CN105602307B - A kind of water-fast clear coat of historical relic's protection - Google Patents
A kind of water-fast clear coat of historical relic's protection Download PDFInfo
- Publication number
- CN105602307B CN105602307B CN201610115783.7A CN201610115783A CN105602307B CN 105602307 B CN105602307 B CN 105602307B CN 201610115783 A CN201610115783 A CN 201610115783A CN 105602307 B CN105602307 B CN 105602307B
- Authority
- CN
- China
- Prior art keywords
- water
- protection
- clear coat
- parts
- historical relic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
A kind of water-fast clear coat of historical relic's protection, it is related to a kind of water resistant coating, the present invention is with anacardol and chlordene（Fluorine, bromine）The synthetic for changing benzyl is base material, is needing cultural artifact surface to be protected to form the clear coat with water-resistant capacity by automatic oxidation reaction.Using this reparation means, the transparency of coating realizes the multiple complete protection of the same area.Advantages of nontoxic raw materials used is harmless, and steam permeability, weatherability, permeability and adhesive force are good, and the products material is easy to get, and production method is simple, and manual operation is convenient, meets environmental protection and requirement, has broad application prospects.Product of the present invention can be used for the protection of cultural artifact surface, be particularly those protections using natural earth pigment as black made from raw material or colored cultural artifact surface.
Description
Technical field
The present invention relates to a kind of water resistant coating, more particularly to a kind of historical relic's protection with water-fast clear coat.
Background technology
China is an ancient and civilized country, there is many historical and cultural heritages, wherein it is substantial amounts of to be unearthed in the last few years
The historical relics such as lacquerware.It is many to make exquisite ANCIENT LACQUER OBJECTS, even if in the long-term underground for being imbedded in humidity or the arid desert, also can
Holding light is gorgeous as new, but can change because of ambient humidity greatly after being unearthed and phenomena such as deformation, discoloration occur.Because air is excessively
Dry, lacquerware is easily broken, and humidity is excessive, then easily occurs deforming and depainting, therefore develop it is a kind of have it is water-fast transparent
Coating protect these historical relics extremely urgent.
Raw lacquer is the natural juice extracted from lacquer tree, is mainly made up of laccol, laccase, gumminess and moisture.Applied with it
Material, there is the specific function such as moisture resistance, high temperature resistant, corrosion-resistant.Raw lacquer becomes the lacquer that can make coating after Exposure to Sunlight is dehydrated.Simultaneously
Tung oil one kind dry vegetable oil is often added in paint, different colored paints can be made again, coloured and dazzling, therefrom we can see
Go out, what lacquerware surface applied is one layer of natural material.Anacardol（Cardanol）Be one kind from natural cashew nut shell oil through advanced skill
Art is refined and formed, similar with the vegetable oil performance in ANCIENT LACQUER OBJECTS coating, while anacardol also has the characteristics that：1. contain phenyl ring
Structure, there is resistance to elevated temperatures；2. the hydroxyl of polarity can provide wetting and activity of the system to contact surface；3. meta is containing unsaturation
The straight chain of carbon 15 of double bond, can provide system good toughness, excellent hydrophobicity and hypotonicity and from dryness.Therefore with cashew nut
Material made from raw material is combined more preferable with lacquerware cultural artifact surface based on phenol.And conventional acrylic resin closed substrate, formed
Fine and close paint film, moisture can not discharge, and with the increase of wall moisture stress, paint film easily bubbles, and ftracture and come off because of condensation
Etc. reason, caused by long-term moisture aggregation, be easily caused floating sand, cohesive force declines.
The content of the invention
It is an object of the invention to provide a kind of historical relic's protection with water-fast clear coat,
The purpose of the present invention is achieved through the following technical solutions：
A kind of water-fast clear coat of historical relic's protection, the coating stoste, prepared using following quality proportioning：
100 parts of anacardol；
Chlordene（Fluorine, bromine）Change benzyl 0.1-10 parts；
Solvent 100-200 parts；
Plumper 1-10 parts；
Such as, six benzyl chlorides and anacardol reaction equation are as follows：
The benzyl chloride target product of anacardol six
Chlorine element can be replaced by fluorine, bromo in reaction equation, and wherein the R in anacardol is：
。
A kind of water-fast clear coat of described historical relic's protection, the solvent is dichloromethane, dichloroethanes, tetrahydrochysene furan
Mutter, dimethylformamide etc..
A kind of water-fast clear coat of described historical relic's protection, the alkali are potassium carbonate, sodium carbonate, sodium hydroxide, hydrogen-oxygen
Change the inorganic base such as potassium, ammoniacal liquor and the organic base such as triethylamine, pyridine.
A kind of water-fast clear coat of described historical relic's protection, the material mixing uniformly after room temperature 2 hours, afterwards
Vacuum abjection solvent produces the water-fast clear coat glue that can be used as historical relic's protection.
Advantages of the present invention is with effect：
Unsaturated long-chain on anacardol side chain of the present invention is allowed to be easier to crosslink reaction with the product of six benzyl chlorides,
With from dryness, protective layer is quickly formed on lacquerware surface；Phenolic hydroxyl group on anacardol molecule has reacted away, so
Improve the water resistance of protective layer；Containing abundant phenyl and in long way in the synthetic of anacardol molecule and six benzyl chloride molecules
Flexible side group, this make it that protective coating does not crease easily and hard and tough；The diaphragm that can be cross-linked to form at normal temperatures is but also with good
The good transparency.
Embodiment
With reference to embodiment, the present invention is described in detail.
A kind of preparation method of the water-fast clear coat of historical relic's protection disclosed in this invention, following instance pair can be combined
The present invention is described in detail.
Example 1：
The stoste of the coating, prepared using following quality proportioning：
100 parts of anacardol
Six 5 parts of benzyl chlorides
100 parts of methylene chloride
8 parts of plumper sodium acid carbonate
Room temperature 2 hours after material mixing will be stated uniformly, the solvent of vacuum abjection afterwards, which produces, can be used as historical relic's protection
Water-fast clear coat glue.
Example 2：
The stoste of the coating, prepared using following quality proportioning：
100 parts of anacardol
Lithium 3 parts of benzyl
180 parts of solvent dimethylformamide
8 parts of plumper triethylamine
Room temperature 2 hours after material mixing will be stated uniformly, the solvent of vacuum abjection afterwards, which produces, can be used as historical relic's protection
Water-fast clear coat glue.
Example 3：
The stoste of the coating, prepared using following quality proportioning：
100 parts of anacardol
Six 8 parts of cylites
120 parts of solvent dichloroethanes
10 parts of plumper ammoniacal liquor
Room temperature 2 hours after material mixing will be stated uniformly, the solvent of vacuum abjection afterwards, which produces, can be used as historical relic's protection
Water-fast clear coat glue.
Claims (3)
1. the water-fast clear coat of a kind of historical relic's protection, it is characterised in that the coating stoste, prepared using following quality proportioning
's：
100 parts of anacardol；
Six benzyl chloride 0.1-10 parts；
Or lithium benzyl 0.1-10 parts；
Or six cylite 0.1-10 parts；
Solvent 100-200 parts；
Plumper 1-10 parts；
Benzyl chloride and anacardol reaction equation are as follows：
The benzyl chloride target product of anacardol six
Chlorine element can be replaced by fluorine, bromo in reaction equation, and wherein the R in anacardol is：
。
2. the water-fast clear coat of a kind of historical relic's protection according to claim 1, it is characterised in that the solvent is two
Chloromethanes, dichloroethanes, tetrahydrofuran, dimethylformamide.
3. the water-fast clear coat of a kind of historical relic's protection according to claim 1, it is characterised in that the material mixing is equal
Room temperature 2 hours after even, the solvent of vacuum abjection afterwards produce the water-fast clear coat glue that can be used as historical relic's protection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610115783.7A CN105602307B (en) | 2016-03-02 | 2016-03-02 | A kind of water-fast clear coat of historical relic's protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610115783.7A CN105602307B (en) | 2016-03-02 | 2016-03-02 | A kind of water-fast clear coat of historical relic's protection |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105602307A CN105602307A (en) | 2016-05-25 |
| CN105602307B true CN105602307B (en) | 2018-01-26 |
Family
ID=55982680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610115783.7A Expired - Fee Related CN105602307B (en) | 2016-03-02 | 2016-03-02 | A kind of water-fast clear coat of historical relic's protection |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105602307B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168645A (en) * | 2006-10-25 | 2008-04-30 | 朱凯琴 | Transparent organic silicon rigidity-increasing dope |
| CN103555086A (en) * | 2013-10-29 | 2014-02-05 | 陕西师范大学 | Earthen ruins return repair protecting agent |
| CN103694896A (en) * | 2014-01-01 | 2014-04-02 | 湖北腾龙洞民族工艺有限公司 | Air-drying colorful color-change raw lacquer coating and modulation method thereof |
| AU2011374671B2 (en) * | 2011-08-05 | 2015-11-26 | Sika Technology Ag | A water-proof coating system for reflecting solar radiation and water-borne coatings for forming the white decorative and reflective layer in the coating system |
-
2016
- 2016-03-02 CN CN201610115783.7A patent/CN105602307B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168645A (en) * | 2006-10-25 | 2008-04-30 | 朱凯琴 | Transparent organic silicon rigidity-increasing dope |
| AU2011374671B2 (en) * | 2011-08-05 | 2015-11-26 | Sika Technology Ag | A water-proof coating system for reflecting solar radiation and water-borne coatings for forming the white decorative and reflective layer in the coating system |
| CN103555086A (en) * | 2013-10-29 | 2014-02-05 | 陕西师范大学 | Earthen ruins return repair protecting agent |
| CN103694896A (en) * | 2014-01-01 | 2014-04-02 | 湖北腾龙洞民族工艺有限公司 | Air-drying colorful color-change raw lacquer coating and modulation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105602307A (en) | 2016-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102585652B (en) | Fire retardant coating | |
| CN102876172B (en) | A kind of aqueous fire-proof coating | |
| CN102808357A (en) | Super-hydrophobic paper and production method thereof | |
| CN204219915U (en) | A kind of glass fibre composite filtering cloth | |
| CN105602307B (en) | A kind of water-fast clear coat of historical relic's protection | |
| CN101245005B (en) | Modified acrylic acid oligomer and dirt-resisting paint containing the oligomer | |
| CN106221450B (en) | Special waterproof material for sprayed roof | |
| CN102977768A (en) | Metal antirust paint prepared from modified phenolic resin, and its preparation method | |
| CN104130631B (en) | Transparent waterproof coating | |
| CN107177126A (en) | A kind of plastic-steel door and window | |
| CN107189669B (en) | A kind of low-surface-energy aqueous polyurethane/nano SiO2Marine anti-pollution coating material and preparation method | |
| CN103466223B (en) | The method for making of a kind of large-scale breeding feed tank and batch can | |
| CN103275434B (en) | Water supply flexible pipe manufactured by polyvinyl chloride plastics | |
| CN104744984B (en) | Preparation method of surface antibacterial coating | |
| CN107880763A (en) | Water-proof environmental protection coating and preparation method thereof | |
| CN114015308A (en) | Color sand-free star-color exquisite stone coating and preparation method thereof | |
| CN102618134A (en) | Water-based glass heat insulation paint | |
| CN106085052A (en) | A kind of engineering machinery Wear-resistant, high-temperature resistant coating | |
| CN105462327A (en) | Production process of insulation decoration integrated board | |
| CN105199579A (en) | Permeation type anti-corrosion sealing coating | |
| CN108912775A (en) | A kind of novel environment friendly water-repellent paint | |
| CN204641119U (en) | A kind of water-fast heat transfer film | |
| CN105315737A (en) | Magnesium acrylate spraying film waterproof material containing continuous basalt fiber | |
| CN103602155B (en) | A kind of environment-friendly waterproof paint | |
| CN107418406A (en) | A kind of high molecular water-proof paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180126 Termination date: 20210302 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |