CN105568736A - Manufacture process of brown paper - Google Patents

Manufacture process of brown paper Download PDF

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Publication number
CN105568736A
CN105568736A CN201510952750.3A CN201510952750A CN105568736A CN 105568736 A CN105568736 A CN 105568736A CN 201510952750 A CN201510952750 A CN 201510952750A CN 105568736 A CN105568736 A CN 105568736A
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Prior art keywords
beating
brown paper
production technology
weight
paper
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CN105568736B (en
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邓绍敏
陈体勇
古胜军
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Zhou Qingfen
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Beihai Guangli Color Printing Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/22Other features of pulping processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21DTREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00Methods of beating or refining; Beaters of the Hollander type
    • D21D1/02Methods of beating; Beaters of the Hollander type

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Abstract

The invention discloses a manufacture process of brown paper. According to the manufacture process, logs are taken as raw material, and body paper is obtained by digesting, blanching, screening, beating, sizing, deslagging, forming on a net, squeezing, drying, rolling and calendering. Beating of the logs is performed by respectively beating and mixing oak, birch, cedar, camphor tree, masson pine, sago cycas and bagasse in an absolute dry weight ratio of (20-40):(10-20):(20-40):(10-20):(40-60):(10-20):25 to obtain a mixed pulp. According to the invention, the types, ratio and beating degree of fibers of pulp of the body paper can be regulated, the surface of the body paper is coated with a film, and the fiber strength can be enhanced by changing technological parameters in each step, thereby obtaining better bursting resistance, water proofness and printing performance.

Description

The production technology of brown paper
Technical field
The present invention relates to pulping and paper-making field.More particularly, the present invention relates to a kind of production technology of brown paper.
Background technology
Exquisite kraft paper is the renewal product of conventional kraft paper, is widely used in the fields such as film packaging, medical package, file pouch, envelope, melon seed bag, hand carrying bag.With the Exquisite kraft paper that micro-drift sulfate wood pulp is produced for raw material, because color and luster is more shallow, smoothness and intensity better, packaging and the print request of packing material can be adapted to, a kind of packaging industry raw material be popular, in very large range instead of common natural kraft, the market demand is in the gesture of growth fast.For this reason, we successfully develop this product in recent years, and product quality has reached domestically leading level, meet the demand in market.But the fibrous raw material that current brown paper production technology uses is more single, burst index, tear index are lower, easily produces and tear phenomenon.In addition, uncoated brown paper, rough surface, quality are loose, smalls soaks by force, easily.
Summary of the invention
An object of the present invention is to solve at least the problems referred to above, and the advantage will illustrated at least is below provided.
A further object of the invention is to provide a kind of production technology of brown paper, it can adjust the kind of raw paper pulp fiber, ratio and beating degree, at body paper surface coating, and by changing the technological parameter of each step, to improve fibre strength, obtain better pop strength, water resistance, printing performance.
In order to realize, according to these objects of the present invention and other advantage, providing a kind of production technology of brown paper, comprising: employing log is raw material, through boiling, bleaching, screening, making beating, applying glue, slagging-off, upper net forming, squeezing, dry, batch and namely obtain body paper with press polish, the making beating of described log is than the Oak Tree being 20 ~ 40:10 ~ 20:20 ~ 40:10 ~ 20:40 ~ 60:10 ~ 20:25 by absolute dry mass, birch, Chinese fir, fragrant camphor tree, masson pine, sago cycas and bagasse are respectively through mixing after making beating process, and the mixing obtained is starched, and the beating consistency of Oak Tree is 3%, beating degree is 28 ° of SR, weight in wet base is 12g, the beating consistency 3% of birch, beating degree is 30 ° of SR, weight in wet base is 14g, and the beating consistency of Chinese fir is 3%, beating degree is 29 ° of SR, weight in wet base is 12g, and the beating consistency of fragrant camphor tree is 3%, beating degree is 32 ° of SR, weight in wet base is 15g, and the beating consistency of masson pine is 3%, beating degree is 29 ° of SR, weight in wet base is 13g, and the beating consistency of sago cycas is 3%, beating degree is 28 ° of SR, weight in wet base is 14g, and the beating consistency of bagasse is 3%, beating degree is 32 ° of SR, weight in wet base is 15g.
Preferably, the production technology of described brown paper, also comprise: at described body paper surface coating coatings, the compound of the methyl silicate of described coating to be mass ratio be 4 ~ 6:2 ~ 3:1 ~ 1.5:0.2, trim,ethylchlorosilane, methyl alcohol and agar, wherein, the absolute dry mass ratio of body paper and coating is 75 ~ 80:20.
Preferably, the production technology of described brown paper, described brown paper before applying coating through resin-dipping hot-pressing processing.
Preferably, the production technology of described brown paper, described resin is cyanurotriamide modified diallyl phthalate, azodiisobutyronitrile is initator, ethanol is solvent, and heat of immersion compression technology is: hot pressing temperature 120 DEG C, pressure 0.2MPa, time 25min.
Preferably, the production technology of described brown paper, the temperature of boiling step is 135 DEG C.
Preferably, the production technology of described brown paper, blanching step comprises successively by three bleaching processes of dense oxonium base delignification, hydrogen peroxide, hydroquinones, the slurry concentration of dense oxonium base delignification process is 6%, temperature is 65 DEG C, oxygen pressure is 250KPa, the slurry concentration of Alkali Hydrogen Peroxide System is 6%, bleaching pH value is 10, the slurry concentration of hydroquinones bleaching process is 3%, and wherein solvent is the magnetized drinking water soaking 3h through cocoanut shell.
Preferably, the production technology of described brown paper will be also the dilute hydrochloric acid solution rinsing of 10% by mass fraction at 40 DEG C after blanching step.
Preferably, the production technology of described brown paper, squeezing step adopts the unipress of four roller three nips and malleation squeezing, and the linear pressure in each district is: a nip 5.5MPa, two nip 6.5MPa, three nip 5MPa, four nip 6MPa.
Preferably, the production technology of described brown paper, calendaring step adopts soft calender.
The present invention at least comprises following beneficial effect:
The first, the preferred Oak Tree of the present invention, birch, Chinese fir, fragrant camphor tree, masson pine, sago cycas and bagasse are as pulp fiber source, improve the more single softwood pulp production difficult problem caused of raw material ratio, effective utilization processing remaining sides plate, save cost, controlled beating consistency, beating degree and weight in wet base technological parameter, keep fibre length, balance high-air-permeability, low tightness and flatness, strengthen the combination between pulp fiber, improve physical strength and formation of sheet, significantly improve outward appearance;
The second, at body paper surface coating coatings, to increase water resistance and printing performance, coating selects the compound of methyl silicate, trim,ethylchlorosilane, methyl alcohol, agar, agar makes surface construction special construction, the static contact angle of coating and water is made to reach 110 °, easy gel, hydrophobic effect is best; Adopt cyanurotriamide modified diallyl phthalate resin surface impregnation, under this hot pressing temperature, pressure, time, WATER RESISTANCE and grease resistance significantly improve, for applying coating improves good basis;
Three, boiling temperature to 135 DEG C is reduced, make different fibrous raw material evenly steaming mixed, Kappa number amplitude of variation is little, and improving the yellow value of slurry for adopting hydrogen peroxide bleaching afterwards provides basis, decrease the impurity such as bark, crude fibre, reduce the dust material in paper and coarse fiber bundle; Blanching step adopts dense oxonium base delignification, hydrogen peroxide, hydroquinones successively, control hydroquinones bleaching according to the Kappa number of slurry now, make slurry form and aspect stablize, reach quality requirement, the magnetized drinking water that cocoanut shell soaked, avoid slurry form and aspect to fluctuate, improve into paper form and aspect stability; Remaining calcium salt base is dissolved in watery hydrochloric acid rinsing, avoids forming rosin acid calcium Chen Ding with free rosin acid anion in the process of visual angle, avoids scale deposition on equipment; The unipress of four roller three nips and malleation squeezing, while making the gas permeability of paper and tightness increase growth fast with squeeze pressure, balances the physical strength of paper; Soft calender improves the smoothness of paper, is convenient to applying coating.
Part is embodied by explanation below by other advantage of the present invention, target and feature, part also will by research and practice of the present invention by those skilled in the art is understood.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, can implement according to this with reference to description word to make those skilled in the art.
Should be appreciated that used hereinly such as " to have ", other element one or more do not allotted in " comprising " and " comprising " term or the existence of its combination or interpolation.
It should be noted that experimental technique described in following embodiment if no special instructions, is conventional method, described reagent and material, if no special instructions, all can obtain from commercial channels.
< embodiment 1>
A production technology for brown paper, comprising: employing log is raw material, through boiling, bleaching, screening, making beating, applying glue, slagging-off, upper net forming, squeezing, dry, batch and namely obtain body paper with press polish, the making beating of described log is than the Oak Tree being 20:10:20:10:40:10:25 by absolute dry mass, birch, Chinese fir, fragrant camphor tree, masson pine, sago cycas and bagasse are respectively through mixing after making beating process, and the mixing obtained is starched, and the beating consistency of Oak Tree is 3%, beating degree is 28 ° of SR, weight in wet base is 12g, the beating consistency 3% of birch, beating degree is 30 ° of SR, weight in wet base is 14g, and the beating consistency of Chinese fir is 3%, beating degree is 29 ° of SR, weight in wet base is 12g, and the beating consistency of fragrant camphor tree is 3%, beating degree is 32 ° of SR, weight in wet base is 15g, and the beating consistency of masson pine is 3%, beating degree is 29 ° of SR, weight in wet base is 13g, and the beating consistency of sago cycas is 3%, beating degree is 28 ° of SR, weight in wet base is 14g, and the beating consistency of bagasse is 3%, beating degree is 32 ° of SR, weight in wet base is 15g.
Wherein, the production technology of described brown paper, also comprises: at described body paper surface coating coatings, the compound of the methyl silicate of described coating to be mass ratio be 4:2:1:0.2, trim,ethylchlorosilane, methyl alcohol and agar, wherein, the absolute dry mass of body paper and coating is than being 75:20.
Wherein, the production technology of described brown paper, described brown paper before applying coating through resin-dipping hot-pressing processing.
Wherein, the production technology of described brown paper, described resin is cyanurotriamide modified diallyl phthalate, azodiisobutyronitrile is initator, ethanol is solvent, and heat of immersion compression technology is: hot pressing temperature 120 DEG C, pressure 0.2MPa, time 25min.
Wherein, the production technology of described brown paper, the temperature of boiling step is 135 DEG C.
Wherein, the production technology of described brown paper, blanching step comprises successively by three bleaching processes of dense oxonium base delignification, hydrogen peroxide, hydroquinones, the slurry concentration of dense oxonium base delignification process is 6%, temperature is 65 DEG C, oxygen pressure is 250KPa, the slurry concentration of Alkali Hydrogen Peroxide System is 6%, bleaching pH value is 10, the slurry concentration of hydroquinones bleaching process is 3%, and wherein solvent is the magnetized drinking water soaking 3h through cocoanut shell.
Wherein, the production technology of described brown paper will be also the dilute hydrochloric acid solution rinsing of 10% by mass fraction at 40 DEG C after blanching step.
Wherein, the production technology of described brown paper, squeezing step adopts the unipress of four roller three nips and malleation squeezing, and the linear pressure in each district is: a nip 5.5MPa, two nip 6.5MPa, three nip 5MPa, four nip 6MPa.
Wherein, the production technology of described brown paper, calendaring step adopts soft calender.
After testing, the brown paper print gloss that embodiment 1 is produced is high, lead content (in Pb) 0.33mg/kg, arsenic content (in As) < 0.2mg/kg, fluorescent substance 254nm and 365nm and Decolorant Test (water, n-hexane) are feminine gender, every 100g large intestine bacterium colony < 30, does not detect pathogenic bacteria.
< embodiment 2>
A production technology for brown paper, comprising: employing log is raw material, through boiling, bleaching, screening, making beating, applying glue, slagging-off, upper net forming, squeezing, dry, batch and namely obtain body paper with press polish, the making beating of described log is than the Oak Tree being 40:20:40:20:60:20:25 by absolute dry mass, birch, Chinese fir, fragrant camphor tree, masson pine, sago cycas and bagasse are respectively through mixing after making beating process, and the mixing obtained is starched, and the beating consistency of Oak Tree is 3%, beating degree is 28 ° of SR, weight in wet base is 12g, the beating consistency 3% of birch, beating degree is 30 ° of SR, weight in wet base is 14g, and the beating consistency of Chinese fir is 3%, beating degree is 29 ° of SR, weight in wet base is 12g, and the beating consistency of fragrant camphor tree is 3%, beating degree is 32 ° of SR, weight in wet base is 15g, and the beating consistency of masson pine is 3%, beating degree is 29 ° of SR, weight in wet base is 13g, and the beating consistency of sago cycas is 3%, beating degree is 28 ° of SR, weight in wet base is 14g, and the beating consistency of bagasse is 3%, beating degree is 32 ° of SR, weight in wet base is 15g.
Wherein, the production technology of described brown paper, also comprises: at described body paper surface coating coatings, the compound of the methyl silicate of described coating to be mass ratio be 6:3:1.5:0.2, trim,ethylchlorosilane, methyl alcohol and agar, wherein, the absolute dry mass of body paper and coating is than being 80:20.
Wherein, the production technology of described brown paper, described brown paper before applying coating through resin-dipping hot-pressing processing.
Wherein, the production technology of described brown paper, described resin is cyanurotriamide modified diallyl phthalate, azodiisobutyronitrile is initator, ethanol is solvent, and heat of immersion compression technology is: hot pressing temperature 120 DEG C, pressure 0.2MPa, time 25min.
Wherein, the production technology of described brown paper, the temperature of boiling step is 135 DEG C.
Wherein, the production technology of described brown paper, blanching step comprises successively by three bleaching processes of dense oxonium base delignification, hydrogen peroxide, hydroquinones, the slurry concentration of dense oxonium base delignification process is 6%, temperature is 65 DEG C, oxygen pressure is 250KPa, the slurry concentration of Alkali Hydrogen Peroxide System is 6%, bleaching pH value is 10, the slurry concentration of hydroquinones bleaching process is 3%, and wherein solvent is the magnetized drinking water soaking 3h through cocoanut shell.
Wherein, the production technology of described brown paper will be also the dilute hydrochloric acid solution rinsing of 10% by mass fraction at 40 DEG C after blanching step.
Wherein, the production technology of described brown paper, squeezing step adopts the unipress of four roller three nips and malleation squeezing, and the linear pressure in each district is: a nip 5.5MPa, two nip 6.5MPa, three nip 5MPa, four nip 6MPa.
Wherein, the production technology of described brown paper, calendaring step adopts soft calender.
After testing, the brown paper print gloss that embodiment 2 is produced is high, lead content (in Pb) 0.31mg/kg, arsenic content (in As) < 0.2mg/kg, fluorescent substance 254nm and 365nm and Decolorant Test (water, n-hexane) are feminine gender, every 100g large intestine bacterium colony < 30, does not detect pathogenic bacteria.
< embodiment 3>
A production technology for brown paper, comprising: employing log is raw material, through boiling, bleaching, screening, making beating, applying glue, slagging-off, upper net forming, squeezing, dry, batch and namely obtain body paper with press polish, the making beating of described log is than the Oak Tree being 30:15:30:15:50:15:25 by absolute dry mass, birch, Chinese fir, fragrant camphor tree, masson pine, sago cycas and bagasse are respectively through mixing after making beating process, and the mixing obtained is starched, and the beating consistency of Oak Tree is 3%, beating degree is 28 ° of SR, weight in wet base is 12g, the beating consistency 3% of birch, beating degree is 30 ° of SR, weight in wet base is 14g, and the beating consistency of Chinese fir is 3%, beating degree is 29 ° of SR, weight in wet base is 12g, and the beating consistency of fragrant camphor tree is 3%, beating degree is 32 ° of SR, weight in wet base is 15g, and the beating consistency of masson pine is 3%, beating degree is 29 ° of SR, weight in wet base is 13g, and the beating consistency of sago cycas is 3%, beating degree is 28 ° of SR, weight in wet base is 14g, and the beating consistency of bagasse is 3%, beating degree is 32 ° of SR, weight in wet base is 15g.
Wherein, the production technology of described brown paper, also comprises: at described body paper surface coating coatings, the compound of the methyl silicate of described coating to be mass ratio be 5:2.5:1:0.2, trim,ethylchlorosilane, methyl alcohol and agar, wherein, the absolute dry mass of body paper and coating is than being 78:20.
Wherein, the production technology of described brown paper, described brown paper before applying coating through resin-dipping hot-pressing processing.
Wherein, the production technology of described brown paper, described resin is cyanurotriamide modified diallyl phthalate, azodiisobutyronitrile is initator, ethanol is solvent, and heat of immersion compression technology is: hot pressing temperature 120 DEG C, pressure 0.2MPa, time 25min.
Wherein, the production technology of described brown paper, the temperature of boiling step is 135 DEG C.
Wherein, the production technology of described brown paper, blanching step comprises successively by three bleaching processes of dense oxonium base delignification, hydrogen peroxide, hydroquinones, the slurry concentration of dense oxonium base delignification process is 6%, temperature is 65 DEG C, oxygen pressure is 250KPa, the slurry concentration of Alkali Hydrogen Peroxide System is 6%, bleaching pH value is 10, the slurry concentration of hydroquinones bleaching process is 3%, and wherein solvent is the magnetized drinking water soaking 3h through cocoanut shell.
Wherein, the production technology of described brown paper will be also the dilute hydrochloric acid solution rinsing of 10% by mass fraction at 40 DEG C after blanching step.
Wherein, the production technology of described brown paper, squeezing step adopts the unipress of four roller three nips and malleation squeezing, and the linear pressure in each district is: a nip 5.5MPa, two nip 6.5MPa, three nip 5MPa, four nip 6MPa.
Wherein, the production technology of described brown paper, calendaring step adopts soft calender.
After testing, the brown paper print gloss that embodiment 3 is produced is high, lead content (in Pb) 0.3mg/kg, arsenic content (in As) < 0.2mg/kg, fluorescent substance 254nm and 365nm and Decolorant Test (water, n-hexane) are feminine gender, every 100g large intestine bacterium colony < 30, does not detect pathogenic bacteria.
Carry out indices detection to the brown paper that embodiment 1 ~ 3 is produced, testing result is as shown in table 1.
Table 1
Index name and unit Embodiment 1 Embodiment 2 Embodiment 3 Quality index
Quantitatively/(gm -2) 80 80 80 (40-120)±5%
Burst index/(kPam -2·g -1) 3.45 3.66 3.75 ≥3
Tear index (longitudinal direction)/(mNm -2·g -1) 9.2 9.4 10.4 ≥8.5
Whiteness/% 23 24 24 22~26
Smoothness (front)/% 17.5 16.7 18.5 ≥8
Delivery moisture/% 8.4 7.9 8.9 9±2
Water absorbent surface/(gm -2) 22 24 20 ≤40
Here the number of devices illustrated and treatment scale are used to simplify explanation of the present invention.The application of the production technology of brown paper of the present invention, modifications and variations be will be readily apparent to persons skilled in the art.
Although embodiment of the present invention are open as above, but it is not restricted to listed in description and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the embodiment described.

Claims (9)

1. a production technology for brown paper, comprising: employing log is raw material, through boiling, bleaching, screening, making beating, applying glue, slagging-off, upper net forming, squeezing, dry, batch and namely obtain body paper with press polish, it is characterized in that, the making beating of described log is than the Oak Tree being 20 ~ 40:10 ~ 20:20 ~ 40:10 ~ 20:40 ~ 60:10 ~ 20:25 by absolute dry mass, birch, Chinese fir, fragrant camphor tree, masson pine, sago cycas and bagasse are respectively through mixing after making beating process, and the mixing obtained is starched, and the beating consistency of Oak Tree is 3%, beating degree is 28 ° of SR, weight in wet base is 12g, the beating consistency 3% of birch, beating degree is 30 ° of SR, weight in wet base is 14g, and the beating consistency of Chinese fir is 3%, beating degree is 29 ° of SR, weight in wet base is 12g, and the beating consistency of fragrant camphor tree is 3%, beating degree is 32 ° of SR, weight in wet base is 15g, and the beating consistency of masson pine is 3%, beating degree is 29 ° of SR, weight in wet base is 13g, and the beating consistency of sago cycas is 3%, beating degree is 28 ° of SR, weight in wet base is 14g, and the beating consistency of bagasse is 3%, beating degree is 32 ° of SR, weight in wet base is 15g.
2. the production technology of brown paper as claimed in claim 1, it is characterized in that, also comprise: at described body paper surface coating coatings, the compound of the methyl silicate of described coating to be mass ratio be 4 ~ 6:2 ~ 3:1 ~ 1.5:0.2, trim,ethylchlorosilane, methyl alcohol and agar, wherein, the absolute dry mass ratio of body paper and coating is 75 ~ 80:20.
3. the production technology of brown paper as claimed in claim 2, is characterized in that, described brown paper before applying coating through resin-dipping hot-pressing processing.
4. the production technology of brown paper as claimed in claim 3, it is characterized in that, described resin is cyanurotriamide modified diallyl phthalate, azodiisobutyronitrile is initator, ethanol is solvent, and heat of immersion compression technology is: hot pressing temperature 120 DEG C, pressure 0.2MPa, time 25min.
5. the production technology of brown paper as claimed in claim 1, it is characterized in that, the temperature of boiling step is 135 DEG C.
6. the production technology of brown paper as claimed in claim 1, it is characterized in that, blanching step comprises successively by three bleaching processes of dense oxonium base delignification, hydrogen peroxide, hydroquinones, the slurry concentration of dense oxonium base delignification process is 6%, temperature is 65 DEG C, oxygen pressure is 250KPa, the slurry concentration of Alkali Hydrogen Peroxide System is 6%, bleaching pH value is 10, the slurry concentration of hydroquinones bleaching process is 3%, and wherein solvent is the magnetized drinking water soaking 3h through cocoanut shell.
7. the production technology of brown paper as claimed in claim 6, is characterized in that, will be also the dilute hydrochloric acid solution rinsing of 10% by mass fraction at 40 DEG C after blanching step.
8. the production technology of brown paper as claimed in claim 1, is characterized in that, squeezing step adopts the unipress of four roller three nips and malleation squeezing, and the linear pressure in each district is: a nip 5.5MPa, two nip 6.5MPa, three nip 5MPa, four nip 6MPa.
9. the production technology of brown paper as claimed in claim 1, is characterized in that, calendaring step adopts soft calender.
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CN108086046A (en) * 2017-12-12 2018-05-29 义乌市义南纸业有限公司 A kind of high-effective water-proof brown paper and preparation method thereof
CN112431060A (en) * 2020-11-13 2021-03-02 福建省青山纸业股份有限公司 Production method of environment-friendly craft paper
CN113062146A (en) * 2021-04-19 2021-07-02 岳阳林纸股份有限公司 Antibacterial cultural paper and manufacturing method thereof

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CN108086046A (en) * 2017-12-12 2018-05-29 义乌市义南纸业有限公司 A kind of high-effective water-proof brown paper and preparation method thereof
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CN113062146A (en) * 2021-04-19 2021-07-02 岳阳林纸股份有限公司 Antibacterial cultural paper and manufacturing method thereof

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