Summary of the invention
The object of this invention is to provide a kind of micro-retractility printed form decorating base paper, in printing and dipping process, cross directional variations is less, does not longitudinally change, and can realize accurate overprinting, synchronous pressing plate; Invention also provides the preparation method of micro-retractility printed form decorating base paper, scientific and reasonable, simple.
Micro-retractility printed form decorating base paper of the present invention, comprises the raw material of following weight percents:
Described bleached cotton starch, bleached softwood slurry, bleaching broad-leaved slurry and wet strength agent are with over dry gauge.
Described bleached softwood slurry is bleached sulphate softwood pulp.
Described bleaching broad-leaved slurry is bleached sulphate yearning between lovers wood pulp.
Described wet strength agent composition is PAE, and usual concentration has 12.5% and 25% two kind.
Described mineral filler is one or more in titanium dioxide, kaolin, talcum powder, bentonite or diatomite.
The preparation method of micro-retractility printed form decorating base paper of the present invention, step is as follows:
(1) bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry to be added respectively in the pulper that 35-45 DEG C of pulping water is housed fully size degradation, beating degree is controlled to respectively 20-24,21-24,25-28 ° of SR, mass concentration and pump into after mill for subsequent use in stock tank after reaching 3.5-4.5%;
(2) mineral filler being diluted to mass concentration is 65-72%, carries adding again fill out in pond with high speed agitator after stirring;
(3) stock tank slurries after mill are pumped into add fill out pond, regulate the pH value adding and fill out slurries in pond to 6.5-7.2, after stirring, add wet strength agent again;
(4) then above-mentioned modulated slurry is diluted again, screen out foreign material after interweave through uniform and dehydration, drying, press polish, coil paper, cut, pack, and to get final product again.
Intertexture described in step (4) adopts multi cylinder line mesh production technology, is equipped with humidifier and soft press-polishing machine in process of production.
Multi cylinder line mesh paper machine can regulate and control slurry network speed ratio, and fourdrinier wire fully dewaters, multi-cylinder ensures fully dry; Humidifier can ensure into the moisture of paper; Soft press-polishing machine can ensure the fine and smooth degree on paper industry surface.Wherein main control parameters: one, starch network speed than 1:1, fiber aspect to arrangement evenly, is mutually wound around, decreases the cross-direction shrinkage in body paper dry run; Two, the stoving process of multi-cylinder, guarantees slow drying, reduces the shrinkage factor in body paper dry run; High temperature cylinder temperature control 120-150 degree, the moisture after oven dry is≤2%, the abundant keratinization of body paper, reduces body paper water suction and moistens the ratio risen; Three, after humidifier effect, body paper moisture reaches 5-7%, and the object of this technique had both improve the ornamenting of soft press-polishing machine to decorating base paper surface, reduces again and the gap of printing rear body paper moisture, reduces the lateral expansion rate of body paper.
The raw material of micro-retractility printed form decorating base paper of the present invention comprises: bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry mixed slurry are main material; Account for the mineral filler of main material quality 20-45%; The quantitative of this decorating base paper is 55-90g/m
2, ash content is 20-45%, and wet strength is 5-9N, and dry strength is 20-50N, and water imbibition is 20-40mm/10min, and air permeability is 10-30s/100ml, horizontal hygroexpansivity≤1.6%, moisture 5-7%, the decorating base paper of seepage velocity≤5s.
It is 5:3:2 that described bleached cotton starch, bleached softwood slurry and bleaching broad-leaved starch preferred mass ratio.
The Substance of described decorating base paper mainly concentrates on 60-85g/m
2.
The performance parameter of decorating base paper of the present invention adopts instrument and condition shown in People's Republic of China (PRC) light industry standard GB/T24989-2010 to perform test.
The present invention compared with prior art, has following beneficial effect:
Product provided by the invention is compared with existing product, and in printing process, vertical cross directional variations is less, and clear patterns after printing, keeps the shape.After downstream client dipping, the change of paper horizontal fabric width is little, and the decorative pattern on paper well can realize coincideing with the decorative pattern on steel plate when overlaying, and during pressing plate, decorative pattern does not depart from.Existing decorating base paper is large because of lateral expansion, occurs off-set phenomenon with decorative pattern on steel plate.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further.
Table 1 embodiment 1-4 and comparative example 1 raw material composition (%)
? |
Embodiment 1 |
Embodiment 2 |
Embodiment 3 |
Embodiment 4 |
Comparative example 1 |
Bleached cotton starch |
30 |
50 |
30 |
35 |
15 |
Bleached softwood is starched |
20 |
24 |
40 |
20 |
15 |
Bleaching broad-leaved slurry |
3 |
5.5 |
9 |
20 |
45 |
Mineral filler |
45 |
20 |
20 |
24 |
23 |
Wet strength agent |
2 |
0.5 |
1 |
1 |
2 |
Embodiment 1
(1) bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry to be added respectively in the pulper that 35 DEG C of pulping water are housed fully size degradation by mass percent in table 1, beating degree is controlled to respectively to pump into after 23,23,26 ° of SR, mass concentrations reach 4% after mill for subsequent use in stock tank; The mass concentration of bleached cotton starch used, bleached softwood slurry and bleaching broad-leaved slurry is all 90%;
(2) mineral filler titanium dioxide, kaolin and talcum powder being diluted to mass concentration is 65%, carries adding again fill out in pond with high speed agitator after stirring;
(3) stock tank slurries after mill are pumped into add fill out pond, regulate and add the pH value to 7 filling out slurries in pond, after stirring, add the wet strength agent that concentration is 12.5% again;
(4) then above-mentioned modulated slurry is diluted again, screen out foreign material after interweave through uniform and dehydration, drying, press polish, coil paper, cut, pack and get final product again.
Interweave and adopt multi cylinder line mesh production technology, be equipped with humidifier and soft press-polishing machine in process of production.Wherein main control parameters: one, starch network speed than 1:1, fiber aspect to arrangement evenly, is mutually wound around, decreases the cross-direction shrinkage in body paper dry run; Two, the stoving process of multi-cylinder, guarantees slow drying, reduces the shrinkage factor in body paper dry run; High temperature cylinder temperature control 120-150 degree, the moisture after oven dry is≤2%; Three, after humidifier effect, body paper moisture reaches 6%.
Decorating base paper is quantitatively 80g/m after testing
2, ash content is 40%, and wet strength is 7N, and dry strength is 35N, and water imbibition is 25mm/10min, and air permeability is 25s/100ml, horizontal hygroexpansivity 1.44%, seepage velocity 4s, the decorating base paper of moisture 6%.
Embodiment 2
(1) bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry to be added respectively in the pulper that 38 DEG C of pulping water are housed fully size degradation by mass percent in table 1, beating degree is controlled to respectively to pump into after 20,23,26 ° of SR, mass concentrations reach 4% after mill for subsequent use in stock tank; The mass concentration of bleached cotton starch used, bleached softwood slurry and bleaching broad-leaved slurry is all 90%;
(2) mineral filler titanium dioxide being diluted to mass concentration is 70%, carries adding again fill out in pond with high speed agitator after stirring;
(3) stock tank slurries after mill are pumped into add fill out pond, regulate and add the pH value to 6.8 filling out slurries in pond, after stirring, add the wet strength agent that concentration is 12.5% again;
(4) then above-mentioned modulated slurry is diluted again, screen out foreign material after interweave through uniform and dehydration, drying, press polish, coil paper, cut, pack and get final product again.
Interweave and adopt multi cylinder line mesh production technology, be equipped with humidifier and soft press-polishing machine in process of production.Wherein main control parameters: one, starch network speed than 1:1, fiber aspect to arrangement evenly, is mutually wound around, decreases the cross-direction shrinkage in body paper dry run; Two, the stoving process of multi-cylinder, guarantees slow drying, reduces the shrinkage factor in body paper dry run; High temperature cylinder temperature control 120-150 degree, the moisture after oven dry is≤2%; Three, after humidifier effect, body paper moisture reaches 7%.
Decorating base paper is quantitatively 80g/m after testing
2, ash content is 20%, and wet strength is 6N, and dry strength is 34N, and water imbibition is 28mm/10min, and air permeability is 27s/100ml, horizontal hygroexpansivity 1.48%, seepage velocity 4s, the decorating base paper of moisture 7%.
Embodiment 3
(1) bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry to be added respectively in the pulper that 38 DEG C of pulping water are housed fully size degradation by mass percent in table 1, beating degree is controlled to respectively to pump into after 22,21,25 ° of SR, mass concentrations reach 3.5% after mill for subsequent use in stock tank; The mass concentration of bleached cotton starch used, bleached softwood slurry and bleaching broad-leaved slurry is all 90%;
(2) mineral filler titanium dioxide and bentonite being diluted to mass concentration is 70%, carries adding again fill out in pond with high speed agitator after stirring;
(3) stock tank slurries after mill are pumped into add fill out pond, regulate and add the pH value to 6.5 filling out slurries in pond, after stirring, add the wet strength agent that concentration is 12.5% again;
(4) then above-mentioned modulated slurry is diluted again, screen out foreign material after interweave through uniform and dehydration, drying, press polish, coil paper, cut, pack and get final product again.
Interweave and adopt multi cylinder line mesh production technology, be equipped with humidifier and soft press-polishing machine in process of production.Wherein main control parameters: one, starch network speed than 1:1, fiber aspect to arrangement evenly, is mutually wound around, decreases the cross-direction shrinkage in body paper dry run; Two, the stoving process of multi-cylinder, guarantees slow drying, reduces the shrinkage factor in body paper dry run; High temperature cylinder temperature control 120-150 degree, the moisture after oven dry is≤2%; Three, after humidifier effect, body paper moisture reaches 5%.
Decorating base paper is quantitatively 85g/m after testing
2, ash content is 20%, and wet strength is 7.2N, and dry strength is 30N, and water imbibition is 26mm/10min, and air permeability is 27s/100ml, horizontal hygroexpansivity 1.52%, seepage velocity 4s, the decorating base paper of moisture 5%.
Embodiment 4
(1) bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry to be added respectively in the pulper that 45 DEG C of pulping water are housed fully size degradation by mass percent in table 1, beating degree is controlled to respectively to pump into after 24,24,28 ° of SR, mass concentrations reach 4.5% after mill for subsequent use in stock tank; The mass concentration of bleached cotton starch used, bleached softwood slurry and bleaching broad-leaved slurry is all 90%, and bleached softwood slurry used is bleached sulphate softwood pulp, and bleaching broad-leaved slurry is bleached sulphate yearning between lovers wood pulp;
(2) mineral filler titanium dioxide and diatomite being diluted to mass concentration is 72%, carries adding again fill out in pond with high speed agitator after stirring;
(3) stock tank slurries after mill are pumped into add fill out pond, regulate and add the pH value to 7.2 filling out slurries in pond, after stirring, add the wet strength agent that concentration is 12.5% again;
(4) then above-mentioned modulated slurry is diluted again, screen out foreign material after interweave through uniform and dehydration, drying, press polish, coil paper, cut, pack and get final product again.
Interweave and adopt multi cylinder line mesh production technology, be equipped with humidifier and soft press-polishing machine in process of production.Wherein main control parameters: one, starch network speed than 1:1, fiber aspect to arrangement evenly, is mutually wound around, decreases the cross-direction shrinkage in body paper dry run; Two, the stoving process of multi-cylinder, guarantees slow drying, reduces the shrinkage factor in body paper dry run; High temperature cylinder temperature control 120-150 degree, the moisture after oven dry is≤2%; Three, after humidifier effect, body paper moisture reaches 5%
Decorating base paper is quantitatively 85g/m after testing
2, ash content is 23%, and wet strength is 6.8N, and dry strength is 30N, and water imbibition is 26mm/10min, and air permeability is 27s/100ml, horizontal hygroexpansivity 1.6%, seepage velocity 4s, the decorating base paper of moisture 5%.
Comparative example 1
(1) bleached cotton starch, bleached softwood slurry and bleaching broad-leaved slurry to be added respectively in the pulper that 36 DEG C of pulping water are housed fully size degradation by mass percent in table 1, beating degree is controlled to respectively to pump into after 25,27,23 ° of SR, mass concentrations reach 4% after mill for subsequent use in stock tank; The mass concentration of bleached cotton starch used, bleached softwood slurry and bleaching broad-leaved slurry is all 90%;
(2) mineral filler titanium dioxide and kaolin being diluted to mass concentration is 70%, carries adding again fill out in pond with high speed agitator after stirring;
(3) stock tank slurries after mill are pumped into add fill out pond, regulate and add the pH value to 7 filling out slurries in pond, after stirring, add the wet strength agent that concentration is 12.5% again;
(4) then above-mentioned modulated slurry is diluted again, screen out foreign material after interweave through uniform and dehydration, drying, press polish, coil paper, cut, pack and get final product again.
Interweave and adopt multi cylinder line mesh production technology, be equipped with humidifier and soft press-polishing machine in process of production.Wherein main control parameters: one, starch network speed than 1:1.05, fiber aspect to arrangement evenly, is mutually wound around, decreases the cross-direction shrinkage in body paper dry run; Two, the stoving process of multi-cylinder, guarantees slow drying, reduces the shrinkage factor in body paper dry run; High temperature cylinder temperature control 120-150 degree, the moisture after oven dry is 4%; Three, after humidifier effect, body paper moisture reaches 7%.
Decorating base paper is quantitatively 85g/m after testing
2, ash content is 22%, and wet strength is 7.8N, and dry strength is 37N, and water imbibition is 29mm/10min, and air permeability is 27s/100ml, horizontal hygroexpansivity 1.72%, seepage velocity 5s, the decorating base paper of moisture 7%.
Can be reached a conclusion by embodiment 1-4 and comparative example 1: in embodiment 1-4, cotton pulp, needle slurry, broad-leaved slurry ratio are in scope, and horizontal hygroexpansivity≤1.6%, meets the requirement of micro stretching shrinkage.And broad-leaved slurry ratio is too high in comparative example 1, beating degree parameter also has larger fluctuation, and testing result proves that horizontal hygroexpansivity is bigger than normal, undesirable.General inventive embodiment, having of controlling to play a major role in paper expansion and contraction: the kind selection, proportioning, making beating parameter, machine direction arrangement, drying parameter, physical index control range etc. of pulpboard.
The above is only preferred embodiment of the present invention, and be not restriction the present invention being made to other form, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the Equivalent embodiments of equivalent variations.But everyly do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the remodeling done above embodiment according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.