CN105603730A - Oil solution special for environmentally-friendly efficient synthetic fiber and preparation method thereof - Google Patents
Oil solution special for environmentally-friendly efficient synthetic fiber and preparation method thereof Download PDFInfo
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- CN105603730A CN105603730A CN201610102043.XA CN201610102043A CN105603730A CN 105603730 A CN105603730 A CN 105603730A CN 201610102043 A CN201610102043 A CN 201610102043A CN 105603730 A CN105603730 A CN 105603730A
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- oil solution
- ether
- environment
- synthetic fibers
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- 229920002994 synthetic fiber Polymers 0.000 title claims abstract description 32
- 239000012209 synthetic fiber Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003921 oil Substances 0.000 claims abstract description 37
- 235000019198 oils Nutrition 0.000 claims abstract description 37
- -1 polyoxypropylene Polymers 0.000 claims abstract description 31
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 22
- 239000004902 Softening Agent Substances 0.000 claims abstract description 21
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 19
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 19
- 239000003240 coconut oil Substances 0.000 claims abstract description 19
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 17
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 15
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 11
- 239000010452 phosphate Substances 0.000 claims abstract description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 29
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 28
- 230000002421 anti-septic effect Effects 0.000 claims description 20
- 239000002202 Polyethylene glycol Substances 0.000 claims description 18
- 125000001931 aliphatic group Chemical group 0.000 claims description 18
- GYQKYMDXABOCBE-UHFFFAOYSA-N chloro-dimethoxy-methylsilane Chemical compound CO[Si](C)(Cl)OC GYQKYMDXABOCBE-UHFFFAOYSA-N 0.000 claims description 18
- 235000021317 phosphate Nutrition 0.000 claims description 18
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 18
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 18
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 17
- 229920001223 polyethylene glycol Polymers 0.000 claims description 17
- 238000010792 warming Methods 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims description 9
- 229940064004 antiseptic throat preparations Drugs 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 150000005217 methyl ethers Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 229910021649 silver-doped titanium dioxide Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims 1
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 claims 1
- UXYBXUYUKHUNOM-UHFFFAOYSA-M ethyl(trimethyl)azanium;chloride Chemical class [Cl-].CC[N+](C)(C)C UXYBXUYUKHUNOM-UHFFFAOYSA-M 0.000 claims 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 27
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 3
- 229930195729 fatty acid Natural products 0.000 abstract description 3
- 239000000194 fatty acid Substances 0.000 abstract description 3
- 239000003242 anti bacterial agent Substances 0.000 abstract 1
- MXOSTENCGSDMRE-UHFFFAOYSA-N butyl-chloro-dimethylsilane Chemical compound CCCC[Si](C)(C)Cl MXOSTENCGSDMRE-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- NOLXQSVNNIIHMV-UHFFFAOYSA-L disodium;2,2-diethyl-3-hexyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCC(C([O-])=O)(S(O)(=O)=O)C(CC)(CC)C([O-])=O NOLXQSVNNIIHMV-UHFFFAOYSA-L 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 229960004275 glycolic acid Drugs 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 description 5
- 238000009987 spinning Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- BGGDRACWOICIIC-KVVVOXFISA-N dodecanoic acid;(z)-octadec-9-enoic acid Chemical compound CCCCCCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O BGGDRACWOICIIC-KVVVOXFISA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000008041 oiling agent Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
- D06M13/517—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond containing silicon-halogen bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an oil solution special for environmentally-friendly efficient synthetic fiber. The oil solution includes, by weight, 10-15 parts of fatty alcohol blocked polyoxypropylene polyoxyethylene ether, 20-30 parts of coconut oil, 5-10 parts of sodium diethylhexyl sulfosuccinate, 6-10 parts of 3-piperazidine propyl methyl dimethyl chloro-silane, 8-12 parts of a polylactic acid-hydroxyacetic acid copolymer, 3-7 parts of fatty acid polyoxyethylene methyl ether, 5-10 parts of phenolic ether phosphate, 10-15 parts of polyethylene methyl ether methacrylate, 2-5 parts of alpha-alkenyl sodium sulfonate, 3-6 parts of an antioxidant, 5-10 parts of a softening agent and 3-5 parts of an antibacterial agent. The invention further discloses a preparation method of the oil solution special for the environmentally-friendly efficient synthetic fiber. The oil solution special for the environmentally-friendly efficient synthetic fiber can effectively improve the inter-fiber holding force, can also protect the fiber strength, accordingly reduce the end breakage rate of the fiber, has a certain biodegradability and is conducive to environmental protection.
Description
Technical field:
The present invention relates to textile auxiliary field, be specifically related to a kind of environment-friendly high-efficiency synthetic fibers oil solution dedicated.
Background technology:
Textile oil agent refers in textile process process in order to improve fibre cohesion, protection fiber strength, minimizingEnd breakage rate and add oil solution dedicated, if do not added this finish, weaving produce will be difficult to normally carry out. FiberThere are two large classes: natural fiber (as wool, the rabbit hair, silkworm, silk, fiber crops, cotton etc.) and chemical fibre. Chemistry is fineDimension is divided into again staple fibre (as viscose rayon) and synthetic fibers (as terylene, polyamide fibre, eyeball synthetic fibre, polypropylene fibre etc.). RespectivelyPlant the requirement difference of fiber to finish.
The preparation process of synthetic fibers mainly comprise spinning, coiling, boundling, drawing-off, curling, cut off,Drip washing and the link such as dry, the auxiliary agent using in these processes is commonly referred to as synthetic fibers finish. They are notOnly can suppress or eliminate the static producing because of the low good poorly conductive of synthetic fibers hygroscopicity in spinning processing processProblem, and can give the characteristics such as fiber softening is level and smooth, make it pass through smoothly later process. Oil for synthetic fibersAgent is mainly made up of surfactant, can form directed adsorption layer at fiber surface. This adsorption layer hydrophilicBase, towards easily absorption moisture wherein of air, forms continuous moisture film on fiber surface, reduces and produces because of friction instituteRaw build-up of static charges. In addition, this oil film had both been isolated fiber, again fiber was had to certain affinity, made itProduce certain convergence and unlikely at random. It also gives fiber certain flatness, makes fiber at friction processIn injury-free, and have good feel, in the time of spinning, can pass through smoothly multiple working procedure, reduce lousiness and disconnectedFirst-class phenomenon, the quality of guarantee fiber product.
As a desirable synthetic fiber oiling agent, should possess following characteristic: (1) have good level and smooth andThe effects such as antistatic property and boundling or obvolvent; (2) Heat stability is good, volatility are low, and metal object is corrodedEffect, washability is good; (3) allotment is with easy to use, and raw material is easy to get, and cost is suitable.
Chinese patent (201510382581.4) discloses the composite finish of a kind of weaving, former by following weight partsMaterial composition: Ethylhexyl stearate 20-30 part, PEO sorbierite four oleic acid monolaurate 10-15 parts,Two ethyl hexanol sulfosuccinates sodium 8-10 parts, methyl ricinolcic acid 5-8 part, bobbin oil 15-17 part,Octylphenol polyethylene oxirane ether 6-10 part, fatty acid methyl ester-α-sodium sulfonate 10-12 part, N, N-dicarboxylic acids ammoniaBase-2-hydroxy propane base sodium sulfonate 3-5 part, hexamethylene 3-5 part, dibutyl sebacate3-5 part, BHT 3-5 part, anhydrosorbitol polyoxyethylene fatty acid ester 10-12 part.Each component comprehensive utilization in this finish, makes fiber have good flatness and flexibility, can also carryThe wearability of high fabric, the ventilative and hygroscopicity of fabric improves, and washing fastness strengthens, and also has certain resisting simultaneouslyBacterium property, but its biological degradability is poor, and environment is had to certain harm.
Summary of the invention:
The object of this invention is to provide a kind of environment-friendly high-efficiency synthetic fibers oil solution dedicated, it can effectively improve fiberBetween cohesive force, can also protect the brute force of fiber, thereby reduce the end breakage rate of fiber, it has certainBiological degradability, is conducive to environmental protection.
The invention also discloses this oil solution dedicated preparation method for environment-friendly high-efficiency synthetic fibers.
For achieving the above object, the present invention is by the following technical solutions:
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
Fatty alcohol block polyoxyethylene polyoxypropylene ether 10-15 part,
Coconut oil 20-30 part, dioctyl sodium sulfosuccinate 5-10 part,
3-piperazine crop propyl group methyl dimethoxy chloro silane 6-10 part,
Poly(D,L-lactide-co-glycolide 8-12 part,
Aliphatic acid polyethenoxy methyl ether 3-7 part, phenolic ether phosphate 5-10 part,
Polyethylene glycol monomethyl ethermethacrylic acid esters 10-15 part,
α-sodium olefin sulfonate 2-5 part, antioxidant 3-6 part,
Softening agent 5-10 part, antiseptic 3-5 part.
As technique scheme preferably, a kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion,Comprise following component:
12 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
30 parts of coconut oil, 10 parts of dioctyl sodium sulfosuccinates,
7 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
10 parts of Poly(D,L-lactide-co-glycolides,
5 parts of aliphatic acid polyethenoxy methyl ethers, 8 parts of phenolic ether phosphates,
11 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
4.5 parts of α-sodium olefin sulfonates, 6 parts of antioxidants,
7.5 parts of softening agents, 5 parts of antiseptics.
As technique scheme preferably, described antioxidant is liquid macroimolecule amount phenolic ester type antioxidantIrganoxL135。
As technique scheme preferably, described softening agent is two (2-butter acylamino-) ethyl-methyl chlorinationThe mixture of the alkoxylated polyalkyleneimine of ammonium and on-quaternised, the two mass ratio is 2:0.5-1.
As technique scheme preferably, described antiseptic is shitosan, nanometer Ag-TiO2, in lanthanum nitrateOne or more mixing.
The preparation method that environment-friendly high-efficiency synthetic fibers are oil solution dedicated, comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 3-5h, adds fatty alcoholBlock polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to60-80 DEG C, constant temperature keeps 2-4h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-thiazolinylSodium sulfonate, antioxidant, softening agent and antiseptic, constant temperature 2-6h, is cooled to room temperature, and it is high that filtration obtains environmental protectionEffect synthetic fibers are oil solution dedicated.
The present invention has following beneficial effect:
Synthetic fibers provided by the invention are oil solution dedicated, have good level and smooth and antistatic property, heat enduranceGood, volatility is low, to metal object corrosiveness, washability is good; It can effectively improve the obvolvent between fiberPower, can also protect the brute force of fiber, never reduces the end breakage rate of fiber, and it has certain biological degradability,Be conducive to environmental protection.
Detailed description of the invention:
In order to deepen the understanding of the present invention, below by embodiment, the present invention is further described, and embodiment onlyBe used for explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
10 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
20 parts of coconut oil, 5 parts of dioctyl sodium sulfosuccinates,
6 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
8 parts of Poly(D,L-lactide-co-glycolides,
3 parts of aliphatic acid polyethenoxy methyl ethers, 5 parts of phenolic ether phosphates,
10 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
2 parts of α-sodium olefin sulfonates, 3 parts of antioxidants,
5 parts of softening agents, 3 parts of antiseptics.
Its preparation method comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 3h, adds fatty alcohol embeddingSection polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to60 DEG C, constant temperature keeps 2h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-olefin sulfonic acidSodium, antioxidant, softening agent and antiseptic, constant temperature 2h, is cooled to room temperature, and it is synthetic that filtration obtains environment-friendly high-efficiencyFiber is oil solution dedicated.
Embodiment 2
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
15 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
30 parts of coconut oil, 10 parts of dioctyl sodium sulfosuccinates,
10 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
12 parts of Poly(D,L-lactide-co-glycolides,
7 parts of aliphatic acid polyethenoxy methyl ethers, 10 parts of phenolic ether phosphates,
15 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
5 parts of α-sodium olefin sulfonates, 6 parts of antioxidants,
10 parts of softening agents, 5 parts of antiseptics.
Its preparation method comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 5h, adds fatty alcohol embeddingSection polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to80 DEG C, constant temperature keeps 4h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-olefin sulfonic acidSodium, antioxidant, softening agent and antiseptic, constant temperature 6h, is cooled to room temperature, and it is synthetic that filtration obtains environment-friendly high-efficiencyFiber is oil solution dedicated.
Embodiment 3
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
12 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
30 parts of coconut oil, 10 parts of dioctyl sodium sulfosuccinates,
7 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
10 parts of Poly(D,L-lactide-co-glycolides,
5 parts of aliphatic acid polyethenoxy methyl ethers, 8 parts of phenolic ether phosphates,
11 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
4.5 parts of α-sodium olefin sulfonates, 6 parts of antioxidants,
7.5 parts of softening agents, 5 parts of antiseptics.
Its preparation method comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 3.5h, adds fatty alcoholBlock polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to65 DEG C, constant temperature keeps 2.5h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-thiazolinyl sulphurAcid sodium, antioxidant, softening agent and antiseptic, constant temperature 3h, is cooled to room temperature, and filtration obtains environment-friendly high-efficiency and closesBecome fiber oil solution dedicated.
Embodiment 4
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
11 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
22 parts of coconut oil, 6 parts of dioctyl sodium sulfosuccinates,
7 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
9 parts of Poly(D,L-lactide-co-glycolides,
4 parts of aliphatic acid polyethenoxy methyl ethers, 6 parts of phenolic ether phosphates,
12 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
3 parts of α-sodium olefin sulfonates, 4 parts of antioxidants,
6 parts of softening agents, 3.5 parts of antiseptics.
Its preparation method comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 4h, adds fatty alcohol embeddingSection polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to70 DEG C, constant temperature keeps 3h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-olefin sulfonic acidSodium, antioxidant, softening agent and antiseptic, constant temperature 4h, is cooled to room temperature, and it is synthetic that filtration obtains environment-friendly high-efficiencyFiber is oil solution dedicated.
Embodiment 5
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
12 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
24 parts of coconut oil, 7 parts of dioctyl sodium sulfosuccinates,
8 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
10 parts of Poly(D,L-lactide-co-glycolides,
5 parts of aliphatic acid polyethenoxy methyl ethers, 7 parts of phenolic ether phosphates,
12 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
4 parts of α-sodium olefin sulfonates, 5 parts of antioxidants,
8 parts of softening agents, 4 parts of antiseptics.
Its preparation method comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 3-5h, adds fatty alcoholBlock polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to75 DEG C, constant temperature keeps 3h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-olefin sulfonic acidSodium, antioxidant, softening agent and antiseptic, constant temperature 5h, is cooled to room temperature, and it is synthetic that filtration obtains environment-friendly high-efficiencyFiber is oil solution dedicated.
Embodiment 6
A kind of environment-friendly high-efficiency synthetic fibers are oil solution dedicated, in weight portion, comprise following component:
13 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
26 parts of coconut oil, 8 parts of dioctyl sodium sulfosuccinates,
9 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
11 parts of Poly(D,L-lactide-co-glycolides,
6 parts of aliphatic acid polyethenoxy methyl ethers, 8 parts of phenolic ether phosphates,
14 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
4.5 parts of α-sodium olefin sulfonates, 5.5 parts of antioxidants,
8 parts of softening agents, 4.5 parts of antiseptics.
Its preparation method comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethyleneglycol firstEther metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 4.5h, adds fatty alcoholBlock polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolic ether phosphate, be warming up to80 DEG C, constant temperature keeps 4h, is cooled to 40-50 DEG C, adds dioctyl sodium sulfosuccinate, α-olefin sulfonic acidSodium, antioxidant, softening agent and antiseptic, constant temperature 5.5h, is cooled to room temperature, and filtration obtains environment-friendly high-efficiency and closesBecome fiber oil solution dedicated.
Claims (6)
1. environment-friendly high-efficiency synthetic fibers are oil solution dedicated, it is characterized in that, in weight portion, compriseFollowing component:
Fatty alcohol block polyoxyethylene polyoxypropylene ether 10-15 part,
Coconut oil 20-30 part, dioctyl sodium sulfosuccinate 5-10 part,
3-piperazine crop propyl group methyl dimethoxy chloro silane 6-10 part,
Poly(D,L-lactide-co-glycolide 8-12 part,
Aliphatic acid polyethenoxy methyl ether 3-7 part, phenolic ether phosphate 5-10 part,
Polyethylene glycol monomethyl ethermethacrylic acid esters 10-15 part,
α-sodium olefin sulfonate 2-5 part, antioxidant 3-6 part,
Softening agent 5-10 part, antiseptic 3-5 part.
2. a kind of environment-friendly high-efficiency synthetic fibers as claimed in claim 1 are oil solution dedicated, it is characterized in that,In weight portion, comprise following component:
12 parts, fatty alcohol block polyoxyethylene polyoxypropylene ether,
30 parts of coconut oil, 10 parts of dioctyl sodium sulfosuccinates,
7 parts, 3-piperazine crop propyl group methyl dimethoxy chloro silane,
10 parts of Poly(D,L-lactide-co-glycolides,
5 parts of aliphatic acid polyethenoxy methyl ethers, 8 parts of phenolic ether phosphates,
11 parts of polyethylene glycol monomethyl ethermethacrylic acid esters,
4.5 parts of α-sodium olefin sulfonates, 6 parts of antioxidants,
7.5 parts of softening agents, 5 parts of antiseptics.
3. a kind of environment-friendly high-efficiency synthetic fibers as claimed in claim 1 are oil solution dedicated, it is characterized in that,Described antioxidant is liquid macroimolecule amount phenolic ester type antioxidant IrganoxL135.
4. a kind of environment-friendly high-efficiency synthetic fibers as claimed in claim 1 are oil solution dedicated, it is characterized in that,Described softening agent is the alkoxylate of two (2-butter acylamino-) ethyl trimethyl ammonium chlorides and on-quaternisedThe mixture of polyalkyleneimine, the two mass ratio is 2:0.5-1.
5. a kind of environment-friendly high-efficiency synthetic fibers as claimed in claim 1 are oil solution dedicated, it is characterized in that,Described antiseptic is shitosan, nanometer Ag-TiO2, one or more mixing in lanthanum nitrate.
6. the oil solution dedicated system of a kind of environment-friendly high-efficiency synthetic fibers as described in as arbitrary in claim 1 to 5Preparation Method, is characterized in that, comprises the following steps:
By 3-piperazine crop propyl group methyl dimethoxy chloro silane, Poly(D,L-lactide-co-glycolide and polyethylene glycolMonomethyl ether metacrylic acid ester joins in reactor, is warming up to 40-50 DEG C, and constant temperature keeps 3-5h,Add fatty alcohol block polyoxyethylene polyoxypropylene ether, coconut oil, aliphatic acid polyethenoxy methyl ether and phenolEther phosphate, is warming up to 60-80 DEG C, and constant temperature keeps 2-4h, is cooled to 40-50 DEG C, adds butanedioic acidDioctyl ester sodium sulfonate, α-sodium olefin sulfonate, antioxidant, softening agent and antiseptic, constant temperature 2-6h,Be cooled to room temperature, it is oil solution dedicated that filtration obtains environment-friendly high-efficiency synthetic fibers.
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| CN110747538A (en) * | 2019-11-20 | 2020-02-04 | 杭州锦尔迪科技有限公司 | Preparation method of antioxidant antistatic ATY oil |
| CN112899824A (en) * | 2021-01-22 | 2021-06-04 | 江苏钟山化工有限公司 | FDY oil agent for polyester spinning |
| CN114687033A (en) * | 2022-04-15 | 2022-07-01 | 桐乡市华家那羊绒服饰有限公司 | Production process of cashmere polylactic acid blended yarn |
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