CN105586769A - Benzoxazole ultraviolet-resistant finishing agent and preparation method thereof - Google Patents
Benzoxazole ultraviolet-resistant finishing agent and preparation method thereof Download PDFInfo
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- CN105586769A CN105586769A CN201610112646.8A CN201610112646A CN105586769A CN 105586769 A CN105586769 A CN 105586769A CN 201610112646 A CN201610112646 A CN 201610112646A CN 105586769 A CN105586769 A CN 105586769A
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- finishing agent
- benzazoles
- ultraviolet finishing
- ultraviolet
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/392—Nitroso compounds; Nitro compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses a benzoxazole ultraviolet-resistant finishing agent which is prepared from the following components in parts by weight: 12-20 parts of 5-amino benzoxazole, 10-15 parts of 2-nitrobenzothiazole-6-acetic acid, 3-9 parts of 2-butanone, 6-15 parts of tetrabutyl titanate, 2-6 parts of isopropyl mercaptan, 5-9 parts of potassium xylene sulfonate, 3-7 parts of sodium lactate, 8-12 parts of glycerophosphate, 20-25 parts of ethylene glycol and 35-45 parts of deionized water. The clothes treated by the finishing agent have an excellent ultraviolet-resistant effect, the duration time is long, and the requirements of people can be relatively well met.
Description
Technical field
The invention belongs to finishing agent field, be specifically related to a kind of benzazoles anti-ultraviolet finishing agent and preparation method thereof.
Background technology
People usually think to get sun human body are highly profitable, because by ultraviolet direct irradiation skin, decapacitationReaching sterilization, also has adjustment outward and improves nerve, endocrine, digestion, circulation, breathing, blood, immune system and promotion and support one's familyThe function that element D generates. But the generation of a series of disease of skin of recent domestic, allows people recognize gradually, excessive purpleOutside line causes photochemical reaction, can make function of human body that a series of variations occur, especially the skin to human body and immune systemDeng working the mischief. But current some safeguard procedures or apparatus exist preventing ultraviolet effect not obvious, the sustainable time difference etc.Not enough.
Summary of the invention
For the above technical problem existing in prior art, the invention provides a kind of benzazoles anti-ultraviolet finishing agentAnd preparation method thereof, there is good preventing ultraviolet effect through the clothing of finishing agent processing in this, and the continuous and effective time is long.
Technical scheme: a kind of benzazoles anti-ultraviolet finishing agent, comprises the amino benzo of the composition of following parts by weight: 5-Azoles 12-20 part, 2-nitrobenzene thiazole-6-acetic acid 10-15 part, 2-butanone 3-9 part, butyl titanate 6-15 part, isopropyl mercaptan2-6 part, xylene monosulfonic acid potassium 5-9 part, sodium lactate 3-7 part, glycerophosphate 8-12 part, ethylene glycol 20-25 part, deionized water35-45 part.
Preferably, the amino benzothiazole 15-18 of described 5-part, 2-nitrobenzene thiazole-6-acetic acid 12-14 part, 2-butanone 5-8Part, butyl titanate 8-12 part, isopropyl mercaptan 3-5 part, xylene monosulfonic acid potassium 6-8 part, sodium lactate 4-6 part, glycerophosphate 9-11 parts, ethylene glycol 22-25 part, deionized water 40-45 part.
Preferably, 17 parts of the amino benzothiazoles of described 5-, 13 parts of 2-nitrobenzene thiazole-6-acetic acid, 7 parts of 2-butanone, metatitanic acidFour 10 parts of butyl esters, 4 parts of isopropyl mercaptans, 7 parts, xylene monosulfonic acid potassium, 5 parts of sodium lactates, 10 parts of glycerophosphates, 23 parts of ethylene glycol, go42 parts of ionized waters.
A preparation method for benzazoles anti-ultraviolet finishing agent, comprises following steps:
(1) by the amino benzothiazole 12-20 of 5-part, 2-nitrobenzene thiazole-6-acetic acid 10-15 part, 2-butanone 3-9 part, titaniumAcid four butyl ester 6-15 parts and isopropyl mercaptan 2-6 part are mixed, and rising temperature is to 60-80 DEG C, insulation reaction 10-15min;
(2) by xylene monosulfonic acid potassium 5-9 part, sodium lactate 3-7 part, glycerophosphate 8-12 part, ethylene glycol 20-25 part with goIonized water 35-45 part is mixed, and rising temperature is to 80-100 DEG C, and stirring and refluxing 1-2h, is cooled to 20-25 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 60-70 DEG C, leaves standstill reaction2-3h, question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
Preferably, described in step (1), temperature is 70 DEG C, and the time of insulation reaction is 12min.
Preferably, described in step (2), temperature is 90 DEG C, and stirring and refluxing 1.5h is cooled to 25 DEG C.
Preferably, described in step (3), temperature is 65 DEG C, leaves standstill reaction 2.5h.
Beneficial effect: the preparation method of a kind of benzazoles anti-ultraviolet finishing agent of the present invention, with the amino benzo of 5-The materials such as azoles, 2-nitrobenzene thiazole-6-acetic acid and glycerophosphate are raw material, through mix and blend, add hot reflux, leave standstill coolingObtain described benzazoles anti-ultraviolet finishing agent etc. technique; The clothing that utilizes this finishing agent to process has good anti-ultravioletLine effect, and the duration is long.
Detailed description of the invention
Embodiment 1
(1) by 12 parts of amino 5-benzothiazoles, 10 parts of 2-nitrobenzene thiazole-6-acetic acid, 3 parts of 2-butanone, butyl titanate 6Part and 2 parts of mixing of isopropyl mercaptan, rising temperature to 60 DEG C, insulation reaction 10min;
(2) by 35 parts of 5 parts, xylene monosulfonic acid potassium, 3 parts of sodium lactates, 8 parts of glycerophosphates, 20 parts of ethylene glycol and deionized watersMix, rising temperature to 80 DEG C, stirring and refluxing 1h, is cooled to 20 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 60 DEG C, leaves standstill reaction 2h,Question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
Comparative example 1
(1) by 3 parts of 2-butanone, 6 parts of butyl titanates and 2 parts of mixing of isopropyl mercaptan, rising temperature to 60 DEG C, insulation reaction10min；
(2) by 5 parts, xylene monosulfonic acid potassium, 3 parts of sodium lactates, 20 parts of ethylene glycol and 35 parts of mixing of deionized water, rising temperatureTo 80 DEG C, stirring and refluxing 1h, is cooled to 20 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 60 DEG C, leaves standstill reaction 2h,Question response can obtain finishing agent after cooling subsequently.
Embodiment 2
(1) by 20 parts of amino 5-benzothiazoles, 15 parts of 2-nitrobenzene thiazole-6-acetic acid, 9 parts of 2-butanone, butyl titanate15 parts and 6 parts of mixing of isopropyl mercaptan, rising temperature to 80 DEG C, insulation reaction 15min;
(2) by 9 parts, xylene monosulfonic acid potassium, 7 parts of sodium lactates, 12 parts of glycerophosphates, 25 parts of ethylene glycol and deionized water 45Part is mixed, rising temperature to 100 DEG C, and stirring and refluxing 2h, is cooled to 25 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 70 DEG C, leaves standstill reaction 3h,Question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
Comparative example 2
(1) by 9 parts of 2-butanone, 15 parts of butyl titanates and 6 parts of mixing of isopropyl mercaptan, rising temperature to 80 DEG C, insulation is anti-Answer 15min;
(2) by 9 parts, xylene monosulfonic acid potassium, 7 parts of sodium lactates, 25 parts of ethylene glycol and 45 parts of mixing of deionized water, rising temperatureTo 100 DEG C, stirring and refluxing 2h, is cooled to 25 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 70 DEG C, leaves standstill reaction 3h,Question response can obtain finishing agent after cooling subsequently.
Embodiment 3
(1) by 15 parts of amino 5-benzothiazoles, 12 parts of 2-nitrobenzene thiazole-6-acetic acid, 5 parts of 2-butanone, butyl titanate 8Part and 3 parts of mixing of isopropyl mercaptan, rising temperature to 60 DEG C, insulation reaction 10min;
(2) by 40 parts of 6 parts, xylene monosulfonic acid potassium, 4 parts of sodium lactates, 9 parts of glycerophosphates, 22 parts of ethylene glycol and deionized watersMix, rising temperature to 80 DEG C, stirring and refluxing 1h, is cooled to 20 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 60 DEG C, leaves standstill reaction 2h,Question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
Embodiment 4
(1) by 18 parts of amino 5-benzothiazoles, 14 parts of 2-nitrobenzene thiazole-6-acetic acid, 8 parts of 2-butanone, butyl titanate12 parts and 5 parts of mixing of isopropyl mercaptan, rising temperature to 80 DEG C, insulation reaction 15min;
(2) by 8 parts, xylene monosulfonic acid potassium, 6 parts of sodium lactates, 11 parts of glycerophosphates, 25 parts of ethylene glycol and deionized water 45Part is mixed, rising temperature to 100 DEG C, and stirring and refluxing 2h, is cooled to 25 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 70 DEG C, leaves standstill reaction 3h,Question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
Embodiment 5
(1) by 17 parts of amino 5-benzothiazoles, 13 parts of 2-nitrobenzene thiazole-6-acetic acid, 7 parts of 2-butanone, butyl titanate10 parts and 4 parts of mixing of isopropyl mercaptan, rising temperature to 70 DEG C, insulation reaction 12min;
(2) by 7 parts, xylene monosulfonic acid potassium, 5 parts of sodium lactates, 10 parts of glycerophosphates, 23 parts of ethylene glycol and deionized water 42Part is mixed, rising temperature to 90 DEG C, and stirring and refluxing 1.5h, is cooled to 25 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 65 DEG C, leaves standstill reaction2.5h, question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
The finishing agent of each embodiment and comparative example gained is applied in clothing, investigates its ultraviolet resistance, resultAs follows:
| Experiment | Do not clean UPF | UPF after cleaning 30 times |
| Embodiment 1 | 35 | 32 |
| Comparative example 1 | 2 | 0 |
| Embodiment 2 | 40 | 38 |
| Comparative example 2 | 5 | 0 |
| Embodiment 3 | 45 | 43 |
| Embodiment 4 | 50 | 48 |
| Embodiment 5 | 55 | 52 |
Claims (7)
1. a benzazoles anti-ultraviolet finishing agent, is characterized in that, comprises the amino benzo of the composition of following parts by weight: 5-Azoles 12-20 part, 2-nitrobenzene thiazole-6-acetic acid 10-15 part, 2-butanone 3-9 part, butyl titanate 6-15 part, isopropyl mercaptan2-6 part, xylene monosulfonic acid potassium 5-9 part, sodium lactate 3-7 part, glycerophosphate 8-12 part, ethylene glycol 20-25 part, deionized water35-45 part.
2. a kind of benzazoles anti-ultraviolet finishing agent according to claim 1, is characterized in that, the amino benzo of described 5-Azoles 15-18 part, 2-nitrobenzene thiazole-6-acetic acid 12-14 part, 2-butanone 5-8 part, butyl titanate 8-12 part, isopropyl mercaptan3-5 part, xylene monosulfonic acid potassium 6-8 part, sodium lactate 4-6 part, glycerophosphate 9-11 part, ethylene glycol 22-25 part, deionized water40-45 part.
3. a kind of benzazoles anti-ultraviolet finishing agent according to claim 2, is characterized in that, the amino benzo of described 5-17 parts of azoles, 13 parts of 2-nitrobenzene thiazole-6-acetic acid, 7 parts of 2-butanone, 10 parts of butyl titanates, 4 parts of isopropyl mercaptans, dimethylbenzene7 parts of potassium sulfonates, 5 parts of sodium lactates, 10 parts of glycerophosphates, 23 parts of ethylene glycol, 42 parts of deionized waters.
4. a preparation method for benzazoles anti-ultraviolet finishing agent, is characterized in that, comprises following steps:
(1) by the amino benzothiazole 12-20 of 5-part, 2-nitrobenzene thiazole-6-acetic acid 10-15 part, 2-butanone 3-9 part, metatitanic acid fourButyl ester 6-15 part and isopropyl mercaptan 2-6 part are mixed, and rising temperature is to 60-80 DEG C, insulation reaction 10-15min;
(2) by xylene monosulfonic acid potassium 5-9 part, sodium lactate 3-7 part, glycerophosphate 8-12 part, ethylene glycol 20-25 part and deionizationWater 35-45 part is mixed, and rising temperature is to 80-100 DEG C, and stirring and refluxing 1-2h, is cooled to 20-25 DEG C subsequently;
(3) mixed liquor step (1) being obtained dropwise adds in step (2), and temperature is risen to 60-70 DEG C, leaves standstill reaction 2-3h,Question response can obtain described benzazoles anti-ultraviolet finishing agent after cooling subsequently.
5. the preparation method of a kind of benzazoles anti-ultraviolet finishing agent according to claim 4, is characterized in that, step(1) temperature described in is 70 DEG C, and the time of insulation reaction is 12min.
6. the preparation method of a kind of benzazoles anti-ultraviolet finishing agent according to claim 4, is characterized in that, step(2) temperature described in is 90 DEG C, and stirring and refluxing 1.5h is cooled to 25 DEG C.
7. the preparation method of a kind of benzazoles anti-ultraviolet finishing agent according to claim 4, is characterized in that, step(3) temperature described in is 65 DEG C, leaves standstill reaction 2.5h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610112646.8A CN105586769A (en) | 2016-02-29 | 2016-02-29 | Benzoxazole ultraviolet-resistant finishing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610112646.8A CN105586769A (en) | 2016-02-29 | 2016-02-29 | Benzoxazole ultraviolet-resistant finishing agent and preparation method thereof |
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| CN105586769A true CN105586769A (en) | 2016-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610112646.8A Pending CN105586769A (en) | 2016-02-29 | 2016-02-29 | Benzoxazole ultraviolet-resistant finishing agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107740269A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of uvioresistant finishing agent of bafta and preparation method thereof |
Citations (4)
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| JP2008518988A (en) * | 2004-11-02 | 2008-06-05 | ディーエスエム アイピー アセッツ ビー．ブイ． | Additives for UV-sunscreen preparations |
| CN202064215U (en) * | 2010-11-30 | 2011-12-07 | 吴江市凌志纺织有限公司 | Ultraviolet protection whitening plus material |
| CN102471605A (en) * | 2009-08-04 | 2012-05-23 | 莱雅公司 | Composite pigment and method for preparation thereof |
| CN104894855A (en) * | 2015-06-15 | 2015-09-09 | 湖州厉华妤婕联合纺织有限公司 | Novel ultraviolet-proof finishing agent for textile |
-
2016
- 2016-02-29 CN CN201610112646.8A patent/CN105586769A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008518988A (en) * | 2004-11-02 | 2008-06-05 | ディーエスエム アイピー アセッツ ビー．ブイ． | Additives for UV-sunscreen preparations |
| CN102471605A (en) * | 2009-08-04 | 2012-05-23 | 莱雅公司 | Composite pigment and method for preparation thereof |
| CN202064215U (en) * | 2010-11-30 | 2011-12-07 | 吴江市凌志纺织有限公司 | Ultraviolet protection whitening plus material |
| CN104894855A (en) * | 2015-06-15 | 2015-09-09 | 湖州厉华妤婕联合纺织有限公司 | Novel ultraviolet-proof finishing agent for textile |
Non-Patent Citations (1)
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| 徐宝财等: "《洗涤剂配方工艺手册》", 31 January 2006, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107740269A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of uvioresistant finishing agent of bafta and preparation method thereof |
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Application publication date: 20160518 |