CN105586773A - Water-repellent anti-UV textile, production method and application thereof - Google Patents
Water-repellent anti-UV textile, production method and application thereof Download PDFInfo
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- CN105586773A CN105586773A CN201410639656.8A CN201410639656A CN105586773A CN 105586773 A CN105586773 A CN 105586773A CN 201410639656 A CN201410639656 A CN 201410639656A CN 105586773 A CN105586773 A CN 105586773A
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Abstract
The invention discloses a water-repellent anti-UV textile, a production method and an application thereof. The textile is a machine-woven fabric which is composed of 100% polyester fibers and is lower than 80 g/m<2> in gram weight. The textile is 5-grade in initial-stage water-repellent property. According to JISL0217103, after being washed in home for 20 times, a test result proves that the textile reaches more than 40 in UV protective coefficient according to AS/NZS4399-1996 standard. The polyester fiber is lower than 50 deniers in fineness. The polyester fiber internally at least contains an UV absorber and a flourescent brightener, the surface of more than 80% of the polyester fibers is coated with resin film. A diffusion promoter increases the entrance amount of the UV absorber and the flourescent brightener into the fibers, so that the textile has excellent anti-UV performance. Anti-UV treatment is carried in a dyeing step in a one-bath manner, so that the production method is free of addition of process steps and further save resources. The textile has an excellent water-repellent effect.
Description
Technical field
The invention belongs to weaving, Material Field, be specifically related to a kind ofly main refuse water ultraviolet ray resistant textiles containing polyster fibre.
Background technology
Along with the maturation of superfine Denier fibre spinning weaving technology, ultrathin chemical fibre textile shared proportion in CRUX clothes is also increasing. Wearing and use due to these type of clothes is out of doors mostly, need to tackle various weather, therefore requires to possess certain uvioresistant function and waterproofing function.
Fine denier polyester textile in ultrathin chemical fibre textile is not only soft, and wrinkle resistance is good, storage property is good, is deeply subject to liking of consumers in general, is widely used in outdoor sports coat. Although the aromatic amino acid in the phenyl ring in polyster fibre and wool protein molecule, the light that wavelength is less than to 300nm all has very strong absorbability, but for fine-denier polyester fiber textile, without the words of uvioresistant processing, to ultraviolet assimilation effect or very poor, ultraviolet protection effect can not play outdoor exercises time, such as the UPF value of the 20D Polyester Textiles that is unstained is only 10. In addition, although the textile of high density designs can play certain protective action to ultraviolet ray, gas permeability is corresponding to be also lowered, and snugness of fit is affected.
In order to give fabric uvioresistant function and waterproofing function simultaneously, people have also carried out a lot of correlative studys. Such as disclosing a kind of method for sorting of nano anti-ultraviolet antibacterial hydrophobic fabrics in Chinese patent literature CN102392346B, specifically by using Nano-Zinc colloidal sol and autogamy long-chain fat family water repellent to process in dressing liquid, although obtained the textile simultaneously with good hydrophobic performance, uvioresistant and anti-microbial property by such processing mode, the washing resistance problem of textile is not resolved.
Summary of the invention
The object of the present invention is to provide a kind of productivity high, refuse all superior textile and production method and purposes of water uvioresistant initial stage and washing resistance.
Textile of the present invention by being formed by 100% polyster fibre, grammes per square metre is 80g/m2Following woven fabric; and the water repellency of this textile is 5 grades of initial stages; this textile is more than 40 according to recording its UV protection coefficient according to AS/NZS4399-1996 standard again after JISL0217103 method home washings 20 times; wherein the fiber number of polyster fibre is that 50 daniers are following, its inner ultra-violet absorber (UV absorbent) and fluorescent whitening agent of at least containing, and more than 80% PET fiber surface is attached with resin molding.
The present invention has the following advantages: (1) spreads promoter by employing increases the amount that UV absorbent and fluorescent whitening agent enter polyster fibre inside, is different from general coating or pads processing, makes grammes per square metre 80g/m2Even if following frivolous terylene class textile is in undyed situation, UV protection coefficient (UPF) also can reach more than 40; According to after JISL0217103 method home washings 20 times, UPF value still can remain on more than 40; (2) 80% above surface attachment in the polyster fibre of formation textile of the present invention has resin molding, and 5 grades of initial stage water repellencies, initial stage soil resistance are 3-4 level. (3) carry out anti UV finishing in the dyeing stage with bathing, do not increase the processing step of production, saved resource. (4) be specially adapted to make outdoor exercises dress ornament.
Detailed description of the invention
Of the present invention refuse water ultraviolet ray resistant textiles by being formed by 100% polyster fibre, grammes per square metre is 80g/m2Following woven fabric; and the water repellency of this textile is 5 grades of initial stages; this textile is more than 40 according to recording its UV protection coefficient according to AS/NZS4399-1996 standard again after JISL0217103 method home washings 20 times; wherein the fiber number of polyster fibre is that 50 daniers are following, its inner ultra-violet absorber and fluorescent whitening agent of at least containing, and more than 80% PET fiber surface is attached with resin molding.
UPF of the present invention (UPF) is according to the method for testing of the Labsphere of cutaneum carcinoma association of U.S. employing. The method of testing of the Labsphere that cutaneum carcinoma association of the U.S. adopts is specially AS/NZS4399-1996(Australian/NewZealandStandard " Sunprotectiveclothing-Evaluationandclassification "), calculate by following formula.
ελ: corresponding erythema nucleus formation parameter under unit wavelength
Eλ: the light splitting radiation illumination (w/m of sunshine2·nm）
Δ λ: unit wavelength (5nm)
Tλ: the transmitance (%) that every 5nm records.
The present invention's UV absorbent used is not particularly limited, and can be that organic can be also mineral-type, is preferably the organic UV absorbent of non-response type, has the structure shown in following formula (I):
Formula (I)
Wherein, R1For-H, C1-6Alkyl ,-OH ,-OCH3、-SCH3Or，
R2For、、、、、、、、、、、、、、、、、、Or，
R3For、、、、、、、、、、、、、、、、、、、、、、、、Or。
O.w.f. when organic UV absorbent uses in the present invention can regulate as required, preferably in the scope of 1～10%o.w.f., more preferably in the scope of 1～5%o.w.f..
Solubility parameter (SP value) and the inorganic Organic (I/O value) of above-mentioned UV absorbent and polyster fibre are close, and affinity is higher, very easily imports again polyster fibre inside; And can absorb 280～360nm ultraviolet ray in a big way, be suitable for the uvioresistant processing of textile. But above-mentioned UV absorbent, because itself is without reactive group, is generally adsorbed on PET fiber surface with unimolecule state, and along with the increase of washing times, the amount of the UV absorbent adsorbing reduces gradually, and washing resistance also decreases. The amount that enters fibrous inside in order to increase UV absorbent improves washing resistance, and the present invention has used the diffusion promoter high with polyster fibre affinity. Spread promoter by use polyster fibre amorphous area is relaxed, make UV absorbent be more prone to enter fibrous inside, improve inlet. The present invention's diffusion used promoter is the one in formic acid, acetic acid, lactic acid, methyl alcohol, ethanol, phenmethylol or Ergol. O.w.f. when diffusion promoter is used can regulate as required, preferably in the scope of 1～10%o.w.f., more preferably in the scope of 1～5%o.w.f..
The present invention's fluorescent whitening agent used is preferably one or more of in Stilbene-based, coumarin type, pyrazoline type, benzo oxygen nitrogen type, BIDA type brightening agent. The application target of fluorescent whitening agent is ultraviolet wave band (315～400nm) to be absorbed, thereby reduce ultraviolet seeing through, raising UV protection coefficient (UPF). O.w.f. when fluorescent whitening agent uses can regulate as required, preferably in the scope of 0.5～1%o.w.f..
The present invention's water repellent used is not particularly limited, and can be fluorine system or non-fluorine system, is preferably carbon 6(C6), carbon 8(C8) etc. fluorine be water repellent, more preferably carbon 6 fluorine are water repellent.
Processing method of refusing water ultraviolet ray resistant textiles of the present invention: first adopt UV absorbent, diffusion promoter, fluorescent whitening agent to arrange in bathing in overflow dyeing machine the woven grey cloth being formed by 100% polyster fibre below 50 daniers, carry out again reduction cleaning, dry, then adopt water repellent to carry out padding finishing, then under the condition of 100～140 degree, be dried 1～3 minute, finally heat treatment 1～2 minute under 160～180 degree conditions, obtaining grammes per square metre is 80g/m2Following product.
In wherein bathing, arrange temperature 90～135 degree, 10～60 minutes time, bath raio 1:5～1:50, can certainly use suitable dyestuff to carry out co-bathing dyeing as required;
60～80 DEG C of the temperature of reduction cleaning, 10～30 minutes time;
Dry employing is hung dry or drying machine is dry;
Working fluid containing water repellent comprises water repellent 30～100g/L, bridging agent 0～30g/L, and bleeding agent 0～10g/L, pads processing (one soaks one rolls), and pick-up rate is 40～80%. Bridging agent is 10～20g/L preferably, and bleeding agent is 5～10g/L preferably.
Bridging agent is not particularly limited, can be isocyanate ester compound, polyurethanes compound, acrylamides, epoxy resin compounds etc. have promote or telomerized polymer strand between one or more of in the material that forms of covalent bond or ionic bond, preferred isocyanate class bridging agent.
Bleeding agent is not particularly limited, can be sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium, SAS, secondary alkyl sulphate sodium, a-sodium olefin sulfonate, Negel, butanedioic acid Arrcostab sodium sulfonate, sulfamic acid sodium, AEO, APES, polyethers, phosphate compounds, and one or more of in alcohols, ketone, ethers etc., preferably alcohols bleeding agent.
The water ultraviolet ray resistant textiles of refusing of the present invention can be used for making outdoor exercises dress ornament etc.
Embodiment
The method of testing of the each index of textile fabric relating in the present invention is as follows.
(1) UV protection coefficient UPF:AS/NZS4399-1996 standard.
(2) home washings standard: JISL02171031999 method.
(3) water repellency standard: JISL10922003 method.
(4) antifouling property standard:
1. antifouling food is got 4 of 10*10cm test specimens (if can get 3 in the little situation of sample cloth);
2. prepare test: 200g loading, plastic plate, surface plate, 1ml dropper, stopwatch, paper extraction, pipe, blotting paper, antifouling food (sesame oil, soy sauce, coffee, tomato ketchup, mayonnaise);
3. sample cloth damping 4 hours above after, respectively antifouling food (sesame oil, soy sauce, coffee, tomato ketchup, mayonnaise) is carried out to easy staining test;
Wherein the taken amount of sesame oil, soy sauce, coffee is 0.1ml, and the taken amount of tomato ketchup, mayonnaise is 0.15m, and coffee coordinates: coffee: companion=1:2.5;
Carry out test operation explanation so that soy sauce food is antifouling as example:
A. getting 0.1ml soy sauce drops in the middle of plastic plate, sample cloth surface is covered downwards on soy sauce, sample cloth is placed after plastic plate again, places 200g loading in the above, timing immediately 1 minute, sample cloth surface upwards, have above smooth paper extraction covers, then with pipe extruding, liquid on sample cloth is blotted, after liquid on sample cloth blots, be laid on blotting paper;
B. after off-test, sample cloth was placed after 24 hours, and sample cloth is carried out to the easily judgement of contamination, when judgement, contrasted and sentenced level with ash card (JISL0805:2005). Then, every kind of antifouling food stays a sample cloth as standard specimen, other sample cloth washs, different antifouling food separately carries out once washing (washing methods: JISL0217103 method), sample cloth after washing is laid on blotting paper, judge every other day (easily decontamination), when judgement, contrast and sentence level with ash card (JISL0805:2005).
Below in conjunction with embodiment and comparative example, the invention will be further described.
In following examples, the structure of related organic UV absorbent is as follows:
UV absorbent A:
；
UV absorbent B:
；
UV absorbent C:
；
UV absorbent D:
；
UV absorbent E:
；
UV absorbent F:
；
UV absorbent G:
；
UV absorbent H:
。
Embodiment 1
Prepare grammes per square metre 68g/m2Unfertile land Woven Polyester Fabrics (being 50D-48f-DTY through weft yarn), dropped in the treatment fluid (bath raio 1:20) being formed by UV absorbent A3%o.w.f., Stilbene-based Fluorescent Brighteners 0.5%o.w.f. and diffusion promoter Ergol acid 3%o.w.f., being warming up to 90 DEG C carries out arranging in bath in 60 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L according to conventional method, 80 DEG C × 20 minutes), within last 130 DEG C × 2 minutes, be dried;
Then adopt water repellent (C6 fluorine system) 50g/L, bridging agent isocyanates 10g/L, bleeding agent isopropyl alcohol 10g/L, carry out soaking one and roll and refuse water processing, 60%, 130 DEG C of pick-up rate is dried 2 minutes, and 170 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 2
Prepare grammes per square metre 30g/m2Unfertile land Woven Polyester Fabrics (being 20D-36f-DTY through weft yarn), dropped into by UV absorbent C5%o.w.f., diffusion promoter styrax acid benzyl ester 2%o.w.f., coumarin type fluorescent whitening agent 0.5%o.w.f. and mixed, bath raio: 1:20; Be warming up to 100 DEG C and carry out arranging in bath in 40 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L, 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (C6 fluorine system) 100g/L, bridging agent polyurethanes 15g/L, bleeding agent AEO 5g/L, carry out soaking one and roll and refuse water processing, 60%, 120 DEG C of pick-up rate is dried 2 minutes, 160 DEG C of thermal finalization 2 minutes, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 3
Prepare grammes per square metre 60g/m2Unfertile land Woven Polyester Fabrics (being 40D-48f-DTY through weft yarn), dropped into by UV absorbent B1%o.w.f., diffusion promoter phenmethylol 2%o.w.f., BIDA type fluorescent whitening agent 1%o.w.f. and mixed, bath raio: 1:30; Be warming up to 110 DEG C and carry out arranging in bath in 30 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L, 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (C8 fluorine system) 30g/L, bridging agent isocyanates 20g/L, bleeding agent isopropyl alcohol 8g/L, carry out soaking one and roll and refuse water processing, 80%, 100 DEG C of pick-up rate is dried 3 minutes, and 180 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 4
Prepare grammes per square metre 60g/m2Unfertile land Woven Polyester Fabrics (being 40D-48f-DTY through weft yarn), dropped into by UV absorbent G5%o.w.f., diffusion promoter lactic acid 4%o.w.f., pyrazoline type fluorescent whitening agent 0.5%o.w.f. and mixed, bath raio: 1:30; Be warming up to 120 DEG C and carry out arranging in bath in 30 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L, 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (C8 fluorine system) 80g/L, bridging agent isocyanates 10g/L, bleeding agent isopropyl alcohol 5g/L, carry out soaking one and roll and refuse water processing, 50%, 130 DEG C of pick-up rate is dried 1 minute, and 170 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 5
Prepare grammes per square metre 70g/m2Unfertile land Woven Polyester Fabrics (being 50D-72f-DTY through weft yarn), dropped into by UV absorbent F3%o.w.f., diffusion promoter formic acid 3%o.w.f., benzo oxygen nitrogen type fluorescent whitening agent 0.5%o.w.f. and mixed, bath raio: 1:30; Be warming up to 135 DEG C and carry out arranging in bath in 10 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L, 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (silicone based) 100g/L, bridging agent isocyanates 15g/L, bleeding agent isopropyl alcohol 10g/L, carry out soaking one and roll and refuse water processing, 40%, 110 DEG C of pick-up rate is dried 2 minutes, 160 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 6
Prepare grammes per square metre 35g/m2Unfertile land Woven Polyester Fabrics (being 30D-32f-DTY through weft yarn), dropped into by UV absorbent E3%o.w.f., diffusion promoter acetic acid 5%o.w.f., coumarin type fluorescent whitening agent 0.5%o.w.f. and mixed, bath raio: 1:25; Be warming up to 125 DEG C and carry out arranging in bath in 30 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L, 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (C6 fluorine system) 100g/L, bridging agent isocyanates 10g/L, bleeding agent isopropyl alcohol 10g/L, carry out soaking one and roll and refuse water processing, 45%, 120 DEG C of pick-up rate is dried 2 minutes, 180 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 7
Prepare grammes per square metre 55g/m2Unfertile land Woven Polyester Fabrics (being 40D-32f-DTY through weft yarn), dropped into by UV absorbent D3%o.w.f., diffusion promoter ethanol 3%o.w.f., pyrazoline type fluorescent whitening agent 0.5%o.w.f. and mixed; bath raio: 1:50 is warming up to 135 DEG C to be carried out arranging in bath in 35 minutes; and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L; 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (C6 fluorine system) 100g/L, bridging agent epoxy resin 20g/L, bleeding agent isopropyl alcohol 10g/L, carry out soaking one and roll and refuse water processing, 55%, 120 DEG C of pick-up rate is dried 2 minutes, 170 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 8
Prepare grammes per square metre 65g/m2Unfertile land Woven Polyester Fabrics (being 50D-48f-DTY through weft yarn), dropped into by UV absorbent A4%o.w.f., diffusion promoter methyl alcohol 1%o.w.f., Stilbene-based Fluorescent Brighteners 0.5%o.w.f. and mixed, bath raio: 1:5; Be warming up to 130 DEG C and carry out arranging in bath in 35 minutes, and then carry out reduction cleaning (30% NaOH solution 2g/L, sodium hydrosulfite 2g/L, 80 DEG C × 20 minutes) according to conventional method, within last 130 DEG C × 2 minutes, be dried.
Then adopt water repellent (C6 fluorine system) 80g/L, bridging agent epoxy resin 15g/L, bleeding agent isopropyl alcohol 10g/L, carry out soaking one and roll and refuse water processing, 70%, 140 DEG C of pick-up rate is dried 1 minute, and 170 DEG C of thermal finalization 1 minute, obtains Polyester Textiles of the present invention. Its properties refers to table 1.
Embodiment 9
Fluorescent whitening agent is selected talan 0.3%o.w.f./cumarin 0.3%o.w.f., and all the other obtain Polyester Textiles of the present invention with embodiment 1. Its properties refers to table 1.
Embodiment 10
Select the mono-benzoic acid resorcinol of UV absorbent H, all the other obtain Polyester Textiles of the present invention with embodiment 1. Its properties refers to table 1.
Comparative example 1
The unfertile land Woven Polyester Fabrics of embodiment 1 is dropped into by UV absorbent A3%o.w.f., in the solution that the acid of diffusion promoter Ergol 3%o.w.f., Stilbene-based Fluorescent Brighteners 0.5%o.w.f., water repellent (C6 fluorine system) 50g/L, bridging agent isocyanates 10g/L, bleeding agent isopropyl alcohol 10g/L mix, carry out soaking one and roll processing, pick-up rate 60%, dry 2 minutes for 130 DEG C, 170 DEG C of thermal finalization 1 minute, obtains Polyester Textiles. Its properties refers to table 1.
Comparative example 2
The unfertile land Woven Polyester Fabrics of embodiment 2 is dropped into by UV absorbent C5%o.w.f., diffusion promoter styrax acid benzyl ester 3%o.w.f., coumarin type fluorescent whitening agent 0.5%o.w.f., water repellent (C6 fluorine system) 100g/L, bridging agent polyurethanes 15g/L, bleeding agent AEO 3g/L, mix, carry out soaking one and roll processing, pick-up rate 60%, dry 2 minutes for 120 DEG C, 160 DEG C of thermal finalization 1 minute, obtains Polyester Textiles. Its properties refers to table 1.
Comparative example 3
Do not adopt diffusion promoter, all the other,, with embodiment 1, obtain Polyester Textiles. Its properties refers to table 1.
Comparative example 4
Do not adopt fluorescent whitening agent, all the other,, with embodiment 1, obtain Polyester Textiles. Its properties refers to table 1.
Table 1
Claims (7)
1. refuse a water ultraviolet ray resistant textiles, it is characterized in that: this textile by being formed by 100% polyster fibre, grammes per square metre is 80g/m2Following woven fabric; and the initial stage water repellency of this textile is 5 grades, this textile is more than 40 according to the UV protection coefficient recording according to AS/NZS4399-1996 standard again after JISL0217103 method home washings 20 times; the fiber number of wherein said polyster fibre is that 50 daniers are following, its inner ultra-violet absorber and fluorescent whitening agent of at least containing, and more than 80% described PET fiber surface is attached with resin molding.
2. the water ultraviolet ray resistant textiles of refusing according to claim 1, is characterized in that: this textile is more than 3 grades according to water repellency, soil resistance after JISL0217103 method home washings 20 times.
3. a production method of refusing water ultraviolet ray resistant textiles as claimed in claim 1, it is characterized in that: first adopt ultra-violet absorber, diffusion promoter, fluorescent whitening agent to arrange in bathing the woven grey cloth being formed by 100% polyster fibre below 50 daniers, carry out again reduction cleaning, dry, then adopt containing the working fluid of water repellent and carry out padding finishing, then under the condition of 100～140 degree, be dried 1～3 minute, finally heat treatment 1～2 minute under 160～180 degree conditions, obtaining grammes per square metre is 80g/m2Following product, arranges temperature 90～135 degree, 10～60 minutes time in wherein bathing.
4. production method of refusing water ultraviolet ray resistant textiles according to claim 3, is characterized in that: described ultra-violet absorber has the structure shown in following formula (I):
Formula (I)
Wherein, R1For-H, C1-6Alkyl ,-OH ,-OCH3、-SCH3Or，
R2For、、、、、、、、、、、、、、、、、、Or，
R3For、、、、、、、、、、、、、、、、、、、、、、、、Or。
5. production method of refusing water ultraviolet ray resistant textiles according to claim 3, is characterized in that: described fluorescent whitening agent is one or more of in Stilbene-based, coumarin type, pyrazoline type, benzo oxygen nitrogen type and BIDA type fluorescent whitening agent.
6. production method of refusing water ultraviolet ray resistant textiles according to claim 3, is characterized in that: described diffusion promoter is formic acid, acetic acid, lactic acid, methyl alcohol, ethanol, styrax acid benzyl ester, phenmethylol or Ergol.
7. refuse by claimed in claim 1 the outdoor exercises dress ornament that water ultraviolet ray resistant textiles makes for one kind.
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| CN106232585A (en) * | 2014-02-20 | 2016-12-14 | 日本烟草产业株式会社 | Triaizine compounds and its medicinal usage |
| CN107254780A (en) * | 2016-11-11 | 2017-10-17 | 成都杰雷遮阳工程有限公司 | It is a kind of to be used for the preparation method of outdoor high-weatherability coated fabric |
| CN107254782A (en) * | 2016-11-11 | 2017-10-17 | 成都杰雷遮阳工程有限公司 | A kind of preparation method of waterproof multi-layer formula cloth for sunshade engineering |
| CN109763327A (en) * | 2017-11-09 | 2019-05-17 | 东丽纤维研究所（中国）有限公司 | A kind of antiultraviolet woven fabric |
| CN111364118A (en) * | 2018-12-26 | 2020-07-03 | 财团法人工业技术研究院 | Composite fiber and fabric |
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2014
- 2014-11-13 CN CN201410639656.8A patent/CN105586773A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106232585A (en) * | 2014-02-20 | 2016-12-14 | 日本烟草产业株式会社 | Triaizine compounds and its medicinal usage |
| CN106232585B (en) * | 2014-02-20 | 2019-04-02 | 日本烟草产业株式会社 | Triaizine compounds and its medicinal usage |
| JP2019065036A (en) * | 2014-02-20 | 2019-04-25 | 日本たばこ産業株式会社 | Triazine compound and pharmaceutical application thereof |
| CN107254780A (en) * | 2016-11-11 | 2017-10-17 | 成都杰雷遮阳工程有限公司 | It is a kind of to be used for the preparation method of outdoor high-weatherability coated fabric |
| CN107254782A (en) * | 2016-11-11 | 2017-10-17 | 成都杰雷遮阳工程有限公司 | A kind of preparation method of waterproof multi-layer formula cloth for sunshade engineering |
| CN109763327A (en) * | 2017-11-09 | 2019-05-17 | 东丽纤维研究所（中国）有限公司 | A kind of antiultraviolet woven fabric |
| CN111364118A (en) * | 2018-12-26 | 2020-07-03 | 财团法人工业技术研究院 | Composite fiber and fabric |
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Application publication date: 20160518 |