CN103073971A - Novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint - Google Patents
Novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint Download PDFInfo
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- CN103073971A CN103073971A CN2012104800524A CN201210480052A CN103073971A CN 103073971 A CN103073971 A CN 103073971A CN 2012104800524 A CN2012104800524 A CN 2012104800524A CN 201210480052 A CN201210480052 A CN 201210480052A CN 103073971 A CN103073971 A CN 103073971A
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Abstract
The invention discloses a novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint, which is characterized in that the bisphenol type A liquid epoxy resin with characteristics of small resistivity, low viscosity, excellent integrated performance and moderate price, an active diluent is added in a formula to reduce the system viscosity, and a conductive filling material selects the zinc oxide whisker or doped polyaniline. The terrace paint has the advantages of excellent antistatic performance, persistence, no influence by time, temperature, humidity and the like; the paint film has the advantages of smooth surface, beauty, wear resistance, pressurization, impact resistance and antibacterial property; the preparation is simple and easy to be operated, the construction is simple, and the application scope is wide.
Description
Technical field
The present invention relates to a kind of novel terrace paint, particularly a kind of no-solvent type anti-electrostatic antibiotic epoxy self-leveling floor coating.
Background technology
Along with modern industry proposes more and more stricter requirement to terrace, the floor material of new generation take Resins, epoxy as representative has obtained developing widely and using over nearly 10 years.Epoxy flooring coating has good water tolerance, oil-proofness and resistance to acids and bases, and coating is smooth, beautiful, and be difficult for cracking, easy cleaning.These advantages all impel it to enjoy the absolute leadership status in industry ground slab coating.
Different according to form of construction work, epoxide terrace can be divided into scumbling type and gravity flow flat pattern.Gravity flow flat pattern epoxide terrace is filmed and is generally 2～3mm, surface smoothing, attractive in appearance, reach mirror effect.Scumbling type epoxide terrace coating thickness is generally 0.5～1mm, good permeability, the surface is also very level and smooth, but surface gloss is inferior to gravity flow flat pattern epoxide terrace, scumbling type epoxide terrace can provide the clean floor that meets the GMP authentication, has simultaneously the immersion of wear-resistant, anti-general acid and alkali corrosion, organic solvent-resistant and mineral oil, the characteristics such as anti-mechanical shock, be applicable to hospital, food processing plant, Electronics Factory, laboratory etc. and require medium acid-alkali-corrosive-resisting, require clean dustless occasion zone.And the coating of scumbling type Resins, epoxy terrace is thinner, and is low than the cost of other epoxide terraces, and the good permeability of filming is used for light work place and wet environment.
The epoxide terrace system has one without characteristics such as seam, easy to clean, corrosion resistance nature attractive in appearance and mechanical property excellences, is the first-selection of clean room Eloor Design.Resins, epoxy and coating thereof are the materials that a class has the forceful electric power insulating property, and the surface very easily produces static electric charge because of friction; In electronics and precision instrument industry, static electric charge very easily punctures electronic devices and components; In military industry, the static discharge effect easily causes the blast of weapons and ammunitions; At medicine and Food industry, static charge can be adsorbed a large amount of dusts, thereby has influence on quality product.Therefore in above field, must carry out modification to common epoxy systems and could obtain to have the coating that certain anti-electrostatic requires, reach service requirements.Popular industrial epoxide terrace system comprises scumbling type epoxy systems, epoxy self-leveling system, epoxy mortar system and fiber glass epoxy system etc. at present, and wherein epoxy self-leveling and epoxy mortar system have had comparatively ripe anti-electrostatic auxiliary products and technique.
Resins, epoxy is insulating material, and volume specific resistance is generally 10
13～10
15Ω cm.Make epoxypaint have conducting function, just must add therein conducting medium.Common anti-electrostatic Self-leveling generally is to add conducting powder in Resins, epoxy, and conducting powder contacts with each other in Resins, epoxy is filmed and could conduct electricity, so addition is large, manufacturing cost is high.The conducting powder oil number is large in addition, causes dope viscosity to increase mobile variation, and construction problem increases.
Anti-electrostatic Solvent-free Self-leveling Epoxy Floor Paint is as film forming matter take Resins, epoxy, take shape in the high performance electrostatic-proof function type coating of concrete floor surface layer with the constructional method of Self-leveling, satisfy modern science and technology and production development to the requirement of terrace, be widely used in electronics, computer, aviation, communication, oil, medicine and other fields.Different from anti-electrostatic solvent epoxy flooring coating and aqueous antistatic epoxy floor paint, the characteristics of Anti-electrostatic Solvent-free Self-leveling Epoxy Floor Paint are: basic VOC free discharging, and environmentally friendly; Anti-static effect is good, lasting, and surface resistivity and volume resistance reach 10
6～10
8Ω; Self-leveling is good, one-pass film-forming more than 1mm, easy construction; Tough and tensile, wear-resisting, the chemicals-resistant, nontoxic, not combustion-supporting of filming; Film coated surface is smooth bright and clean, has well ornamentally, can satisfy 100 grades of cleanliness factor calling hierarchies.
Summary of the invention
The objective of the invention is to overcome the defective of prior art, provide a kind of antistatic performance good, lasting, not affected by time, temperature, humidity etc.; Coating surface is smooth, attractive in appearance, and is wear-resisting, withstand voltage, shock-resistant, has simultaneously the terrace paint of anti-microbial property concurrently.
In order to realize above goal of the invention, the present invention by the following technical solutions: a kind of Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating, composed of the following components by massfraction: 100 parts of bisphenol-A liquid epoxy resins; 20～30 parts of reactive thinners; 10～20 parts of conductive filler materials; 1～3 part of antiseptic-germicide; 1～5 part of auxiliary agent; 1～3 part of Self-leveling mill base; 2～5 parts in solidifying agent; 0.2～0.5 part of siccative.
Described reactive thinner is a kind of in ethylene glycol diglycidylether, 1,2-PD diglycidylether or the BDDE.
Described conductive filler material is doped polyaniline or ZnOw.
Described auxiliary agent is defoamer, thickening material, wetting agent and dispersion agent.
Described antiseptic-germicide is the negative ion antibiotic agent.
Described solidifying agent is modification cycloaliphatic amines compound.
Resins, epoxy has that mechanical property is good, bond performance is high, cure shrinkage is low and the characteristics such as good combination property, is the terrace paint synthetic resins that is most widely used at present.The type of Resins, epoxy and relative molecular mass are very large on the impact of coating property, and the viscosity of Bisphenol F type liquid epoxies is very low, good leveling property, but on the high side; Epoxy resin E-44 is semi-solid state, and viscosity is high, is difficult to Self-leveling behind the adding color stuffing.This select that resistivity less, viscosity are lower, high comprehensive performance and moderate bisphenol-A liquid epoxy resin, epoxy equivalent (weight) about 190 is as solvent-free terrace coating resin.
Often need to add reactive thinner in the prescription with reduction system viscosity, constructability, reactive thinner contains epoxy group(ing), can participate in curing reaction.
Conductive filler material is the important component part of addition type Antistatic Paint, and it is kind, shape and the consumption of selecting as required suitable conductive filler material.Conductive filler material commonly used comprises that metal is that filler, carbon are filler, burning system filler and complex conductive fillers etc.Metal is the shortcomings such as filler exists expensive or oxygen-proof property is poor; Carbon is that filler also has the problems such as dispersion stabilization is poor, color is single; Burning system filler since technology and Cost Problems also be not widely used; The complex conductive fillers free settling hardens, and surface coated conducting material easily peels off during high speed dispersion, causes the coating antistatic performance unstable, and comprises the harmful heavy metals such as tin, antimony, indium, does not meet increasingly strict environmental requirement.ZnOw has unique solid four acicular structures, when being distributed in the base material, it can in system, form very effective three-dimensional netted conductive channel, thereby required addition is much smaller than sphere or laminal filler, and this electroconductibility is electronic conduction, and stability is high; And this whisker is water white monocrystalline, and itself does not have color emissivity whisker, and it can be combined to form pure white or other shades of colour with pigment etc.; Owing to high strength and the high-modulus of whisker, therefore not only can not affect the mechanical property of coating, can strengthen on the contrary shock-resistance, weathering resistance and the sticking power of coating; This product does not contain the harmful materials such as tin, antimony, indium, is beneficial to environmental protection.
Major advantage of the present invention and beneficial effect are:
(1) terrace paint antistatic performance of the present invention is good, lasting, not affected by time, temperature, humidity etc.; Coating surface is smooth, attractive in appearance, and is wear-resisting, withstand voltage, shock-resistant, has simultaneously anti-microbial property concurrently;
(2) terrace paint preparation of the present invention is simple, easy handling; And construction is simple, applied range.
Embodiment
The present invention is further illustrated below by embodiment.
Embodiment one:
Prepare raw material by following mass fraction: 100 parts of bisphenol-A liquid epoxy resins; 30 parts of ethylene glycol diglycidylethers; 20 parts of doped polyanilines; 3 parts of negative ion antibiotic agent; 0.2 part of 0.3 part of defoamer, 2 parts of thickening materials, 0.1 part of wetting agent and dispersion agent; 1 part of Self-leveling mill base; 2 parts of modification cycloaliphatic amines compounds; 0.2 part of siccative;
Bisphenol-A liquid epoxy resin is added the ethylene glycol diglycidylether mixing and stirring, and it is the first component that middling speed stirs 20min;
Defoamer, thickening material, wetting agent, dispersion agent, doped polyaniline, negative ion antibiotic agent, Self-leveling mill base are mixed, high speed dispersion 30min, form slurry after grinding adds modification cycloaliphatic amines compound and siccative, and stirring is the second component;
First, second component mixed be terrace paint.
Embodiment two:
Prepare raw material by following mass fraction: 100 parts of bisphenol-A liquid epoxy resins; 20 parts of 1,2-PD diglycidylethers; 10 parts of ZnOws; 1 part of negative ion antibiotic agent; 0.8 part of 0.5 part of defoamer, 1 part of thickening material, 0.4 part of wetting agent and dispersion agent; 2 parts of Self-leveling mill bases; 3 parts of modification cycloaliphatic amines compounds; 0.3 part of siccative;
Bisphenol-A liquid epoxy resin is added 1,2-PD diglycidylether mixing and stirring, and it is the first component that middling speed stirs 20min;
Defoamer, thickening material, wetting agent, dispersion agent, ZnOw, negative ion antibiotic agent, Self-leveling mill base are mixed, high speed dispersion 30min, form slurry after grinding adds modification cycloaliphatic amines compound and siccative, and stirring is the second component;
First, second component mixed be terrace paint.
Embodiment three:
Prepare raw material by following mass fraction: 100 parts of bisphenol-A liquid epoxy resins; 25 parts of BDDEs; 14 parts of doped polyanilines; 2 parts of negative ion antibiotic agent; 0.3 part of 0.8 part of defoamer, 1 part of thickening material, 0.2 part of wetting agent and dispersion agent; 3 parts of Self-leveling mill bases; 4 parts of modification cycloaliphatic amines compounds; 0.4 part of siccative;
Bisphenol-A liquid epoxy resin is added the BDDE mixing and stirring, and it is the first component that middling speed stirs 20min;
Defoamer, thickening material, wetting agent, dispersion agent, doped polyaniline, negative ion antibiotic agent, Self-leveling mill base are mixed, high speed dispersion 30min, form slurry after grinding adds modification cycloaliphatic amines compound and siccative, and stirring is the second component;
First, second component mixed be terrace paint.
Embodiment four:
Prepare raw material by following mass fraction: 100 parts of bisphenol-A liquid epoxy resins; 28 parts of ethylene glycol diglycidylethers; 20 parts of doped polyanilines; 3 parts of ZnOws; 0.2 part of 0.3 part of defoamer, 2 parts of thickening materials, 0.1 part of wetting agent and dispersion agent; 1 part of Self-leveling mill base; 2 parts of modification cycloaliphatic amines compounds; 0.2 part of siccative;
Bisphenol-A liquid epoxy resin is added the ethylene glycol diglycidylether mixing and stirring, and it is the first component that middling speed stirs 20min;
Defoamer, thickening material, wetting agent, dispersion agent, ZnOw, negative ion antibiotic agent, Self-leveling mill base are mixed, high speed dispersion 30min, form slurry after grinding adds modification cycloaliphatic amines compound and siccative, and stirring is the second component;
First, second component mixed be terrace paint.
With the terrace paint of making test plate (panel) processed, detect its performance, test result sees Table 1.
The performance of table 1 Horizon coating
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Surface drying/h | ≤2 | ≤2 | ≤2 | ≤2 |
| Do solid work/h | ≤12 | ≤12 | ≤12 | ≤12 |
| Pencil hardness | 2H | 2H | 2H | 2H |
| Sticking power/level | 0 | 0 | 0 | 0 |
| Wear resistance (750g/500r)/g | 0.012 | 0.014 | 0.013 | 0.015 |
| Shock-resistance/cm | 50 | 50 | 55 | 60 |
| Abrasion resistance/time | 〉10000 | 〉10000 | 〉10000 | 〉10000 |
| Alkali resistance (10%NaOH) | 30d is unchanged | 30d is unchanged | 30d is unchanged | 30d is unchanged |
| Acid resistance (10%HCl) | 20d is unchanged | 20d is unchanged | 20d is unchanged | 20d is unchanged |
| Anti-machine oil | 30d is unchanged | 30d is unchanged | 30d is unchanged | 30d is unchanged |
| Resistivity/Ω | 10 6 | 10 6 | 10 6 | 10 6 |
| Fungi-proofing grade | 1 | 1 | 1 | 1 |
| Sterilizing rate/% | ≥99 | ≥99 | ≥99 | ≥99 |
| 96h PARA FORMALDEHYDE PRILLS(91,95) clearance/% | ≥96 | ≥96 | ≥96 | ≥96 |
Good, lasting from the visible terrace paint antistatic performance of the present invention of test result, not affected by time, temperature, humidity etc.; Coating surface is smooth, attractive in appearance, and is wear-resisting, withstand voltage, shock-resistant, has simultaneously anti-microbial property concurrently, can be widely used in that medicine, instrument, electronics, daily use chemicals etc. need to clean, the occasion of aseptic, anti-electrostatic.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (6)
1. a Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating is characterized in that by massfraction composed of the following components: 100 parts of bisphenol-A liquid epoxy resins; 20～30 parts of reactive thinners; 10～20 parts of conductive filler materials; 1～3 part of antiseptic-germicide; 1～5 part of auxiliary agent; 1～3 part of Self-leveling mill base; 2～5 parts in solidifying agent; 0.2～0.5 part of siccative.
2. Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating according to claim 1, it is characterized in that: described reactive thinner is ethylene glycol diglycidylether, 1, a kind of in 2-propylene glycol diglycidylether or the BDDE.
3. Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating according to claim 1, it is characterized in that: described conductive filler material is doped polyaniline or ZnOw.
4. Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating according to claim 1, it is characterized in that: described auxiliary agent is defoamer, thickening material, wetting agent and dispersion agent.
5. Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating according to claim 1, it is characterized in that: described antiseptic-germicide is the negative ion antibiotic agent.
6. Novel solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating according to claim 1, it is characterized in that: described solidifying agent is modification cycloaliphatic amines compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104800524A CN103073971A (en) | 2012-11-23 | 2012-11-23 | Novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint |
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|---|---|---|---|
| CN2012104800524A CN103073971A (en) | 2012-11-23 | 2012-11-23 | Novel solvent-free antistatic antibiosis epoxy self-leveling terrace paint |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387914A (en) * | 2014-12-09 | 2015-03-04 | 苏州明轩地坪涂料有限公司 | Anti-skid abrasion-resistant floor coating |
| CN104861827A (en) * | 2015-05-07 | 2015-08-26 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling floor coating suitable for low-temperature environment |
| CN111363448A (en) * | 2020-04-17 | 2020-07-03 | 绵阳惠利环氧工程有限公司 | Solvent-free antistatic matte epoxy floor compound |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387914A (en) * | 2014-12-09 | 2015-03-04 | 苏州明轩地坪涂料有限公司 | Anti-skid abrasion-resistant floor coating |
| CN104861827A (en) * | 2015-05-07 | 2015-08-26 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling floor coating suitable for low-temperature environment |
| CN104861827B (en) * | 2015-05-07 | 2017-01-25 | 洛阳双瑞防腐工程技术有限公司 | Solvent-free epoxy self-leveling floor coating suitable for low-temperature environment |
| CN111363448A (en) * | 2020-04-17 | 2020-07-03 | 绵阳惠利环氧工程有限公司 | Solvent-free antistatic matte epoxy floor compound |
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Application publication date: 20130501 |