CN105602266A - Novel antibacterial natural fiber material, and preparation method thereof - Google Patents
Novel antibacterial natural fiber material, and preparation method thereof Download PDFInfo
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- CN105602266A CN105602266A CN201510779803.6A CN201510779803A CN105602266A CN 105602266 A CN105602266 A CN 105602266A CN 201510779803 A CN201510779803 A CN 201510779803A CN 105602266 A CN105602266 A CN 105602266A
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- natural fiber
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Abstract
The invention discloses a novel antibacterial natural fiber material, and a preparation method thereof. The novel antibacterial natural fiber material is prepared from, by weight, 70 to 80 parts of natural fiber, 10 to 12 parts of polyethylene glycol, 8 to 11 parts of octadecyl vinyl ether, 6 to 8 parts of polyvinyl alcohol, 6 to 8 parts of paraffin oil, 3 to 5 parts of carboxy methyl cellulose, 2 to 4 parts of polypropylene carbonate succinate, 1 to 2 parts of metasilicic acid trimethyl ester, 0.5 to 1 part of isopimpinellin, 0.5 to 1 part of stachydrine, 0.3 to 0.5 part of dimethylol urea, and 0.02 to 0.05 part of pinene. The invention also provides the preparation method of the novel antibacterial natural fiber material,.
Description
Technical field
The invention belongs to fibrous material field, particularly a kind of novel antibacterial natural fiber material and preparation method thereof.
Background technology
Anti-biotic material refers to self to have killing or suppresses a class new function material of microbial function, medical field,There is extremely wide application prospect in the fields such as household supplies, household electrical appliance, packaging for foodstuff.
Anti-biotic material can be divided into inorganic antiseptic and organic antibacterial agent, has many materials itself just to have good at occurring in natureGood sterilization or suppress the function of microorganism, as part with the organic compound of special groups, some inorganic metal materials andIts compound, part mineral matter and natural materials. But anti-biotic material more refers to by adding certain antibacterial material at present,Thereby material is there is suppress or kills a class new function material of surface bacteria ability, as antibiotic plastic, anti-bacterial fibre andFabric, anti-bacteria ceramic, antibacterial metallic materials etc.
Summary of the invention
For above-mentioned demand, the present invention provides a kind of novel antibacterial natural fiber material and preparation method thereof especially.
Object of the present invention can be achieved through the following technical solutions:
A kind of novel antibacterial natural fiber material, made by the component that comprises following weight portion:
Natural fiber 70-80 part,
Polyethylene glycol 10-12 part,
Octadecyl vinyl ether 8-11 part,
Polyvinyl alcohol 6-8 part,
Paraffin oil 6-8 part,
CMC 3-5 part,
The sub-propyl ester 2-4 of poly-carbonic acid succinic acid part,
Metasilicic acid trimethyl 1-2 part,
Isopimpinellin 0.5-1 part,
Stachydrine 0.5-1 part,
Dimethylol urea 0.3-0.5 part,
Firpene 0.02-0.05 part.
Described natural fiber is selected from one or more the mixing in cotton fiber, flaxen fiber, bamboo fibre or silk fiber.
The mean molecule quantity of described polyethylene glycol is 800-1000.
The mean molecule quantity of described polyvinyl alcohol is 1500-2000.
A preparation method for novel antibacterial natural fiber material, the method comprises the following steps:
(1) take polyethylene glycol 10-12 part, octadecyl vinyl ether 8-11 part, polyvinyl alcohol 6-8 part, paraffin oil 6-8Part, CMC 3-5 part, the sub-propyl ester 2-4 of poly-carbonic acid succinic acid part, metasilicic acid trimethyl 1-2 part, isopimpinellin 0.5-1Part, stachydrine 0.5-1 part, dimethylol urea 0.3-0.5 part and firpene 0.02-0.05 part are stirred 15-25 at 120-150 DEG CMinute;
(2) add natural fiber 70-80 part, at 190-200 DEG C, heat 15-20 minute, twist, cooling, pelletizing,Obtain antimicrobial natural fibrous material.
Compared with prior art, its beneficial effect is in the present invention:
(1) the antimicrobial natural fibrous material that the present invention makes is taking natural fiber as primary raw material, by add polyethylene glycol,Octadecyl vinyl ether, polyvinyl alcohol, paraffin oil, CMC, the sub-propyl ester of poly-carbonic acid succinic acid, metasilicic acid front threeEster, isopimpinellin, stachydrine, dimethylol urea and firpene, the antimicrobial natural fibrous material making has good mechanical strengthAnd tenacity of fibre, and this antimicrobial natural fibrous material has good antibacterial and bactericidal property.
(2) the antimicrobial natural fibrous material that the present invention makes has good antistatic performance.
(3) antimicrobial natural fibrous material of the present invention, its preparation method is simple, is easy to suitability for industrialized production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) taking mean molecule quantity is that 800 polyethylene glycol 10kg, octadecyl vinyl ether 8kg, mean molecule quantity are1500 polyvinyl alcohol 6kg, paraffin oil 6kg, CMC 3kg, the sub-propyl ester 2kg of poly-carbonic acid succinic acid, metasilicic acid front threeEster 1kg, isopimpinellin 0.5kg, stachydrine 0.5kg, dimethylol urea 0.3kg and firpene 0.02kg stir 15 points at 120 DEG CClock;
(2) add cotton fiber 70kg, heat 20 minutes at 190 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Embodiment 2
(1) taking mean molecule quantity is 1000 polyethylene glycol 10kg, octadecyl vinyl ether 8kg, mean molecule quantityBe 2000 polyvinyl alcohol 6kg, paraffin oil 6kg, CMC 3kg, the sub-propyl ester 2kg of poly-carbonic acid succinic acid, metasilicic acid threeMethyl esters 1kg, isopimpinellin 0.5kg, stachydrine 0.5kg, dimethylol urea 0.3kg and firpene 0.02kg stir 15 at 120 DEG CMinute;
(2) add flaxen fiber 70kg, heat 20 minutes at 190 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Embodiment 3
(1) taking mean molecule quantity is 1000 polyethylene glycol 12kg, octadecyl vinyl ether 11kg, mean molecule quantityBe 2000 polyvinyl alcohol 8kg, paraffin oil 8kg, CMC 5kg, the sub-propyl ester 4kg of poly-carbonic acid succinic acid, metasilicic acid threeMethyl esters 2kg, isopimpinellin 1kg, stachydrine 1kg, dimethylol urea 0.5kg and firpene 0.05kg stir 25 points at 150 DEG CClock;
(2) add flaxen fiber 80kg, heat 15 minutes at 200 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Embodiment 4
(1) taking mean molecule quantity is 1000 polyethylene glycol 12kg, octadecyl vinyl ether 11kg, mean molecule quantityBe 2000 polyvinyl alcohol 8kg, paraffin oil 8kg, CMC 5kg, the sub-propyl ester 4kg of poly-carbonic acid succinic acid, metasilicic acid threeMethyl esters 2kg, isopimpinellin 0.5kg, stachydrine 0.5kg, dimethylol urea 0.3kg and firpene 0.02kg stir 25 at 120 DEG CMinute;
Add bamboo fibre 80kg, heat 15 minutes at 200 DEG C, twist, cooling, pelletizing, obtains antimicrobial natural fibreDimension material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Embodiment 5
(1) taking mean molecule quantity is 900 polyethylene glycol 11kg, octadecyl vinyl ether 10kg, mean molecule quantityBe 2000 polyvinyl alcohol 7kg, paraffin oil 7kg, CMC 4kg, the sub-propyl ester 3kg of poly-carbonic acid succinic acid, metasilicic acid threeMethyl esters 1kg, isopimpinellin 0.8kg, stachydrine 0.8kg, dimethylol urea 0.4kg and firpene 0.04kg stir 20 at 130 DEG CMinute;
(2) add silk fiber 75kg, heat 18 minutes at 195 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Comparative example 1
(1) taking mean molecule quantity is 1000 polyethylene glycol 12kg, octadecyl vinyl ether 11kg, mean molecule quantityBe 2000 polyvinyl alcohol 8kg, paraffin oil 8kg, CMC 5kg, metasilicic acid trimethyl 2kg, isopimpinellin 1kg, waterThe alkali 1kg of Soviet Union and dimethylol urea 0.5kg stir 25 minutes at 150 DEG C;
(2) add flaxen fiber 80kg, heat 15 minutes at 200 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Comparative example 2
(1) taking mean molecule quantity is 1000 polyethylene glycol 12kg, octadecyl vinyl ether 11kg, mean molecule quantityBe 2000 polyvinyl alcohol 8kg, paraffin oil 8kg, CMC 5kg, the sub-propyl ester 4kg of poly-carbonic acid succinic acid, metasilicic acid threeMethyl esters 2kg, isopimpinellin 1kg, stachydrine 1kg and firpene 0.05kg stir 25 minutes at 150 DEG C;
(2) add flaxen fiber 80kg, heat 15 minutes at 200 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Comparative example 3
(1) taking mean molecule quantity is 1000 polyethylene glycol 12kg, octadecyl vinyl ether 11kg, mean molecule quantityBe 2000 polyvinyl alcohol 8kg, paraffin oil 8kg, CMC 5kg, the sub-propyl ester 4kg of poly-carbonic acid succinic acid, metasilicic acid threeMethyl esters 2kg, stachydrine 1kg, dimethylol urea 0.5kg and firpene 0.05kg stir 25 minutes at 150 DEG C;
(2) add flaxen fiber 80kg, heat 15 minutes at 200 DEG C, twist, cooling, pelletizing, obtains antimicrobial naturalFibrous material.
The performance test results that makes antimicrobial natural fibrous material is as shown in table 1.
Table 1
The invention is not restricted to the embodiment here, those skilled in the art, according to announcement of the present invention, do not depart from the present inventionThe improvement that category is made and amendment all should be within protection scope of the present invention.
Claims (5)
1. a novel antibacterial natural fiber material, is characterized in that, is made up of the component that comprises following weight portion:
Natural fiber 70-80 part,
Polyethylene glycol 10-12 part,
Octadecyl vinyl ether 8-11 part,
Polyvinyl alcohol 6-8 part,
Paraffin oil 6-8 part,
CMC 3-5 part,
The sub-propyl ester 2-4 of poly-carbonic acid succinic acid part,
Metasilicic acid trimethyl 1-2 part,
Isopimpinellin 0.5-1 part,
Stachydrine 0.5-1 part,
Dimethylol urea 0.3-0.5 part,
Firpene 0.02-0.05 part.
2. novel antibacterial natural fiber material according to claim 1, is characterized in that, described natural fiber is selected from cotton fineThe mixing of one or more in dimension, flaxen fiber, bamboo fibre or silk fiber.
3. novel antibacterial natural fiber material according to claim 1, is characterized in that, the average mark of described polyethylene glycolSon amount is 800-1000.
4. novel antibacterial natural fiber material according to claim 1, is characterized in that, the average mark of described polyvinyl alcoholSon amount is 1500-2000.
5. a preparation method for novel antibacterial natural fiber material, is characterized in that, the method comprises the following steps:
(1) take polyethylene glycol 10-12 part, octadecyl vinyl ether 8-11 part, polyvinyl alcohol 6-8 part, paraffin oil 6-8 part,CMC 3-5 part, the sub-propyl ester 2-4 of poly-carbonic acid succinic acid part, metasilicic acid trimethyl 1-2 part, isopimpinellin 0.5-1 part,Stachydrine 0.5-1 part, dimethylol urea 0.3-0.5 part and firpene 0.02-0.05 part are stirred 15-25 and are divided at 120-150 DEG CClock;
(2) add natural fiber 70-80 part, at 190-200 DEG C, heat 15-20 minute, twist, cooling, pelletizing, obtainsAntimicrobial natural fibrous material.
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| CN201510779803.6A CN105602266A (en) | 2015-11-13 | 2015-11-13 | Novel antibacterial natural fiber material, and preparation method thereof |
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| CN201510779803.6A CN105602266A (en) | 2015-11-13 | 2015-11-13 | Novel antibacterial natural fiber material, and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108541865A (en) * | 2018-04-10 | 2018-09-18 | 柳州潜荣健康产业有限公司 | A kind of preparation method of fluid food anti-corrosive fresh-keeping material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101693391A (en) * | 2009-10-13 | 2010-04-14 | 中国人民解放军总后勤部军需装备研究所 | Natural fiber granulating process for preparing composite materials |
| CN102212962A (en) * | 2011-04-07 | 2011-10-12 | 上海水星家用纺织品股份有限公司 | Composite antibiotic finishing agent and preparation method and finishing process thereof for application to mucilage glue and cotton fiber interweaved jacquard fabric |
| CN104287303A (en) * | 2014-10-21 | 2015-01-21 | 常熟市任阳工艺鞋厂 | Antibacterial insole |
-
2015
- 2015-11-13 CN CN201510779803.6A patent/CN105602266A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101693391A (en) * | 2009-10-13 | 2010-04-14 | 中国人民解放军总后勤部军需装备研究所 | Natural fiber granulating process for preparing composite materials |
| CN102212962A (en) * | 2011-04-07 | 2011-10-12 | 上海水星家用纺织品股份有限公司 | Composite antibiotic finishing agent and preparation method and finishing process thereof for application to mucilage glue and cotton fiber interweaved jacquard fabric |
| CN104287303A (en) * | 2014-10-21 | 2015-01-21 | 常熟市任阳工艺鞋厂 | Antibacterial insole |
Non-Patent Citations (3)
| Title |
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| 上海服装行业协会等: "《中国服装大典》", 30 November 1999, 文汇出版社 * |
| 冼杏娟等: "《竹纤维增强树脂复合材料及其微观形貌》", 30 June 1995, 科学出版社 * |
| 张幼珠等: "《纺织应用化学》", 31 August 2009, 东华大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108541865A (en) * | 2018-04-10 | 2018-09-18 | 柳州潜荣健康产业有限公司 | A kind of preparation method of fluid food anti-corrosive fresh-keeping material |
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