain described fabric crease preventing finishing agent.
Preferably, described in step (1), temperature is 44 DEG C, reaction 26min.
The time of preferably, stirring described in step (2) is 10-15min.
Preferably, the described speed of step (3) is 350r/min, and temperature is 73 DEG C, and the time is 2.5h.
Beneficial effect: the preparation method of a kind of fabric crease preventing finishing agent of the present invention, with Using Salicyl Hydroximic Acid, erucic acid acylThe raw materials such as amine, methyl naphthalene sulfonic acid sodium formaldehyde resin are prepared fabric crease preventing finishing agent; This preparation technology is simple, process is not multipleAssorted; Apply crease proofing agent of the present invention, can improve elasticity, crease recovery and the dimensional stability of cotton goods.
Detailed description of the invention
Embodiment 1
(1) 9 parts of 8 parts of Using Salicyl Hydroximic Acids, 3 parts of erucyl amides, 13 parts of glyoxals and maleic anhydrides are added to reactorIn, rising temperature to 40 DEG C, reaction 20min;
(2) 35 parts of 15 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 2 parts of trisodium citrates, 1 part of diethylene glycol (DEG) and deionized waters are stirredMix to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently 7 parts of ammonium persulfatesWith 3 parts, tartaric acid aluminium, pass into nitrogen, under temperature 60 C, react 1h with speed 300r/min, after finishing, question response can obtainDescribed fabric crease preventing finishing agent.
Comparative example 1
(1) 13 parts of glyoxals are added in reactor to rising temperature to 40 DEG C, reaction with 9 parts of maleic anhydrides20min；
(2) 35 parts of 2 parts of trisodium citrates, 1 part of diethylene glycol (DEG) and deionized waters are stirred to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently 7 parts of ammonium persulfatesWith 3 parts, tartaric acid aluminium, pass into nitrogen, under temperature 60 C, react 1h with speed 300r/min, after finishing, question response can obtainFinishing agent.
Embodiment 2
(1) 15 parts of 15 parts of Using Salicyl Hydroximic Acids, 9 parts of erucyl amides, 18 parts of glyoxals and maleic anhydrides are added to reactionIn still, rising temperature to 50 DEG C, reaction 30min;
(2) 45 parts of 20 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 6 parts of trisodium citrates, 5 parts of diethylene glycol (DEG)s and deionized waters are stirredMix to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently ammonium persulfate 12Part and 8 parts, tartaric acid aluminium, pass into nitrogen, at 80 DEG C of temperature, react 1h with speed 500r/min, after question response finishes, get final productTo described fabric crease preventing finishing agent.
Comparative example 2
(1) 18 parts of glyoxals are added in reactor to rising temperature to 50 DEG C, reaction with 15 parts of maleic anhydrides30min；
(2) 45 parts of 6 parts of trisodium citrates, 5 parts of diethylene glycol (DEG)s and deionized waters are stirred to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently ammonium persulfate 12Part and 8 parts, tartaric acid aluminium, pass into nitrogen, at 80 DEG C of temperature, react 1h with speed 500r/min, after question response finishes, get final productTo finishing agent.
Embodiment 3
(1) 11 parts of 10 parts of Using Salicyl Hydroximic Acids, 5 parts of erucyl amides, 14 parts of glyoxals and maleic anhydrides are added to reactionIn still, rising temperature to 40 DEG C, reaction 20min;
(2) 38 parts of 17 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 3 parts of trisodium citrates, 2 parts of diethylene glycol (DEG)s and deionized waters are stirredMix to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently 9 parts of ammonium persulfatesWith 5 parts, tartaric acid aluminium, pass into nitrogen, under temperature 60 C, react 1h with speed 300r/min, after finishing, question response can obtainDescribed fabric crease preventing finishing agent.
Embodiment 4
(1) 14 parts of 13 parts of Using Salicyl Hydroximic Acids, 8 parts of erucyl amides, 17 parts of glyoxals and maleic anhydrides are added to reactionIn still, rising temperature to 50 DEG C, reaction 30min;
(2) 42 parts of 19 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 5 parts of trisodium citrates, 4 parts of diethylene glycol (DEG)s and deionized waters are stirredMix to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently ammonium persulfate 11Part and 7 parts, tartaric acid aluminium, pass into nitrogen, at 80 DEG C of temperature, react 4h with speed 500r/min, after question response finishes, get final productTo described fabric crease preventing finishing agent.
Embodiment 5
(1) 13 parts of 12 parts of Using Salicyl Hydroximic Acids, 6 parts of erucyl amides, 16 parts of glyoxals and maleic anhydrides are added to reactionIn still, rising temperature to 44 DEG C, reaction 26min;
(2) 40 parts of 18 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 4 parts of trisodium citrates, 3 parts of diethylene glycol (DEG)s and deionized waters are stirredMix to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently ammonium persulfate 10Part and 6 parts, tartaric acid aluminium, pass into nitrogen, at 73 DEG C of temperature, react 2.5h with speed 350r/min, after question response finishesObtain described fabric crease preventing finishing agent.
The finishing agent that each embodiment and comparative example are obtained, is applied in textile clothes, tests treated weaving clothingThe creasy recovery angle of thing and tearing brute force retention rate, result is as follows:
Claims (7)
1. a fabric crease preventing finishing agent, is characterized in that, comprises the composition of following parts by weight: Using Salicyl Hydroximic Acid 8-15Part, methyl naphthalene sulfonic acid sodium formaldehyde resin 15-20 part, ammonium persulfate 7-12 part, erucyl amide 3-9 part, trisodium citrate 2-6 part,Maleic anhydride 9-15 part, tartaric acid aluminium 3-8 part, diethylene glycol (DEG) 1-5 part, glyoxal 13-18 part, deionized water 35-45 part.
2. a kind of fabric crease preventing finishing agent according to claim 1, is characterized in that, described Using Salicyl Hydroximic Acid 10-13Part, methyl naphthalene sulfonic acid sodium formaldehyde resin 17-19 part, ammonium persulfate 9-11 part, erucyl amide 5-8 part, trisodium citrate 3-5 part,Maleic anhydride 11-14 part, tartaric acid aluminium 5-7 part, diethylene glycol (DEG) 2-4 part, glyoxal 14-17 part, deionized water 38-42 part.
3. a kind of fabric crease preventing finishing agent according to claim 2, is characterized in that, 12 parts of described Using Salicyl Hydroximic Acids,18 parts of methyl naphthalene sulfonic acid sodium formaldehyde resins, 10 parts of ammonium persulfates, 6 parts of erucyl amides, 4 parts of trisodium citrates, maleic anhydride13 parts, 6 parts, tartaric acid aluminium, 3 parts of diethylene glycol (DEG)s, 16 parts of glyoxals, 40 parts of deionized waters.
4. a preparation method for fabric crease preventing finishing agent, is characterized in that, comprises the steps:
(1) Using Salicyl Hydroximic Acid 8-15 part, erucyl amide 3-9 part, glyoxal 13-18 part and maleic anhydride 9-15 part are addedIn reactor, rising temperature, to 40-50 DEG C, is reacted 20-30min;
(2) by methyl naphthalene sulfonic acid sodium formaldehyde resin 15-20 part, trisodium citrate 2-6 part, diethylene glycol (DEG) 1-5 part and deionized water 35-45 parts are stirred to uniform state;
(3) step (1) gained reactant liquor and step (2) gained reactant liquor are mixed, add successively subsequently ammonium persulfate 7-12 partWith tartaric acid aluminium 3-8 part, pass into nitrogen, at temperature 60-80 DEG C, react 1-4h with speed 300-500r/min, question response finishesAfter can obtain described fabric crease preventing finishing agent.
5. the preparation method of a kind of fabric crease preventing finishing agent according to claim 4, is characterized in that, in step (1)Described temperature is 44 DEG C, reaction 26min.
6. the preparation method of a kind of fabric crease preventing finishing agent according to claim 4, is characterized in that, in step (2)The time of described stirring is 10-15min.
7. the preparation method of a kind of fabric crease preventing finishing agent according to claim 4, is characterized in that, step (3) instituteStating speed is 350r/min, and temperature is 73 DEG C, and the time is 2.5h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111207.5A CN105603735A (en) | 2016-02-29 | 2016-02-29 | Anti-crease finishing agent for textiles and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610111207.5A CN105603735A (en) | 2016-02-29 | 2016-02-29 | Anti-crease finishing agent for textiles and preparation method thereof |
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| CN105603735A true CN105603735A (en) | 2016-05-25 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280514A (en) * | 2008-03-04 | 2008-10-08 | 浙江传化股份有限公司 | Non-ironing crease-proofing agent and use method thereof |
| CN102634973A (en) * | 2012-04-16 | 2012-08-15 | 盛虹集团有限公司 | Citric acid wrinkle proofing technology for real silk fabrics |
| CN103696250A (en) * | 2013-11-30 | 2014-04-02 | 江苏常朔针纺纱科技有限公司 | Production method of wash-and-wear shirt |
| CN103757903A (en) * | 2013-12-23 | 2014-04-30 | 苏州纺友新材料有限公司 | Crease-resistant finishing agent for high-end fabrics and preparation method thereof |
| CN104018339A (en) * | 2014-05-19 | 2014-09-03 | 际华三五零九纺织有限公司 | Crease-resistant finishing method for point-like crosslinked fabric based on spraying method |
-
2016
- 2016-02-29 CN CN201610111207.5A patent/CN105603735A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280514A (en) * | 2008-03-04 | 2008-10-08 | 浙江传化股份有限公司 | Non-ironing crease-proofing agent and use method thereof |
| CN102634973A (en) * | 2012-04-16 | 2012-08-15 | 盛虹集团有限公司 | Citric acid wrinkle proofing technology for real silk fabrics |
| CN103696250A (en) * | 2013-11-30 | 2014-04-02 | 江苏常朔针纺纱科技有限公司 | Production method of wash-and-wear shirt |
| CN103757903A (en) * | 2013-12-23 | 2014-04-30 | 苏州纺友新材料有限公司 | Crease-resistant finishing agent for high-end fabrics and preparation method thereof |
| CN104018339A (en) * | 2014-05-19 | 2014-09-03 | 际华三五零九纺织有限公司 | Crease-resistant finishing method for point-like crosslinked fabric based on spraying method |
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Application publication date: 20160525 |