CN105587101B - Non-solvent epoxy antistatic floor - Google Patents

Non-solvent epoxy antistatic floor Download PDF

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Publication number
CN105587101B
CN105587101B CN201511012636.9A CN201511012636A CN105587101B CN 105587101 B CN105587101 B CN 105587101B CN 201511012636 A CN201511012636 A CN 201511012636A CN 105587101 B CN105587101 B CN 105587101B
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parts
antistatic
byk
dispersant
defoamer
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CN105587101A (en
Inventor
陈遵厚
苗建程
谢桂秀
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Fuzhou Royal Floor Co Ltd
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Fuzhou Royal Floor Co Ltd
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • E04F15/181—Insulating layers integrally formed with the flooring or the flooring elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/267—Magnesium carbonate
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E04F2290/048—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against static electricity

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a kind of non-solvent epoxy antistatic floor, from bottom to top including permeable primer layer, screed-coat, antistatic copper foil layer, conductive floating coat, antistatic backing, arranged net when laying antistatic copper foil with the m of 5 m × 5, per 500m2An earth point is drawn to be connected with ground connection main line.The present invention timely and effectively can transfer out the electrostatic of accumulation, solve traditional terrace only lean against in each coating add anti-static material caused by anti-static effect difference the defects of, effectively eliminate the potential safety hazard caused by terrace static buildup, there are the excellent properties such as environmental protection, green, heatproof, fire-retardant, wear-resisting simultaneously, especially suitable for electronics computer room, electronic equipment factory, munitions factory, placement ammunition depot and various inflammable and explosive places.

Description

Non-solvent epoxy antistatic floor
Technical field
The invention belongs to the preparation field of terrace, and in particular to a kind of non-solvent epoxy antistatic floor.
Background technology
Terrace is the part being in contact with concrete layer between bottom, and it bears the load between bottom, it is desirable to is had certain Strength and stiffness, and with protection against the tide, waterproof, warming, wear-resisting performance.And the place of electrostatic charge is easily accumulated at some（Such as electricity Handset room, electronic equipment factory, munitions factory, placement ammunition depot and other inflammable and explosive fields）, terrace is required for being prevented Electrostatic Treatment.In the past, it is in recent years, quiet with resisting mostly using the method for pasting antistatic sheet material in the place for needing antistatic The development of electric material, adds anti-static material in terrace more, can play certain anti-static effect.But will to electrostatic at some Ask in high place, the antistatic effect of this terrace can not meet to require, therefore, invention one kind can prevent electrostatic or energy Enough terraces for effectively eliminating electrostatic are necessary.
The content of the invention
It is an object of the invention in view of the shortcomings of the prior art, providing a kind of non-solvent epoxy antistatic floor.The terrace In addition to the excellent properties such as environmental protection, green, heatproof, fire-retardant, wear-resisting, and it can also eliminate and prevent electrostatic and electromagnetism Ripple.
To achieve the above object, the present invention adopts the following technical scheme that：
Non-solvent epoxy antistatic floor, from bottom to top including permeable primer layer, screed-coat, antistatic copper foil layer, lead Electric floating coat, antistatic backing；Arranged net when laying antistatic copper foil with the m of 5 m × 5, per 500m2Draw an earth point and ground connection Main line connects.
Described permeable primer layer is made up of following components by weight：Epoxy resin 40-60 parts, normal-butyl Glycidol ether 10-20 parts and polyamide curing agent 10-20 parts.
Described screed-coat is made up of following components by weight：Epoxy resin 50-60 parts, normal-butyl are shunk sweet Oily ether 10-20 parts, polyamide curing agent are 10-20 parts, talcum powder 12-15 parts, dolomite dust 8-10 parts, dispersant 0.8-1.3 Part, levelling agent 0.9-1.5 parts and defoamer 1.2-1.6 parts；Described dispersant is BYK-110；Described levelling agent is BYK- One kind in 323 and CERAFLOUR 996；Described defoamer is BYK-A530.
Described conductive floating coat is made up of following components by weight：Epoxy resin 35-45 parts, normal-butyl contracting Water glycerin ether 20-40 parts, polyamide curing agent are 8-10 parts, conductive black 8-10 parts, dispersant 0.5-0.8 parts, levelling agent 0.4-0.8 parts and defoamer 0.4-0.8 parts；Described dispersant is BYK-110；Described levelling agent be BYK-323 and One kind in CERAFLOUR 996；Described defoamer is BYK-A530.
Described antistatic backing is made up of following components by weight：Epoxy resin E-54 30-35 parts, positive fourth Base glycidol ether 20-40 parts, polyamide curing agent are 10-15 parts, powdered whiting 2-5 parts, electroconductive glass fibre 20-25 Part, dispersant 0.8-1.2 parts, levelling agent 0.8-1.2 parts, defoamer 0.8-1.2 parts and scratching resistant 0.5-1.0 parts；Described Dispersant is BYK-110；Described levelling agent is one kind in BYK-323 and CERAFLOUR 996；Described defoamer is BYK-A530；Described scratching resistant is NANOBYK-3601.
The beneficial effects of the present invention are：
（1）The present invention adds one layer of antistatic copper foil in terrace process of deployment, and finds receiving body for the output of electrostatic, Timely and effectively the electrostatic of accumulation can be transferred out, solve traditional terrace and only lean against in each coating and add anti-static material The defects of caused anti-static effect difference, effectively eliminate the potential safety hazard caused by terrace static buildup；
（2）Antistatic backing uses anti-static material, has good antistatic property, and with environmentally friendly, green, resistance to The excellent properties such as warm, fire-retardant, wear-resisting；
（3）The present invention has a wide range of application, especially suitable for electronics computer room, electronic equipment factory, munitions factory, placement ammunition Warehouse and various inflammable and explosive places.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
Non-solvent epoxy antistatic floor, from bottom to top including permeable primer layer, screed-coat, antistatic copper foil layer, lead Electric floating coat, antistatic backing；Arranged net when laying antistatic copper foil with the m of 5 m × 5, per 500m2Draw an earth point and ground connection Main line connects.
Described permeable primer layer is made up of following components by weight：40 parts of epoxy resin, normal-butyl contracting 10 parts of 10 parts of water glycerin ether and polyamide curing agent.
Described screed-coat is made up of following components by weight：50 parts of epoxy resin, n-butyl glycidyl 10 parts of ether, polyamide curing agent are 10 parts, 12 parts of talcum powder, 8 parts of dolomite dust, 0.8 part of dispersant, 0.9 part of levelling agent and are disappeared 1.2 parts of infusion；Described dispersant is BYK-110；Described levelling agent is BYK-323；Described defoamer is BYK-A530.
Described conductive floating coat is made up of following components by weight：35 parts of epoxy resin, normal-butyl shrink 20 parts of glycerin ether, polyamide curing agent are 8 parts, 8 parts of conductive black, 0.5 part of dispersant, 0.4 part of levelling agent and defoamer 0.4 Part；Described dispersant is BYK-110；Described levelling agent is BYK-323；Described defoamer is BYK-A530.
Described antistatic backing is made up of following components by weight：30 parts of epoxy resin E-54, normal-butyl contracting 20 parts of water glycerin ether, polyamide curing agent are 10 parts, 2 parts of powdered whiting, 20 parts of electroconductive glass fibre, 0.8 part of dispersant, stream 0.5 part of flat 0.8 part of agent, 0.8 part of defoamer and scratching resistant；Described dispersant is BYK-110；Described levelling agent is BYK- 323；Described defoamer is BYK-A530；Described scratching resistant is NANOBYK-3601.
Embodiment 2
Non-solvent epoxy antistatic floor, from bottom to top including permeable primer layer, screed-coat, antistatic copper foil layer, lead Electric floating coat, antistatic backing；Arranged net when laying antistatic copper foil with the m of 5 m × 5, per 500m2Draw an earth point and ground connection Main line connects.
Described permeable primer layer is made up of following components by weight：50 parts of epoxy resin, normal-butyl contracting 15 parts of 15 parts of water glycerin ether and polyamide curing agent.
Described screed-coat is made up of following components by weight：55 parts of epoxy resin, n-butyl glycidyl 15 parts of ether, polyamide curing agent be 15 parts, 13.5 parts of talcum powder, 9 parts of dolomite dust, 1.2 parts of dispersant, 1.2 parts of levelling agent and 1.4 parts of defoamer；Described dispersant is BYK-110；Described levelling agent is CERAFLOUR 996；Described defoamer is BYK-A530。
Described conductive floating coat is made up of following components by weight：40 parts of epoxy resin, normal-butyl shrink 30 parts of glycerin ether, polyamide curing agent are 9 parts, 9 parts of conductive black, 0.65 part of dispersant, 0.6 part of levelling agent and defoamer 0.6 Part；Described dispersant is BYK-110；Described levelling agent is CERAFLOUR 996；Described defoamer is BYK-A530.
Described antistatic backing is made up of following components by weight：32.5 parts of epoxy resin E-54, normal-butyl 30 parts of glycidol ether, polyamide curing agent are 12.5 parts, 3.5 parts of powdered whiting, 22.5 parts of electroconductive glass fibre, dispersant 0.75 part of 1 part, 1 part of levelling agent, 1 part of defoamer and scratching resistant；Described dispersant is BYK-110；Described levelling agent is CERAFLOUR 996；Described defoamer is BYK-A530；Described scratching resistant is NANOBYK-3601.
Embodiment 3
Non-solvent epoxy antistatic floor, from bottom to top including permeable primer layer, screed-coat, antistatic copper foil layer, lead Electric floating coat, antistatic backing；Arranged net when laying antistatic copper foil with the m of 5 m × 5, per 500m2Draw an earth point and ground connection Main line connects.
Described permeable primer layer is made up of following components by weight：60 parts of epoxy resin, normal-butyl contracting 20 parts of 20 parts of water glycerin ether and polyamide curing agent.
Described screed-coat is made up of following components by weight：60 parts of epoxy resin, n-butyl glycidyl 20 parts of ether, polyamide curing agent are 20 parts, 15 parts of talcum powder, 10 parts of dolomite dust, 1.3 parts of dispersant, 1.5 parts of levelling agent and are disappeared 1.6 parts of infusion；Described dispersant is BYK-110；Described levelling agent is BYK-323；Described defoamer is BYK-A530.
Described conductive floating coat is made up of following components by weight：45 parts of epoxy resin, normal-butyl shrink 40 parts of glycerin ether, polyamide curing agent are 10 parts, 10 parts of conductive black, 0.8 part of dispersant, 0.8 part of levelling agent and defoamer 0.8 Part；Described dispersant is BYK-110；Described levelling agent is CERAFLOUR 996；Described defoamer is BYK-A530.
Described antistatic backing is made up of following components by weight：35 parts of epoxy resin E-54, normal-butyl contracting 40 parts of water glycerin ether, polyamide curing agent are 15 parts, 5 parts of powdered whiting, 25 parts of electroconductive glass fibre, 1.2 parts of dispersant, stream 1.0 parts of flat 1.2 parts of agent, 1.2 parts of defoamer and scratching resistant；Described dispersant is BYK-110；Described levelling agent is BYK- 323；Described defoamer is BYK-A530；Described scratching resistant is ANOBYK-3601.
The non-solvent epoxy antistatic floor of above-described embodiment 3, form of construction work are as follows：
（1）Permeable primer layer：With the very strong permeable primer of permeability and adhesive force in uniform roller coating on surface of base Permeable primer layer is formed together；
（2）Screed-coat：Levelling coating point multiple tracks is scratched in levelling to be formed in permeable primer layer surface with trowel Layer, untill applying and scrape rear surfacing；
（3）Antistatic copper foil is laid：Arranged net with the m of 5 m × 5, per 500m2An earth point is drawn to be connected with ground connection main line；
（4）Conductive floating coat：Material even spread will be applied in conduction together with trowel or several is to form conductive floating coat；
（5）Antistatic backing：At least applied and formed by one of antistatic backing material trowel.
The construction method of other embodiment can refer to the construction method of embodiment 3.
The foregoing is only presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, it should all belong to the covering scope of the present invention.

Claims (3)

  1. A kind of 1. non-solvent epoxy antistatic floor, it is characterised in that：Include permeable primer layer, screed-coat from bottom to top, prevent Electrostatic copper foil layer, conductive floating coat, antistatic backing；Arranged net when laying antistatic copper foil with the m of 5 m × 5, per 500m2Draw one Earth point is connected with ground connection main line；Described antistatic backing is made up of following components by weight：Epoxy resin E-54 30-35 parts, n-butyl glycidyl ether 20-40 parts, polyamide curing agent are 10-15 parts, powdered whiting 2-5 parts, conductive glass Glass fiber 20-25 parts, dispersant 0.8-1.2 parts, levelling agent 0.8-1.2 parts, defoamer 0.8-1.2 parts and scratching resistant 0.5- 1.0 part；Described permeable primer layer is made up of following components by weight：Epoxy resin 40-60 parts, normal-butyl contracting Water glycerin ether 10-20 parts and polyamide curing agent 10-20 parts；Described screed-coat is by following components group by weight Into：Epoxy resin 50-60 parts, n-butyl glycidyl ether 10-20 parts, polyamide curing agent are 10-20 parts, talcum powder 12-15 Part, dolomite dust 8-10 parts, dispersant 0.8-1.3 parts, levelling agent 0.9-1.5 parts and defoamer 1.2-1.6 parts；Described leads Electric floating coat is made up of following components by weight：Epoxy resin 35-45 parts, n-butyl glycidyl ether 20-40 parts, Polyamide curing agent is 8-10 parts, conductive black 8-10 parts, dispersant 0.5-0.8 parts, levelling agent 0.4-0.8 parts and defoamer 0.4-0.8 parts.
  2. 2. non-solvent epoxy antistatic floor according to claim 1, it is characterised in that：Described dispersant is BYK- 110；Described levelling agent is one kind in BYK-323 and CERAFLOUR 996；Described defoamer is BYK-A530.
  3. 3. non-solvent epoxy antistatic floor according to claim 1, it is characterised in that：Described scratching resistant is NANOBYK-3601。
CN201511012636.9A 2015-12-31 2015-12-31 Non-solvent epoxy antistatic floor Active CN105587101B (en)

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Publication number Priority date Publication date Assignee Title
CN106336773B (en) * 2016-08-29 2018-12-25 福州皇家地坪有限公司 It can load-carrying solvent-free epoxy resin floor coatings
CN107652845A (en) * 2017-10-19 2018-02-02 石家庄超硕地坪工程有限公司 A kind of novel electrostatic prevention terrace system and manufacture method
CN108753108A (en) * 2018-06-20 2018-11-06 上海维度化工科技有限公司 A kind of non-solvent epoxy super abrasive anti-corrosion antistatic floor coatings and preparation method thereof
CN109535931A (en) * 2018-11-19 2019-03-29 福州皇家地坪有限公司 Water-base epoxy antistatic floor material
CN109608982A (en) * 2018-11-28 2019-04-12 河北晨阳工贸集团有限公司 A kind of novel solvent-free epoxy antistatic floor

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DE102005010967A1 (en) * 2005-03-10 2006-09-14 Degussa Ag Aqueous paint compositions for wood
CN201228430Y (en) * 2008-06-03 2009-04-29 广州秀珀化工股份有限公司 Permanent electrostatic prevention floor coating layer structure
CN103850422A (en) * 2012-11-30 2014-06-11 孙大勇 Anti-static thermal insulating floor
CN104612373A (en) * 2013-11-01 2015-05-13 西安联合交通设施工程有限公司 Anti-static floor sample block
CN104788901B (en) * 2015-04-07 2018-01-09 郑州中德新亚建筑材料有限公司 With the super freeze-thawing resistant circulation epoxy resin grouting material of superior workability superfluidity
CN105017929B (en) * 2015-07-21 2017-05-31 厦门双瑞船舶涂料有限公司 A kind of low-resistivity non-solvent epoxy carbon electrostatic conductive paint
CN105062004B (en) * 2015-08-21 2017-11-17 卡本复合材料（天津）有限公司 A kind of epoxy grouting material for glass sleeve reinforcement system and preparation method thereof

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